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    Rasi WPT Xi Che Iit Key 01-1-1-24

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    Deena chemist
    The document discusses various concepts related to organic chemistry including: 1) The stability of carbanions decreases with increasing inductive (+I) effect in the order (CH3)3C- > (CH3)2CH- > CH3CH2- > C6H5CH2- due to resonance effects. 2) The order of stability for free radicals is tertiary > secondary > primary due to hyperconjugation and resonance effects. 3) The order of stability for carbanions is 1° > 2° > 3° due to inductive effects.

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    Rasi WPT Xi Che Iit Key 01-1-1-24

    Uploaded by

    Deena chemist
    12 views2 pages
    The document discusses various concepts related to organic chemistry including: 1) The stability of carbanions decreases with increasing inductive (+I) effect in the order (CH3)3C- > (CH3)2CH- > CH3CH2- > C6H5CH2- due to resonance effects. 2) The order of stability for free radicals is tertiary > secondary > primary due to hyperconjugation and resonance effects. 3) The order of stability for carbanions is 1° > 2° > 3° due to inductive effects.

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    RASI WPT XI CHE IIT KEY 01-1-1-24

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    The document discusses various concepts related to organic chemistry including: 1) The stability of carbanions decreases with increasing inductive (+I) effect in the order (CH3)3C- > (CH3)2CH- > CH3CH2- > C6H5CH2- due to resonance effects. 2) The order of stability for free radicals is tertiary > secondary > primary due to hyperconjugation and resonance effects. 3) The order of stability for carbanions is 1° > 2° > 3° due to inductive effects.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    12 views2 pages

    Rasi WPT Xi Che Iit Key 01-1-1-24

    Uploaded by

    Deena chemist
    The document discusses various concepts related to organic chemistry including: 1) The stability of carbanions decreases with increasing inductive (+I) effect in the order (CH3)3C- > (CH3)2CH- > CH3CH2- > C6H5CH2- due to resonance effects. 2) The order of stability for free radicals is tertiary > secondary > primary due to hyperconjugation and resonance effects. 3) The order of stability for carbanions is 1° > 2° > 3° due to inductive effects.

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    of 2

    PINNAACLE CLASSES

    26.(b): Stability of carbanions decreases with increase in +I effect. +I effect is maximum in


    ( CH 3 ) 3 C− , followed by ( CH 3 ) 2 CH − and CH 3 CH −2 . in C 6 H 5 CH −2 , resonance effect increases the
    stability Hence, the order of stability is
    (iv) > (iii) > (ii) > (i).

    27.(d): It is stabilized both by +I effect and hyper – conjugation.

    28.(a): Due to displacement of σ - electrons towards more electronegative atom the bond
    becomes polar. The polar bond induces polarity to the adjacent bonds.

    29.(a): On the basis of hyperconjugation, the order of stability of free radicals is as follows t > s
    > p. Benzyl free radicals are stabilized by resonance and hence are more stable than alkyl
    free radicals. More the number of phenyl groups attachend to the carbon atom, more is the
    stability of free radical.

    30.(d): Free radical is formed as a result of hemolytic fission hence it has an unpaired electron.

    o o o
    31.(c): Order of stability of carbanions is1 >2 >3

    32.(d): −NO 2 shows maximum electron withdrawing or


    – I effect.

    +
    +
    33.(c): ( CH 3 ) 3 C is more stable than CH 3 C HCH 3 Rst all are primary carbocations hence less
    stable.

    34.(c): The electronegative atom in the carbon chain produces – I effect.

    35.(d): The strength of the acid increases with the inductive effect of the electronegative group
    attached to it (-I effect). The strength of the acid decreases with the presence of electron
    releasing group.

    36.(a):

    Thus, the stability of carbocations decreases in the order: II > I > III.

    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371
    PINNAACLE CLASSES

    37.(a): As Cl is most electronegative element among Cl, Mg, Br and C thus, it has grater – I
    effect and the asterisk marked carbon in CH 3 −CH 2−Cl is expected to have greater positive
    charge.

    HBr → H + + Br−
    38.(a): Step – I : ( Electrophile )

    39.(c):

    o
    Thus, 2 Carbocation is formed.

    40.(c) As per the definition.

    41.(b)
    42.(b) Order of +I = (CH3)3 C – > (CH3)2 CH – > CH3 CH2 – > – CH3.

    43.(c)
    44.(d) –NO2 > – CN > –Cl > – NH2.

    45.(b)

    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371

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