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    Acid Based Organic

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    Acid Based Organic

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    shashwat
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    Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best notes for jee Best n

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    ACID-BASED-ORGANIC

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    Acid Based Organic

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    shashwat
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    of 5

    CHEMISTRY DPP # 2

    Chapter : Heterolysis, Carbocation, Carbanion


    Direction 1 to 5 Short Answer Type
    Q1. What is Heterolysis of covalent bonds.

    Q2. Gives favourable conditions for Heterolysis.

    Q3. What is hybridization, Geometry and electronic nature of carbocation.

    Q4. Give factors which affecting stability of carbocation.

    Q5. How EN affects stability of anion.

    Direction 6 to 10 True / False


    Q6. Polar solvent is favourable medium for Heterolysis. (T/F)

    Q7. Carbanion have pyramidal geometry like Ammonia. (T/F)

    Q8. Hyperconjugation increase stability of Carbanion. (T/F)

    Q9. Cyclopentadienyl anion is Aromatic in nature. (T/F)

    Q10. Carbocation is paramagnetic and nucleophile. (T/F)

    Direction 11 to 20 Objective Type



    Q11. The number of electrons present in the valence shell of carbon of CH3CH2 ion bearing +ve
    charge :

    (A) 8

    (B) 7

    (C) 6

    (D) 4

    Q12. Heterolytic fission of carbon-chlorine bond produces -

    (A) two free radicals

    (B) two carbonium ions

    (C) two carbonions

    1
    Chemistry DPP #2

    (D) one cation and one anion

    Q13. In CH3CH2OH, the bond that undergoes heterolytic cleavage most readily is -

    (A) C—C

    (B) C—O

    (C) C—H

    (D) O—H

    Q14. The hybridisation of saturated carbanion is -

    (A) sp3

    (B) sp2

    (C) sp

    (D) dsp3

    Q15. Carbanion of CH3 CH2 has geometry -

    (A) Planar

    (B) Pyramidal

    (C) Square bipyramidal

    (D) Linear

    Q16. Which of the following reaction intermediates is not electrophilic in character -

    (A) Carbocation (B) Carbanion

    (C) Free radicals (D) Carbenes

    (A) Only b

    (B) a and c

    (C) a, c and d

    (D) a, b, c and d

    Q17. Which of the following is most stable -



    (A) CH3

    (B) CH3–CH2

    (C) CH3–CH –CH3

    (D) CH2=CH–CH2

    2
    Chemistry DPP #2

    Q18. Least stable Carbanion is -


    (A) HC≡C

    (B)
    (C) CH2=CH
    (D) CH3–CH2

    Q19. Which of the following statement is correct about arrow headed 'C' of
    (A) Negative charge is delocalised due to sp2 hybridisation
    (B) sp2 hybridised but negative charge charge is localised.
    (C) sp3 hybridised and negative charge charge is not delocalised.
    (D) sp3 hybridised and negative charge charge is delocalized

    Q20. Which is most stable carbanion -

    (A)

    CH2

    (B)

    (C)

    (D) CH2=CH–CH –CH=CH2

    3
    Chemistry DPP #2

    Answer Key & Solutions


    Short Answer Type Questions
    1.

    Sol. Unequal distribution of shared electron while bond breaking is known as hetrolysis.

    A- B ⎯⎯
    → A  B

    2.

    Sol. (i) low temperature

    (ii) Polar solvent

    (iii) Difference in electro negativity

    3.

    +
    C
    Sol. , sp2 hybridization. Planner geometry and carbocation is electrophile.

    4.

    Sol. (i) +M effect

    (ii) +I effect

    (iii) +H effect

    (iv) Low electro negativity

    5.

    Sol. Stability of carbocation  EN

    True / False

    6. T
    7. T
    8. F
    9. T
    10. F

    4
    Chemistry DPP #2

    Single Option Correct Questions


    11.

    Sol. (C) carbocation has 6 electron in valence shell.

    12.

    Sol. → CH 3 + Cl
    CH3Cl ⎯⎯

    cation anion

    13.

    Sol. O-H bond readily undergoes heterolytic fission due to more difference in electro negativity.

    14.

    -
    C
    Sol. 3 + 1 l.p. = sp3 (hybridization)
    15.

    Sol. Carbanion has sp3 hybridization which has pyramidal shape.

    16.

    Sol. Carbocation, free radical and carbene are electron deficient which are electrophilic in nature.

    17.

    Sol. CH2=CH–CH2 is most stable due to resonance.
    18.
    Sol. CH3–CH2 is least stable due to low electro negativity.
    19.
    Sol. Negative charge is localized and hybridization of carbon is sp 2.

    20.

    Sol. is most stable carbanion due to arematicity.

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