Biosperse 250 Pail 25L Us
Biosperse 250 Pail 25L Us
Biosperse 250 Pail 25L Us
SECTION 1. IDENTIFICATION
Product identifier
Trade name : Biosperse™ 250
MICROBIOCIDE
™ Trademark, Solenis or its subsidiaries or affiliates,
registered in various countries
[email protected]
Solenis LLC
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Skin corrosion : Category 1B
Hazard statements : H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
Precautionary statements :
Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
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Other hazards
None known.
Components
Chemical name CAS-No. Classification Concentration (%)
5-CHLORO-2-METHYL-4- 26172-55-4 Acute Tox. 3; H301 >= 1 - < 1.5
ISOTHIAZOLIN-3-ONE Acute Tox. 3; H331
Acute Tox. 3; H311
Skin Corr. 1B; H314
Eye Dam. 1; H318
Skin Sens. 1; H317
In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Most important symptoms : Signs and symptoms of exposure to this material through
and effects, both acute and breathing, swallowing, and/or passage of the material through
delayed the skin may include:
stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
May cause an allergic skin reaction.
Causes serious eye damage.
Causes severe burns.
Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
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Water spray
Foam
Carbon dioxide (CO2)
Dry chemical
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Methods and materials for : Keep in suitable, closed containers for disposal.
containment and cleaning up
Do not smoke.
Container hazardous when empty.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Eye protection : Wear chemical splash goggles and face shield when there is
potential for exposure of the eyes or face to liquid, vapor or
mist.
Maintain eye wash station in immediate work area.
Skin and body protection : Wear resistant gloves (consult your safety equipment
supplier).
Wear as appropriate:
Impervious clothing
Chemical resistant apron
Safety shoes
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
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Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
Ensure that eyewash stations and safety showers are close
to the workstation location.
When using do not smoke.
pH : 2-5
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Solubility(ies)
Water solubility : completely soluble
Viscosity
Viscosity, dynamic : ca. 8 mPa.s (70 °F / 21 °C)
Acute toxicity
Not classified based on available information.
Components:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Acute oral toxicity : Assessment: The component/mixture is classified as acute
oral toxicity, category 3.
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Acute oral toxicity : LD50 (Rat, female): 183 mg/kg
Method: OECD Test Guideline 401
GLP: yes
Skin corrosion/irritation
Causes severe burns.
Product:
Remarks : May cause skin irritation in susceptible persons.
Causes severe skin burns and eye damage.
Components:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Result : Corrosive after 3 minutes to 1 hour of exposure
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Species : Rabbit
Method : OECD Test Guideline 404
Result : Corrosive after 3 minutes to 1 hour of exposure
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Components:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
Not classified based on available information.
Product:
Remarks : May cause allergic skin reaction.
Components:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Result : May cause sensitisation by skin contact.
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
NTP No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
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Components:
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Exposure routes : Inhalation
Target Organs : Respiratory Tract
Assessment : May cause respiratory irritation.
Product:
Remarks : No data available
Ecotoxicity
Product:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 6.16 mg/l
Exposure time: 96 h
Test Type: static test
Toxicity to daphnia and other : LC 50 (Water flea (Ceriodaphnia dubia)): 17.7 mg/l
aquatic invertebrates Exposure time: 7 d
Test Type: static test
Ecotoxicology Assessment
Acute aquatic toxicity : Acute aquatic toxicity Category 2; Toxic to aquatic life.
Chronic aquatic toxicity : Chronic aquatic toxicity Category 2; Toxic to aquatic life with
long lasting effects.
Components:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.19 mg/l
Exposure time: 96 h
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Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.16 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.172 mg/l
aquatic invertebrates End point: Reproduction Test
(Chronic toxicity) Exposure time: 21 d
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 4.77 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 0.93 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.04 mg/l
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity)
Product:
Biodegradability : Test Type: Zahn-Wellens Test
Biodegradation: < 70 %
Exposure time: 28 d
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Components:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Biodegradability : Result: Inherently biodegradable.
Method: OECD Test Guideline 301B
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Biodegradability : Result: Inherently biodegradable.
Method: OECD Test Guideline 301B
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological : An environmental hazard cannot be excluded in the event of
information unprofessional handling or disposal.
Toxic to aquatic life with long lasting effects.
Components:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
Additional ecological : No data available
information
Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
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International Regulations
IATA-DGR
UN number : UN 3265
Proper shipping name : Corrosive liquid, acidic, organic, n.o.s. (5-CHLORO-2-
METHYL-4-ISOTHIAZOLIN-3-ONE)
Class : 8
Packing group : II
Marine pollutant : yes
IMDG-Code
UN number : UN 3265
Proper shipping name : Corrosive liquid, acidic, organic, n.o.s. (5-CHLORO-2-
METHYL-4-ISOTHIAZOLIN-3-ONE)
Class : 8
Packing group : II
EmS Code : F-A, S-B
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
49 CFR
UN number : UN 3265
Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (5-
CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE)
Class : 8
Packing group : II
ERG Code : 153
Marine pollutant : no
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TSCA list
No substances are subject to a Significant New Use Rule.
Biocides
EPA Reg. # 74655-20
This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ
from the classification criteria and hazard information required for safety data sheets, and for
workplace labels of non-pesticide chemicals. Following is the hazard information as required on
the pesticide label:
Danger, Corrosive., Causes irreversible eye damage and skin burns., May cause allergic skin
reaction., Harmful if inhaled., Harmful if swallowed or absorbed through the skin., Do not get in
eyes, on skin or on clothing.
Further information
Revision Date : 08/22/2022
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS -
Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
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Concentration associated with x% growth rate response; ERG - Emergency Response Guide;
GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise
Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals;
OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS
- Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-
Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization
Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text. This SDS has been prepared by
the Solenis Environmental Health and Safety Department.
US / EN
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