Dop (KLJ)
Dop (KLJ)
Dop (KLJ)
KLJ GROUP
SDS: DS/FG/K-07 ISSUE DATE :- 01/01/2002
REVISION DATE:- 09/06/2016
KANATOL 800 REVISION NO. :- 07
GHS HCS-2012 §1910.1200
Read the entire SDS for a complete hazard assessment.
1.2 Recommended use: Plasticizer in PVC resins, replacement for PCB in dielectric fluids, solvent, inert
ingredient in pesticides.
1.3 Restricted Use: Commercial use only.
In the US: For a transport accident or leak, fire or major spill, call CHEMTREC, (800) 424-9300.
International: CHEMTREC assistance, call 1-703-527-3887 (collect calls accepted).
Symbol:
Signal word: Danger
Hazard Statement: H360-Suspected of damaging fertility or the unborn child
H351 - Suspected of causing cancer
H373 - May cause damage to organs through prolonged or repeated
exposure testes, liver
H413- Toxic to aquatic life with long lasting effects
Precautionary Statements
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Wear
protective gloves/protective clothing/eye protection/face protection. Wash face, hands
and any exposed skin thoroughly after handling.
Do not breathe dust/fume/gas/mist/vapors/spray.
Avoid release to the environment.
Response:
If exposed or concerned: Get medical advice/attention.
If in eyes: Immediately flush eyes thoroughly with water for several minutes. Remove contact lenses
after one to two minutes and continue flushing for several more minutes. If redness, itching or burning
sensation develops, seek medical attention.
If on skin: Wash with plenty of soap and water. If irritation or rash occurs: Get medical advice/attention.
If inhaled: Remove victim to fresh air. If a cough or other respiratory symptoms develop, consult medical
personnel.
If swallowed: DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person.
Gently wipe or rinse the inside of the mouth with water. Sips of water can be given. If symptoms persist,
contact a poison control center, emergency room, or physician for treatment information.
Storage:
Store in accordance with local, regional, national, and international regulations. Store locked up.
Disposal:
Dispose of contents/container in accordance with local, regional, national, and international regulations.
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous
area.
4.1 Inhalation:
Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and continue to
monitor. Consult medical attention.
Wash skin with plenty of soap and water. If symptoms persist, seek medical attention. Wash contaminated clothing
before use.
Immediately flush eyes thoroughly with water for several minutes. Remove contact lenses after one to two minutes
and continue flushing for several more minutes. If redness, itching or burning sensation develops, seek medical
attention.
4.4 Ingestion:
DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person. Gently wipe or rinse the
inside of the mouth with water. Sips of water can be given. If symptoms persist, contact a poison control center,
emergency room, or physician for treatment information.
Persons with pre-existing skin, eye, or respiratory conditions may be at an increased risk from the irritant properties of
this material. Attending physician should treat exposed patients symptomatically.
Use personal protective equipment. Remove all sources of ignition. Avoid breathing vapors, mist, or gas. Avoid
skin and eye contact. Evacuate personnel to safe areas. Spilled material may cause a slipping hazard. Use
appropriate safety equipment. See Section 8 for information on personal protective equipment.
Prevent further leakage or spillage if safe to do so. Do not let product enter drains, sewers, waterways, and/or
groundwater.
6.3 Methods and material for containment and cleaning up:
Contain spilled material if possible. Sweep up using non-sparking tools. Collect in suitable and properly labeled
containers. See Section 13, Disposal Considerations, for additional information.
6.4. Reference to Other Sections See Section 8, Exposure Controls and Personal Protection.
Combustible liquid. Avoid contact with high temperature objects, spark, and strong oxidizing agents. Use with local
exhaust ventilation. Do not eat, drink, and/or smoke in work areas. Wash hands after use. Remove contaminated
clothing and protective equipment before entering eating areas.
Store in cool place. Avoid heat and ignition sources. Keep container tightly closed in a dry and well-ventilated place.
Do not store together with oxidizing agents or alkalis. Protect against UV-solarization/sunlight. Store in accordance
with good manufacturing practices.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure
limits.
Eye protection:
Use safety glasses. If there is a potential for exposure to mists which could cause eye discomfort, wear chemical
goggles, or use a full-face respirator.
Hand protection:
Contact should be minimized. Protective gloves are recommended when skin contact cannot be avoided. Use
insulated gloves when handling molten materials. The glove(s) listed may provide protection against permeation
(gloves of other chemically resistant materials may not provide adequate protection): Polyvinyl chloride (PVC), NBR
(Nitrile). Selection of gloves will depend on the task.
Respiratory protection:
Concentration in air determines the level of respiratory protection needed. Use only NIOSH certified respiratory
equipment. Respiratory protection is not usually needed unless product is heated or misted. Half-mask air purifying
respirator with dust mist filters or HEPA filter cartridges is acceptable for exposures to ten (10) times the exposure
limit. Full-face air purifying respirator with dust mist filters or HEPA filter cartridges is acceptable for exposures to
fifty (50) times the exposure limit. Protection by air purifying respirators is limited. Use a positive pressure-demand
full-face supplied air respirator or SCBA for exposures greater than fifty (50) times the exposure limit. If exposure is
above the IDLH (Immediately Dangerous to Life and Health), or there is the possibility of an uncontrolled release, or
exposure levels are unknown, then use a positive pressure-demand full-face supplied air respirator with escape bottle
or SCBA. Wear a NIOSH-approved (or equivalent) full-face piece airline respirator in the positive pressure mode
with emergency escape provisions.
Other:
Remove contaminated clothing and wash before reuse. For non fire emergencies, respiratory protection may be
necessary and wear appropriate protective clothing to avoid contact with material. Have eyewash station and safety
shower in work area. Do not consume or store food in the work area. Wash hands before smoking or eating.
Remarks: The above information is not intended for use in preparing product specifications, Contact supplier before
writing specifications.
10.1 Chemical stability: Stable under normal temperature conditions and recommended use. Decompose at >
3930C
10.2 Possibility of hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated.
10.3 Conditions to avoid: Avoid high temperatures. Exposure to elevated temperatures can cause
decomposition. Avoid static discharge. Avoid moisture. Note the risk of self-ignition in contact with air if the
substance has been soaked in rags, cotton wool insulation materials or similar heat isolating materials.
10.4 Incompatible materials: Strong oxidizing agents or bases, copper alloys or reducing agents.
11.1 Information on the likely routes of exposure: Inhalation, ingestion, skin and eye contact.
According to the harmonized classification and labeling (CLP00) approved by the European Union, this substance
may damage fertility and may damage the unborn child.
11.4 Chronic Exposure: Repeated or prolonged exposure may produce mild skin irritation.
11.6 Carcinogenicity:
IARC: There is inadequate evidence in humans for the carcinogenicity of di(2-ethylhexyl) phthalate. There is
sufficient evidence in experimental animals for the carcinogenicity of di(2-ethylhexyl) phthalate. Overall evaluation:
Di(2-ethylhexyl) phthalate is not classifiable as to its carcinogenicity to humans (Group 3).
NTP: bis(2-Ethylhexyl) Phthalate: reasonably anticipated to be a human carcinogen.
EPA: CLASSIFICATION: B2; probable human carcinogen. BASIS FOR CLASSIFICATION: Orally administered
DEHP produced significant dose-related increases in liver tumor responses in rats and mice of both sexes. HUMAN
CARCINOGENICITY DATA: Inadequate. ANIMAL CARCINOGENICITY DATA: Sufficient.
ACGIH: A3; Confirmed animal carcinogen with unknown relevance to humans.
LC-50 (Water Flea, 96 h): > 0.16 mg/l (limit of solubility in fresh water)
NOEC: (Water Flea, 96 h): > 0.16 mg/l (limit n fresh water)
Empty container retains product residue. Observe all hazard precautions. Do not distribute, make available, furnish
or reuse empty container except for storage and shipment of original product. Remove all product residue.
14.2 UN proper shipping name: Environmentally hazardous substances, liquid, n.o.s. (bis(2-ethylhexyl)
phthalate)
14.3 Transport hazard class: Class 9, Packing Group III when material is shipped in quantities in one
package at or above the Reportable Quantity and when no other hazard class applies; otherwise, not
regulated . Reportable Quantity: 45.4 kg (bis(2-ethylhexyl) phthalate).
14.4
14.5 Packing group (if applicable): III
U.S. Regulations
15.1 US TSCA inventory:
All chemical substances in this product comply with all rules or orders under TSCA. All intentionally added
ingredients either are listed on the TSCA Inventory list or exempt from listing.
15.6 California Proposition 65: Warning! This product is known to contain chemical(s) known to the State of
California to cause cancer and/or reproductive harm.
Canadian Regulations:
WHMIS Statement: This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the SDS contains all the information required by the Controlled Products Regulations.
This product is classified as controlled in accordance with the Canadian Controlled Products Regulations.
OTHER
DOP (DEHP ) should not be used in toys and infant intended to be placed in the mouth by children under 3 years of
age ( Commission Decision ; 1999:815 CE )
DOP (DEHP ) not be used as a substance or constituent of preparations in concentrations higher than 0,1% by
mass of the plasticized material, in toys and infant which can be placed in the mouth by children.
DOP (DEHP ) is prohibited for use in cosmetic products ( Commission Directive 2004/93/EC ) .
We assigned NFPA and HMIS ratings to this product based on the hazards of its ingredient(s). Because the customer
is most aware of the application of the product, the customer must ensure that the proper personal protective
equipment (PPE) is provided consistent with information contained in the product SDS. This information is intended
solely for the use of individuals trained in the particular hazard rating system.
Key: 0 = least, 1 = slight, 2 = moderate, 3 = high, 4 = extreme
NFPA (National Fire Protection Association) - Classification
Health 1slight
Flammability 1 slight
Instability or Reactivity 0 least
Special Hazards none
NFPA, HMIS® rating involves data interpretations that may vary from company to company. They are intended only
for rapid, general identification of the magnitude of the specific hazard. To deal adequately with the safe handling of
this material, all the information contained in this SDS must be considered. This information is supplied solely for the
use of individuals trained in the particular hazard rating system.
16.3 Training advice: Provide adequate information, instruction and training for operators.
16.4 Key or legend to abbreviations and acronyms used in the safety data sheet :
END OF SDS