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inexamlike enyironment. Give yourself four marks for corresponding
Extracted from NCERT
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Alithe Best!

21 Types of Solutions 10. What will be the molarity of 30 mL of 0.5 MH,SO4

, Homogeneous MIxture of two Or more than two solution diluted to 500mL?
(a) 0.3 M (b) 0.03 M (c) 3 M (d) 0.103 M
components is called
(a) solute (b) solvent 11. How many Na ions are present in 100 mL of
(c) both (a) and (b) (d) solution. 0.25 M of NaCl solution?
(a) 0.025 x 1023 (b) 1.505 x 1022
, Which of the following is an example of
solution?
gaseous (c) 15 x 1022 (d) 2.5 x 1023
(a) Camphor in nitrogen gas 12. How many grams of NaOH are present in 250 mLof
(b) Solution of hydrogen in palladium 0.5 M NaOH solution?
ic Chloroform mixed with nitrogen gas (a) 7.32 g (b) 3.8g (c) 5 g (d) 0.5 g
(d) Both (a) and (c) 13. 250 mL of sodium carbonate solution contains
3. In amalgam of mercury with sodium, solvent is 2.65 g of Na,CO3. If 10 mL of this solution is
(a) mercury (b) sodium diluted to 500 mL, the concentration of the diluted
(c) amalgam (d) none of these. acid will be
(a) 0.01l M (b) 0.001 M
(c) 0.05 M (d) 0.002 M
22 Expressing Concentration of
Solutions 14. The density of a solution prepared by dissolving
120g of urea (mol. mass = 60 u) in 1000 g of water
4. What is the mass percentage of carbon tetrachloride is 1.15 g/mL. The molarity of this solution is
if 22 g of benzene is dissolved in 122 g of carbon (a) 1.78 M(b) 1.02 M (c) 2.05 M (d) 0.50 M
tetrachloride? 15. What will be the molality of a solution of glucose
(a) 84.72% (b) 15.28% (c) 50% (d) 44% in water which is 10% w/ W?
5. What is the mole fraction of glucose in 10% w/W (a) 0.01 m (b) 0.617 m
glucose solution? (c) 0.668 m (d) 1.623 m
(a) 0.01 (b) 0.02 (c) 0.03 (d) 0.04
16. The molality of 648 g of pure water is
6. Asolution is obtained by mixing 200 gof 30% and (a) 36 m (b) 55.5 m (c) 3.6 m (d) 5.55 m
300 g of 20% solution by weight. What is the 17. What is the mass of urea required for making
percentage of solute in the final solution?
2.5 kg of 0.25 molal aqueous solution?
(a) 50% (b) 28% (c) 64% (d) 24%
(a) 37 g (b) 25 g (c) 125 g (d) 27.5 g
When 1.04 gof BaCl, is present in 10° gof solution 18. Concentration terms like mass percentage, ppm,
the concentration of solution is mole fraction and molality do not depend on
(a) 0.104 ppm (b) 10.4 ppm
(c) 0.0104 ppm (d) 104 ppm. temperature. However, molarity is a function of
temperature because
What will be the mole fraction of ethanol in a (a) volume depends on temperature and molarity
Sample of spirit containing 85% ethanol by mass? involves volume
(a) 0.69 (b) 0.82 (c) 0.85 (d) 0.60 (b) molarity involves non-volatile solute while all
9
What is the molarity of a solution containing 10g other terms involve volatile solute
of NaOH in 500 mL of solution? (c) number of moles of solute change with change
(a) 0.25 mol L! (b) 0.75 mol L-! in temperature
(c) 0.5 mol L-! (d) 1.25 mol L-! (d) molarity is used for polar solvents only.
 34 wtG Objective NCERT
Henry's law at your
19. Express the terms 24. According to
formulae. representing the followinB the gas in vapour phase (p) is
the partial
pr eFsinugrtoeerins of
(i)
No. of moles of solute
Volume of solution in litres =(W)
No. of moles of solute
mole fraction of the gas
different gases the correct
constant is pr
(x) in the
op
statemento rtiso
on
l
aboutu a
tilo n . the
For
given Henrys
(ii) (X) (a) higher the value of
Mass of solvent in kg KH at a
higher is the solubility
of the gas
(iii)
No. of moles of component
Moles in the solution = (Y) (b) higher the value of KH at a
lower is the solubility of the given
pres ure
nature of gas pres ure.
(iv) Mass of component =(Z) (c) KH is not afunction of gas
Mass of solution (d) KH value for all gases is
W X Y pressure.
same at a
(a) Molality Molarity Mass fraction Mole fraction
(b) Molarity Molality Mass fraction Molefraction 25. The value of Henry's law
given
constant for
(C) Molarity Molality Mole fraction Mass fraction 293 Kis given below.
Arrange the some gases at
(d) Molality Molarity Mole fraction Mass fraction increasing order of their solubility. gases in the
He : 144.97 kbar, H, : 69.16 kbar.
2.3 Solubility N,:76.48 kbar, O, : 34.86 kbar
(a) He < N < H, < O; (b) O, < H, <N, u
20. Solubility of asubstance is its maximum amount that (c) H, < N2 < O, < He (d)
can be dissolved in aspecified amount of solvent. He < O2 <
It depends upon 26. H,S is a toxic gas used in qualitative N<H,
(i) nature of solute
(iii) temperature
(ii) nature of solvent If solubility of H,S in water at
what is the value of Ky?
STP is 0.195 m annalysis.
(iv) pressure
(a) Only (i), (ii) and (iii) (a) 0.0263 bar (b) 69.16 bar
(b) Only (i), (iii) and (iv) (c) 192 bar (d) 282 bar
(c) Only (i) and (iv)
(d) (i), (ii), (iii) and (iv) 27. Henry's law constant for molality of methane in
benzene at 298 K is 4.27 x 10 mm Hg. The mole
21. During dissolution when solute is added to the fraction of methane in benzene at 298 K under
solvent, some solute particles separate out from the 760 mm Hg is
solution as a result of crystallisation. At the stage
(a) 1.78 x 10-3 (b) 17.43
of equilibrium, the concentration of solute in the
solution at given temperature and pressure (c) 0.114 (d) 2.814
(a) increases (b) decreases 28. When a gas is bubbled through water at 298 K,
(c) remains constant (d) keeps changing. a very dilute solution of gas is obtained. Henry's
22. Consider the two figures given below. law constant for the gas is 100 kbar. If gas exerts
a pressure of 1 bar, the number of moles of gas
Piston dissolved in 1litre of water is
Gaseous WË< Wy < W; (a) 0.555 (b) 55.55 x 10-5
Solution
particles (c) 55.55 × 10-3 (d) 5.55 x 10
Solution
() (ii) 29. How much oxygen is dissolved in 100 mL waterandat
Which of the following statements regarding the
experiment is true? 298 Kif partial pressure of oxygen is 0.5 atm
(a) The solubility of a gas in liquid in beaker (i) Kå = 1.4 x 10- mol/L/atm?
is greater than that in beaker (ii). (a) 22.4 mg (b) 22.4 g
(b) The solubility of a gas in beaker (i) is less than (c) 2.24 g (d) 2.24 mg
that in beaker (ii). 30. At high altitudes the partial pressure of oxygen
(c) The solubility of a gas is equal in both beakers. less than that at the ground level. This leads to
the bloodand
(d) The solubility of a gas remains unaffected by (a) low concentrations of oxygen in
change in weights. tissues blood
Oxygenin the
23. The law which indicates the relationship between (b) high concentrations of
solubility of agas in liquid and pressure is and tissues formnation
(a) Raoult's law (b) Henry's law (c) release of dissolved gases and
(c) lowering of vapour pressure
(d) van't Hoff law bubbles of nitrogen in the blood
(d) thickening of blood and tissues.
Chemistry/Solutions
35

Vapour Pressure of Liquid S0. The given graph shows the vapour pressure-
Solutions temperature curves for some liquids.
Partial pressure ofa solution component is directiy
proportionalto its mole fraction. This is
(a) Henry'slaw
known as
(b) Raoult's law
VP
(c) Distribution law (d)
Ostwald's dilution law.
moles of Pand 2 moles of Qare mixed, what
32. 3will be their total vapour pressure in the solution T-

Liquids A, B, Cand D respectively are

iftheir partial vapour pressures are 80 and 60torr (a) diethyl ether, acetone, ethyl alcohol, water
respectively? (b) acetone, ethyl alcohol, diethyl ether, water
(a) 80 torr (b) 140 torr (c) 72 torr (d) 70 torr (c) water, ethyl alcohol, acetone, diethyl ether
Vapour
ressure (d) ethyl alcohol, acetone, diethyl ether, water.
33. Ptotal )

2.5 ldeal and Non-ideal Solutions

37. For an ideal solution with pA > PB which of the
following is true?
> , =(2)
(a) (xA)iquid = (XA)vapour
1. =(1) Mole fraction
(b) (xA)liquid > (xvapour
Y YandZ in the above graph are (c) (xaiguid < (X )vapour
(a) X= pi tP2 Y=1, Z = 0 (d) (x)liquid and (xA)vapour do not bear any
(b) X= P1 + P2, Y= 0, Z = 1 relationship with each other.
(c) X= Pi XP2, Y= 0, Z = 1 38. What are the conditions for an ideal solution
(d) X=p) - P2, Y=1, Z = 0 which obeys Raoult's law over the entire range of
concentration?
34. Among the following substances the lowest vapour
pressure is exerted by (a) AmixH = 0, Amix V= 0, Protal= PÅXA + PË XB
(a) water (b) alcohol (b) AmigH = +ve, Amix V= 0, Potal PÅ XA + pË XB
(c) AmixH=0, AmigV= +ve, Protal = PÅXA + PÅ xB
(c) ether (d) mercury. (d) AmiyH = 0, Amix V= 0, Protal = På XB
35. In three beakers labelled as (A), (B) and (C), 39. Intermolecular forces between n-hexane and
100 mL of water, 100 mL of 1 M solution of glucose n-heptane are nearly same as between hexane and
in water and 100 mL of 0.5 M solution of glucose heptane individually. When these two are mixed,
in water are taken respectively and kept at same which of the following is not true about the solution
formed?
temperature.
IMglucose 0.5 M glucose (a) It obeys Raoult's law, i.e.pA =XA PÅ and pB =Xp PË
Water
solution solution (b) AHmixing iS zero.
(c) AVmixing iS Zero.
(d) It forms minimum boiling azeotrope.
40. Which of the following solutions shows positive
deviation from Raoult's law?
B
Which of the following statements is correct? (a) Acetone + Aniline (b) Acetone + Ethanol
is (c) Water + Nitric acid (d) Chloroform + Benzene
a) Vapour pressure in all the three beakers
41. Which of the following solutions is an example of
same.
(b) Vapour pressure of beaker Bis highest. negative deviation from Raoult's law?
(c) Vapour pressure of beaker Cis highest. (a) Acetone + Ethanol
(b) Carbon tetrachloride + Chloroform
(a) Vapour pressure of beaker Bis lower than that
(c) Acetone + Chloroform
oC and vapour pressure of beaker C is lower (d) Water + Ethanol
than that of A.
 36
MatG Objective NCERT at your Fingertine
42. Study the figures given below and mark the correct 46. Match the column Iwith column Il and mark .
statenment. appropriate choice.
Column I
Column II
VP. P P
P (A) AHmix = 0, AVmix = 0 () Non-ideal
solution
(B) AHmiy ± 0, AVmix # 0 (ii) Positive
(1)
deviation
(i1)
(a) (i) Nitric acid + Water, (C) AHmix <0, AVmix <0 (iii) Ideal solution
(ii) Acetone + Ethyl alcohol (D) AHmix > 0, AVmix > 0 (iv) Negative
(b) (i) Water + Ethyl alcohol, deviation
(ii) Acetone + Benzene
(c) (i) Acetone + Ethyl alcohol, (a) (A) ’ (i), (B) ’ (iii), (C) ’ (ii), (D) (iv
(b) (A) ’ (iii), (B) ’ (), (C) ’ (iv), (D) ’ (i)
(ii) Acetone + Chloroform (c) (A) ’ (ii), (B) ’ (iii), (C) ’ (iv), (D) ’ ()
(d) (i) Benzene + Chloroform,
(d) (A) ’ (iii), (B) ’ (ii), (C) ’ (i), (D) ’ (iv)
(ii) Acetone + Chloroform
47. Fill in the blanks with appropriate words.
43. When acetone and chloroform are mixed together,
hydrogen bonds are formed between them. Which Azeotropic mixtures boil without change in their
of the following statements is correct about the
Azeotropic mixtures exist in solutions
solution made by mixing acetone and chloroform? showing
solutions do
Or deviations.
not form azeotropes.
(a) Mixing acetone and chloroform will form an (a) colour, positive, negative, non-ideal
ideal solution.
(b) On mixing acetone and chloroform positive (b) properties, positive, negative, ideal
deviation is shown since the vapour pressure (c) boiling point, positive, negative, non-ideal
increases. (d) composition,positive, negative, ideal
(c) On mixing acetone and chloroform negative 48. The system that formns maximum boiling azeotrope
deviation is shown since there is decrease in is
vapour pressure. (a) acetone - chloroform
(d) At a specific composition acetone and (b) ethanol - acetone
chloroform will form minimum boiling (c) n-hexane - n-heptane
azeotrope. (d) carbon disulphide - acetone.
44. Few mixtures formed by mixing two components 49. Two liquids HNO; (A) and water (B) form a
are given. Which of the following binary mixtures maximum boiling azeotrope when mixed in the
will have same composition in liquid and vapour ratio of 68% and 32% respectively. It means
phase? (a) A B interactions are stronger than A - Aand
(i) Ethanol + Chloroform B - B interactions
(ii) Nitric acid + Water (b) A - B interactions are weaker than A - A and
(ii) Benzene + Toluene B- B interactions
(iv) Ethyl chloride + Ethyl bromide (C) vapour pressure of solution is more than the
(a) (i) and (iii) (b) (i) and (ii) pure components
(c) (i), (ii) and (ii) (d) (iii) and (iv) (d) vapour pressure of solution is less since only
45. When acetone and one component vaporises.
chloroform are mixed HC 50. Which of the following azeotropes is not correctly
together, which of the
C=0 + CI-C- H
H,C matched?
following observations (4) CI (a) HNO, (68%) + H,O (32%): Maximum boiling
is correct? (B)
azeotrope, boiling point = 393.5 K
(a) A -A and B B interactions are stronger than (b) H,O (43%) + HI (57%) : Minimum boiling
A- Binteractions. azeotrope, boiling point = 290 K
(b) A-AandB - Binteractions are weaker than (c) C,H,OH (95.5%) + H,O (4.5%) : Minimum
A - B interactions.
boiling azeotrope, boiling point = 351.15 k
(c) A- A, B - B and A - B interactions are equal. (d) Chloroform (93.2%) + C,H;OH (6.8'%) :
(d) The liquids form separate layers and are Minimum boiling azeotrope, boiling poin
immiscible. = 332.3 K
 37
Chemistry Solutions
K1 Match the coBumn Iwith column II and mark the 56. A solution containing 12.5 g of non-electrolyte
appropriate choice. substance in 185 g of water shows boiling point
elevation of 0.80 K. Calculate the molar mass of
Column I Column II mol)
the substance. (K, = 0.52(b)K kg25.3 g mol-!
(A) Ethylalcohol +Water (1) p=p°x (a) 53.06 g mol-!
(B) Benzene + Toluene (c) 16.08 g mol-! (d) 43.92 g mol
(ii) Effect of pressure
dissolved
on gas solutions 57. lgof solute (molar mass = 50 g mol-') is
in 50 g of solvent and the elevation in boiling point
(C) Henry's law (iii) Ideal solution is
(D) Raoult's law is 1 K. The molal elevation constant of the solvent
(iv) Azeotropic (a) 2 (b) 3 (c) 2.5 (d) 5
mixture

(a) (A) ’ (i), (B) ’ (ii), (C) ’ (ii), (D) (iv) 58. In the given graph, pq, qr and st represent
(b) (A) (i), (B) -’ (ii),(C) ’ (i), (D) ’ (iv) S

(c) (A) - (iv), (B) ’ (ii), (C)’ (ii), (D) ’ (i)

(d) (A) (iii), (B) ’ (ii), (C) ’ (1), (D) ’ (iv)
VP.

26 Colligative Properties and

Determination of Molar Mass
(a) pq- liquid state of solution, qr’ solid state
52. The relative lowering in vapour pressure is of solution,st ’ liquid state of solvent
proportional to the ratio of number of (b) pq’ liquid state of solvent, qr ’ solid state
(a) solute molecules to solvent molecules of solvent,st ’ liquid state of solution
(b) solvent molecules to solute molecules (c) pq ’ liquid state of solvent, qr’ solid state
(c) solute molecules to the total number of of solution, st ’ liquid state of solution
molecules in solution (d) pq-’ solid state of solvent, qr - liquid state
(d) solvent molecules to the total number of of solvent, st ’ solid state of solution.
molecules in solution.
59. 2 g of sugar is added to one litre of water to give
53. Vapour pressure of a pure liquid X is 2 atm at sugar solution. What is the effect of addition of
300K. It is lowered to I atm on dissolving 1g of sugar on the boiling point and freezing point of
Y in 20 g of liquid X. If molar mass of X is 200, water?
what is the molar mass of Y? (a) Both boiling point and freezing point increase.
(a) 20 (b) 50 (c) 100 (d) 200 (b) Both boiling point and freezing point decrease.
54. An aqueous solution of 2% non-volatile solute
(c) Boiling point increases and freezing point
exerts a pressure of 1.004 bar at the normal boiling decreases.
point of the solvent. What is the molecular mass (d) Boiling point decreases and freezing point
increases.
of the solute?
(a) 23.4g mol-! (b) 41.35 g mol-! 60. Sprinkling of salt helps in clearing the snow covered
(c) 10 g mol (d) 20.8 g mol roads in hills. The phenomenon involved in the
process is
55. In the graph plotted (a) lowering in vapour pressure of snow
between vapour (b) depression in freezing point of snow
pressure (V.P.) and
(c) increase in freezing point of snow
temperature (T), (d) melting of ice due to increase in temperature
(a) PQ is the curve V.
by puting salt.
for solvent, XY
is the curve of 61. Equimolal solutions in the same solvent have
solution and ATis
T (a) same elevation in boiling point and same
molal depression depression in freezing point
(b) different elevation in boiling point and different
in freezing point depression in freezing point
(b) PQ is the curve for solution, XY is the curve
(c) same elevation in boiling point but different
for solvent and AT is elevation in boiling point
(C) PQis the curve for solvent, XY is the curve for depression in freezing point
(d) same depression in freezing point but different
solution and AT is molal elevation in boiling
point elevation in boiling point.
(d) PQ is the curve for solvent, XY is the curve for 62. A 5% solution (w/W) of cane sugar (molar mass =
solution and AT is elevation in boiling point. 342 g mol) has freezing point 271 K. What will
38 WtG Objective NCERT at Chem

your
be the freezing point of 5% glucose (molar mass = In the above paragraph p, 4, r, s and
t Fingertiçps
18 g mol)in water if freezing point of pure water
is 273.15 K?
(a) 273.07 K
(c) 273.15 K
(b) 269.07 K
(d) 260.09 K
are

(a) colligative, solution, higher

lower concentration, solution
(b) colligative, solvent, higher
rconceesnpetrcatitvioen,ly
lower concentration.
63. What weight of glycerol should be added to lower concentration, solution
600 g of water in order to lower its freezing point (c) colligative, solution,
by 10°C? (K= 1.86° C m)
(a) 496 g (b) 297 g (c) 310 g (d) 426 g
higher concentration, solvent
(d) colligative, solvent, 1lower concentration,
64. If semipermeable menmbrane is placed between the
solvent and solution as shown in the given figure then 67.
higher concentration, solution.
The osmotic pressure of asolution can be concentration,
by
(a) increasing the volume
increased
I= hpg (b) increasing the number of solute molecnles
(c) decreasing the temperature
Solvent (d) removing semipermeable membrane.
Solution 68. People taking lot of salt experience puffiness or
Semipermeable
swelling of the body due to
membrane (a) water retention in tissue cells and intercell.
spaces because of osmosis 76
(a) the solvent molecules will flow through the (b) water loss from the cells through skin
membrane fromn solution to pure solvent tissues
(b) the solvent molecules will flow continuously (c) capillary action of water through skin Dores
(d) excessive thirst and drinking more water.
till the equilibrium is attained
(c) the flow of the solvent from its side to solution 69. The preservation of meat by salting and of fruits by
side across a semipermeable membrane can be adding sugar protects them from bacterial action
stopped if some extra pressure (called osmotic because
pressure) is applied on the solution. (a) bacteria die of eating sugar or salt
(d) both (b) and (c). (b) due to osmosis bacteria lose water on salted
meat or candied fruit and die
65. Study the following figure showing osmosis and (c) due to osmosis bacteria gain water on salted
mark the correct statement.
Piston Flow indicator meat or candied fruit and die
(d) bacteria get stuck to the salt and sugar layers
and die.
70. Sea water is desalinated to get fresh water by which
Solvent of the following methods?
(a) When pressure more than osmotic pressure
Solution Semipermeable
membrane is applied pure water is squeezed out of sea
(a) The external pressure applied on the solution water by reverse osmosis.
to stop osmosis is called osmotic pressure. (b) When excess pressure is applied on sea water
(b) The external pressure applied on the solvent pure water moves in by osmosis.
to stop osImosis is called osmotic pressure. (c) Water moves out from sea water due to
osmosis.
(c) The hydrostatic pressure built up on solvent
which just stops osmosis is called osmotic (d) Salt is precipitated from sea water when kept
pressure. undisturbed for sometime.
(d) Pressure developed by solvent while solution 71. A 5% solution of cane sugar (Mol. wt. = 342) 15
flows through semipermeable membrane is isotonic with 1% solution of substance X. The
called osmotic pressure. molecular weight of X is
66. Relative lowering of vapour pressure, osmotic (a) 171.2 (b) 68.4 (c) 34.2 (d) 136.2
pressure of a solution and elevation in boiling 72. Which of the following statements is correct about
points are (p)_ properties. Osmosis is the passage diffusion and osmosis?
of (a) through a semipermeable membrane from (i) In osmosis, a semipermeable membrane 15
a solution of (r) towards a solution of (s) used while diffusion is without membrane.
Osmotic pressure is equivalent to mechanical (ii) In osmosis, movement of molecules occurs
pressure which must be applied on ( ) to prevent one direction while in diffusion, movemeut
osmosis. 0ccurs in all directions.
Chemistry| Solutions 39

(ii) In osmosis, only the solvent moves while in 81. Which of the following statements is correct?
diffusion both solute and solvent move. (a) A saturated solution will remain saturated at
(a) Only (i) and (ii) (b) Only (i) all temperatures.
(c) Only (ii) and (iii) (d) (i), (ii) and (iii) (b) Aplant cellswells when placed in hypertonic
73. 10% solution of urea is isotonic with 6% solution solution.
of a non-volatile solute X. What is the molecular (c) The depression in freezing point is directly
mass of solute X? proportional to molality of the solution.
(a) 6g mol-! (b) 60 g mol (d) Lowering in vapour pressure is a colligative
(c) 36 g mol-l (d) 32 g mol-! property.
74. Asolution containing 10.2 g glycerine per litre is 82. For carrying reverse osmosis for desalination of
/sotonic with a 2% solution of glucose. What is the water the material used for making semipermeable
molecular mass of glycerine? membrane is
(a) 91.8g (b) 1198 g (c) 83.9 g (d) 890.3 g
(a) potassium nitrate
75. What will be the osmotic pressure in pascals (b) parchment membrane
exerted by a solution prepared by dissolving (c) cellulose acetate
1.0g of polymer of molar mass 150,000 in 500 mL (d) cellmembrane.
of water at 37 °C?
(a) 30.96 (b) 34.36 (c) 68.72 (d) 48.25 83. Which of the following is not an industrial or
76. Osmotic pressure of a solution containing 2 g biological importance of osmosis?
dissolved protein per 300 cm² of solution is (a) Movement of water from soil into plant roots
20 mm of Hg at 27 °C. The molecular mass of and upper portion of plant.
protein is (b) Salting of meat to prevent bacterial action.
(a) 6239.6 g mol-l (b) 12315.5 g mol (c) Reverse osmosis for desalination of sea water.
(c) 3692.1 g mol! (d) 7368.4 g mol-l (d) Filling of ink in a fountain pen.
77. Asolution is made by dissolving 20 gof asubstance 84. Match the column I with column II and mark the
in 500 mL of water. Its osmotic pressure was found appropriate choice.
to be 600 mm of Hg at 15 °C. Find the molecular
Column I Column II
weight of the substance.
(a) 1198 (b) 500 (c) 1200 (d) 1000 K; x W, x1000
(A) K, (i)
78. Which of the following statements is not correct? AT, XW,
(a) 5% aqueous solutions of NaCl and KCI are
said to be isomolar. W, x1000
(B) M, (ii)
(b) 1Msucrose solution and 1Mglucose solution M, XW,
are isotonic.
(c) Reverse osmosis is used in desalination of sea
(C) T (iii) RT;
water. 1000× Ly
AT, K
(d) For the same solution, AT,xdRT
AT; K (D) m (iv)
1000x K,
79. Grapes placed in three beakers X, Y and Z
containing different types of solutions are shown (a) (A) (), (B) ’ (iii), (C) - (ii), (D) (iv)
in figures. (b) (A) - (iv), (B) - (i), (C) ’ (i), (D) ’ (iii)
(c) (A) (ii), (B) ’ (iv), (C) ’ (iii), (D) ’ )
(a) (A)’ (ii), (B) ’ (i), (C) ’ (iv), (D) ’ (i)
2.7 Abnormal Molar Masses
X
If beaker X contains water, Yand Z contain 85. Why is the molecular mass determined by
(a) Y- hypotonic solution, Z-hypertonic solution measuring colligative property in case of some
(b) Y- hypertonic solution, Z-hypotonic solution solutes is abnormal?
(c) Yand Z- isotonic solutions (a) Due to association or dissociation of solute
(d) Yand Z- hypotonic solutions molecules.
S0. A plant cell shrinks when it is kept in a (b) Due to insolubility of solute molecules.
(a) hypotonic solution (b) hypertonic solution (c) Due to decomposition of solute molecules.
(c) isotonic solution (d) pure water. (d) Due to large size of solute molecules.
 40 mtG Objective NCERT
your
86. Which of the following representations of i(van't
Hoff lactor) is not correct?
(a) I m NaCl solution (b) 1 m KCI
(c) I mAlCi, solution (d) I
Fisolutniogenrtigs
(a)

(b) i=
i= Observedcolligative property
Expected colligative property
Normal molecular mass
91. If o. is the degree of dissociation of
van't Hoff's factor (i) used for
molecular mass is
(a) 1 + . (b) | - .
mCocalH1c2ulNa,06asStoiO4,nlugtiothethen
(c) 1 + 20.
Observed molecular mass (d) 1 - 20.
Number of molecules actually present 92. For which off the following solutes the
(c) i
Number of molecules expected to factor is not greater than one? van't Hoff
be prescnt (a) NaNO, (b) BaC,
(c) K,[Fe(CN) 6l (d)
NH,CONH,
Total number of particles taken 93. What will be the degree of dissociation
before association/dissociation of
(d) i= Mg(NO;)2 solution if van't Hoff factor is 2.74?0.1 M
Number of particles after (a) 75% (b) 87% (c) 100% (d) 92%
association/dissociation 94. Which of the following will have the highecs
87. Which of the following relations is not correctly freezing point at one atmosphere?
matched with the formula? (a) 0.1 M NaCl solution (b) 0.1 M sugar
i-1 (c) 0.1 M BaCl, solution (d) 0.1 M FeCl, solution
solution
(a) In case of association, . =
95. A solute X when dissolved in a solvent
-1 associates
to form a pentamer. The vaBue of van't Hoff factor
(i) for the solute will be
(b) In case of dissociation, . = i-1 (a) 0.5 (b) 5
n+1
(c) 0.2 (d) 0.1
(c) Relative lowering of vapour pressure 96. What will be the freezing point of a 0.5 m KCI
solution? The molal freezing point constant of water

(d) Elevation in boiling point,

PAPA=i
PA
is 1.86 °C m
(a) 1.86°C
(c) - 3.2°C (d) 0°c
(b) - 0.372°C

W; x 1000 97. What amount of CaCi, (i = 2.47) is dissolved in

AT, = K,x 2 litres of water so that its
M¡ X WA is 0.5 atm at 27 °C?
osmotic pressure
88. Which of the following will have same value of (a) 3.42 g (b) 9.24 g (c) 2.834 g (d) 1.820 g
van't Hoff factor as that of K4 [Fe(CN)]? 98. The van't Hoff factor of 0.005 M aqueous
(a) Al,(SO)3 (b) AlCl; solution
of KCI is 1.95. The degree of ionisation of KCI is
(c) Al(NO;)3 (d) Al(OH), (a) 0.95 (b) 0.97 (c) 0.94 (d) 0.96
89. Arrange the following aqueous solutions in the
order of their increasing boiling points. 99. The elevation in boilingpoint ofa solution of 9.45
(i) 10- M NaCI of MgCl, in 1 kg of water is (Ky = 0.52 Kkg mol
(ii) 10 M Urea
(ii) 10 MMgCl, (iv) 10 M NaCI Molar mass of MgCl, = 94.3 g mol)
(a) 0.156 (b) 0.52 (c) 0.17 (d) 0.94
(a) (i) < (ii) < (iv) < (iii)
(b) (ii) < (i) = (iii) < (iv) 100.0.001 molal solution of Pt(NH;)4Cl4 in water had
(c) (ii) < (i) < (iii) < (iv) a treezing point depression of 0.0054 °C.compound
If K, tor
(d) (iv) < (iii) < (i) = (iü) water is 1.80, the correct the
formula of
is
90. Which of the following has the highest
point? freezing (a) [Pt(NH;),Cl;|cI (b) [Pt(NH;),ClË)
(c) (Pr(NH,),CI,JCI, (d) [Pt(NH}),Cl]CIs
 ANSWER KEY
MCQs Corner
I. (d) 2. (d) 3. (b) 4. (a) 5. (a) 6. (d) 7. (b) 8.
16.
(a) 9. (c) 10. (b) 11. (b) 12. (c) 13. (d) 14. (c) 15. (b)
(b) 17. (a) 18. (a) 19. (c) 20. (d) 21. (c) 22. (b) 23. (b) 24. (b) 25. (a) 26. (d) 27. (a) 28. (b) 29. (d) 30. (a)
31. (b) 32. (c) 33. (b) 34. (d) 35. (d) 36. (a) 37. (c) 38. (a) 39. (d) 40. (b) 41. (c) 42. (c) 43. (c) 44. (b) 45. (b)
46. (b) 47. (d) 48. (a) 49. (a) 50. (b) 51. (c) 52. (c) 53. (a) 54. (b) 55. (d) 56. (d) 57. (c) 58. (b) 59. (c) 60. (b)
61. (a) 62. (b) 63. (b) 64. (d) 65. (a) 66. (d) 67. (b) 68. (a) 69. (b) 70. (a) 71. (b) 72. (d) 73. (c) 74. (a) 75. (b)
76. (a) 77. (a) 78 (a) 79. (a) 80. (b) 81. (c) 82. (c) 83. (d) 84. (d) 85. (a) 86. (d) 87. (b) 88. (a) 89. (c) 90. (d)
91. (c) 92. (d) 93. (b) 94. (b) 95. (c) 96 (a) 97. (d) 98. (a) 99. (a) 100.(c)
NCERT Exemplar Problems
1. (a) 2. (d) 3. (c) 4. (b) 5. (c) 6. (b) 7. (a) 8. (b) 9. (b) 10. (a) 11. (c) 12. (d) 13. (a) 14. (b) 15. (a)
16. (a) 17. (c) 18. (d) 19. (d) 20. (c)
Exam Scorer
A &R Corner
1. (c) 2. (b) 3. (b) 4. (a) 5. (d) 6. (a) 7. (d) 8. (c) 9. (a) 10. (d) 11. (b) 12. (d) 13. (a) 14. (a)
Case Based Questions
1. (a) 2. (b) 4. (b) 5. (b) 6.
(d) 3. (c) 7. (a) 8. (c) 9. (b) 10. (a) 11. (b) 12. (b) 13. (c)
Nurnerical Value Type Questions
1. (1198) 2. (100.08) 3. (0.92) 4. (-11.625) 5. (1)
Thinking Corner
1. (a) 2. (d) 3. (a) 4. (a) 5. (c)
Exam Archive
I. (b) 2. (b) 3. (b) 4. (b) 5. (c) 6. (a) 7. (a) 8. (d) 9. (c) 10. (d) 11. (a) 12. (b) 13. (c) 14. (b) 15. ()
16. (a) 17. (d) 18. (c) 19. (b) 20. (a) 21. (d) 22. (c)