Kinetic Interpretation of Temperature

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Kinetic Theory of Gases

3. Kinetic Interpretation of Temperature


According to assumption of Kinetic theory of gases, there is only translation motion of the
molecule and there is not any potential acting between them, so
Average energy E of gases are equivalent to Average translation energy of a molecule

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E  m v2
2
1 2 1  2
Pressure at P as P  mn v 2  n m v 2   n E
3 3 2  3
2 2 N
PV  Vn E PV  N E where n  number density
3 3 V
3 RT 3 R 
E  and E   T
2 NA 2 NA 

H.N. 28 A/1, Jia Sarai, Near IIT-Delhi, Hauz Khas, New Delhi-110016
#: +91-89207-59559, 8076563184
Website: www.pravegaa.com | Email: [email protected]
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Education
CSIR NET-JRF, GATE, IIT-JAM, JEST, TIFR and GRE for Physics
H.N. 28 A/1, Jia Sarai, Near IIT-Delhi, Hauz Khas, New Delhi-110016
Contact: +91-89207-59559, 8076563184
Website: www.pravegaa.com | Email: [email protected]

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E  K BT where k B is Boltzman constant
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So average kinetic energy is given by
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E  k B T where T is absolute temperature.
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Example: It is possible to treat electromagnetic radiation in container whose wall is mirrors, as
a gas of particle (photons) with a constant speed c and whose energy is related to their
momentum p which is directed parallel to their velocity by E  pc . Show that if container is
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full of radiation the equation of state is PV  E
3
1 1 1  
Solution: Pressure P  nm v 2  n mv  v  n p  v
3 3 3
For Photon v  c and velocity is parallel to momentum, so
1 1N
P  n Pc  P pc
3 3V
1 1
PV  Npc  PV  E
3 3

H.N. 28 A/1, Jia Sarai, Near IIT-Delhi, Hauz Khas, New Delhi-110016
#: +91-89207-59559, 8076563184
Website: www.pravegaa.com | Email: [email protected]
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