2level System

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1 Two level system coupled to thermal reservoir


• two level system with ground state |ai, excited state |bi and energy differ-
ence ωba = ω.
• Thermal reservoir with temperature T

The rates are


2π ω 
Γa→b = ¯ |Cabq |2 n̄ Tq
~
2π  ω 
Γa→b = ¯ |Cbaq |2 n̄ Tq + 1

~

notation adopt the notation

Γ↑ = Γa→b
Γ↓ = Γb→a

there is only particle/energy exchagne between the system and the reservoir
mode q which has the same energy as the energy difference between the system
levels, thus for which
ωq = ω.
write
|C| = |Cabq | = |Cbaq |
furthermore use the short-hand notation
ω
n̄ = n̄ .
T
So we have

Γ↑ = ¯ |C|2 n̄
~
2π 2
Γ↓ = ¯ |C| (n̄ + 1)
~
simly. Furthermore introduce


Γ = ¯ |C|2
~
such that
Γ↓ = Γ↑ + Γ

Master equations for populations


(sec)
X
σ̇mn (t) = −ıωmn σab + Rmnop σop
op

1
Assume we are interested in timescales ∆t much larger than the evolution
timescale of the coherences |1/ωab |. Then, the populations do not douple to
any of the coherences but only to the populations themselves.

σ̇aa (t) = Raaaa σaa + Raabb σbb


σ̇bb (t) = Rbbaa σaa + Rbbbb σbb

With
Rmmnn = Γn→m (m 6= n)

σ̇aa = +Γ σbb − Γ↑ (σaa − σbb )


σ̇bb = −Γ σbb + Γ↑ (σaa − σbb ) = −σ̇aa
transformation
1
σ± = (σaa ± σbb )
2
Use σaa + σbb ≡ 1 such that σ+ ≡ 21 . So

1
σaa = σ+ + σ− = + σ−
2
1
σbb = σ+ − σ− = − σ− = 1 − σaa
2
Differential equations for σ−
 
1 1
σ̇− = (σ̇aa − σ̇bb ) = σ̇aa = Γ σbb − Γ↑ (σaa − σbb ) = Γ − σ− − Γ↑ (2σ− )
2 2
or
1
σ̇− + (Γ + 2Γ↑ )σ− = Γ
2
solution of σ−

1
σ− = c1 e−(Γ +2Γ↑ )t + c2
2
with
Γ 1 ω
c2 = = = tanh
2Γ↑ + Γ 1 + 2n̄ 2T
1
c1 = σ− (0) − c2
2
Solution of populations
1  
σaa = σaa (0)e−(Γ +2Γ↑ )t + (1 + c2 ) 1 − e−(Γ +2Γ↑ )t
2
−(Γ +2Γ↑ )t 1  
σbb = σbb (0)e + (1 − c2 ) 1 − e−(Γ +2Γ↑ )t
2

2
Equilibrium properties
 
lim σaa (t) = 1 1 Γ 1 + n̄
t→∞
(1 + c2 ) = 1+ =
2 2 Γ + 2Γ↑ ) 1 + 2n̄
 
lim σbb (t) = 1 1 Γ n̄
t→∞
(1 − c2 ) = 1− =
2 2 Γ + 2Γ↑ ) 1 + 2n̄

and
σbb (∞) Γ↑ n̄
= = = e−ωba /T
σaa (∞) Γ + Γ↑ n̄ + 1
Thus, the stationary (equilibrium) ratio of the populations is equal to the
ratio of the Boltzmann factors
σbb (∞) e−ωb /T
= −ω /T
σaa (∞) e a

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