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    Barium Chloride 5

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    rajdevsinhkapletia
    The document describes an experiment to analyze an unknown salt and identify its acid and basic radicals. Preliminary tests showed the salt was soluble, colorless, and produced a green flame with HCl, indicating the presence of barium chloride. Confirmatory tests for the chloride anion included the production of chlorine gas with sulfuric acid and a white precipitate with silver nitrate. Tests also confirmed the presence of the barium cation through the formation of yellow, white, and white precipitates with potassium chromate, ammonium sulfate, and ammonium oxalate solutions respectively. The given salt was identified as barium chloride.

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    Barium Chloride 5

    Uploaded by

    rajdevsinhkapletia
    18 views4 pages
    The document describes an experiment to analyze an unknown salt and identify its acid and basic radicals. Preliminary tests showed the salt was soluble, colorless, and produced a green flame with HCl, indicating the presence of barium chloride. Confirmatory tests for the chloride anion included the production of chlorine gas with sulfuric acid and a white precipitate with silver nitrate. Tests also confirmed the presence of the barium cation through the formation of yellow, white, and white precipitates with potassium chromate, ammonium sulfate, and ammonium oxalate solutions respectively. The given salt was identified as barium chloride.

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    The document describes an experiment to analyze an unknown salt and identify its acid and basic radicals. Preliminary tests showed the salt was soluble, colorless, and produced a green flame with HCl, indicating the presence of barium chloride. Confirmatory tests for the chloride anion included the production of chlorine gas with sulfuric acid and a white precipitate with silver nitrate. Tests also confirmed the presence of the barium cation through the formation of yellow, white, and white precipitates with potassium chromate, ammonium sulfate, and ammonium oxalate solutions respectively. The given salt was identified as barium chloride.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    18 views4 pages

    Barium Chloride 5

    Uploaded by

    rajdevsinhkapletia
    The document describes an experiment to analyze an unknown salt and identify its acid and basic radicals. Preliminary tests showed the salt was soluble, colorless, and produced a green flame with HCl, indicating the presence of barium chloride. Confirmatory tests for the chloride anion included the production of chlorine gas with sulfuric acid and a white precipitate with silver nitrate. Tests also confirmed the presence of the barium cation through the formation of yellow, white, and white precipitates with potassium chromate, ammonium sulfate, and ammonium oxalate solutions respectively. The given salt was identified as barium chloride.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 4

    lOMoARcPSD|30808435

    Barium Chloride -5

    Valuable Studies (DAV Senior Secondary Public School)

    Studocu is not sponsored or endorsed by any college or university


    Downloaded by Malharsinh Mahida ([email protected])
    lOMoARcPSD|30808435

    EXPERIMENT NO:
    DATE:
    BARIUM CHLORIDE
    AIM:
    To analyse the given salt and identify its acid and basic
    radical.

    EXPERIMENT OBSERVATION INFERENCE


    PRELIMINARY TEST:
    Note the colour of the salt. Colourless Absence of copper, nickel,
    cobalt, manganese
    Added distilled water to The salt was soluble Absence of heavy metals
    the salt taken in clean dry carbonates
    test tube.
    Added one drop of No characteristic ash is Absence of aluminium,
    dil.cobalt nitrate to the salt formed zinc, magnesium
    solution. Dipped a filter
    paper and burned it.
    Made a paste of the salt Apple green flame was Presence of barium
    with conc.HCl in a watch obtained chloride indicated
    glass. Introduced a little of
    the paste into the blue part
    of the flame.
    INDICATORY TESTS:
    Added dil.H2SO4 to the salt No characteristic Absence of carbonate,
    taken in a test tube. change sulphate, sulphide and
    nitrite
    Added conc.H2SO4 to the A colourless gas with a Presence of chloride
    salt taken in a test tube. pungent smell evolved indicated
    which formed white
    fumes with a rod dipped
    in NH4OH solution
    PREPARATION OF Na2Co3 EXTRACT:
    Take one spatula of the given salt, two spatula of Na2Co3 and 20ml of distilled
    water in a boiling test tube and boiled the contents for 10 minutes. Cooled and

    Downloaded by Malharsinh Mahida ([email protected])


    lOMoARcPSD|30808435

    filtered the solution to obtain the clear extract. Performed the confirmatory tests
    for anion.
    CONFIRMATORY TEST FOR CHLORIDE:
    Added MnO2 and A greenish yellow gas Presence of Chloride
    conc.H2SO4 to the salt and was obtained. confirmed
    heated
    Acidified the extract with A curdy white Presence of Chloride
    dil.HNO3 acid and added precipitate was formed confirmed
    AgNO3 solution which was soluble in
    NH4OH.
    CHROMYL CHLORIDE
    TEST:
    Added a pinch of K2Cr2O7 Red oily vapours evolved Presence of Chloride
    and conc. H2SO4 to the salt which gave a yellow confirmed
    and heated precipitate with lead
    acetate solution
    TEST FOR GROUP O
    CATION:
    The salt was heated with No Ammonia evolved. Absence of ammonia
    conc.NaOH solution. indicated
    Inter Group Separation: The Original salt solution (OSS) was prepared with
    water.
    To the OSS added dil.HCl No white precipitate was Absence of group I
    obtained. radicals
    To the above solution No characteristic Absence of group II
    passed H2S precipitate was radicals
    obtained.
    To the OSS added solid No characteristic Absence of group III
    NH4Cl and NH4OH precipitate was radicals
    obtained.
    To the above solution No characteristic Absence of group IV
    passed H2S precipitate was radicals
    obtained.
    To the OSS added solid A white precipitate was Presence of group V
    NH4Cl, NH4OH solution obtained radicals
    and (NH4)2CO3 solution
    CONFIRMATORY TEST FOR GROUP V - BARIUM

    Downloaded by Malharsinh Mahida ([email protected])


    lOMoARcPSD|30808435

    To OSS added potassium A yellow precipitate was Presence of barium


    chromate solution obtained confirmed
    To the OSS added A white precipitate Presence of barium
    (NH4)2SO4 solution confirmed
    To the OSS added A white precipitate was Presence of barium
    ammonium oxalate obtained. confirmed
    solution

    Chemical Equations for Ba2+:


    BaCl2 + K2CrO4 BaCrO4 + HCl
    (Yellow Precipitate)

    BaCl2 + (NH4)2SO4 BaSO4 + NH4Cl


    (White Precipitate)

    RESULT:
    Acid Radical: Chloride
    Basic radical: Barium
    The given salt is: Barium chloride

    Downloaded by Malharsinh Mahida ([email protected])

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