ALL INDIA INTERNAL TEST SERIES

PHYSICS, CHEMISTRY & MATHEMATICS

SET – A
APT - 4 000000 Ai2TS - 1
Time Allotted : 3 Hours Maximum Marks: 186
INSTRUCTIONS
• Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
• You are not allowed to leave the Examination Hall before the end of the test.

Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions

✓ Attempt ALL the questions. Answers have to be marked on the OMR sheets.
✓ This question paper contains Three Sections.
✓ Section – I is “Physics”, Section – II is “Chemistry” and Section – III is “Mathematics”.
CLASS – XI (AI2TS – 1)

✓ Each Section is further divided into two Parts: Part – A & Part – C.
✓ Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
✓ Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

PART-A (01 – 08) Contains 08 Multiple Choice Questions which have One or More Than One Correct answer. Each question carries
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened. Partial Marks: +1 For darkening a
bubble corresponding to each correct option, provided NO incorrect option is darkened. Zero Marks: 0 If none of the bubbles is
darkened.
Negative Marks: -1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result in +4 marks; darkening
only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in -2 marks, as a wrong option is also darkened.
PART-A (09 – 12) Contains 02 Paragraphs Based upon each paragraph, 02 Multiple Choice Questions have to be answered. Each
question has Only One Correct answer and carries +3 marks for the correct answer and –1 mark for a wrong answer.
PART-A (13– 14) Contain 02 List-Match Sets, each List-Match set has 02 Multiple Choice Questions. Each List-Match set has two
lists: List-I and List-II. FOUR options are given in each Multiple Choice Question based On List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question. Each question carries +3 Marks for correct combination
chosen and -1 mark for wrong options chosen.
PART-C (01 – 04) Contains 04 Numerical based questions, the answer of which maybe positive or negative numbers or decimals
(e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3 marks for correct answer. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places. There is no negative marking.

Name of Candidate :

Batch ID : Date of Examination : / / 2 0 2 3

Enrolment Number :

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Ai2TS – 1 ( X ) | SET – A | APT – 4 | Page |1

Section – I (PHYSICS)
PART – A
(One or More Than One Correct Type)

1. (
Velocity of a particle moving in a curvilinear path varies with time as V = 2ti + t 2 j m / s . Then t is in sec. )
At t = 1 sec
6
(A) acceleration of particle is 8m / s 2 (B) tangential acceleration of particle is m / s2
5
2 5 5
(C) Radial acceleration of particle is m / s2 (D) Radius of curvature to the paths is m
5 2
1. B,C,D
Sol. a = 2iˆ + 2tjˆ
at t = 1sec
a = 2iˆ + 2 j and v = 2iˆ + ˆj
at = vˆ.a
6
= m / sec 2
5
ar = a 2 − at2
36
= 8−
5
4 2
= =
5 5
5 5 5
R= =
2/ 5 2

2. A 10 kg block is placed on a horizontal surface whose coefficient of friction is 0.25. A horizontal force P = 15 N
first acts on it in the eastward direction. Later, in addition to P a second horizontal force Q = 20 N acts on it in
the northward direction : (Both east and west are in the plane of the fig and the gravity acts perpendicular to
this plane )
(A) The block will not move when only P acts, but will be about to move when both P and Q act
(B) If the block moves, the acceleration will be 0.5 m/s 2.
(C) When the block moves, its direction of motion will be tan −1 (4/3) east of north
(D) When both P and Q act, the direction of the force of friction acting on the block will be tan −1 (3/4) west of
south
2. A, D
Sol. frmax =  N = 25 N
When P acts friction is sufficient to stop it but when Q acts net free will be balanced by friction and the
condition is about to move
North

20 N 25 N

530
East
15 N

3. In the adjoining figure if acceleration of M with respect to

ground is a, then (string s and pulleys are ideal and all surfaces
are smooth)
(A) acceleration of m with respect M is a a m
(B) acceleration of m with respect ground is 2a sin ( / 2) M
(C) acceleration of m with respect to ground is a 

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(D) acceleration of m with respect to ground is a tan 

3. A,B
Sol. 
ares = 2a sin a
2
a

ares

4. In the arrangement shown in figure, which statement(s) is/are true

 3 4
sin 37 = 5 and cos37 = 5 
0 0

  10 kg
(A) direction of force of friction is up the plane  = 0.7 4 kg
(B) the magnitude of force of friction is zero 0
37
(C) the tension in the string is 40 N
(D) magnitude of force of friction is 56 N
4. A,C
Sol. As the system is at rest T = 40 N and friction acts up the incline.

5. Choose the correct alternative(s).

(A) If the greatest height to which a man can throw a stone is h, then the greatest horizontal distance upto
which he can throw the stone is 2h
(B) The angle of projection for a projectile motion whose range R is n times the maximum height H is
4
tan −1  
n
(C) The time of flight T and the horizontal range R of a projectile are connected by the equation
gT 2 = 2 R tan  where,  is the angle of projection
(D) A ball is thrown vertically up. Another ball is thrown at an angle  with the vertical. Both of them remain in
air for the same period of time. Then the ratio of heights attained by two balls is 1 : 1
5. A, B, C, D
Sol. Option (A)
For greatest height  = 900
u 2 = 2 gh
For greatest range  = 450
u 2 sin 90
R= = 2h
g
Option (B)
R = nH
u 2 sin 2  nu 2 sin 2 
=
g 2g
Option (C)
2u sin  u 2 sin 2
T= , R=
g g

Option (D)
2u1 u2
For vertically up t1 = , h= 1
g 2g

2u2 sin 
At angle  , t2 =
g
t1 = t2
 u1 = u2 sin 

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u22 sin 2 
h2 =
2g
u12
h2 = = h1
2g

6. In Fig., if F = 4N, m = 2kg, M = 4kg, then k = 0.08

(A) The acceleration of m w.r.t. ground is 2/3 ms-2
(B) The acceleration of m w.r.t. ground is 1.2 ms-2 s = 0.1 F =0
m
(C) Acceleration of M is 0.4 ms-2
(D) Acceleration of M w.r.t. ground is 2/3 ms-2 M
Ground
6. B, C
Sol.  S mg = 2 , k mg = 1.6
Let both blocks move together
2
Fnet = ( M + m ) a  4 = 6a  a =
3
2 8
f =  4 = = 2.67  2  there is a sliding between both the blocks and kinetic friction is acting.
3 3
Hence, 4 − 1.6 = 2a1  a1 = 1.2
1.6 = 4a2  a2 = 0.4

7. A particle moves in a straight line and its velocity is given by u = 2t − 3. Then

(A) The distance travelled by the particle in 5 seconds is 14.5 m
(B) The distance travelled by the particle in 5 seconds is 12.5 m
(C) The displacement of the particle in 5 seconds is 10 m
(D) The displacement of the particle in 5 seconds is 8 m
7. A, C
Sol. Distance = Area under u - t graph

8. A particle is projected at an angle  with horizontal. Its velocity of projection is u:

(A) the radius of curvature at the highest point of the trajectory is u − 2 gH where H is the maximum height.
2

u 2 − 2 gH
(B) the radius of curvature at the highest point of the trajectory is .
g
g 2T
(C) the component of acceleration at the point of projection along direction of projection is where T is
2u
the time of flight.
2
(D) the component of acceleration at the point of projection along direction of projection is g T .
8. B, C
Sol. At the highest point a = an = v R
2
v = g cos 
But a = g and v = u cos .
u
u 2 cos 2 
So, g =
Rc a=g

u 2 cos 2  u (1 − sin  ) u 2 2u 2 sin 2 

2 2

Rc = = = − 
g g g 2g
u2 u 2 − 2 gH u
= − 2H =
g g
Component of acceleration at the point of projection along 
direction of projection.
= − g cos ( 90 −  ) = − g sin 
(90-)

=  2u sin   g 2T g sin  g cos 

= −g 2   = − .
 2ug  2u
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Comprehension Type
Paragraph for question Nos. 09 to 10

Two masses m1 = 8 kg and m2 = 7 kg are suspended by a weightless inextensible

string passing over a frictionless pulley. m2 is touching the ground when m1 is kept
at a height of 3 m above the ground with string tight. Mass 8 kg is released which
will move down while mass 7 kg will move up. Take g = 10 ms2

9. What will be velocity of 7 kg mass when 8 kg mass just touches the ground 8 kg
:
2
(A) ms −1 (B) 2 ms-1 3m
3
4
(B) 3 ms-1 (D) ms −1 7 kg
3
9. B
(8 − 7)  10
Sol. a=
15
V2 = 2as, s = 3 m

10. Mass 7 kg will again stop after covering total distance

(A) 3 m (B) 4 m
(C) 3.2 m (D) 3.4 m
10. C
v2
Sol. S+
2g
Paragraph for question Nos. 11 to 12
A mosquito net over a 7 ft  4 ft bed is 3 ft high. The net has a hole at one corner of the bed through which a
mosquito enters the net. Take the hole as origin, the length of the bed as the x-axis, its width as the y-axis and
vertically up as the z-axis. Now answer the following question based on the paragraph.

11. It the mosquito files and sits at the diagonally opposite upper corner of the net, then what is the displacement
of the mosquito?
(A) 7iˆ + 3 ˆj + 4kˆ (B) 7iˆ + 4 ˆj + 3kˆ (C) 3iˆ + 7 ˆj + 4kˆ (D) 4iˆ + 3 ˆj + 7kˆ
11. B
Sol. From figure z
A = 7iˆ + 4 ˆj + 3kˆ
B = 7iˆ + 4 ˆj
A 3

x
O
4
7 B
y

12. What is the unit vector along the plane of the bed, which is directed away from the hole along the diagonal of
the bed?
7i + 4 ˆj 4iˆ + 7 ˆj
(A) 7iˆ + 4 ˆj (B) 4iˆ + 7 ˆj (C) (D)
65 65
12. C

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Sol. From figure z

A = 7iˆ + 4 ˆj + 3kˆ
B = 7iˆ + 4 ˆj
Now use the formula of unit A 3
vector.
x
O
4
7 B
y

List Match Type

13. A mass is subjected to a force F = (at – bx) iˆ initially the mass lies at the origin at rest. Here x refers to the x
co-ordinate of the mass, t refers to the time elapsed. All the values are in S.I. units. (i.e. F, m, t, x, a and b).
Take m = 1 kg, a = 1 N/s, b = 1 N/m. Now match the list – I (All values in List – II are in S.I. units)
List – I List – II
Maximum velocity attained by the
(1) (P) 1
mass
Average velocity of the particle during
(2) (Q) 2
the subsequent motion
Average acceleration of the particle
(3) (R) 0
during subsequent motion
 
(4) Position of particle at t = (S) −1
2 2
(A) (1) →(R), (2) → (S), (3) → (P), (4) → (Q)
(B) (1) →(S), (2) → (R), (3) → (P), (4) → (Q)
(C) (1) →(Q), (2) → (P), (3) → (R), (4) → (S)
(D) (1) →(P), (2) → (Q), (3) → (R), (4) → (S)
13. C
Sol. F =t −x
d2x
=t−x
dt 2
X = x −t
dX dx
= −1
dt dt
d 2 X d 2x
= 2 = −X
dt 2 dt
X = Asin ( t +  )
x − t = A sin ( t +  )
x = t + A sin ( t +  )  0 = 0 + Asin   = 0
dx
v= = 1 + A cos ( t )
dt
0 = 1 + A cos0  A = −1
x = t − sin ( t )
dx d2x
= 1 − cos t  2 = sin t
dt dt
vmax = 2
 v = 1
 aavg = 0
x = t −1

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14.
Column - I Column - II
(1) A particle is moving in circle (P) The acceleration may be perpendicular
to its velocity
(2) A particle is moving in a straight line (Q) The acceleration may be in the direction
of velocity
(3) A particle is undergoing projectile (R) The acceleration may be at some angle
motion with angle of projection  ,  
  with the velocity  0    
0    2
2
(4) A particle is moving is space (S) The acceleration may be opposite to its
velocity
(A) (1) →(PR), (2) → (QS), (3) → (PR), (4) → (PQRS)
(B) (1) →(RS), (2) → (PQRS), (3) → (RS), (4) → (PS)
(C) (1) →(PR), (2) → (PQRS), (3) → (PQ), (4) → (RS)
(D) (1) →(RS), (2) → (PQ), (3) → (RS), (4) → (PQRS)
14. A
Sol. (1) Particle may be in uniform or non uniform circular motion.
(2) For motion along straight line a should not have component perpendicular to velocity.
(3) Angle will vary as 90 −     90 + 
(4) All situations are possible

PART – C
Numerical Based Questions

1. Two unequal masses 1 kg and 2 kg are connected by a string going over a clamped light
smooth pulley as shown in figure. The system is released from rest. The larger mass is
stopped for a moment 1 second after the system is set in motion. The time clasped before the
1
string is tight again is sec then B = _______ sec
B
1 kg

2 kg

1. 3.00
g
Sol. a=
3
g
v after 1 sec = m / sec2
3
For smaller block
g 1
s= t − gt 2
3 2
For heavier block
1 2
s= gt
2
1
Solving t = sec
3

2. The acceleration time graph of a particle is shown in the figure. The a(m/s)
velocity of the particle at t = 8s if its initial velocity of the particle is 3
ms −1 (in ms −1 ) 4

4 8 t(sec)
0
-1

2. 7.00

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Sol. v = area under the curve

v −3= 4
v=7

3. Coefficient of friction between two blocks shown in figure is  = 0.4. Floor is 1 kg 2 m/s
smooth. The blocks are given velocities of 2 m/s and 8 m/s in the directions
shown in figure at t = 0. The time when relative motion between them will stop 2 kg 8 m/s
is (in sec.)
3. 1.00
Sol.  mg = ( 0.4)(1)(10) = 4 N is the friction force.
 a1 = +4m / s 2
a2 = −2m / s 2
2 + 4t = 8 − 2t
 t = 1s

4. Block A is on a frictionless horizontal table. A massless inextensible string fixed at one end of the string is
connected to block B of mass m. Initially the block B is is held at rest so that  = 30°. What will be the
magnitude of acceleration of block B just after it is released (in m/s2, take g = 10 m/s2)
P ●

300

A m

B m

4. 2.00
Sol. From constraint relation
Win = 0 300
T
a
So, = a ' ....(1) a
2 O
T
= ma ...( 2 )
2 T
m a’

mg − T = ma ' ….(3)
from solving the equation
a = 4 m/s2
a ' = 2m / s 2

space for rough work

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Section – II (CHEMISTRY)
PART – A
(One or More Than One Correct Type)

1. 0.6 moles of K 2Cr2O7 can oxidize

(A) 3.6 Moles of FeSO4 to Fe2 ( SO4 )3 (B) 0.1 moles of FeSO4 to Fe2 ( SO4 )3
(C) 0.05 moles of Sn2+ to Sn4+ (D) 1.8 moles of Sn2+ to Sn4+
1. A, D
Sol. neq of K 2Cr2O7 in 0.6 moles of K 2Cr2O7 = 0.6  6 = 3.6
 0.6 moles of k2Cr2O7 will oxidise 3.6 eq. of FeSO4 or 3.6 moles of Sn2+
Hence choice (A) is correct and (B) is wrong
Also 0.6 moles of K 2Cr2O7 will oxidise 3.6 eq of Sn2+ or 1.8 moles of Sn2+
Hence (D) is correct and (C) is wrong.

2. Choose the correct statements amount the following

(A) A node is a point in space where the wave function  has zero amplitude
(B) The number of maxima (Peaks) in radial distribution in n −
(C) Radial probability density is 4 r 2 Rn2, ( r )
(D)  represents probability of finding electron
2

2. A,B,C,D
Sol. All statements are correct.

3. Which of the following pairs of ions do not have the same electronic configuration?
3+ 3+ 3+ 2+ 3+ 3+ 3+ 3+
(A) Cr , Fe (B) Fe , Mn (C) Fe , Co (D) Se , Cr
3. A,C,D
Sol. Fe3+ and Mn 2 + have same electronic configuration.

4. The Vander Waal gas constant 𝑎 is given by

1 1 𝑅𝑇𝐶 27 𝑅 2 𝑇𝐶2
(A) 𝑉 (B) 𝑃𝐶 𝑉𝐶2 (C) (D)
3 𝐶 8 𝑃𝐶 64 𝑃𝐶
4. B,D
𝑎
Sol. 𝑃𝐶 =
27𝑏 2
𝑉𝐶 = 3𝑏
8𝑎
𝑇𝐶 =
27𝑅𝑏
64𝑎2
𝑇𝐶2 =
27×27𝑅 2 𝑏 2
𝑇𝐶2 64𝑎2 27𝑏 2 27𝑅 2 𝑇𝐶2
= × ⇒𝑎=
𝑃𝐶 27×27𝑅 2 𝑏 2 𝑎 64𝑃𝐶

5. In acidic medium dichromate ion oxidises stannous ion as:

xSn2+ + yCr2O72− + zH + ⎯⎯ → aSn4+ + bCr 3+ + cH 2O
(A) x : y is 1 : 3 (B) x + y + z = 18 (C) a : b is 3 : 2 (D) z − c = 7
5. B,C,D
Sol. 3Sn2+ + Cr2O72− + 14H + ⎯⎯
→ 3Sn4+ + 2Cr +3 + 7 H 2O

6. Which is/are correct graph?

   
K.E. K.E. K.E. of K.E.
photo-
(A) (B) (C) electron
(D)
Intensity
→ → of light→ →

6. B,C
Sol. h = w + K .E.
K .E of electron do not depend on intensity of light

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h
=
2 K .E.m

7. Select incorrect statements real gases

(A) In low pressure region repulsive forces dominates.
(B) Volume of gas particles is not negligible in low pressure
(C) Gas behaves as an ideal gas at low pressure and low temperature
(D) In high pressure region attractive forces dominates
7. A,B,C,D
Sol. Factual

8. If a gas expands at a constant pressure by providing heat. Which of the following statements are incorrect?
(A) The temperature increases
(B) K.E. of gaseous molecules remains same
(C) K.E. of gaseous molecules decreases
(D) The number of molecules of gas decreases
8. C,D
Sol. K.E. is a function of temperature.

Comprehension Type
Paragraph for question Nos. 09 to 10

Werner Heisenberg considered the limits of how precisely we can measure the properties of an electron or other
microscopic particle. He determined that there is a fundamental limit to how closely we can measure both position and
momentum. The more accurately we measure the momentum of particle, the less accurately we can determine its
position. The converse is also true. This is summed up in what we now call the Heisenberg uncertainty principle. The
equation is
x.(mv)  h/4
The uncertainty in the position or in the momentum of a macroscopic object like a baseball is too small to observe.
However, the mass of microscopic object such as an electron is small enough for the uncertainty to be relatively large
and significant.

9. If the uncertainties in position and momentum are equal, the uncertainty in the velocity is:
h h 1 h
(A) (B) (C) (D) none of these
 2 2m 
9. C
h h
Sol. xp =  p 2 =
4 4
h 1 h
 m v =  v =
2 2

4 2m 

10. If the uncertainty in velocity and position is same, then the uncertainty in momentum will be:
hm h h 1 h
(A) (B) m (C) (D)
4 4 4 m m 4
10. A
h h
Sol. x = ; xp =
4 m 4
h h mh
p = , p =
4 m 4 4

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Paragraph for question Nos. 11 to 12

Molecular weight (or Atomic weight)
Equivalent weight=
n-factor
n-factor is very important in redox as well as non-redox reactions. With the help of n-factor we can predict the molar
ratio of the reactant species taking part in reactions. The reciprocal of n-factor’s ratio of the reactants is molar ratio of
the reactions.
In general n-factor of acid/base is number of moles H+/OH– furnished per mole of acid/base. n-factor of a reactant is
no. of moles of electrons lost or gained per mole of reactant in a redox reaction.

Example 1:
1. In acidic medium: KMnO4 (n.f = 5) ⎯→ Mn2+
2. In neutral medium: KMnO4 (n.f = 3) ⎯→ Mn2+
3. In basic medium: KMnO4 (n.f = 1) ⎯→ Mn6+

Example 2: FeC2O4 ⎯⎯→ Fe3+ + 2CO2

Total no. of moles of e– lost by 1 mole of FeC2O4 = 1 + 1 × 2 = 3

11. n-factor of Ba(MnO4)2 in acidic medium is:

(A) 2 (B) 6 (C) 10 (D) None of these
11. C
Sol. n-factor = 5 × 2 = 10

12. For the reaction, H3 PO2 + NaOH ⎯⎯

→ NaH 2 PO2 + H 2O
What is the equivalent weight of H3PO2? (mol. wt. is M)
(A) M (B) M/2 (C) M/3 (D) None of these
12. A
Sol. H3PO2 is a monobasic acid
 n-factor = 1

List Match Type

13. If ‘M’ is the molar mass
LIST-I LIST-II (Equivalent mass)
(1) NH ⎯⎯ → NO −
3 3
P. M/5

(2) Q. M/2
MnO4− ⎯⎯
→ Mn+2
(3) R. M/8
CaCO3 + 2HCl ⎯⎯
→ CaCl2 + H 2O + CO2
(4) CuS ⎯⎯
→ CuSO4 S M

(A) (1) →(R), (2) → (P), (3) → (Q), (4) → (R) (B) (1) →(P), (2) → (R), (3) → (Q), (4) → (P)
(C) (1) →(Q), (2) → (P), (3) → (R), (4) → (R) (D) (1) →(P), (2) → (R), (3) → (S), (4) → (Q)
13. A
Sol. (1) N −3 ⎯⎯→ N +5 + 8e −
nf =8

(2) 5e − + Mn +7 ⎯⎯
→ Mn +2
nf = 5

(3) nfCaCO3 = 2
(4) S −2 ⎯⎯
→ S +6 + 8e −
nf =8

14. Match the contents of Column – I with contents of Column – II for 1 mole of gas.
LIST − I LIST – II
(1) When force of attraction among gas P. PV = RT
molecules is negligible
(2) At STP Q. (P + a/V2)(V − b) = RT
(3) At low pressure and high temperature R. PV = RT − a/V
(4) When volume of gas molecules is negligible S. PV = RT + Pb
(A) (1) →(Q), (2) → (S), (3) → (P), (4) → (R) (B) (1) →(S), (2) → (Q), (3) → (P), (4) → (R)
(C) (1) →(S), (2) → (P), (3) → (R), (4) → (Q) (D) (1) →(S), (2) → (R), (3) → (P), (4) → (Q)
14. B
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Sol. (1) When force of attraction among gas molecules is negligible then a = 0.
(2) At STP, Both a and b will be significant.
(3) At low pressure and high temperature Vanderwaal equation converts into PV = RT for 1 mole of gas.
(4) When volume of gas molecules is negligible, b = 0.

PART – C
Numerical Based Questions

1. Volume strength of H 2O2 is X. When 0.2 mole KMnO4 are react with 100 mL H 2O2 . Find the value of
( X + 4)
. Given that Products of the reaction are O2 and MnO .
12
1. 5
Sol. Volume strength=5.6* Normality
Normality=Eq/Volume in L. Hence N=0.2*5/0.1=10. Hence X=56.

2. The amount of energy required to remove electron from a Li 2+ ion in its ground state is how many times
greater than the amount of energy needed to remove the electron from an H-atom in its ground state?
2. 9
ELi2+ = −13.6 ( 3) eV
2

Sol. =9
EH = −13.6  (1) eV
2

3. How many of the following statements is/are correct?

h
(1) The orbital angular momentum for a d-electron is 6
2
(2) The number of orbital in a shell with principal quantum number n is 2n 2 .
 1
(3) The set of quantum numbers for the unpaired electron of Cl atom is 3,1,1, − 
 2
(4) The ratio of energy in the first Bohr orbit of H-atom to the electron in the first excited state of Be3+ is 1:4.
(5) The electronic configuration of Co ends with 3d 7 4s 2 .
(6) The order of energy of subshells in a given principal quantum level for an H-atom are ns  np  nd  ...
(7) In silver atom (at.no. 47), 23 electron have a spin of one type and 24 electrons have a spin opposite type.
3. 5
h
Sol. (1) The orbital angular momentum for a d-electron is 6 .
2
(2) The number of orbitals in a shell with principal quantum number n is n2
 1
(3) The set of quantum numbers for the last unpaired electron of Cl atom is 3,11, − 
 2
(4) The ratio of energy in the first Bohr orbit H-atom to the electron in the first excited state of Be3+ is 1:4.
(5) The electronic configuration of Co ends with 3d 7 4s 2
(6) The energy of subshells in a given principal quantum level for an H-atom are equal
(7) in silver atom (at. No. 47), 23 electron have a spin of one type and 24 electrons have a spin of opposite
type.

4. 3.55 g sample of bleaching powder suspended in H2 O was treated with enough acetic acid and KI solution.
Iodine thus liberated required 80 mL of 0.2 M hypo for titration. Calculate the % of available chlorine.
4. 16
80  0.2
Sol. Moles of iodine=moles of chlorine =  10 −3 = 8  10 −3
2
8  71 10−3
So required % =  100% = 16%
3.55
space for rough work

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Section – III (MATHEMATICS)

PART – A
(One or More Than One Correct Type)

1. The equation of the line bisecting the angle between lines y –x =2 and 3 y +x =5 are
y−x−2 3y + x − 5 y+ x−2 3y + x − 5
(A) = (B) =
2 2 2 2
y − x−2 5− 3 y − x
(C) = (D) none of these
2 2
1. A, C
Sol. y–x–2=0 …(1)
3 y + x −5= 0 ….(2)
The bisectors of (1) and (2) are given by
y−x−2 3 y + x −5
=
2 2
y−x−2 3 y + x −5
 = ….(3)
2 2
y − x−2 5− 3 y − x
and = ….(4)
2 2
Answer A, C

If ( 2a + b ) − 4c = 0, then the family of lines ax + by + c = 0 passes through a fixed point having co-ordinates
2 2
2.
 1  1
(A)  1,  (B) (1, - 1) (C) (2, - 1/2) (D)  −1, − 
 2  2
2. A, D
Sol. 2a + b + 2c = 0 , ax + by + c = 0
On composing the coefficients of x, y and const term we see
b 1
a+ + c = 0  x = 1, y =
2 2
and 2a + b - 2c = 0
Answer A, D.

If sin 5 = a sin  + b sin 3  + c sin  then

5
3.
(A) a − 2c = 5 (B) a − 2c = 6 (C) b + 3c = 5 (D) b + 3c = −5
3. B, D
 
Sol. Put = given a + b + c = 1 &
, a + 2b + 4c = −4
2 4
 a − 2c = 6, b + 3c = −5

n −1
 r 
4. If f ( n ) =  cos
r =1
2

 n 
 ; n  2 then

(A) f ( 2 ) = 0 (B) f (8) = 3 (C) f ( 9 ) = 7 (D) f (12 ) = 5

4. A, B, D
n
 2r  1 1 2 4 
Sol. f ( n ) =  1 + cos  = ( n − 1) + cos + cos + ....cos ( 2n − 2 )  
r =1  n  2 2 n n 
 2   2  2  
 sin ( n − 1)  2  + ( n − 2) 
1 1 2n cos   n  n  
f ( n ) = ( n − 1) +  
2 2  sin 2  2 
  
2n  
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  n −1  
  cos  
1   n 
sin
1  n
f ( n ) = ( n − 1) +   = −1
2 2   2
sin
 n 
n−2
 f ( n) =
2

( )
log 1 a 3
log 27 a 2 +1
2 24
−3 − 2a
5. If f ( a ) = then
7 4log 49 a
− a −1

(A) f ( 7 ) = 57 (B) f ( 5) = 28 (C) f ( 4 ) = 21 (D) None of these

5. A, C
24log2 a − 3
3log 3 3 a 2 +1( )
Sol. 4log a
7 72 − a − 1
a 4 − a 2 − 2a − 1
= = ( a 2 + a + 1)
a2 − a − 1
 f ( 7 ) = 57, f ( 5) = 31, f ( 4 ) = 21

6. If x = at2 and y = 2at then

dy 1 dx
(A) is equal to (B) is equal to t
dx t dy
dy 2a dx y
(C) is equal to (D) is equal to
dx y dy 2a

6. A, B, C, D
dx dy dy 1 2a
Sol. = 2at , = 2a  = or
dt dt dx t y

2 1 2x −1
7. Range of values of x satisfying the inequality −  3
x − x +1 x +1 x +1
2

(A) ( −,3 (B) −16, −7 (C) ( −,1 (D) ( −, −2
7. B, D
2 ( x + 1) − ( x 2 − x + 1) − ( 2 x − 1)
Sol. 0
( x + 1) ( x 2 − x + 1)
2− x
 0 x  −1
x − x +1
2

 x  2 & x  −1

x −1
8. Let f(x) = . Then:
2 x − 7x + 5
2

1 1
(A) Limit f(x) = − (B) Limit f(x) = −
x →1 3 x→0 5
(C) Limit f(x) = 0 (D) f ( x ) is not defined for exactly two values of x.
x→

8. A,B,C,D
x −1 −1
Sol. lim =
x →1 ( x − 1)(2 x − 5) 3

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x −1 −1
lim =
x →0( x − 1)(2 x − 5) 5
x −1
lim =0
x → ( x − 1)(2 x − 5)

x −1
lim = does not exist.
x→
5 ( x − 1)(2 x − 5)
2
Comprehension Type
Paragraph for question Nos. 09 to 10

If Pn = sin  + cos  , where n  w and

n n
 R .

9. If P1 = m then the value of 4 (1 − P6 )

(A) 3 ( m − 1) ( ) (C) 3 ( m + 1) ( )
2 2
(B) 3 m − 1 (D) 3 m + 1
2 2 2 2

9. B
Sol. P1 = ( sin  + cos ) = m
 m2 − 1 
 sin  cos =  
 2 
sin 6  + cos6  = 1 − 3sin 2  cos 2 
2
 m2 − 1 
P6 = 1 − 3  
 2 
3 ( m 2 − 1)
2

1 − P6 =
4
 4 (1 − P6 ) = 3 ( m2 − 1)

P7 − P5
10. The value of is
P5 − P3
P7 P5 P3 P3
(A) (B) (C) (D)
P5 P3 P1 P5
10. C
Pn − Pn − 2
Sol. = − sin 2  cos 2 
Pn − 4
P − P5
 7 = − sin 2  cos 2 
P3
P − P3
 5 = − sin 2  cos 2 
P1
P − P5 P3
 7 =
P5 − P3 P1
Paragraph for question Nos. 11 to 12

The locus of a moving point is the path traced out by that point under one or more given conditions.
Technically, a locus represents the ‘set of all points’ which lies on it.
A relation f (x, y) = 0 between x and y which is satisfied by each point on the locus and such that each point
satisfying the equation is on the locus is called the equation of the locus.
On the basis of above information, answer the following questions:

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11. Locus of centroid of the triangle whose vertices are (a cos t, a sin t), (b sin t, – b cos t) and (1, 0), where t is a
parameter, is
(A) ( 3x − 1) + ( 3 y ) = a − b (B) ( 3x − 1) + ( 3 y ) = a + b
2 2 2 2 2 2 2 2

(C) ( 3x + 1) + ( 3 y ) = a + b (D) ( 3x + 1) + ( 3 y ) = a − b
2 2 2 2 2 2 2 2

11. B
Sol. Centroid is
a cos t + b sin t + 1
x=
3
 3x − 1 = a cos t + b sin t ………………(i)
a sin t − b cos t + 0
and y=
3
 3 y = a sin t − b cos t ……………(ii)
Squaring and adding Eqs. (i) and (ii), we get
( 3x − 1) + ( 3 y ) = ( a cos t + b sin t ) + ( a sin t − b cos )
2 2 2 2

or ( 3x − 1) + ( 3 y ) = a + b
2 2 2 2

12. Let A (2, –3) and B (–2, 1) be vertices of a ABC. If the centroid of this triangle moves on the line 2 x + 3 y = 1,
then the locus of the vertex C is the line
(A) 2 x + 3 y = 9 (B) 2 x − 3 y = 7
(C) 3x + 2 y = 5 (D) 3x − 2 y = 3
12. A
Sol. Let (x, y) be coordinate of vertex C and ( x1 , y1 ) be coordinates of centroid of the triangle
x+2−2 y − 3 +1
 x1 = and y1 =
3 3
x y−2
 x1 = and y1 =
3 3
 The centroid ( x1 , y1 ) lies on the line 2 x + 3 y = 1
 2 x1 + 3 y1 = 1
 x  y−2
 2   + 3  =1
3  3 
 2 x + 3 y = 9, which is the required locus of the vertex C.
List Match Type
13. Match the column.
LIST – I LIST – II
The value of log2 log2 log4 256 + 2log 2
4
(1) (P) 1
is
If log3 (5x − 2) − 2log3 3x + 1 = 1 − log3 4
(2) (Q) 6
,then x=
Product of root of the equation
(3) − 4 x +5) (R) 4
= ( x − 1) is
2
7log7 ( x
Integral value of x satisfying
log 2 x − 2 ( log1/4 x ) + 1 = 0 is.
(4) 2 (S) 9

(A) 1 → P (B) 3 → S (C) 4 → R (D) 2 → Q

13. C
Sol. 1. A=log2 log2 log4 256 + 2log 2 4
= log2 log2 log4 44+8

= log2 log2 4+8=1+8=9

2. log3 (5x − 2) − 2log3 3x + 1 = 1 − log3 4

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or log 3 (5 x − 2) − log 3 (3 x + 1) + log 3 4 = 1

 (5 x − 2)(4)  (5 x − 2)(4)
or log 3   = 1 or =3
 3 x + 1  3x + 1
or x=1

7log7 ( x −4 x +5) = ( x − 1)
2
3.
or x2-4x+5=x-1
or x2-5x+6=0
or (x-2)(x-3)=0  x=2 or x=3
also we must have x2-4x+5>0 and x-1>0
 x>1(as x2-4x+5 >0 is true for all real numbers)
2
1  log 2 x 
4. x>0, log 2 x − 2   +1 = 0
2  2 
 log 2 x − ( log 2 x ) + 2 = 0
2

 ( log 2 x ) − log 2 x − 2 = 0
2

 (t − 2)(t + 1) = 0
 x = 4, x = 1 / 2

14.
LIST - II
LIST – I
(1) Distance of point P ( cos  ,sin  ) from the (P) 4
line x sin  + y cos  + 5 − sin 2 = 0 is……
(2) 1  dy  (Q) 5
If y = e x then   at x = 1 is …….
3

e  dx 
(3) 1 (R) 7

Value of 3 ( x + 1) 2 dx
0
(4)  (S) 3
2 x
Value of  /2 2cosec  2  dx
(A) 1 →(R) (B) 2 → (S) (C) 3 → (P) (D) 4 → (Q)
14. B
cos  sin  + sin  cos  + 5 − cos 2
Sol. (1) Perpendicular distance = =5
1
dy
= 3x 2 e x  3e
3
(2)
dx
(3) (( x + 1) )3 1

0
=7

  /2
2 x  x
(4) 2  / 2 co sec  2  dx = 4  cot 2  = 4
PART – C
Numerical Based Questions

1. Number of points at unit distance from the lines 3x –4y + 11 = 0 and 5x –12y + 7 = 0 is
1. 4
Sol. 3x − 4 y + 11 = 5
 3x − 4 y + 6 = 0 ….(1) solving (1) and (3)  first solution
3x – 4y – 16 = 0 ….(2) solving (1) and (4)  second solution
5x – 12y + 7 =  13
 5x – 12y + 20 = 0 ….(3) solving (2) and (3)  third solution
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5x – 12y – 6 = 0 ….(4) solving (2) and (4)  fourth solution

2. A,B and C are three sets such that n ( A) = 40, n ( B ) = 30 , max n ( A  B ) = 10, and n ( C ) = 60 , If
min n ( A  B  C ) is k then k/10 is….
2. 6
Sol. min n ( A  B ) = 40 + 30 − 10 = 60
if min n ( A  B ) = n ( C ) then min n ( A  B  C ) = 60

x −1
3. Total number of integral value of x satisfying the equation  0 equals to
x −3
3. 4
Sol. x 1,3)  x  ( −3, −1  1,3)
Integral values of x are −2, −1,1,2

   3  7  9 
4. The value of 16 1 + cos 1 + cos 1 + cos 1 + cos  is
 10  10  10  10 
4. 1
   3  3   
Sol. 1 + cos 1 + cos  1 − cos  1 − cos 
 10  10  10  10 
 2   2 3  2  3
1 − cos 1 − cos  = sin sin 2
 10  10  10 10
2
 5 −1 5 +1 1
= sin 18 sin 54 = 
2 o 2

o
 =
 4 4  16

space for rough work

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Ai2TS – 1 ( X ) | SET – A | APT – 4 | P a g e | 18

ALL INDIA INTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS
SET – A
APT - 4 000000 Ai2TS - 1

ANSWER KEY

Section – I (PHYSICS)
PART – A

Section – II (CHEMISTRY)

PART – A

Section – III (MATHEMATICS)

PART – A

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7042202900/8800309344

FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448
www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com