Ai TS 4 (XII) - SET A PDF

ALL INDIA INTERNAL TEST SERIES
CHEMISTRY, MATHEMATICS & PHYSICS

SET – A
APT - 1 124432 Ai2TS-4
Time Allotted : 3 Hours Maximum Marks: 210

INSTRUCTIONS
• Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
• You are not allowed to leave the Examination Hall before the end of the test.
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
✓ Attempt ALL the questions. Answers have to be marked on the OMR sheets.
✓ This question paper contains Three Sections.
✓ Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
✓ Each Section is further divided into two Parts: Part – A & Part – C.
✓ Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
✓ Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
CLASS XII
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Parts.
(i) PART-A (01 – 10) contains 10 Multiple Choice Questions which have One or More Correct answer. Each
question carries +4 marks for correct answer and – 2 marks for wrong answer.
(ii) PART-C (01 – 10) contains 10 Numerical Based questions with Single Digit Integer as answer, ranging
from 0 to 9 and each question carries +3 marks for correct answer and –1 mark for wrong answer.
Name of Candidate :
Batch ID : Date of Examination : / / 2 0 1
Enrolment Number :
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com, Email: [email protected]
Ai2TS – 4 ( XII ) | SET – A | APT – 1 | Page |1
SECTION – I : CHEMISTRY
PART – A
(Straight Objective Type)
This section contains 10 multiple choice type questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE or MORE THAN ONE are correct.
1. Which of the following statements are incorrect?

(A) [Ni(CN)4]2– ion has square planar geometry and is diamagnetic
(B) [Cu(NH3)4]2+ ion has tetrahedral geometry and is diamagnetic
(C) [NiCl4]2– ion has square planar geometry and is diamagnetic
(D) [Fe(CN)6]4– ion has octahedral geometry and is diamagnetic
2. The most stable ion is

(A) Mn2+ (B) Sc4+
(C) Fe2+ (D) Mn3+
3. A solution of KI3 in water contains
(A) K3+ ions (B) I− ions
(C) K+ ions (D) I3− ions
4. (NH4)2Cr2O7 on heating gives a gas which is also given by

(A) Heating NH4NO2 (B) Heating NH4NO3
(C) Mg3N2 + H2O (D) Na(comp.) + H2O2
Space for rough work
5. Identify the correct statement.

Cl
(A) CH 2 CH Cl
Cl
has greater ability to get ionized due to reverse hyperconjugation
..
N: .. NH 2
(B) < < HN C is the order of basic strength.
. NH 2
.
.N. .N.
(C) < < < is the order of
heat of combustion of the compounds.

+ + +
NH 3 NH 3 NH 3
CH3
(D) > > is the correct order of acidic strength.
CH3
6.
Cl , NO 2
I II
Which is/are correct statement(s) about I and II?
(A) Both Cl and NO2 are deactivating groups
(B) Both are meta–directing
(C) Both are ortho–and para–directing
(D) Cl is ortho–para directing while NO2 is meta–directing
7. The initial rate of hydrolysis of methyl acetate (1 M) by a weak acid (HA, 1M) is 1/100th of that of a strong
acid (HX, 1M), at 25oC. The Ka of HA is
(A) 1 × 10-4 (B) 1 × 10-5
(C) 1 × 10 -6 (D) 1 × 10-3
8. Among P, Q, R and S, the aromatic compound(s) is/are

Cl
⎯⎯⎯
AlCl3
→P
⎯⎯⎯
NaH
→Q
( NH )
⎯⎯⎯⎯→4 2 CO
3
100 −115o C
R
O O
O
⎯⎯ ⎯
HCl
→S
(A) P (B) Q
(C) R (D) S
9. Hydrogen bonding plays a central role in the following phenomena:

(A) Ice floats in water.
(B) Higher Lewis basicity of primary amines than tertiary amines in aqueous solutions.
(C) Formic acid is more acidic than acetic acid.
(D) Dimerisation of acetic acid in benzene.
10. The reactivity of compound Z with different halogens under appropriate conditions is given below:
OH mono halo substituted derivative when X2 = I2
X2
di halo substituted derivative when X 2 = Br2
C(CH3 )3
Z
tri halo substituted derivative when X 2 = Cl 2
The observed pattern of electrophilic substitution can be explained by
(A) the steric effect of the halogen
(B) the steric effect of the tert-butyl group
(C) the electronic effect of the phenolic group
(D) the electronic effect of the tert-butyl group
PART – C
(Integer Type)
This section contains 10 questions. Each question, when worked out will result in one integer from 0 to 9 (both
inclusive).
1. Number of P−O−P bonds in P4O10 is

() 2 6
CH3 − CH = CH2 ⎯⎯⎯⎯⎯ → CH3 − CH2 − CH2 − OH . How many molecules of alcohols can be formed
i BH
2. THF
(ii) H2O2 /OH−
from one molecule of B2H6?
3. How many visible lines are emitted during transition from 5 th orbit to ground state in hydrogen emission
spectrum?
4. In CaF2 unit cell, the co-ordination number of F– ion is
5. The atomic masses of He and Ne are 4 and 20 a.m.u., respectively. The value of the de Broglie
wavelength of He gas at – 73oC is “M” times that of the de Broglie wavelength of Ne at 727 o C. M is
6. Among PbS, CuS, HgS, MnS, Ag2S, NiS, CoS, Bi2S3 and SnS2, the total number of BLACK coloured
sulphides is
7. The total no. of stereoisomers shown by Cr (NH3 )4 Cl2  Br are -

8. Potassium ferro cyanide reacts with ferric chloride to give a blue coloured compound. Secondary valency
of iron in that blue compound is.
9. Number of S – S bonds in H2S4O6 will be:
10. How many neutral oxides are among these

N2O, NO, NO2, SiO2, CO, OF2
SECTION – II : MATHEMATICS
PART – A
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.
x −2 y −3 z−4 x −1 y − 4 z − 5
1. If the lines = = and = = intersect at a point (, , ), then
1 1   2 1
(A)  = – 1 (B)  = 2
(C)  = – 3 (D)  = 0
2. The equation of three planes are x − 2y + z = 3, 5x − y − z = 8, and x + y − z = 7 then

(A) they form a triangular prism
(B) all three plane have a common line of intersection
x y z
(C) line = = is parallel to each plane
1 2 3
x y z
(D) line = = intersect all three plane
1 3 4
3. The plane x − 2y + 7z + 21 = 0
x +1 y − 3 z + 2
(A) Contains the line = = (B) Contains the point ( 0,7, −1)
−3 2 1
x y z
(C) Is parallel to the line = = (D) Is parallel to the plane x − 2y + 7z = 0
1 −2 7
4. The projection of line 3x − y + 2z − 1 = 0 = x + 2y − z − 2 on the plane 3x + 2y + z = 0 is

x +1 y −1 z −1
(A) = = (B) 3x − 8y + 7z + 4 = 0 = 3x + 2y + z
11 −9 −15
x + 12 y + 8 z + 14 x + 12 y + 8 z + 14
(C) = = (D) = =
11 −9 15 11 −9 −15
sin−1 ( sin x ) | x |
5. If A = lim and B = lim , then
x →0 cos ( cos x )
−1 x →0 x
(A) A = 1 (B) A does not exist

(C) B = 0 (D) B = 1
/ 2
sin 2 nx
6. If Un = 
0
sin 2 x
dx , then
 n
(A) U1 = (B) Un =
2 2

(C) Un − Un−1 = (D) U1, U2 , … are in A.P.
2
7. If u = a2 cos2  + b2 sin2  + a2 sin2  + b2 cos2  , then which of the following is/are true
(A) umax = (a2 + b2) (B) umin = 0
u 1
(C) umax − umin = 2(a2 + b2) (D) max =
umin 2
8. Consider a pyramid OPQRS located in the first octant (x  0, y  0, z  0) with O as origin, and OP and
OR along the x-axis and the y-axis, respectively. The base OPQR of the pyramid is a square with
OP = 3. If the point S is directly above the mid-point T of diagonal OQ such that TS = 3, then

(A) the acute angle between OQ and OS is
3
(B) the equation of the plane containing the triangle OQS is x – y = 0
3
(C) the length of the perpendicular from P to the plane containing the triangle OQS is
2
15
(D) the perpendicular distance from O to the straight line containing RS is
2
9. If f(x) = [x sin  x], (where [.] denotes the greatest integer function) then f(x) is
(A) continuous at x = 0 (B) continuous in (− 1, 0)
(C) differentiable at x = 1 (D) differentiable in (− 1, 1).
dy
x+y
dx = x sin (x + y ) is
2 2 2
10. Solution of the differential equation
y−x
dy y3
dx
2
x y2
(A) − cot(x + y ) =   + c
2 2
(B) = − tan2 (x 2 + y 2 )
y x +y c
2 2
2
y y 2 + x 2c
(C) − cot(x 2 + y 2 ) =   + c (D) = − tan2 (x 2 + y 2 )
x x2
PART – C
(Integer Type)
This section contains 10 questions. The answer to each of the questions is a single-digit integer, ranging from
0 to 9. The correct digit below the question number in the ORS is to be bubbled.
1. The area bounded by the curve y = 2 cos x, the x-axis, x = 0 and x = 2 is equal to _____
2. If the system of equations ax + y + z = a – 1, x + ay + z = a – 1, x + y + az = a – 1 has no solution, then

5 | a |2
is equal to ____________
4
x −1 y z 7
3. If the lines = = and x – y + z – 2 = 0 = x + 3z + 5 are coplanar, then is equal to
2 −1 2 31
_________
x y −1 z −1 x y −1 z −1
4. If the projection of the line = = on a plane P is = = and the plane P passes
2 2 1 1 1 −1
through (k, –2, 0) then k is equal to __________
5. In a triangle, if cot A, cot B, cot C are in A.P. then (a2 + c2)/b2 is equal to ______
6. Of the three independent events E1, E2, and E3, the probability that only E1 occurs is , only E2 occurs is 
and only E3 occurs is . Let the probability p that none of events E1, E2 or E3 occurs satisfy the equations
( − 2) p =  and ( − 3) p = 2. If all the given probabilities are assumed to lie in the interval (0, 1),
Probability of occurrence of E1
then is equal to ___________
Probability of occurrence of E3
7. Let (x, y, z) be points with integer coordinates satisfying the system of equations
3x − y − z = 0
− 3x + z = 0
− 3x + 2y + z = 0.
Then the number of such points for which x2 + y2 + z2  100 is equal to ______
8. Point (, , ) lies on the plane x + y + z = 2. If a = ˆi + ˆj + kˆ and kˆ  (kˆ  a) = 0 , then  is equal to
______
9. A line is perpendicular to x + 2y + 2z = 0 and passes through (0, 1, 0). If the perpendicular distance of this
6
line from the origin is 'd' then d is equal to __________
5
( )
2
x + cos−1 3x A
( )
3
10. If  1 − 9x 2
dx = −
9
1 − 9x 2 − 9B cos−1 3x + c , where c is constant of integration, then A is
equal to ________
SECTION – III : PHYSICS

PART – A
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.
1. One mole of an ideal gas in initial state A undergoes a cyclic process V

ABCA, as shown in the figure. Its pressure at A is P0. Choose the correct B
4V0
option(s) from the following
(A) Internal energies at A and B are the same
(B) Work done by the gas in process AB is P0V0 n 4 V0 C A
P
(C) Pressure at C is 0 T0 T
4
T
(D) Temperature at C is 0
4
2. Which of the following statements is/are correct

(A) The work done by the electric field of a nucleus in moving an electron around it in a complete orbit is
zero irrespective of whether the orbit is circular or elliptical.
(B) The equipotential surfaces corresponding to the electric field of an isolated point charge are
concentric spheres with the point charge as the common centre.
(C) If coulomb’s law involved 1/r3 dependence instead of 1/r2, Gauss law would still hold good.
(D) A single conductor cannot have any capacitance.
3. In a Young’s double-slit experiment, let A and B be the two slits. A thin film of thickness t and refractive
index  is placed in front of A. Let  = fringe width. The central maximum will shift
(A) towards A (B) towards B
 
(C) by t( − 1) (D) by t
 
Ai2TS – 4 ( XII ) | SET – A | APT – 1 | P a g e | 10
dN dN
4. A radioactive nuclide decays with a decay constant . Let A = ln , where is
dt dt A
A0
the number of radioactive decay acts taking place per second. Suppose the A0
experiment starts at t = 0 and the curve between A and t is shown in the adjacent 2
figure. O t0 (sec) t
Now, choose the correct statement(s) from the following.
A
(A) Decay constant of the radioactive sample is 0 .
2t 0
t0 A0
(B) Number of radioactive nuclei at the start of the experiment was e .
A0
t0 A0
(C) Number of radioactive nuclei after half-life is e .
2A 0
(D) Half-life of the radioactive sample is t0.
5. A ray OP of monochromatic light is incident on the face AB of prism ABCD B

near vertex B at an incident angle of 60 (see figure). If the refractive index O 60
of the material of the prism is 3 , which of the following is (are) correct? P
C
(A) The ray gets totally internally reflected at face CD 135
(B) The ray comes out through face AD
90 75
(C) The angle between the incident ray and the emergent ray is 90 A D
(D) The angle between the incident ray and the emergent ray is 120
6. For photo-electric effect with incident photon wavelength , the stopping potential is V0. Identify the
correct variation(s) of V0 with  and 1/.
V0 V0
(A) (B)
 
V0 V0
(C) (D)
1/ 1/
7. When the temperature of an organ pipe increases, then (neglecting any thermal expansion of pipe):
(A) the velocity of sound increase
(B) the velocity of sound decreases
(C) the fundamental frequency of organ pipe increases
(D) the wavelength of sound increases.
8. The molar heat capacity for an ideal gas

(A) is zero for an adiabatic process
(B) is infinite for an isothermal process
(C) depends only on the nature of the gas for a process in which either volume or pressure is constant
(D) is equal to the product of the molecular weight and specific heat capacity for any process
9. An observer A and a charge Q are fixed in a stationary frame F1. An A B

observer B is fixed in a frame F2, which is moving with respect to F1. Q
F1 F2
(A) Both A and B will observe electric field.
(B) Both A and B will observe magnetic field.
(C) Neither A nor B will observe magnetic fields.
(D) B will observe a magnetic field, but A will not.
10. T is a point at the bottom of a tank filled with water, as shown. The refractive Y O
index of water is 4/3. YPT is the vertical line through T. To an observer at the
position O, T will appear to be P
(A) to the left of YT 4m
(B) somewhere on YT T
(C) at a depth 3 m below T
(D) at a depth <3 m below T
PART – C
(Integer Type)
This section contains 10 questions. The answer to each of the questions is a single-digit integer, ranging from
0 to 9. The correct digit below the question number in the ORS is to be bubbled.
1. A closed organ pipe and an open pipe of the same length produce 4 beats when they are set into
vibrations simultaneously. If the length of each of them were twice their initial lengths, then find the
number of beats produced.
2. A stationary source is emitting sound at a fixed frequency f 0, which is reflected by two cars approaching
the source. The difference between the frequencies of sound reflected from the cars is 1.2% of f 0. What is
the difference in the speeds of the cars (in km per hour) to the nearest integer ? The cars are moving at
constant speeds much smaller than the speed of sound which is 330 ms-1.
3. Nine similar resistors of resistance R are connected as shown in the A

figure. Equivalent resistance between points A and B is (K/5) R. Find
the value of K.
4. A point object O is placed at a distance of 20 cm in front of an O

equi-convex lens (ag = 1.5) of focal length 10 cm. The lens is
placed on a liquid of refractive index 2 as shown. Image will be
formed at a distance h from lens. The value of h is 10  K cm. Then,
find the value of K.
5. An electron in the ground state of hydrogen atom goes to an excited state by absorbing 12.1eV energy. In
the course of its transition to lower energy states, then find the possible number of spectral lines of
different wavelength.
6. A Young’s double slit interference

arrangement with slits S1 and S2 is immersed
in water (refractive index = 4/3) as shown in
S1
the figure. The positions of maxima on the
d
surface of water are given by x2 = p2m22 – d2, x Air
where  is the wavelength of light in air d
water
(refractive index = 1), 2d is the separation S2
between the slits and m is an integer. The
value of p is
7. An electron in a hydrogen atom undergoes a transition from an orbit with quantum numebr ni to another
with quantum number nf. Vi and Vf are respectively the initial and final potential energies of the electon. If
vi
= 6.25 , then the smallest possible nf is
vf
8 Water of volume 2 litre in a container is heated with a coil of 1 kW at 27C. The lid of the container is
open and energy is dissipated at the rate of 160 J/s. In k minutes and 20 seconds, temperature will rise
from 27C to 77C. Find the value of k.
(Given Cwater = 4.2 kJ/kg)
9. Two electron beams having their momenta in the ratio 1 : 2 are subjected to identical magnetic fields at
right angles to the directions of motions of electron beams. The ratio of deflections produced is k : 3. Find
the value of k.
10. Hydrogen atom are excited to n = 4 state. In the spectrum of emitted radiation, number of lines in the
visible reason are _____.

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ALL INDIA INTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS

Time Allotted : 3 Hours Maximum Marks: 210

B. Filling of OMR Sheet

C. Marking Scheme For All Parts.

Batch ID : Date of Examination : / / 2 0 1

1. Which of the following statements are incorrect?

2. The most stable ion is

4. (NH4)2Cr2O7 on heating gives a gas which is also given by

Space for rough work

5. Identify the correct statement.

(C) < < < is the order of

heat of combustion of the compounds.

Space for rough work

8. Among P, Q, R and S, the aromatic compound(s) is/are

9. Hydrogen bonding plays a central role in the following phenomena:

Space for rough work

1. Number of P−O−P bonds in P4O10 is

from one molecule of B2H6?

4. In CaF2 unit cell, the co-ordination number of F– ion is

7. The total no. of stereoisomers shown by Cr (NH3 )4 Cl2  Br are -

10. How many neutral oxides are among these

Space for rough work

2. The equation of three planes are x − 2y + z = 3, 5x − y − z = 8, and x + y − z = 7 then

4. The projection of line 3x − y + 2z − 1 = 0 = x + 2y − z − 2 on the plane 3x + 2y + z = 0 is

Space for rough work

(A) A = 1 (B) A does not exist

Space for rough work

2. If the system of equations ax + y + z = a – 1, x + ay + z = a – 1, x + y + az = a – 1 has no solution, then

Space for rough work

Space for rough work

SECTION – III : PHYSICS

1. One mole of an ideal gas in initial state A undergoes a cyclic process V

2. Which of the following statements is/are correct

5. A ray OP of monochromatic light is incident on the face AB of prism ABCD B

Space for rough work

8. The molar heat capacity for an ideal gas

9. An observer A and a charge Q are fixed in a stationary frame F1. An A B

Space for rough work

3. Nine similar resistors of resistance R are connected as shown in the A

4. A point object O is placed at a distance of 20 cm in front of an O

Space for rough work

6. A Young’s double slit interference

Space for rough work

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