PH II Sankalp2224 PCM - 20!10!2224 Mains Set A

FIITJEE – JEE (Main)
Physics, Chemistry & Mathematics

(PANINI-PINNACLE-eSANKALP2224 LOT A to B)
QP Code:100681.1
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
Important Instructions
A. General Instructions
BATCHES –2024
1. This question paper contains Three Part.

2. PART-I is Physics, PART-II is Chemistry and PART-III is Mathematics.
3. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.
B. Marking Scheme for All Two Parts:
(i) Section-1 (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options
each and only one correct option. Each question will be awarded + 4 Marks for correct answer and -1
mark will be deducted for every incorrect answer.
(ii) Section-2 (01-05) contains Five (05) Numerical based questions with single digit integer as answer,
ranging from 0 to 9 (both inclusive). Each question will be awarded + 4 Marks for correct answer and NO
MARKS will be deducted for every incorrect answer.
Name of the Candidate :_______________________________________________
Batch :_______________________ Date of Examination :____________________
Enrolment Number :___________________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
SANKALP2224 BATCHES eSANKALP2224P1 TO PNB1 & PH1, PHASE-2-PCM(100681.1)-2
PART I: PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE option is correct.
1. In a region of gravitational field of mass M a particle is shifted from A t o B via three different paths are
w1, w2 and w3 respectively then
(A) w1 = w2 = w3 (B) w1 = w2 > w3 (C) w1 > w2 > w3 (D) w1 < w2 < w3
2. If a man increases his speed by 2m/s, his K.E. is doubled. The original speed of man is
(A) (2  2 )m / s (B) (2  2 2)m / s (C) 4m/s (D) (1  2 )m / s
3. A particle of mass m slides down a smooth hemisphere of radius R.

The height at which the body breaks off from the hemisphere is
(A) h = R/2 (B) h = R/3
(C) h = 2R/3 (D) h = R/4
4. There is a hemispherical bowl of radius R. A block of mass m slides from the rim of the bowl to the
bottom. The velocity of the block at the bottom will be:
(A) Rg (B) 2Rg (C) 2Rg (D) 2Rg
5. A 1 kg particle strikes a wall with velocity 1 m/s at an angle 30o and reflects at the same angle. If its
remains in contact with wall for 0.1 sec, then find the force.
(A) 0 (B) 10 3 (C) 30 3 (D) 40 3

6. A force F  6t 2 ˆi  4tjˆ is acting on a particle of mass 3 kg then what will be velocity of particle at
t = 3 sec if at t = 0, particle is at rest -
(A) 18iˆ  6ˆj (B) 18iˆ  12ˆj (C) 12iˆ  6ˆj (D) none
Space for rough work
7. A body of mass 0.1 kg moving with a velocity of 10 m/s hits a spring (fixed at the other end) of force
constant 1000 N/m and comes to rest after compressing the spring. The compression of the spring is
(A) 0.01 m (B) 0.1 m (C) 0.2 m (D) 0.5 m
8. When the K.E. of a body is increased by 300% the momentum of the body is increased by
(A) 20% (B) 50% (C) 100% (D) 200%
9. A spring of natural length L and spring constant k is fixed on the

ground and the other is fitted with a smooth ring of mass m which
slides on a horizontal rod fixed at a height also equal to L (see Fig.).
Initially the spring makes an angle of 37° with the vertical when the L
system is released from rest. What is the speed of the ring when the
spring becomes vertical?
L k k k k
(A) (B) L (C) 2L (D) 4L
4 m m m m
10. A lamina is made by removing a small disc of diameter 2R from a bigger disc of
uniform mass density and radius 2R, as shown in the figure. The moment of
inertia of this lamina about axes passing through O and P is IO and IP,
respectively. Both these axes are perpendicular to the plane of the lamina. The
ratio IP/IO to the nearest integer is
(A) 7 (B) 3
(C) 8 (D) 5
K
11. A particle of mass m is moving in a horizontal circle of radius r under a centripetal force equal to  ,
r2
where K is a constant. Then KE of the particle will be
K
(A) 2 (B) kr (C) 2k/r (D) k/2r
r
12. An external agent moves the block m on slowly from A to B, along a B

smooth hill such that every time he applies the force tangentially. Find
the work done by the agent in this interval. Fagent
2 2 2 2
mgH mgH H
(A) (B) Smooth
L L Hill
(C) mg (H + L) (D) mgH
A
L
13. The linear density of rod is given by  = Bx2 where B is a constant. Then the co-ordinates of centre of
mass are
 3L   3L   4L   4L 
(A)  ,0  (B)  0,  (C)  ,0  (D)  0, 
 4   4   3   3 
14. A block (B) is attached to two unstretched springs S1 and 2

M2 S2 M1
1
S1 I
S2 with spring constants k and 4k, respectively (see figure B
I). The other ends are attached to identical supports M1
and M2 not attached to the walls. The springs and 2 x M1 1
M2 S2 S1
II
supports have negligible mass. There is no friction B
anywhere. The block B is displaced towards wall 1 by a
small distance x (figure II) and released. The block returns x
and moves a maximum distance y towards wall 2.
Displacements x and y are measured with respect to the
y
equilibrium position of the block B. The ratio is
x
1 1
(A) 4 (B) 2 (C) (D)
2 4
15. A force F =  K(xiˆ  yj)

ˆ (where K is a positive constant) acts on a particle moving in the x-y plane.
Starting from the origin, the particle is taken along the positive x - axis to the point (a, 0) and then to

the point (a, a). The total work done by the force F on the particle is
(A) 2Ka2 (B) 2Ka2 (C) Ka2 (D) Ka2
16. A uniform chain of length L and mass M is lying on a smooth table and one-third of its length is
hanging vertically down over the edge of the table. If g is acceleration due to gravity, the work required
to pull slowly the hanging part on the table is
MgL MgL MgL
(A) MgL (B) (C) (D)
3 6 18
17. A 5 kg block is kept on a horizontal platform which

starts from rest with a horizontal acceleration of 1
m/s2 relative to the ground as shown in the figure.
The co-efficient of friction between the block and the 1 m/s2
Ground
platform is 0.2. The work done by the force of friction
on the block in ground frame of reference in 10s is
(A) +250 J (B) 250 J (C) +500 J (D) 500 J
18. A ball of mass 400 gm is dropped from a height of 5 m. A body on the ground hits the ball vertically
upwards with a bat an average force of 100 Newton so that it attains a vertical height of 20 m. The
2
time for which the ball remains in contact with the bat is ( g = 10 m/sec )
(A) 0.12 s (B) 0.08 s (C) 0.04 s (D) 12 s

19. A force F   3xy  5z  ˆj  4zkˆ is applied on a particle. The work done by the
(2,4,0)
force when the particle moves from the point (0,0,0) to the point (2,4,0) as
shown in the figure is
280 140 232 192 y = x2
(A) (B) (C) (D)
5 5 5 5 x
(0, 0, 0)
20. The figure shows a hollow cube of side a of volume V. there

is a small chamber of volume V/4 in the cube as shown. This
chamber is completely filled by m kg of water. Water leaks
through a hole and spreads in the whole cube. Then the
work done by gravity in this process assuming that the
complete water finally lies at the bottom of the cube is :
1 3
(A) mga (B) mga
2 8
5 1
(C) mga (D) mga
8 8
SECTION – 2: (Only Integer Value Correct Type)
This section contains 5 questions. Each question, when worked out will result in one integer from 0 to 9 (both
inclusive).
1. A bullet is fired normally on a immovable wooden plank. It loses 25 % of its kinetic energy in
penetrating a thickness x = 2m of the plank. What is the total thickness penetrated by the bullet in
meter?
2. A light inextensible string that goes over a smooth fixed pulley as shown in the figure
2
connects two blocks of masses 0.36 kg and 0.72 kg. Taking g = 10 m/s , find the work
done (in joules) by the string on the block of mass 0.36 kg during the first second after the
system is released from rest.
3. A position dependent force F = 7 - 2x + 3x2 N, acts on a small body of mass 2 kg and displaces it
from x = 0 to x = 5m. The work done in Joules is 27 K then find the value of K.
4. A particle of mass 4 kg which is at rest explodes into three fragments. Two of the fragments each of
mass 1 kg are found to move with a speed 2m/s each in mutually perpendicular directions. Find the
total energy released in the process of explosion in Joule.
5. A block of mass m moving at a velocity v collides with another block of mass 2m at rest. The lighter
block comes to rest after collision. The coefficient of restitution is K/2, then find the value of K.
PART II : CHEMISTRY
1. Which of the following molecule has zero dipole moment?
(A) CCl4 (B) CH3Cl (C) CHCl3 (D) CH2Cl2
2. The pair of species having identical shapes for molecules of both species is
(A) CF4, SF4 (B) XeF2, CO2 (C) BF3, PCl3 (D) PF5, IF5
3. Hydrogen chloride gas has

(A) Hydrogen bond (B) Covalent bond
(C) Ionic bond (D) Coordinate bond
4. If Na+ ion is larger than Mg2+ ion and S2- ion is larger than Cl− ion, which of the following will be more
covalent.
(A) NaCl (B) Na2S (C) MgCl2 (D) MgS
5. Which of the following has zero dipole moment?

(A) CO2 (B) SO2 (C) H2O (D) NH3
6. Paramagnetism is not shown by

(A) O2 (B) H2+ (C) O2 (D) O22
7. Pick out tetrahedral (structure) species from the following.

(A) BF4 (B) H3O+ (C) SF4 (D) NH3
8. The molecule which has T-shaped structure is

(A) BCl3 (B) NH3 (C) ClF3 (D) PCl3
9. Which of the following is most volatile?

(A) HF (B) HCl (C) HBr (D) HI
10. Consider the following amines:

(1) C6H5NH2 (2) oNO2C6H4NH2 (3) mNO2C6H4NH2 (4) pNO2C6H4NH2
Arrange these compounds in decreasing order of basicity:
(A) (1) > (2) > (3) > (4) (B) (2) > (1) > (3) > (4)
(C) (1) > (3) > (4) > (2) (D) (1) > (3) > (2) > (4)
11. Most acidic hydrogen is present in:

O O O
(A) (B) (C) (CH3CO)3CH (D) (CH3)3COH
12. Which of the following carbanion is most stable?

CH2 CH2 CH2 CH2
NO2 CN
(A) (B) (C) (D)
NO2 CN
13. Which one of the following compound is most acidic?
(A) HOCH2COOH (B) O2NCH2COOH (C) ClCH2COOH (D) NCCH2COOH
14. Arrange homolytic bond energies of CH bonds designated by (I), (II), (III), (IV) and (V) in increasing
order.
(II)
(V) H (I)
H H
(III)
H
CH2H
(IV)
(A) (II) < (V) < (IV) < (III) < (I) (B) (III) < (V) < (IV) < (II) < (I)
(C) (I) < (III) < (IV) < (II) < (V) (D) (II) < (IV) < (V) < (I) < (III)
15. Arrange basicity of the given compounds in decreasing order.

(A) CH3CH2NH2 (B) CH2=CHNH2 (C) CHCNH2
(A) (A) > (B) > (C) (B) (A) > (C) > (B) (C) (C) > (B) > (A) (D) (B) > (C) > (A)
16. The most stable free radical is

Me
(A) (B) (C) (D)
17. Which of the following compound is most acidic?

OH OH OH
NO2
(A) OH (B) (C) (D)
NO2
NO2
18. IUPAC name of
H C4H9
CH3 C C CH3
C2H5 CH3
(A) 2-butyl-2-methyl-3-ethyl-butane (B) 2-ethyl, 3-3-dimethyl heptane
(C) 3, 4, 4-trimethyl heptane (D) 3, 4, 4-trimethyl octane
19. IUPAC name of CH3—O—C2H5 is

(A) dimethyl ether (B) methyl ethyl ether
(C) methoxy ethane (D) ethyl methyl ether
20. The IUPAC name of tert-butyl chloride is

(A) 4-chlorobutane (B) 2-chlorobutane
(C) 1-chloro-3-methylpropane (D) 2-chloro-2-methylpropane

This section contains 5 questions. Each question, when worked out will result in one integer from 0
to 9 (both inclusive).
1. The number of structural isomers of C4H10O are___________.
2. The number of possible structure of amines C7H9N having one benzene ring is_____________.
3. The total number of lone pairs of electrons on the central atom in XeOF4, I3 , ClF3 is/are
4. Among the following molecules how many are having sp3d hybridization of this central atom?
XeOF2 , SF6 , SF4 , I3 , BrF3 , XeF2 , POCl3 , ClO 4 , XeF4 , PCl3F2


5. Among CCl3 , O  SiH3 2 , N  SiH3 3 and BF3 , number of compound shows (p-d) back bonding.
PART III: MATHEMATICS

1. If the distinct points A1(0, 0), A2(0, 1), A3(1, 0), A4(2a, 3a) are given to be concyclic, then
(A) a < 0 (B) a (0, 1)
(C) ‘a’ can attain only rational values (D) none of these
2. PA is tangent to x 2 + y2 = a2 and PB is tangent to x2 + y2 = b2 (b > a). If PAB = /2 then locus of

point P is
(A) x2 – y2 = a2 – b2 (B) x2 + y2 = b2 – a2
2 2 2 2
(C) x + y = a + b (D) x2 – y2 = b2 – a2
2 2 2 2
3. Tangents are drawn to x + y = 16 at the points where it is cut by the circle x + y – 6x – 4y + 9 =
0. Intersection point of these tangents is
 16 14   64 96   4 16   96 64 
(A)  ,  (B)  ,  (C)  ,  (D)  , 
 25 25   25 25   25 25   25 25 
4. The circles having radii r1 and r2 intersect orthogonally. Length of their common chord is
2r1 r2 2r12 r2 r1 r2 2 r22 r2
(A) (B) (C) (D)
r12  r22 r12  r22 r12  r22 r12  r22
5. The angle between tangents drawn from ‘P’ to the circle x 2 + y2 + 4x – 6y + 9 sin2
+ 13 cos2 = 0 is 2. Locus of point P is
(A) x2 + y2 + 4x – 6y – 9 = 0 (B) x2 + y2 + 4x – 6y – 4 = 0
2 2
(C) x + y + 4x – 6y + 9 = 0 (D) x2 + y2 + 4x – 6y + 4 = 0
6. Tangent to circle x2 + y2 = 5 at (1, –2) also touches the circle x 2 + y2 – 8x + 6y + 20 = 0. Co–

ordinate of the corresponding point of contact is
(A) (3, 1) (B) (3, –1) (C) (–3, 1) (D) (–3, –1)
2 2 2 2
7. Equation of the circle drawn of the common chord of circles x + y = 1 and x + y – 2x – 2y + 1 =
0 as diameter is
(A) x2 + y2 + x + y = 0 (B) x2 + y2 + x – y = 0
2 2
(C) x + y – x – y = 0 (D) x2 + y2 – x + y = 0
8. If the angle between tangents drawn to x2 + y2 + 2gx + 2fy + c = 0 from (0, 0) is /2 then
(A) g2 + f2 = 3c (B) g2 + f2 = 2c (C) g2 + f 2 = 5c (D) g2 + f 2 = 4c
9. Two consecutive vertices of a regular hexagon A1A2 A3A4A5A6 are A1 (1, 0), A2  (3, 0). If the
center of hexagon lies above the x–axis then equation of the circumcircle of the hexagon is
17 25
(A) x2 + y2 – 4x – 2 3y  =0 (B) x2 + y2 – 4x – 2 3y 0
3 3
(C) x2 + y2 – 4x – 2 3y+3=0 (D) none of these
2 2
10. If P(at1 , 2at 1 ) and Q(at 2 , 2at 2 ) are two variable points on the curve y2 = 4ax and PQ subtends
a right angle at the vertex, then t1 t2 is equal to
(A) – 1 (B) – 2 (C) – 3 (D) – 4.
11. The line x  my  n  0 is a normal to the parabola y2 = 4ax if

(A) a(   2m )  m n  0 (B) a(  2m )  m n
2 2 2 2 2 2
(C) a(2  m )   m n (D) a(2  m )  2m n .

2 2 2 2 2 2
12. Two tangents are drawn from the point (– 2, – 1) to the parabola y2 = 4x. If  is the angle
between these tangents, then tan  =
(A) 3 (B) 1/3 (C) 2 (D) 1/2.
2 2
13. The tangents at the points (at1 , 2at 1 ), (at 2 , 2at 2 ) on the parabola y2 = 4ax are at right angles if
(A) t1 t2 = – 1 (B) t1t2 = 1 (C) t1 t2 = 2 (D) t1 t2 = – 2.
14. The mid–point of the chord 2x + y – 4 = 0 of the parabola y2 = 4x is

5   5 3 
(A)  ,  1 (B)  1,  (C)  ,  1 (D) none of these.
2   2 2 
2
15. Three normals to the parabola y = x are drawn through a point (C, 0), then
(A) C = 1 / 4 (B) C = 1 / 2 (C) C > 1 / 2 (D) none of these.
2
16. The distance between the parallel lines given by (x + 7y) + 4 2 (x + 7y) – 42 = 0 is
(A) 4/5 (B) 4/ 2 (C) 2 (D) 10 2
17. If the lines joining the origin to the intersection of the line y = mx + 2 and the curve x 2 + y2 = 1 are
at right angles, then
2 2 2 2
(A) m = 1 (B) m = 3 (C) m = 7 (D) 2m = 1
2 2
18. The equation x – y = 4 and x + 4xy + y = 0 represent the sides of
(A) an equilateral triangle (B) a right angled triangle
(C) an isosceles triangle (D) none of these
19. If y = mx bisects the angle between the lines x 2 (tan2 + cos2) + 2xy tan – y2 sin2 = 0 when  =
/3, then the value of 3 m3 + 4m is
(A) 1 (B) 1/ 3 (C) 3 (D) 7 3
20. The lines joining the origin to the point of intersection of 3x 2 + xy – 4x + 1 = 0 and 2x + y – 1 = 0
are at right angles for
(A)  = – 4 (B)  = 4 (C)  = 7 (D) all values of 

This section contains 5 questions. Each question, when worked out will result in one integer from 0
to 9 (both inclusive).

1. If the straight line drawn through the point P  
3,2 & inclined at an angle
6
with the x-axis,
meets the line 3 x – 4y + 8 = 0 at Q. Find the length PQ
2. The circle x 2  y 2  4x  4y + 4 = 0 is inscribed in a triangle which has two of its sides along the
coordinate axes. The locus of the circumcentre of the triangle is x + y  xy + K x 2  y 2 = 0.
Find absolute value of K
3. If 3x + 4y + k = 0 represents the equation of the tangent at the vertex of the parabola

16x2 – 24xy + 9y2 + 14x + 2y + 7 = 0, then find the value of k.
3 3
4. If the line y = 3x cuts the curve x + y = xy + 2 at the points A, B, C. If O is the origin, then
[OA. OB. OC] = __________ (where [.] denotes the greatest integer function).
5. From a point P (which lies on the axis of parabola) common tangents are drawn to the circle x2 +
y2 = a2/2 & parabola y2 = 4ax. Then the area of the quadrilateral formed by the common tangents,
the chord of contact of the circle and the chord of contact of the parabola is 15 a2/ λ, then the
value of λ is
FIITJEE - JEE (Main)

(PANINI-PINNACLE-eSANKALP2224 LOT A to B)
JEE - MAIN 2024
Phase Test – 2
(Q.P Code – 100681.1)
ANSWERS
PHYSICS
SECTION-1
1. A
2. B
3. C
4. B
5. B
6. A
7. B
8. C
9. A
10. B
11. D
12. D
13. A
14. C
15. C
16. D
17. A
18. A
19. D
20. C
SECTION-2
1. 8
2. 8
3. 5
4. 6
5. 1
CHEMISTRY
SECTION - 1
1. A
2. B
3. B
4. D
5. A
6. D
7. A
8. C
9. B
10. C
11. C
12. A
13. B
14. A
15. A
16. D
17. D
18. D
19. C
20. D
SECTION - 2
1. 7
2. 5
3. 6
4. 6
5. 3
MATHEMATICS
SECTION-1
1. D
2. BONUS GIVEN ANSWER C CORRECT BONUS
3. D
4. A
5. C
6. B
7. C
8. B
9. A
10 D
11. A
12 D
13 A
14 A
15 C
16. C
17. C
18. A GIVEN ANSWER C CORRECT A
19. BONUS GIVEN ANSWER C CORRECT BONUS
20. D
SECTION-2
1. 6
2. 1
3. 3
4. 2
5. 4

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FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics

1. This question paper contains Three Part.

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

3. A particle of mass m slides down a smooth hemisphere of radius R.

Space for rough work

9. A spring of natural length L and spring constant k is fixed on the

Space for rough work

12. An external agent moves the block m on slowly from A to B, along a B

14. A block (B) is attached to two unstretched springs S1 and 2

15. A force F =  K(xiˆ  yj)

Space for rough work

17. A 5 kg block is kept on a horizontal platform which

20. The figure shows a hollow cube of side a of volume V. there

Space for rough work

SECTION – 2: (Only Integer Value Correct Type)

Space for rough work

3. Hydrogen chloride gas has

5. Which of the following has zero dipole moment?

6. Paramagnetism is not shown by

7. Pick out tetrahedral (structure) species from the following.

Space for rough work

8. The molecule which has T-shaped structure is

9. Which of the following is most volatile?

10. Consider the following amines:

11. Most acidic hydrogen is present in:

(A) (B) (C) (CH3CO)3CH (D) (CH3)3COH

12. Which of the following carbanion is most stable?

Space for rough work

15. Arrange basicity of the given compounds in decreasing order.

16. The most stable free radical is

(A) (B) (C) (D)

17. Which of the following compound is most acidic?

Space for rough work

19. IUPAC name of CH3—O—C2H5 is

20. The IUPAC name of tert-butyl chloride is

SECTION – 2: (Only Integer Value Correct Type)

1. The number of structural isomers of C4H10O are___________.

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PART III: MATHEMATICS

2. PA is tangent to x 2 + y2 = a2 and PB is tangent to x2 + y2 = b2 (b > a). If PAB = /2 then locus of

6. Tangent to circle x2 + y2 = 5 at (1, –2) also touches the circle x 2 + y2 – 8x + 6y + 20 = 0. Co–

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11. The line x  my  n  0 is a normal to the parabola y2 = 4ax if

(C) a(2  m )   m n (D) a(2  m )  2m n .

14. The mid–point of the chord 2x + y – 4 = 0 of the parabola y2 = 4x is

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SECTION – 2: (Only Integer Value Correct Type)

meets the line 3 x – 4y + 8 = 0 at Q. Find the length PQ

3. If 3x + 4y + k = 0 represents the equation of the tangent at the vertex of the parabola

FIITJEE - JEE (Main)

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