Magnetic Compass Liquid MSDS

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SAFETY DATA SHEET

According to EC No 1907/2006 as amended as at the date of this SDS


ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier


Trade name : ShellSol TD
Product code : Q7411
Registration number : 01-2119471991-29-0001
Synonyms : Hydrocarbons, C10-C12, isoalkanes, < 2% aromatics
CAS-No. : 64741-65-7
EC-No. : 923-037-2

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the : Industrial Solvent.
Substance/Mixture Please refer to Ch16 for the registered uses under REACH.

Uses advised against : This product must not be used in applications other than the
above without first seeking the advice of the supplier.

1.3 Details of the supplier of the safety data sheet


Manufacturer/Supplier : Shell Chemicals Europe B.V.
PO Box 2334
3000 CH Rotterdam
Netherlands
Telephone : +31 (0)10 441 5137 / +31 (0)10 441 5191
Telefax : +31 (0)20 716 8316 / +31 (0)20 713 9230
Email Contact for Safety Data : [email protected]
Sheet

1.4 Emergency telephone number


+44 (0) 1235 239 670
Giftnotruf (Berlin): +49 (0) 30 3068 6790

Other information : SHELLSOL is a trademark owned by Shell Trademark


Management B.V. and Shell Brands Inc. and used by affiliates
of Royal Dutch Shell plc.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Classification (REGULATION (EC) No 1272/2008)
Flammable liquids, Category 3 H226: Flammable liquid and vapour.
Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters
airways.
Long-term (chronic) aquatic hazard, H411: Toxic to aquatic life with long lasting effects.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Category 2
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)


Hazard pictograms :

Signal word : Danger

Hazard statements : PHYSICAL HAZARDS:


H226 Flammable liquid and vapour.
HEALTH HAZARDS:
H304 May be fatal if swallowed and enters
airways.
ENVIRONMENTAL HAZARDS:
H411 Toxic to aquatic life with long lasting effects.

Supplemental Hazard : EUH066 Repeated exposure may cause skin


Statements dryness or cracking.

Precautionary statements : Prevention:


P210 Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No
smoking.
P243 Take action to prevent static discharges.
P273 Avoid release to the environment.
Response:
P301 + P310 IF SWALLOWED: Immediately call a
POISON CENTER/doctor.
P331 Do NOT induce vomiting.
Storage:
No precautionary phrases.
Disposal:
P501 Dispose of contents and container to
appropriate waste site or reclaimer in
accordance with local and national
regulations.

2.3 Other hazards


The substance does not fulfill all screening criteria for persistence, bioaccumulation and toxicity and
hence is not considered to be PBT or vPvB.
May form flammable/explosive vapour-air mixture.
This material is a static accumulator.
Even with proper grounding and bonding, this material can still accumulate an electrostatic charge.
If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-
vapour mixtures can occur.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

SECTION 3: Composition/information on ingredients


3.1 Substances
Hazardous components
CAS-No.
Chemical name Concentration [%]
EC-No.
Hydrocarbons, C10-C12, Not Assigned 100
isoalkanes, < 2% aromatics 923-037-2

SECTION 4: First aid measures

4.1 Description of first aid measures


General advice : Not expected to be a health hazard when used under normal
conditions.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

If inhaled : No treatment necessary under normal conditions of use. If


symptoms persist, obtain medical advice.

In case of skin contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.

In case of eye contact : Flush eye with copious quantities of water.


Remove contact lenses, if present and easy to do. Continue
rinsing.
If persistent irritation occurs, obtain medical attention.

If swallowed : Call emergency number for your location / facility.


If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Not considered to be an inhalation hazard under normal
conditions of use.
Possible respiratory irritation signs and symptoms may include
a temporary burning sensation of the nose and throat,
coughing, and/or difficulty breathing.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Skin irritation signs and symptoms may include a burning


sensation, redness, or swelling.

No specific hazards under normal use conditions.


Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision.

If material enters lungs, signs and symptoms may include


coughing, choking, wheezing, difficulty in breathing, chest
congestion, shortness of breath, and/or fever.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.

Defatting dermatitis signs and symptoms may include a


burning sensation and/or a dried/cracked appearance.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Call a doctor or poison control center for guidance.
Potential for chemical pneumonitis.
Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable extinguishing : Do not use water in a jet.
media
5.2 Special hazards arising from the substance or mixture
Specific hazards during : Clear fire area of all non-emergency personnel. Hazardous
firefighting combustion products may include: A complex mixture of
airborne solid and liquid particulates and gases (smoke).
Carbon monoxide. Unidentified organic and inorganic
compounds. Flammable vapours may be present even at
temperatures below the flash point. The vapour is heavier
than air, spreads along the ground and distant ignition is
possible. Will float and can be reignited on surface water.
5.3 Advice for firefighters
Special protective equipment : Proper protective equipment including chemical resistant
for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).
Specific extinguishing : Standard procedure for chemical fires.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

methods
Further information : Keep adjacent containers cool by spraying with water.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Personal precautions : Observe all relevant local and international regulations.
Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur.
Local authorities should be advised if significant spillages
cannot be contained.
6.1.1 For non emergency personnel:
Avoid contact with skin, eyes and clothing.
Isolate hazard area and deny entry to unnecessary or
unprotected personnel.
Do not breathe fumes, vapour.
Do not operate electrical equipment.
6.1.2 For emergency responders:
Avoid contact with skin, eyes and clothing.
Isolate hazard area and deny entry to unnecessary or
unprotected personnel.
Do not breathe fumes, vapour.
Do not operate electrical equipment.

6.2 Environmental precautions


Environmental precautions : Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use
appropriate containment to avoid environmental
contamination. Prevent from spreading or entering drains,
ditches or rivers by using sand, earth, or other appropriate
barriers. Attempt to disperse the vapour or to direct its flow to
a safe location for example by using fog sprays. Take
precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment.
Monitor area with combustible gas indicator.

6.3 Methods and materials for containment and cleaning up


Methods for cleaning up : For small liquid spills (< 1 drum), transfer by mechanical
means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

safe disposal. Do not flush away residues with water. Retain


as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely
Ventilate contaminated area thoroughly.
If contamination of site occurs remediation may require
specialist advice.

6.4 Reference to other sections


For guidance on selection of personal protective equipment see Chapter 8 of this Safety Data Sheet.,
For guidance on disposal of spilled material see Chapter 13 of this Safety Data Sheet.

SECTION 7: Handling and storage

General Precautions : Avoid breathing of or direct contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Ensure that all local regulations regarding handling and
storage facilities are followed.

7.1 Precautions for safe handling


Advice on safe handling : Avoid inhaling vapour and/or mists.
Avoid contact with skin, eyes and clothing.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Bulk storage tanks should be diked (bunded).
When using do not eat or drink.

The vapour is heavier than air, spreads along the ground and
distant ignition is possible.

Product Transfer : Even with proper grounding and bonding, this material can still
accumulate an electrostatic charge. If sufficient charge is
allowed to accumulate, electrostatic discharge and ignition of
flammable air-vapour mixtures can occur. Be aware of
handling operations that may give rise to additional hazards
that result from the accumulation of static charges. These
include but are not limited to pumping (especially turbulent
flow), mixing, filtering, splash filling, cleaning and filling of
tanks and containers, sampling, switch loading, gauging,
vacuum truck operations, and mechanical movements. These
activities may lead to static discharge e.g. spark formation.
Restrict line velocity during pumping in order to avoid
generation of electrostatic discharge (≤ 1 m/s until fill pipe

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

submerged to twice its diameter, then ≤ 7 m/s). Avoid splash


filling. Do NOT use compressed air for filling, discharging, or
handling operations.

Refer to guidance under Handling section.

7.2 Conditions for safe storage, including any incompatibilities


Requirements for storage : Refer to section 15 for any additional specific legislation
areas and containers covering the packaging and storage of this product.

Storage class (TRGS 510) : 3, Flammable liquids

Other data : Storage Temperature: Ambient.

Bulk storage tanks should be diked (bunded). Locate tanks


away from heat and other sources of ignition. Cleaning,
inspection and maintenance of storage tanks is a specialist
operation, which requires the implementation of strict
procedures and precautions. Must be stored in a diked
(bunded) well- ventilated area, away from sunlight, ignition
sources and other sources of heat. Keep away from aerosols,
flammables, oxidizing agents, corrosives and from other
flammable products which are not harmful or toxic to man or
to the environment. Electrostatic charges will be generated
during pumping. Electrostatic discharge may cause fire.
Ensure electrical continuity by bonding and grounding
(earthing) all equipment to reduce the risk. The vapours in the
head space of the storage vessel may lie in the
flammable/explosive range and hence may be flammable.

Packaging material : Suitable material: For containers, or container linings use mild
steel, stainless steel., For container paints, use epoxy paint,
zinc silicate paint.
Unsuitable material: Avoid prolonged contact with natural,
butyl or nitrile rubbers.

Container Advice : Do not cut, drill, grind, weld or perform similar operations on or
near containers.

7.3 Specific end use(s)


Specific use(s) : Please refer to Ch16 and/or the annexes for the registered
uses under REACH.

See additional references that provide safe handling practices


for liquids that are determined to be static accumulators:
American Petroleum Institute 2003 (Protection Against
Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practices
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Value type (Form


Components CAS-No. Control parameters Basis
of exposure)
Isoparaffinic 300 mg/m3 DE TRGS 900
solvents 180 - 220
Biological occupational exposure limits
No biological limit allocated.

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:


No DNEL value has been established.

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:


Substance is a hydrocarbon with a complex, unknown or variable composition. Conventional
methods of deriving PNECs are not appropriate and it is not possible to identify a single
representative PNEC for such substances.

Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure controls.
For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and samples
analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or contact
the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil

8.2 Exposure controls


Engineering measuresRead in conjunction with the Exposure Scenario for your specific use
contained in the Annex.
Use sealed systems as far as possible.
Adequate explosion-proof ventilation to control airborne concentrations below the exposure
guidelines/limits.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Local exhaust ventilation is recommended.


Firewater monitors and deluge systems are recommended.
Eye washes and showers for emergency use.
Where material is heated, sprayed or mist formed, there is greater potential for airborne
concentrations to be generated.
The level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures
include:

General Information:
Always observe good personal hygiene measures, such as washing hands after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment
to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Define procedures for safe handling and maintenance of controls.
Educate and train workers in the hazards and control measures relevant to normal activities
associated with this product.
Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g.
personal protective equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or maintenance.
Retain drain downs in sealed storage pending disposal or subsequent recycle.
Personal protective equipment
Read in conjunction with the Exposure Scenario for your specific use contained in the Annex.
The provided information is made in consideration of the PPE directive (Council Directive
89/686/EEC) and the CEN European Committee for Standardisation (CEN) standards.

Personal protective equipment (PPE) should meet recommended national standards. Check with
PPE suppliers.

Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.
Approved to EU Standard EN166.

Hand protection

Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. Longer term protection: Nitrile
rubber gloves. Incidental contact/Splash protection: PVC,
neoprene or nitrile rubber gloves For continuous contact we
recommend gloves with breakthrough time of more than 240
minutes with preference for > 480 minutes where suitable
gloves can be identified. For short-term/splash protection we
recommend the same but recognize that suitable gloves
offering this level of protection may not be available and in this
case a lower breakthrough time maybe acceptable so long as
appropriate maintenance and replacement regimes are
followed. Glove thickness is not a good predictor of glove
resistance to a chemical as it is dependent on the exact
composition of the glove material. Glove thickness should be

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

typically greater than 0.35 mm depending on the glove make


and model. Suitability and durability of a glove is dependent
on usage, e.g. frequency and duration of contact, chemical
resistance of glove material, dexterity. Always seek advice
from glove suppliers. Contaminated gloves should be
replaced. Personal hygiene is a key element of effective hand
care. Gloves must only be worn on clean hands. After using
gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.

Skin and body protection : Skin protection is not required under normal conditions of use.
For prolonged or repeated exposures use impervious clothing
over parts of the body subject to exposure.
If repeated and/or prolonged skin exposure to the substance
is likely, then wear suitable gloves tested to relevant Standard,
and provide employee skin care programmes.

Protective clothing approved to EU Standard EN14605.

Wear antistatic and flame-retardant clothing, if a local risk


assessment deems it so.

Respiratory protection : If engineering controls do not maintain airborne


concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing apparatus.
Where air-filtering respirators are suitable, select an
appropriate combination of mask and filter.
If air-filtering respirators are suitable for conditions of use:
Select a filter suitable for organic gases and vapours [Type A
boiling point > 65°C (149°F)] meeting EN14387.

Hygiene measures : Wash hands before eating, drinking, smoking and using the
toilet. Launder contaminated clothing before re-use. Do not
ingest. If swallowed, then seek immediate medical assistance.

Environmental exposure controls


General advice : Read in conjunction with the Exposure Scenario for your
specific use contained in the Annex.
Take appropriate measures to fulfil the requirements of
relevant environmental protection legislation. Avoid
contamination of the environment by following advice given in
Section 6. If necessary, prevent undissolved material from

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

being discharged to waste water. Waste water should be


treated in a municipal or industrial waste water treatment plant
before discharge to surface water.
Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Minimise release to the environment. An environmental
assessment must be made to ensure compliance with local
environmental legislation.
Information on accidental release measures are to be found in
section 6.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Appearance : Liquid.

Colour : colourless
Odour : Paraffinic
Odour Threshold : Data not available
pH : Not applicable
Melting point/freezing point : Data not available
Boiling point/boiling range : Typical 172 - 185 °C
Flash point : Typical 44 °C
Method: IP 170

Evaporation rate : 70
Method: DIN 53170, di-ethyl ether=1

0,18
Method: ASTM D 3539, nBuAc=1

Flammability (solid, gas) : Not applicable

Upper explosion limit : 6 %(V)

Lower explosion limit : 0,6 %(V)

Vapour pressure : Typical 40 Pa (0 °C)

Typical 160 Pa (20 °C)

Typical 1,000 Pa (50 °C)

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Relative vapour density : Data not available


Relative density : Data not available
Density : Typical 751 kg/m3 (15 °C)
Method: ASTM D4052

Solubility(ies)
Water solubility : insoluble
Partition coefficient: n- : log Pow: 6,2 - 7,2
octanol/water
Auto-ignition temperature : 450 °CMethod: ASTM E-659

Decomposition temperature : Data not available

Viscosity
Viscosity, dynamic : Data not available
Viscosity, kinematic : Typical 1,6 mm2/s (25 °C)

Explosive properties : Not applicable


Oxidizing properties : Data not available

9.2 Other information


Surface tension : Typical 23 mN/m, 20 °C, ASTM D-971

Conductivity : Low conductivity: < 100 pS/m


The conductivity of this material makes it a static
accumulator., A liquid is typically considered nonconductive if
its conductivity is below 100 pS/m and is considered semi-
conductive if its conductivity is below 10,000 pS/m., Whether a
liquid is nonconductive or semi-conductive, the precautions
are the same., A number of factors, for example liquid
temperature, presence of contaminants, and anti-static
additives can greatly influence the conductivity of a liquid
Molecular weight : 160 g/mol

SECTION 10: Stability and reactivity

10.1 Reactivity
The product does not pose any further reactivity hazards in addition to those listed in the following
sub-paragraph.
10.2 Chemical stability

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

No hazardous reaction is expected when handled and stored according to provisions, Stable under
normal conditions of use.
10.3 Possibility of hazardous reactions
Hazardous reactions : Reacts with strong oxidising agents.

10.4 Conditions to avoid


Conditions to avoid : Avoid heat, sparks, open flames and other ignition sources.

In certain circumstances product can ignite due to static


electricity.

10.5 Incompatible materials


Materials to avoid : Strong oxidising agents.

10.6 Hazardous decomposition products


Hazardous decomposition : Hazardous decomposition products are not expected to form
products during normal storage.
Thermal decomposition is highly dependent on conditions. A
complex mixture of airborne solids, liquids and gases
including carbon monoxide, carbon dioxide, sulphur oxides
and unidentified organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative
degradation.

SECTION 11: Toxicological information


11.1 Information on toxicological effects

Basis for assessment : Information given is based on product testing, and/or similar
products, and/or components.
Information on likely routes of : Exposure may occur via inhalation, ingestion, skin absorption,
exposure skin or eye contact, and accidental ingestion.

Acute toxicity
Product:
Acute oral toxicity : LD50 Rat: > 5000 mg/kg
Remarks: Low toxicity:

Acute inhalation toxicity : Rat: Remarks: Low toxicity:


LC50 greater than near-saturated vapour concentration.

Acute dermal toxicity : LD50 Rabbit: > 5000 mg/kg


Remarks: Low toxicity:

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Skin corrosion/irritation
Product:
Remarks: Causes mild skin irritation., Prolonged/repeated contact may cause defatting of the
skin which can lead to dermatitis.

Serious eye damage/eye irritation


Product:
Remarks: Not irritating to eye.

Respiratory or skin sensitisation


Product:
Remarks: Not a sensitiser., Based on available data, the classification criteria are not met.

Germ cell mutagenicity


Product:
: Remarks: Not mutagenic.
Carcinogenicity
Product:

Remarks: Tumours produced in animals are not considered relevant to humans., Not a
carcinogen., Based on available data, the classification criteria are not met.

Material GHS/CLP Carcinogenicity Classification


Hydrocarbons, C10-C12, No carcinogenicity classification.
isoalkanes, < 2% aromatics

Reproductive toxicity

Product:
:
Remarks: Not a developmental toxicant., Based on available
data, the classification criteria are not met., Does not impair
fertility.

STOT - single exposure


Product:
Remarks: Based on available data, the classification criteria are not met.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

STOT - repeated exposure


Product:
Remarks: Kidney: caused kidney effects in male rats which are not considered relevant to
humans

Aspiration toxicity
Product:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Further information
Product:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

Summary on evaluation of the CMR properties


Germ cell mutagenicity- : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Carcinogenicity - : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

Reproductive toxicity - : This product does not meet the criteria for classification in
Assessment categories 1A/1B.

SECTION 12: Ecological information

12.1 Toxicity

Basis for assessment : Incomplete ecotoxicological data are available for this product.
The information given below is based partly on a knowledge of
the components and the ecotoxicology of similar products.
Product:
Toxicity to fish (Acute : Remarks: Not toxic at limit of water solubility:
toxicity)
Toxicity to crustacean (Acute : Remarks: Not toxic at limit of water solubility:
toxicity)
Toxicity to algae/aquatic : Remarks: Not toxic at limit of water solubility:
plants (Acute toxicity)
Toxicity to fish (Chronic : Remarks: Data not available
toxicity)
Toxicity to crustacean : Remarks: NOEC/NOEL > 0.1 - <=1.0 mg/l
(Chronic toxicity)

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According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Toxicity to microorganisms : (Pseudomonas putida): > 2


(Acute toxicity) Exposure time: 5 h
Remarks: Practically non toxic:
LC/EC/IC50 > 100 mg/l

12.2 Persistence and degradability


Product:
Biodegradability : Remarks: Inherently biodegradable., Oxidises rapidly by
photo-chemical reactions in air.

12.3 Bioaccumulative potential


Product:
Bioaccumulation : Remarks: Has the potential to bioaccumulate.

Partition coefficient: n- : log Pow: 6,2 - 7,2


octanol/water
12.4 Mobility in soil
Product:
Mobility : Remarks: Floats on water., If it enters soil, it will adsorb to soil
particles and will not be mobile.
12.5 Results of PBT and vPvB assessment
Product:
Assessment : The substance does not fulfill all screening criteria for
persistence, bioaccumulation and toxicity and hence is not
considered to be PBT or vPvB.
12.6 Other adverse effects
Product:
Additional ecological : Does not have ozone depletion potential.
information

SECTION 13: Disposal considerations

13.1 Waste treatment methods


Product : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal
methods in compliance with applicable regulations.

Do not dispose into the environment, in drains or in water

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courses
Waste product should not be allowed to contaminate soil or
ground water, or be disposed of into the environment.
Waste, spills or used product is dangerous waste.

Disposal should be in accordance with applicable regional,


national, and local laws and regulations.
Local regulations may be more stringent than regional or
national requirements and must be complied with.

Contaminated packaging : Drain container thoroughly.


After draining, vent in a safe place away from sparks and fire.
Residues may cause an explosion hazard. Do not puncture,
cut or weld uncleaned drums.
Send to drum recoverer or metal reclaimer.
Comply with any local recovery or waste disposal regulations.

SECTION 14: Transport information

14.1 UN number
ADN : 1268
ADR : 1268
RID : 1268
IMDG : 1268
IATA : 1268
14.2 Proper shipping name
ADN : PETROLEUM DISTILLATES, N.O.S.
(NAPHTHA)
ADR : PETROLEUM DISTILLATES, N.O.S.
RID : PETROLEUM DISTILLATES, N.O.S.
IMDG : PETROLEUM DISTILLATES, N.O.S.
(NAPHTHA)

IATA : Petroleum distillates, n.o.s.


14.3 Transport hazard class
ADN : 3
ADR : 3
RID : 3
IMDG : 3
IATA : 3
14.4 Packing group
ADN
Packing group : III
Classification Code : F1
Labels : 3 (N2, F)
CDNI Inland Water Waste : NST 8963 Solvent
Agreement
ADR

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Packing group : III


Classification Code : F1
Hazard Identification Number : 30
Labels : 3
RID
Packing group : III
Classification Code : F1
Hazard Identification Number : 30
Labels : 3
IMDG
Packing group : III
Labels : 3
IATA
Packing group : III
Labels : 3
14.5 Environmental hazards
ADN
Environmentally hazardous : yes
ADR
Environmentally hazardous : yes
RID
Environmentally hazardous : yes
IMDG
Marine pollutant : yes
14.6 Special precautions for user
Remarks : Special Precautions: Refer to Section 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied. MARPOL Annex 1 rules apply for bulk shipments by sea.

Additional Information : This product may be transported under nitrogen blanketing.


Nitrogen is an odourless and invisible gas. Exposure to
nitrogen may cause asphyxiation or death. Personnel must
observe strict safety precautions when involved with a
confined space entry.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - List of substances subject to authorisation : Product is not subject to
(Annex XIV) Authorisation under REACH.

REACH - Candidate List of Substances of Very High : This product does not contain

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Concern for Authorisation (Article 59). substances of very high concern


(Regulation (EC) No
1907/2006 (REACH), Article 57).
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
P5c FLAMMABLE LIQUIDS
E2 ENVIRONMENTAL HAZARDS

Water contaminating class : WGK 1 slightly hazardous to water


(Germany) Code Number: 27
Remarks: Classification according to AwSV

Other regulations : The regulatory information is not intended to be


comprehensive. Other regulations may apply to this material.

Product is subject to Stoerfallverordnung (12. BImSchV)


based on Seveso III directive (2012/18/EU).

Product is subject Betriebs-Sicherheits-Verordnung


(BetrSichV).

Compliance with paragraph 22 of Youth Employment Law.

Take note of Law on the protection of mothers at work, in


education and in studies (Maternity Protection Act - MuSchG).

Regulation (EC) No 1907/2006 of the European Parliament


and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH), annex XIV.
Regulation (EC) No 1907/2006 of the European Parliament
and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH), annex XVII.
Directive 2004/37/EC on the protection of workers from the
risks related to exposure to carcinogens or mutagens at work
and its amendments.
Directive 1994/33/EC on the protection of young people at
work and its amendments.
Council Directive 92/85/EEC on the introduction of measures
to encourage improvements in the safety and health at work of
pregnant workers and workers who have recently given birth
or are breastfeeding and its amendments.

The components of this product are reported in the following inventories:


AIIC : Listed
DSL : Listed
IECSC : Listed
KECI : Listed

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NZIoC : Listed
PICCS : Listed
TSCA : Listed
TCSI : Listed
EINECS : Listed

15.2 Chemical safety assessment


A Chemical Safety Assessment was performed for all substances of this product.

SECTION 16: Other information

Abbreviations and Acronyms : The standard abbreviations and acronyms used in this
document can be looked up in reference literature (e.g.
scientific dictionaries) and/or websites.

ACGIH = American Conference of Governmental Industrial


Hygienists
ADR = European Agreement concerning the International
Carriage of Dangerous Goods by Road
AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits
BTEX = Benzene, Toluene, Ethylbenzene, Xylenes
CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches Institut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission
EC50 = Effective Concentration fifty
ECETOC = European Center on Ecotoxicology and
Toxicology Of Chemicals
ECHA = European Chemicals Agency
EINECS = The European Inventory of Existing Commercial
Chemical Substances
EL50 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
IMDG = International Maritime Dangerous Goods
INV = Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the

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determination of polycyclic aromatics DMSO-extractables


KECI = Korea Existing Chemicals Inventory
LC50 = Lethal Concentration fifty
LD50 = Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LL50 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No
Observed Effect Level
OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of
Dangerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act
TWA = Time-Weighted Average
vPvB = very Persistent and very Bioaccumulative

Further information
Training advice : Provide adequate information, instruction and training for
operators.

Other information : The eSDS(s) received to date have been reviewed for the
registered components in this mixture. The advice provided in
the body of this SDS covers all necessary Risk Management
Measures.
For Industry guidance and tools on REACH please visit the
CEFIC website at http://cefic.org/Industry-support.
The substance does not fulfill all screening criteria for
persistence, bioaccumulation and toxicity and hence is not
considered to be PBT or vPvB.
A vertical bar (|) in the left margin indicates an amendment
from the previous version.

This product is classified as H304 (May be fatal if swallowed


and enters airways). The risk relates to potential for aspiration.
The risk arising from aspiration hazard is solely related to the

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physico-chemical properties of the substance. The risk can


therefore be controlled by implementing risk management
measures tailored to this specific hazard and included within
Section 8 of the SDS. An exposure scenario is not presented.

This product is classified as R66 / EUH066 (Repeated


exposure may cause skin dryness or cracking). The risk
relates to the potential for repeated or prolonged dermal
contact. The risk arising from contact is solely related to the
physico-chemical properties of the substance. The risk can
therefore be controlled by implementing risk management
measures tailored to this specific hazard and included within
Section 8 of the SDS. An exposure scenario is not presented.

There has been a significant change in transport classification


in section 14.

Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).

Identified Uses according to the Use Descriptor System


Uses - Worker
Title : Water treatment chemicals- Professional

Uses - Worker
Title : Water treatment chemicals- Industrial

Uses - Worker
Title : Polymer processing- Professional

Uses - Worker
Title : Polymer processing- Industrial

Uses - Worker
Title : Use in laboratories- Professional

Uses - Worker
Title : Use in laboratories- Industrial

Uses - Worker
Title : Functional Fluids- Professional

Uses - Worker

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Title : Functional Fluids- Industrial

Uses - Worker
Title : Use as a fuel- Professional

Uses - Worker
Title : Use as a fuel- Industrial

Uses - Worker
Title : Use in Agrochemicals uses- Professional

Uses - Worker
Title : Metal working fluids / rolling oils- Professional

Uses - Worker
Title : Metal working fluids / rolling oils- Industrial

Uses - Worker
Title : Lubricants- ProfessionalHigh Environmental Release

Uses - Worker
Title : Lubricants- ProfessionalLow Environmental Release

Uses - Worker
Title : Lubricants- Industrial

Uses - Worker
Title : Use in Cleaning Agents- Professional

Uses - Worker
Title : Use in Cleaning Agents- Industrial

Uses - Worker
Title : Uses in Coatings- Professional

Uses - Worker
Title : Uses in Coatings- Industrial

Uses - Worker
Title : Formulation & (re)packing of substances and mixtures-
Industrial

Uses - Worker
Title : Distribution of substance- Industrial

Uses - Worker
Title : Manufacture of substance- Industrial
Identified Uses according to the Use Descriptor System
Uses - Consumer
Title : Uses in Coatings
- Consumer

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Uses - Consumer
Title : Use in Cleaning Agents
- Consumer

Uses - Consumer
Title : Lubricants
- Consumer
Low Environmental Release

Uses - Consumer
Title : Lubricants
- Consumer
High Environmental Release

Uses - Consumer
Title : Use in Agrochemicals uses
- Consumer

Uses - Consumer
Title : Use as a fuel
- Consumer

Uses - Consumer
Title : Functional Fluids
- Consumer

Uses - Consumer
Title : Other Consumer Uses
- Consumer

This information is based on our current knowledge and is intended to describe the product for the
purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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Exposure Scenario - Worker


300000000339

SECTION 1 EXPOSURE SCENARIO TITLE


Title Water treatment chemicals- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 13
Environmental Release Categories: ERC8f, ESVOC
SpERC 8.22b.v1

Scope of process Covers the use of the substance for the treatment of water in
open and closed systems.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 15
Fraction of Regional tonnage used locally: 0,1
Annual site tonnage (tonnes/year): 1,5
Maximum daily site tonnage (kg/day): 4
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,0E-02
Release fraction to wastewater from wide dispersive use: 9,9E-01
Release fraction to soil from wide dispersive use (regional only): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater sediment.

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Prevent discharge of undissolved substance to or recover from onsite


wastewater.
Onsite waste water treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 98,5
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 59,9
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 98,5
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 4
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.

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Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

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Exposure Scenario - Worker


300000000338

SECTION 1 EXPOSURE SCENARIO TITLE


Title Water treatment chemicals- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 13
Environmental Release Categories: ERC3, ERC4, ESVOC
SpERC 3.22a.v1

Scope of process Covers the use of the substance for the treatment of water at
industrial facilities in open and closed systems.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 15
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 15
Maximum daily site tonnage (kg/day): 49
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 5,0E-02
Release fraction to wastewater from process (initial release prior to 9,5E-01
RMM):
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil

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Risk from environmental exposure is driven by freshwater sediment.


Onsite waste water treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 99,9
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 96,6
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 99,9
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 49
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.

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Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

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Exposure Scenario - Worker


300000000337

SECTION 1 EXPOSURE SCENARIO TITLE


Title Polymer processing- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 6, PROC 8a,
PROC 8b, PROC 14, PROC 21
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.21b.v1

Scope of process Processing of formulated polymers including material


transfers, moulding and forming activities, material re-works
and associated maintenance.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 42
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 2,1E-02
Maximum daily site tonnage (kg/day): 5,7E-02
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 9,8E-01
Release fraction to wastewater from process (initial release prior to 1,0E-02
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-02
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air

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emissions and releases to soil


Risk from environmental exposure is driven by freshwater.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 5,0
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.

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Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

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Exposure Scenario - Worker


300000000336

SECTION 1 EXPOSURE SCENARIO TITLE


Title Polymer processing- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 5, PROC 6, PROC 8a, PROC 8b, PROC 9, PROC 13,
PROC 14, PROC 21
Environmental Release Categories: ERC4, ESVOC SpERC
4.21a.v1

Scope of process Processing of formulated polymers including material


transfers, additives handling (e.g. pigments, stabilisers, fillers,
plasticisers, etc.), moulding, curing and forming activities,
material re-works, storage and associated maintenance.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 7,3
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 7,3
Maximum daily site tonnage (kg/day): 370
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 0,25
Release fraction to wastewater from process (initial release prior to 0
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

release estimates used.


Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
Treat air emission to provide a typical removal efficiency of (%) 80
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Not applicable as there is no release to wastewater.
Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 3,3E+04
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management

35 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

36 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000335

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use in laboratories- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 10, PROC 15
Environmental Release Categories: ERC8a, ESVOC
SpERC 8.17.v1

Scope of process Use of small quantities within laboratory settings, including


material transfers and equipment cleaning.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 0,5
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 2,5E-04
Maximum daily site tonnage (kg/day): 6,8E-04
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 5,0E-01
Release fraction to wastewater from wide dispersive use: 5,0E-01
Release fraction to soil from wide dispersive use (regional only): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Treat air emission to provide a typical removal efficiency of (%) 0


Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 6,1E-02
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet

38 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

(http://cefic.org).

39 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000334

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use in laboratories- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 10, PROC 15
Environmental Release Categories: ERC2, ERC4

Scope of process Use of the substance within laboratory settings, including


material transfers and equipment cleaning.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 0,5
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 0,5
Maximum daily site tonnage (kg/day): 25
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 2,5E-02
Release fraction to wastewater from process (initial release prior to 2,0E-02
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-04
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater sediment.
If discharging to domestic sewage treatment plant, no onsite

40 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

wastewater treatment required.


Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 87,8
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 80
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.

41 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

42 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000333

SECTION 1 EXPOSURE SCENARIO TITLE


Title Functional Fluids- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 8a,
PROC 9, PROC 20
Environmental Release Categories: ERC9a, ERC9b,
ESVOC SpERC 9.13b.v1

Scope of process Use as functional fluids e.g. cable oils, transfer oils, coolants,
insulators, refrigerants, hydraulic fluids in professional
equipment including maintenance and related material
transfers.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 20
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 0,01
Maximum daily site tonnage (kg/day): 0,027
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 5,0E-02
Release fraction to wastewater from wide dispersive use: 2,5E-02
Release fraction to soil from wide dispersive use (regional only): 2,5E-02
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

emissions and releases to soil


Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 2,4
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite

44 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

technologies, either alone or in combination.


Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

45 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000332

SECTION 1 EXPOSURE SCENARIO TITLE


Title Functional Fluids- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 9
Environmental Release Categories: ERC7, ESVOC SpERC
7.13a.v1

Scope of process Use as functional fluids e.g. cable oils, transfer oils, coolants,
insulators, refrigerants, hydraulic fluids in industrial equipment
including maintenance and related material transfers.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 20
Fraction of Regional tonnage used locally: 0,5
Annual site tonnage (tonnes/year): 10
Maximum daily site tonnage (kg/day): 500
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 5,0E-03
Release fraction to wastewater from process (initial release prior to 1,0E-06
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-03
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

emissions and releases to soil


Risk from environmental exposure is driven by freshwater.
Prevent discharge of undissolved substance to or recover from onsite
wastewater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 4,4E+04
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management

47 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

48 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000331

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use as a fuel- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 8a,
PROC 8b, PROC 16
Environmental Release Categories: ERC9a, ERC9b,
ESVOC SpERC 9.12b.v1

Scope of process Covers the use as a fuel (or fuel additive) and includes
activities associated with its transfer, use, equipment
maintenance and handling of waste.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 100
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 0,05
Maximum daily site tonnage (kg/day): 0,14
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,0E-04
Release fraction to wastewater from wide dispersive use: 1,0E-05
Release fraction to soil from wide dispersive use (regional only): 1,0E-05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil

49 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Risk from environmental exposure is driven by freshwater.


No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 12
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls.

Waste combustion emissions considered in regional exposure assessment.

Conditions and measures related to external recovery of waste


This substance is consumed during use and no waste of substance is generated.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.

50 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

51 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000330

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use as a fuel- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 8a,
PROC 8b, PROC 16
Environmental Release Categories: ERC7, ESVOC SpERC
7.12a.v1

Scope of process Covers the use as a fuel (or fuel additive) and includes
activities associated with its transfer, use, equipment
maintenance and handling of waste.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 100
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 100
Maximum daily site tonnage (kg/day): 5,000
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 5,0E-03
Release fraction to wastewater from process (initial release prior to 1,0E-05
RMM):
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air

52 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

emissions and releases to soil


Risk from environmental exposure is driven by freshwater sediment.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 95
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 1,6E+05
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls.

Waste combustion emissions considered in regional exposure assessment.

Conditions and measures related to external recovery of waste


This substance is consumed during use and no waste of substance is generated.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite

53 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

technologies, either alone or in combination.


Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

54 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000329

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use in Agrochemicals uses- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 4, PROC 8a,
PROC 8b, PROC 11, PROC 13
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.11a.v1

Scope of process Use as an agrochemical excipient for application by manual


or machine spraying, smokes and fogging; including
equipment clean-downs and disposal.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 50
Fraction of Regional tonnage used locally: 2,0E-03
Annual site tonnage (tonnes/year): 0,1
Maximum daily site tonnage (kg/day): 0,27
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 9,0E-01
Release fraction to wastewater from wide dispersive use: 1,0E-02
Release fraction to soil from wide dispersive use (regional only): 9,0E-02
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil

55 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Risk from environmental exposure is driven by freshwater.


No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 22
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.

56 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

57 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000328

SECTION 1 EXPOSURE SCENARIO TITLE


Title Metal working fluids / rolling oils- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 5,
PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC
13, PROC 17
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.7c.v1

Scope of process Covers the use in formulated MWFs including transfer


operations, open and contained cutting/machining activities,
automated and manual application of corrosion protections,
draining and working on contaminated/ reject articles, and
disposal of waste oils.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 3,8
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 1,9E-03
Maximum daily site tonnage (kg/day): 5,3E-03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,5E-01
Release fraction to wastewater from wide dispersive use: 5,0E-02
Release fraction to soil from wide dispersive use (regional only): 5,0E-02
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process

58 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

release estimates used.


Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 0,47
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management

59 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

60 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000327

SECTION 1 EXPOSURE SCENARIO TITLE


Title Metal working fluids / rolling oils- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10,
PROC 13, PROC 17
Environmental Release Categories: ERC4, ESVOC SpERC
4.7a.v1

Scope of process Covers the use in formulated MWFs/rolling oils including


transfer operations, rolling and annealing activities,
cutting/machining activities, automated and manual
application of corrosion protections (including brushing,
dipping and spraying), equipment maintenance, draining and
disposal of waste oils.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 15
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 15
Maximum daily site tonnage (kg/day): 7,7E+02
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 2,0E-02
Release fraction to wastewater from process (initial release prior to 1,0E-06
RMM):
Release fraction to soil from process (initial release prior to RMM): 0

61 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Technical conditions and measures at process level (source) to prevent release


Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
Prevent discharge of undissolved substance to or recover from onsite
wastewater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 70
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 6,6E+04
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

62 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

63 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000326

SECTION 1 EXPOSURE SCENARIO TITLE


Title Lubricants- ProfessionalHigh Environmental Release
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC
13, PROC 17, PROC 18, PROC 20
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.6c.v1

Scope of process Covers the use of formulated lubricants in closed and open
systems including transfer operations, operation of engines
and similar articles, reworking on reject articles, equipment
maintenance and disposal of waste oil.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 3,7
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 1,8E-03
Maximum daily site tonnage (kg/day): 5,0E-03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,5E-01
Release fraction to wastewater from wide dispersive use: 5,0E-02
Release fraction to soil from wide dispersive use (regional only): 5,0E-02
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.

64 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Technical onsite conditions and measures to reduce or limit discharges, air


emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 0,45
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.

65 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Required removal efficiency for wastewater can be achieved using onsite/offsite


technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

66 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000325

SECTION 1 EXPOSURE SCENARIO TITLE


Title Lubricants- ProfessionalLow Environmental Release
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC
13, PROC 17, PROC 18, PROC 20
Environmental Release Categories: ERC9a, ERC9b,
ESVOC SpERC 9.6b.v1

Scope of process Covers the use of formulated lubricants in closed and open
systems including transfer operations, operation of engines
and similar articles, reworking on reject articles, equipment
maintenance and disposal of waste oil.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 3,7
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 1,8E-03
Maximum daily site tonnage (kg/day): 5,0E-03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,0E-02
Release fraction to wastewater from wide dispersive use: 1,0E-02
Release fraction to soil from wide dispersive use (regional only): 1,0E-02
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.

67 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Technical onsite conditions and measures to reduce or limit discharges, air


emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 0,45
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.

68 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Required removal efficiency for wastewater can be achieved using onsite/offsite


technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

69 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000324

SECTION 1 EXPOSURE SCENARIO TITLE


Title Lubricants- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC
13, PROC 17, PROC 18
Environmental Release Categories: ERC4, ERC7, ESVOC
SpERC 4.6a.v1

Scope of process Covers the use of formulated lubricants in closed and open
systems including transfer operations, operation of
machinery/engines and similar articles, reworking on reject
articles, equipment maintenance and disposal of wastes.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 7,3
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 7,3
Maximum daily site tonnage (kg/day): 3,7E+02
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 5,0E-03
Release fraction to wastewater from process (initial release prior to 1,0E-06
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-03
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process

70 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

release estimates used.


Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
Prevent discharge of undissolved substance to or recover from onsite
wastewater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 70
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 3,2E+04
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment

71 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

72 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000323

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use in Cleaning Agents- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 10, PROC 11, PROC 13
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.4b.v1

Scope of process Covers the use as a component of cleaning products


including pouring/unloading from drums or containers; and
exposures during mixing/diluting in the preparatory phase and
cleaning activities (including spraying, brushing, dipping,
wiping automated and by hand).

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 7
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 3,5E-03
Maximum daily site tonnage (kg/day): 9,6E-03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 2,0E-02
Release fraction to wastewater from wide dispersive use: 1,0E-06
Release fraction to soil from wide dispersive use (regional only): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process
release estimates used.

73 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Technical onsite conditions and measures to reduce or limit discharges, air


emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 0,86
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Required removal efficiency for wastewater can be achieved using onsite/offsite


technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

75 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000322

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use in Cleaning Agents- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 7, PROC 8a, PROC 8b, PROC 10, PROC 13
Environmental Release Categories: ERC4, ESVOC SpERC
4.4a.v1

Scope of process Covers the use as a component of cleaning products


including transfer from storage, pouring/unloading from drums
or containers. Exposures during mixing/diluting in the
preparatory phase and cleaning activities (including spraying,
brushing, dipping, wiping, automated and by hand), related
equipment cleaning and maintenance.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 7,5
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 7,5
Maximum daily site tonnage (kg/day): 380
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 1,0
Release fraction to wastewater from process (initial release prior to 1,0E-07
RMM):
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release

76 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Common practices vary across sites thus conservative process


release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
Prevent discharge of undissolved substance to or recover from onsite
wastewater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 70,0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 3,4E+04
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

77 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

78 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000321

SECTION 1 EXPOSURE SCENARIO TITLE


Title Uses in Coatings- Professional
Use Descriptor Sector of Use: SU 22
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 5, PROC 8a, PROC 8b, PROC 10, PROC 11, PROC
13, PROC 15, PROC 19
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.3b.v1

Scope of process Covers the use in coatings (paints, inks, adhesives, etc)
including exposures during use (including materials receipt,
storage, preparation and transfer from bulk and semi-bulk,
application by spray, roller, brush, spreader by hand or similar
methods, and film formation), and equipment cleaning,
maintenance and associated laboratory activities.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 2,4E+02
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 0,12
Maximum daily site tonnage (kg/day): 0,33
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 9,8E-01
Release fraction to wastewater from wide dispersive use: 1,0E-02
Release fraction to soil from wide dispersive use (regional only): 1,0E-02
Technical conditions and measures at process level (source) to prevent release

79 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Common practices vary across sites thus conservative process


release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 25
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all

80 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

81 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000320

SECTION 1 EXPOSURE SCENARIO TITLE


Title Uses in Coatings- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10,
PROC 13, PROC 14, PROC 15
Environmental Release Categories: ERC4, ESVOC SpERC
4.3a.v1

Scope of process Covers the use in coatings (paints, inks, adhesives, etc)
including exposures during use (including materials receipt,
storage, preparation and transfer from bulk and semi-bulk,
application by spray, roller, spreader, dip, flow, fluidised bed
on production lines and film formation) and equipment
cleaning, maintenance and associated laboratory activities.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 60
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 60
Maximum daily site tonnage (kg/day): 3,000
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 9,8E-01
Release fraction to wastewater from process (initial release prior to 2,0E-05
RMM):
Release fraction to soil from process (initial release prior to RMM): 0

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Technical conditions and measures at process level (source) to prevent release


Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater sediment.
Prevent discharge of undissolved substance to or recover from onsite
wastewater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 90,0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 8,0E+04
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

83 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

84 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000319

SECTION 1 EXPOSURE SCENARIO TITLE


Title Formulation & (re)packing of substances and mixtures-
Industrial
Use Descriptor Sector of Use: SU 3, SU 10
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 5, PROC 8a, PROC 8b, PROC 9, PROC 14, PROC 15
Environmental Release Categories: ERC2, ESVOC SpERC
2.2.v1

Scope of process Formulation, packing and re-packing of the substance and its
mixtures in batch or continuous operations, including storage,
materials transfers, mixing, tabletting, compression,
pelletisation, extrusion, large and small scale packing,
sampling, maintenance and associated laboratory activities.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 17
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 17
Maximum daily site tonnage (kg/day): 1,7E+03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 10
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (after typical onsite RMMs 1,0E-02
consistent with EU Solvent Emissions Directive requirements):
Release fraction to wastewater from process (initial release prior to 5,0E-06
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-04

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Technical conditions and measures at process level (source) to prevent release


Common practices vary across sites thus conservative process
release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
Prevent discharge of undissolved substance to or recover from onsite
wastewater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 0
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 1,1E+05
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

86 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

87 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000318

SECTION 1 EXPOSURE SCENARIO TITLE


Title Distribution of substance- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 9, PROC 15
Environmental Release Categories: ERC1, ERC2, ERC3,
ERC4, ERC5, ERC6a, ERC6b, ERC 6C,, ERC7, ESVOC
SpERC 1.1b.v1

Scope of process Loading (including marine vessel/barge, rail/road car and IBC
loading) and repacking (including drums and small packs) of
substance, including its sampling, storage, unloading
distribution and associated laboratory activities.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 140
Fraction of Regional tonnage used locally: 2,0E-03
Annual site tonnage (tonnes/year): 2,8E-01
Maximum daily site tonnage (kg/day): 1,4E+01
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 1,0E-03
Release fraction to wastewater from process (initial release prior to 1,0E-07
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process

88 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

release estimates used.


Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater.
No wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 90
Treat onsite wastewater (prior to receiving water discharge) to provide 0
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 1,3E+03
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or regional
regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management

89 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

90 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Worker


300000000317

SECTION 1 EXPOSURE SCENARIO TITLE


Title Manufacture of substance- Industrial
Use Descriptor Sector of Use: SU 3
Process Categories: PROC 1, PROC 2, PROC 3, PROC 4,
PROC 8a, PROC 8b, PROC 15
Environmental Release Categories: ERC1, ERC4, ESVOC
SpERC 1.1.v1

Scope of process Manufacture of the substance or use as a process chemical


or extraction agent. Includes recycling/ recovery, material
transfers, storage, maintenance and loading (including
marine vessel/barge, road/rail car and bulk container),
sampling and associated laboratory activities.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Worker Exposure


Product Characteristics

Contributing Scenarios Risk Management Measures

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 900
Fraction of Regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 900
Maximum daily site tonnage (kg/day): 4,5E+04
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from process (initial release prior to RMM): 1,0E-02
Release fraction to wastewater from process (initial release prior to 1,0E-05
RMM):
Release fraction to soil from process (initial release prior to RMM): 1,0E-04
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process

91 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

release estimates used.


Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soil
Risk from environmental exposure is driven by freshwater sediment.
Prevent discharge of undissolved substance to or recover from onsite
wastewater.
If discharging to domestic sewage treatment plant, no secondary
wastewater treatment required.
Treat air emission to provide a typical removal efficiency of (%) 90,0
Treat onsite wastewater (prior to receiving water discharge) to provide 32,3
the required removal efficiency of >= (%)
If discharging to domestic sewage treatment plant, no secondary 0
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.

Sludge should be incinerated, contained or reclaimed.

Conditions and Measures related to municipal sewage treatment plant


Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite 96,2
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (MSafe) based on release following 8,0E+05
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 10.000
Conditions and Measures related to external treatment of waste for disposal
During manufacturing no waste of the substance is generated.

Conditions and measures related to external recovery of waste


During manufacturing no waste of the substance is generated.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all

92 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone
or in combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

93 / 109 800001000856
DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001027

SECTION 1 EXPOSURE SCENARIO TITLE


Title Uses in Coatings - Consumer
Use Descriptor Sector of Use: SU 21
Product Categories: PC1, PC4, PC8 (excipient only), PC9a,
PC9b, PC9c, PC15, PC18, PC23, PC24, PC31, PC34
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.3c.v1

Scope of process Covers the use in coatings (paints, inks, adhesives, etc)
including exposures during use (including product transfer
and preparation, application by brush, spray by hand or
similar methods) and equipment cleaning.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 10
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 5,0E-03
Maximum daily site tonnage (kg/day): 0,014
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 9,85E-01
Release fraction to wastewater from wide dispersive use: 1,0E-02
Release fraction to soil from wide dispersive use (regional only): 5,0E-03
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

treatment (%)
Maximum allowable site tonnage (MSafe) based on release following 1,2
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or
regional regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

95 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001028

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use in Cleaning Agents - Consumer
Use Descriptor Sector of Use: SU 21
Product Categories: PC3, PC4, PC8 (excipient only), PC9a,
PC24, PC35,
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.4c.v1

Scope of process Covers general exposures to consumers arising from the use
of household products sold as washing and cleaning
products, aerosols, coatings, de-icers, lubricants and air care
products.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 0,5
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 2,5E-04
Maximum daily site tonnage (kg/day): 6,8E-04
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 9,5E-01
Release fraction to wastewater from wide dispersive use: 2,5E-02
Release fraction to soil from wide dispersive use (regional only): 2,5E-02
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2

96 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

treatment (%)
Maximum allowable site tonnage (MSafe) based on release following 6,2E-02
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or
regional regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

97 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001029

SECTION 1 EXPOSURE SCENARIO TITLE


Title Lubricants - Consumer Low Environmental Release
Use Descriptor Sector of Use: SU 21
Product Categories: PC1, PC24, PC31
Environmental Release Categories: ERC9a, ERC9b,
ESVOC SpERC 9.6d.v1

Scope of process Covers the consumer use of formulated lubricants in closed


and open systems including transfer operations, application,
operation of engines and similar articles, equipment
maintenance and disposal of waste oil.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 2,5
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 1,3E-03
Maximum daily site tonnage (kg/day): 3,4E-03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,0E-02
Release fraction to wastewater from wide dispersive use: 1,0E-02
Release fraction to soil from wide dispersive use (regional only): 1,0E-02
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Maximum allowable site tonnage (MSafe) based on release following 0,31


total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or
regional regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

99 / 109 800001000856
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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001030

SECTION 1 EXPOSURE SCENARIO TITLE


Title Lubricants - Consumer High Environmental Release
Use Descriptor Sector of Use: SU 21
Product Categories: PC1, PC24, PC31
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.6e.v1

Scope of process Covers the consumer use of formulated lubricants in closed


and open systems including transfer operations, application,
operation of engines and similar articles, equipment
maintenance and disposal of waste oil.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 2,5
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 1,3E-03
Maximum daily site tonnage (kg/day): 3,4E-03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,5E-01
Release fraction to wastewater from wide dispersive use: 5,0E-02
Release fraction to soil from wide dispersive use (regional only): 5,0E-02
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)

100 / 109 800001000856


DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Maximum allowable site tonnage (MSafe) based on release following 0,31


total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or
regional regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

101 / 109 800001000856


DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001031

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use in Agrochemicals uses - Consumer
Use Descriptor Sector of Use: SU 21
Product Categories: , PC27
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.11b.v1

Scope of process Covers the consumer use in agrochemicals in liquid and solid
forms.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 50
Fraction of Regional tonnage used locally: 2,0E-03
Annual site tonnage (tonnes/year): 0,1
Maximum daily site tonnage (kg/day): 0,27
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 9,0E-01
Release fraction to wastewater from wide dispersive use: 1,0E-02
Release fraction to soil from wide dispersive use (regional only): 9,0E-02
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Maximum allowable site tonnage (MSafe) based on release following 22
total wastewater treatment removal (kg/d)

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Assumed domestic sewage treatment plant flow (m3/d) 2.000


Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or
regional regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

103 / 109 800001000856


DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001032

SECTION 1 EXPOSURE SCENARIO TITLE


Title Use as a fuel - Consumer
Use Descriptor Sector of Use: SU 21
Product Categories: PC13
Environmental Release Categories: ERC9a, ERC9b,
ESVOC SpERC 9.12c.v1

Scope of process Covers consumer uses in liquid fuels.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 100
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 0,05
Maximum daily site tonnage (kg/day): 0,14
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 1,0E-04
Release fraction to wastewater from wide dispersive use: 1,0E-05
Release fraction to soil from wide dispersive use (regional only): 1,0E-05
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Maximum allowable site tonnage (MSafe) based on release following 12
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Conditions and Measures related to external treatment of waste for disposal


Combustion emissions limited by required exhaust emission controls.

Waste combustion emissions considered in regional exposure assessment.

Conditions and measures related to external recovery of waste


This substance is consumed during use and no waste of substance is generated.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

105 / 109 800001000856


DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001033

SECTION 1 EXPOSURE SCENARIO TITLE


Title Functional Fluids - Consumer
Use Descriptor Sector of Use: SU 21
Product Categories: PC16, PC17
Environmental Release Categories: ERC9a, ERC9b,
ESVOC SpERC 9.13c.v1

Scope of process Use of sealed items containing functional fluids e.g. transfer
oils, hydraulic fluids, refrigerants.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 20
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 0,01
Maximum daily site tonnage (kg/day): 0,027
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 5,0E-02
Release fraction to wastewater from wide dispersive use: 2,5E-02
Release fraction to soil from wide dispersive use (regional only): 2,5E-02
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2
treatment (%)
Maximum allowable site tonnage (MSafe) based on release following 2,4
total wastewater treatment removal (kg/d)

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DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Assumed domestic sewage treatment plant flow (m3/d) 2.000


Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or
regional regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

107 / 109 800001000856


DE
SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

Exposure Scenario - Consumer


300000001034

SECTION 1 EXPOSURE SCENARIO TITLE


Title Other Consumer Uses - Consumer
Use Descriptor Sector of Use: SU 21
Product Categories: PC28, PC39
Environmental Release Categories: ERC8a, ERC8d,
ESVOC SpERC 8.16.v1

Scope of process Consumer uses e.g. as a carrier in cosmetics/personal care


products, perfumes and fragrances. Note: For cosmetic and
personal care products, risk assessment only required for the
environment under REACH as human health is covered by
alternative legislation.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES
Additional Information No exposure assessment presented for human health.

Section 2.1 Control of Consumer Exposure


Product Characteristics

Product Categories OPERATIONAL CONDITIONS AND RISK MANAGEMENT


MEASURES

Section 2.2 Control of Environmental Exposure


Substance is complex UVCB.
Predominantly hydrophobic.
Amounts Used
Fraction of EU tonnage used in region: 0,1
Regional use tonnage (tonnes/year): 5
Fraction of Regional tonnage used locally: 5,0E-04
Annual site tonnage (tonnes/year): 2,5E-03
Maximum daily site tonnage (kg/day): 6,8E-03
Frequency and Duration of Use
Continuous release.
Emission Days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Other Operational Conditions affecting Environmental Exposure
Release fraction to air from wide dispersive use (regional only): 9,5E-01
Release fraction to wastewater from wide dispersive use: 2,5E-02
Release fraction to soil from wide dispersive use (regional only): 2,5E-02
Conditions and Measures related to municipal sewage treatment plant
Risk from environmental exposure is driven by freshwater.
Estimated substance removal from wastewater via domestic sewage 96,2

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SAFETY DATA SHEET
According to EC No 1907/2006 as amended as at the date of this SDS
ShellSol TD
Version 3.0 Revision Date 15.10.2019 Print Date 23.10.2019

treatment (%)
Maximum allowable site tonnage (MSafe) based on release following 0,61
total wastewater treatment removal (kg/d)
Assumed domestic sewage treatment plant flow (m3/d) 2.000
Conditions and Measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or
regional regulations.

Conditions and measures related to external recovery of waste


External recovery and recycling of waste should comply with applicable local and/or regional
regulations.

SECTION 3 EXPOSURE ESTIMATION


Section 3.1 - Health
No exposure assessment presented for human health.

Section 3.2 -Environment


The Hydrocarbon Block Method has been used to calculate environmental exposure with
the Petrorisk model.

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE


EXPOSURE SCENARIO
Section 4.1 - Health
No exposure assessment presented for human health.

Section 4.2 -Environment


Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org).

109 / 109 800001000856


DE

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