Safety Data Sheet: Shunsol Ess

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SAFETY DATA SHEET

SHUNSOL ESS
According to Regulation (EC) No. 1907/2006
Version: 2
Date: 16.11.2020

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING
1.1. Product identifier:
Product name: SHUNSOL ESS
Chemical name: Polyurethane.
1.2. Relevant identified uses of the substance or mixture and uses advised against:
Relevant identified uses: Industrial purposes only.
Uses advised against: Textile auxiliary
1.3. Details of the manufacturer of the safety data sheet:
Name: SHUNCHEER Enterprise Corporation
Address: 2F, No.54-1, Zichon St., Xinzhuang Dist, New Taipei City 242, TAIWAN
Telephone: 886-2688-1198
Fax: 886-2676-4469
E-mail: [email protected]
1.4. Emergency telephone number:
Name: SHUNCHEER Enterprise Corporation
Telephone: +886-2688-1198 (only during office hours)

2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture:
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Hazard classes/categories Hazard Statements
Acute toxicity, Oral (Category 4) H302: Harmful if swallowed.
Serious eye damage (Category 1), H318: Causes serious eye damage.

DSD/DPD-Classification according to 67/548/EEC and 1999/45/EC:


Hazard classes/categories Hazard Statements
Xn; Harmful R22: Harmful if swallowed.
R41: Causes serious eye damage.

2.2. Label elements (according to EC 1272/2008):


Hazard pictogram:

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Signal word(s): Warning
Hazard statement(s): H302: Harmful if swallowed.
H318: Causes serious eye damage.

Precautionary
statement(s):
Prevention P280 Wear protective gloves/ eye protection/ face protection.
P264 Wash skin thoroughly after handling.
Response P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately calls a POISON CENTER or doctor/ physician.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.

2.3. Other hazards:


Not applicable.

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances:
Component % Classification according to Classification according to
Directive 67/548/EEC. Regulation (EC) No. 1272/2008
[CLP]
Polyurethane 40 Xn; R22, R41 Acute Tox. 4 (Oral), H302
Eye Dam. 1, H318
CAS No. : 9009-54-9

Water 60
CAS No. : 7732-18-5

4. FIRST AID MEASURES


4.1. Description of first aid measures:
After eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
After skin contact: Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. When symptoms persist or in all cases of
doubt seek medical advice. Wash contaminated clothing before re-use.

After inhalation: Remove to fresh air. If breathing is irregular or stopped, administer artificial
respiration. Call a physician immediately.

After ingestion: If swallowed, call a poison control center or doctor immediately. Do not induce
vomiting without medical advice. Never give anything by mouth to an unconscious
person.

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4.2. Most important symptoms and effects, both acute and delayed:
Treat symptomatically.

4.3. Indication of any immediate medical attention and special treatment needed:
No data available.

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing Media:
Suitable extinguishing media:
Water spray, Foam, Dry chemical, Carbon dioxide (CO2)
5.2. Special hazards arising from the substance or mixture:
No data available.
5.3. Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures:
Keep unnecessary personnel away. Ventilate the area. Wear appropriate protective equipment and clothing
during clean-up.

6.2. Environmental precautions:


Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers or sewers, inform
appropriate authorities in accordance with local regulations.
6.3. Methods and materials for containment and cleaning up:
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13). Clean
preferably with a detergent; avoid use of solvents.
6.4. Reference to other sections:
Not applicable.

7. HANDLING AND STORAGE


7.1. Precautions for safe handling:
Store in tightly closed containers away from strong oxidizing and reducing agents. Use normal safety practices
to avoid spills and exposure.

7.2. Conditions for safe storage, including any incompatibilities:


Keep container tightly closed and store in a cool, dry well-ventilated location.
Keep away from any area where the fire hazard may be acute. Outside or detached storage is preferred.

7.3. Specific end use(s):


No data available

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Control parameters:
No data available
8.2. Exposure controls:
8.2.1. Engineering controls:
Ensure adequate ventilation, especially in confined areas.
8.2.2. Personal
protection: Eye/face
protection:
Wear as appropriate: Goggles, Face-shield
Skin/ Body protection:
Full protective clothing, chemical boots, and chemical gloves. High standards of skin care and personal
hygiene should be exercised at all times.
Respiratory protection:
Use respirator when performing operations involving potential exposure to vapour of the product. Use NIOSH
approved respiratory protection.
Control of environmental exposure:
There is no exposure limits established for this product. Trace amounts of ethylene oxide may be present in this
product. The ethylene oxide in this product is not expected to result in significant exposures or present a health
hazard.

9. PHYSICAL AND CHEMICAL PROPERTIES


9.1. Information on basic physical and chemical properties:
Form Liquid
Colour Clear
Odour Product specific
n
pH (value) 4~6 (1% Sol .)
Solidifying point: Not determined
Boiling point/ range (°C) Not determined
0
Density < 0.1 hPa at 20 C
Vapor pressure Not determined
0
Viscosity Approx. 30 mPa.s at 60 C
Solubility in water Miscible in water
Flash point Not determined
Ignition temperature >250 °C
9.1. Other information:
No data available.

10. STABILITY AND REACTIVITY


10.1. Reactivity:

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Stable at normal ambient temperature and pressure.
10.2. Chemical stability:
No decomposition if stored and applied as directed.
10.3. Possibility of hazardous reactions:
No data available.
10.4. Conditions to avoid:
Heat, flames, ignition sources and incompatibles.

11. TOXICOLOGICAL INFORMATION


11.1. Information on toxicological effects:
Acute toxicity LD50 oral rat >2,000 mg/kg
Skin corrosion/irritation no data available
Eye damage/irritation Risk of serious damage to eyes.
Sensitization: no data available
Mutagenicity: no data available
Carcinogenicity: no data available
Reproductive toxicity: no data available
STOT-single exposure: no data available
STOT-repeated exposure: no data available
Aspiration hazard: no data available
Additional Information no data available

12. ECOLOGICAL INFORMATION


12.1. Toxicity:
LC50 Fish >10 mg/l,
(Oncorhynchus mykiss)
EC50 Water >10 mg/l,
(Daphnia magna)

12.2. Persistence and degradability:


Chemical oxygen demand (COD): 2,625 mg/g
Biochemical oxygen demand (BOD): 330 mg/g
Ratio BOD/COD: 30.2 %
Assessment biodegradation and elimination (H2O)
Readily biodegradable (according to OECD criteria).Mobility in soil.

Elimination information:
>= 90 % Bismuth-active substance (mod. OECD 303A)

> 60 % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC,
C.4-C) Readily biodegradable (according to OECD criteria).
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12.3. Bio accumulative potential.
No data available.
12.4. Results of PBT and vPvB assessment:
No data available.
12.5. Other adverse effects:
The product components are not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.

13. DISPOSAL CONSIDERATIONS


13.1. Waste treatment methods:
Waste Code:
Any unused product or empty containers may be disposed of as non-hazardous in accordance with state and
federal requirements. Re-evaluation of the product may be required by the user at the time of disposal, since
the product uses, transformations, mixtures, contamination, and spillage may change the classification. If the
resulting material is determined to be hazardous, please dispose in accordance with state and federal (40 CFR
262) hazardous waste regulations.
Disposal methods:
Dispose of only in accordance with local, state, and federal regulations.
Empty containers:
Empty containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME,
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE
INJURY OR DEATH. Empty drums should be completely drained, triple-rinsed, properly bunged and promptly
returned to a drum reconditioned, or properly disposed.

14. TRANSPORT INFORMATION


In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA
14.1. UN number Not dangerous goods
14.2. UN proper shipping name Not dangerous goods
14.3. Transport hazard class(es) Not applicable
14.4. Packing Group Not applicable
14.5. Environmental hazards no
14.6. Special precautions for user Not applicable
14.7. Transport in bulk according to Not applicable
annex II of MARPOL73/78 and the IBC Code

15. REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislations specific for the substance or
mixture:
No data available.
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15.2. Chemical safety assessment:
No data available.

16. OTHER INFORMATION


This MSDS is a complement to the technical brochure of the product but does not replace it. The information and
data presented are based on our knowledge of the product as of the date 20/11/2014. Except as set forth above,
SHUNCHEER makes no warranties, whether express, implied or statutory, as to the product which is the subject of
this document. Without limiting the generality of the foregoing, SHUNCHEER makes no warranty of merchantability
of the product or of the fitness of the product for any particular purpose. Buyer assumes all risk and liability resulting
from the use or sale of the product, hither singly or in combination with other goods. The information set forth herein
is furnished free of charge and is based on technical data that SHUNCHEER believes to be reliable. It is intended for
use by persons having technical skill and at their own discretion and risk. Since conditions of use are outside
SHUNCHEER’s control, SHUNCHEER makes no warranties, express or implied, and assumes no liability in
connection with any use of this information. Nothing herein is to be taken as a license to operate or a
recommendation to infringe any patents.

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