Form Four Notes PDF
Form Four Notes PDF
Form Four Notes PDF
Skills to develop
At the end of this module, a form four student is expected to do the following:
Identify the effects of heat to the surrounding
Define heat and temperature.
Measure temperature and give its units
Calibrate a thermometer
Determine the amount of heat in a solid or liquid
Explain a change of state during heating
THERMOMEMTERS
Definition: a thermometer is an instrument used in measuring temperature.
There exists a variety of thermometers. Some are more accurate and some less accurate.
They make use of some thermometric property of certain substances.
A thermometric property is the property of a material that varies linearly with
changes in temperature. Example, change in the length of mercury column,
change in volume of a liquid, change in emf, change in volume of a gas at constant
pressure, change in the pressure of a gas at constant volume, change in the
electrical resistance of a conductor and change in the colours of a very hot object
etc.
L100 L0 100 0C
L L0
x (L100 L0 ) = 100 0C x (L L0 )
L L0
x 100 0C
L100 L0
Examples
16 cm 4 cm 12 cm
a) x 100 0C 60 0C
24 cm 4 cm 20 cm
28 cm 4 cm
b) x 100 0C 12 0C
24 cm 4 cm
2 cm 4 cm
c) x 100 0C 10 0C
24 cm 4 cm
X X 0
Generally, x 100 0C . This relationship holds for all thermometers.
X 100 X 0
TEMPERATURE SCALE
The temperature scales in common use are:
a) Celsius scale: it is also known as the centigrade scale. Its lower fixed point is at 0 0C
and upper fixed point at 100 0C. Its fundamental interval is 100 – 0 division (i.e. 100)
b) Fahrenheit scale: its temperature is measured in 0F. The lower fixed point is 32 0F and
upper fixed point 212 0F. The fundamental interval is 180 (212 – 32) divisions.
Converting from Fahrenheit to degree Celsius
Let F = temperature in Fahrenheit scale and θ = temperature in Celsius scale.
( F 32) 180(212 - 32)
( 0) 100(100 - 0)
180
180 = 100(F -32) (F -32) =
100
9 5
F=( + 32) 0 F and = ( F 32) 0 C
5 9
Example
Convert a) 37 0C to thermodynamic scale b) 200 K to 0C.
Solution
a) T = (θ + 273) K = (37 + 273) K = 310 K. b) θ = (T – 273) 0C = (200 -273) 0C = -73 0C.
Types of thermometers
There are many types of thermometers.
1. liquid-in-glass thermometer: it is consist of a length of transparent glass filled with
mercury or alcohol. It is preferred to other thermometers because it is convenient; easy to
read and portable. Its limitations are fragile and limited range.
Properties of a good thermometer
A good thermometer must be
Sensitive, accurate, easily come to thermal equilibrium with other system.
Advantages of mercury in liquid-in-glass thermometer
Does not wet glass
Coloured making it easy to be seen through glass
Good conductor of heat therefore response quickly to temperature change
Has a high boiling point and so does not evaporate easily
Expands uniformly with temperature change
Has a low specific heat capacity.
In addition to the features of a normal liquid-in-glass, the clinical thermometer has the
following extra features:
Kink (constriction): to keep mercury at its maximum level to read the body’s
temperature out of the body.
Range: it has a limited range of temperature from 35 0C or 43 0C. It is not sterilized
by boiling since its upper fixed point is 42 0C which is lower than 100 0C.
2) Resistance thermometer
It make use of the fact that the electrical resistance of metals increases with temperature.
R - R 0
x 100 0 C
R100 - R 0
It is advantageous because it responds fast to temperature change, has a wide range and
readings can be fed into a computer. Used in industries for measuring temperature of very
small substances.
4) constant-volume-gas thermometer
It uses pressure of a fixed mass of gas as its thermometric substance
P - P0
x 100 0 C
P100 - P0
It is advantageous in that it has a wide range of temperature, accurate and used to read ideal
gas temperature directly.
Its disadvantage is that: it is bulky, slow to respond to temperature change.
5) Pyrometer
Uses colours of thermal radiation from hot objects as thermometric substance.
It is advantageous because it has no contact with the object and is portable. Its disadvantage
is that it is not accurate and cannot measure low temperatures.
6) Bimetallic strip thermometer
Units: Joules per Kelvin (J K-1) or Joules per degree Celsius (J 0C-1)
Example
Calculate the heat capacity of a substance if 4200 J of heat energy is needed to raise the
temperature of the substance from 25 0C to 35 0C.
Solution
Q = 4200 J, θ1 = 25 0C, θ2 = 35 0C, C =?
Q C ( 2 - 1 )
Q 4200 4200
C = 420 J 0C 1
2 - 1 (35 - 25) 10
Example
A piece of copper of copper of mass 2 kg gains 16 kJ of heat energy and its temperature
rises from 20 0C to 40 0C. Calculate the specific heat capacity of copper.
Solution
Q 16000 J
c= = = 400 J kg 1K 1
m( 2 - 1 ) 0
(2 kg)(40 - 20) C
Procedure:
Drill two holes in the metal block; one to hold the heater and the other the
thermometer.
Using a balance, find the mass m of the metal block.
Precaution
Oil is put in the thermometer hole to ensure a good thermal contact with the metal
block.
Metal block is lagged to prevent heat lost by radiation to the surrounding.
Examples
1) A metal of mass 1.5 kg was heated from 27 0C to 47 0C in 4 minutes by a heater of 7.5
V, 10 A. rating. Calculate the specific heat capacity of the metal. State any assumption
made in your calculation.
Solution
m = 1.5 kg, 1 = 27 0C , 2 = 47 0C , t = 4 min = 240 s, V = 7.5 V, I = 10 A, c =?
Heat loss by heater = heat gain by the metal block
IVt = mc( 2 - 1 )
IVt (10 A)(7.5 V)(240 s)
c= = = 600 J kg 1 K 1
m( 2 - 1 ) 0
(1.5 kg)(47 - 27) C
Procedure
Using a balance determine the mass m1 of the copper calorimeter and stirrer.
Pour a good quantity of liquid in the calorimeter and determine the combined mass
m2 of the calorimeter and liquid. The difference of the two masses is calculated to
have the mass of liquid m
Place the calorimeter in a container and surround it with cotton to prevent heat loss
by conduction.
Insert the thermometer and heater into the liquid. Fit a cork lid to prevent heat loss
by evaporation and convection.
After taking the initial temperature θ1 of the liquid, switch on the current at the same
time with the stopwatch started. Note the voltmeter reading V and maintain a steady
A phase is different from a state. Phase is used for two states of the same substance present.
For instance, when ice starts melting, there is ice (solid state) and water (liquid state)
present. To study phase changes, a graph of temperature against time is drawn.
The melting point of a substance is the temperature at which the solid phase and the liquid
phase of the substance are in equilibrium at standard atmospheric pressure.
c) Condensation or liquefaction: change of state from gas to liquid. E.g. at night, water
vapour condenses on plant leaves and roofs of houses to form dew. It takes place when
water vapour meets a cold surface and gives out its latent heat of vapourisation to change
into liquid.
d) Sublimation: change of state from solid directly to gas. e.g camphor (naphthalene).
Form four physics notes by Nnoko Maxwell 20
e) Deposition: change of state from gas directly to solid.
HEAT TRANSFER
Heat is transferred in three main ways seen below
Conduction: is when heat flows through a heated solid through a heat current moving
through the material. You can observe conduction when heating a stove burner element or
a bar of metal, which goes from red hot to white hot.
Convection: is when heated particles transfer heat to another substance, such as cooking
something in boiling water.
Natural phenomena due to convection
There are many natural phenomena due convection
1) Land and sea breezes
During the day, the sun shines equally on land and sea. The land warms up quickly than
the sea because it has a low specific heat capacity. The air above the land warms up,
expands and becomes less dense. The warm air rises and the colder more dense air from
the sea moves in to replace it (sea breeze). During the night, the land cools faster than the
sea and its temperature soon becomes below that of the sea. Thus, the air over the sea is
warmer (hence less dense) than that over the land. This air rises and colder air from above
the land moves in to replace it (land breeze). See diagrams below.
Radiation: is when heat is transferred through electromagnetic waves, such as from the
sun. Radiation can transfer heat through empty space, while the other two methods require
some form of matter-on-matter contact for the transfer.
Black or rough surfaces absorb heat better than white or silvery surfaces. They equally
good emitters than white or silvery surfaces. In addition, the shape of a body affects how
much heat it radiates or absorbs. Spherical and cylindrical bodies tend to absorb less heat
than other shapes. This is because they present a smaller surface area. These two factors
explain why petrol tankers are often painted white and have cylindrical shape.
The diagram below is an illustration of the three ways of heat transfer.