Quiz 08

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CHEM 1020 – Fall 2023 – Quiz 08 - Key

Due 11.59 pm Saturday, April 1st


10 × 1 = 10 Points

1. How much heat is released to the surroundings when 1.5 kg of water at 100 °C cools to 25 °C?
a) −7.5 × 106 J
b) −3.1 × 105 J
c) −4.7 × 105 J
d) 7.5 × 106 J
e) 3.1 × 106 J

2. How much heat is required for an aluminum block weighing 55.0 g at 27.5 C to rise to 42.1 C?
Specific heat capacity of Al = 0.903 J/g·C.
a) 176 J
b) 225 J
c) 842 J
d) 725 J
e) 911 J

3. Which of the statements is false?


a) For a chemical reaction: ∆Erxn = Eproducts – Ereactants
b) In bomb calorimeter, all of the energy changes that occur during a chemical reaction is forced
to manifest itself as heat rather than work.
c) A bomb calorimeter is used to accurately measure ∆E of combustion reactions.
d) For many reactions, we can measure ∆Hrxn fairly simply using a coffee-cup calorimeter.
e) For a gas generating reaction, ∆Erxn < ∆Hrxn.

4. Hydrogen reacts with oxygen to form water:


2 H2 (g) + O2 (g) → 2 H2O (g) H = −483.5 kJ
What is the minimum mass of O2 (g) required to produce 226 kJ of heat?
a) 8.63 g
b) 15.0 g
c) 29.9 g
d) 9.42 g
e) 19.4 g

5. An endothermic reaction occurs in a flask. What happens to the temperature of the flask?

1
a) The temperature rises.
b) The temperature falls.
c) The temperature remains unchanged.

6. When a sample of sugar is combusted in a bomb calorimeter, the temperature rises from 25.1 to 56.2
C. What is the quantity of heat released by the combustion reaction of the sugar if the heat capacity of
the bomb calorimeter is 5.86 kJ/C?
a) −111 kJ
b) −410 kJ
c) 152 kJ
d) 122 kJ
e) −182 kJ

7. If 2.10 g of C6H12O6 is the sugar sample taken in the combustion above, what is the change in internal
energy (Erxn) for the combustion reaction?
a) −15.6 × 103 kJ
b) −21.1 × 103 kJ
c) −24.2 × 103 kJ
d) −13.3 × 103 kJ
e) −11.2 × 103 kJ

8. Calculate ∆Hrxn for the reaction:


Fe2O3 (s) + 3 CO (g) → 2 Fe (s) + 3 CO2 (g)
Use the following reactions and given ΔH’s:
3
2 Fe (s) + O2 (g) → Fe2O3 (s) ∆H = −824.2 kJ Eq 1
2

CO (g) + ½ O2 (g) → CO2 (g) ∆H = −282.7 kJ Eq 2

a) 541.5 kJ
b) −1106.9 kJ
c) 258.8 kJ
d) − kJ
e) −1672.3 kJ
9. Write an equation for the formation of NH3 (g) from its elements in their standard states and find the
standard enthalpy of formation (𝐻𝑓° ) of NH3 (g) from Appendix IIB.
For example, the equation for the formation of CO (g) from its elements in their standard states can be
written without any formatting as follows.

2
C (s, graphite) + 1/2 O2 (g) = CO (g) Standard Enthalpy of Formation = -110.5 kJ
Please write your answer in the given space. I will grade this question manually.

10. N2H4 is oxidized by N2O4 according to the following equation:


N2H4 (l) + N2O4 (g) → 2 N2O (g) + 2 H2O (g) 𝐻𝑟𝑥𝑛
°
=?
Calculate 𝐻𝑟𝑥𝑛
°
for this reaction.
a) −119.5 kJ
b) −380.2 kJ
c) −421.2 kJ
d) − kJ
e) −172.3 kJ

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