Indicate The Answer Choice That Best Completes The Statement or Answers The Question

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Practice Exam 2
Indicate the answer choice that best completes the statement or answers the question.
1. Which of the following classes of organic compound is not a component of crude oil?
a. aromatics
b. alkanes
c. alkenes
d. cycloalkanes
e. alcohols
2. Compounds used as reference standards for octane ratings of 100 and 0, respectively, are
a. isooctane and octane.
b. gasoline and diesel fuel.
c. 2,2,4-trimethylpentane and heptane.
d. octane and isooctane.
e. isooctane and 2,2,4-trimethylpentane.
3. Prior to 1975, the most common octane enhancer used in gasoline in the United States was
a. 2,2,4-trimethylpentane.
b. ethanol.
c. methanol.
d. tetraethyllead.
e. ozone.
4. Which of these pollutants are associated with gasoline and its combustion?
a. hydrocarbons
b. carbon monoxide
c. ozone
d. nitrogen oxides
e. all of these choices
5. The first stage in extracting aromatic hydrocarbons from coal is called

a. catalytic cracking.
b. pyrolysis.
c. catalytic reforming.
d. combustion.
e. fractional distillation.
6. In gas chromatography, volatile compounds in a mixture are separated by their

a. interactions with a stationary liquid phase in a column.
b. mass.
c. density.
d. diffusion rates through a semipermeable polymer
membrane.
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Practice Exam 2
e. boiling points.
7. Over 8 billion pounds of methanol are produced yearly in the United States by
a. the reaction of carbon monoxide and hydrogen gases.
b. the heating of hardwoods in the presence of water.
c. the heating of hardwoods in the presence of oxygen.
d. the heating of hardwoods in the absence of air.
e. the oxidation of ethanol.
8. Which statement about energy is false?

a. The thermal energy of nanoscale objects is a type of potential energy.
b. The chemical energy of foods and fuels is a type of potential energy.
c. Working and heating are processes that transfer energy.
d. Thermodynamics is the science of working and heating processes.
e. Chemical reactions are processes that transfer energy.
9. Thermal energy in matter is a result of

a. nanoscale particles in motion
b. the change in volume in a liquid
c. heat transfer from a hot object to a cold object
d. work done by nanoscale particles
−1 −1
10. A 20.0 g sample of aluminum (specific heat = 0.902 J g °C ) with an initial temperature of 48.6°C is heated with
427 J of energy. What is the final temperature of the sample?
a. 23.7°C
b. 74.8°C
c. 72.3°C
d. 26.2°C
e. 24.9°C
11. What is the enthalpy change for the combustion of 1.44 g C4H10 in excess oxygen?
2 C4H10(g) + 13 O2(g) 8 CO2(g) + 10 H2O(g) H° = −3788 kJ
a. −22.6 kJ
b. −93.9 kJ
c. −1.32 × 103 kJ
d. −46.9 kJ
e. −2.63 × 103 kJ
12. A 0.100 mole sample of CH4 reacts completely in a calorimeter having a heat capacity of 783 J/°C. The calorimeter
contains 254 g of water. Determine the temperature increase of the calorimeter.
CH4(g) + 2O2(g) 2H2O(g) + CO2(g) H° = −802.3 kJ
a. 43.5°C
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Practice Exam 2
b. 7.56°C
c. 10.2°C
d. 31.6°C
e. 4.35 × 10−3 °C
13. The standard enthalpies of formation for several substances are given below:
FeS2(s) = −178.2 kJ/mol FeCl2(s) = −341.8 kJ/mol
FeCl3(s) = −399.5 kJ/mol HCl(g) = −92.3 kJ/mol
HCl(aq) = −167.1 kJ/mol H2S(g) = −20.6 kJ/mol
H2O(g) = −271.8 kJ/mol
Calculate the H° for the reaction below.

2FeS2(s) + 8HCl(g) 2FeCl3(s) + 4H2S(g) + Cl2(g)
a. +149.6 kJ
b. −149.6 kJ
c. +213.4 kJ
d. −811.8 kJ
e. −881.4 kJ
14. Determine the heat of reaction for the process

TiO2(s) + 4HCl(g) TiCl4(l) + 2H2(g) + O2(g)
using the information given below:
Ti(s) + O2(g) TiO2(s) H° = −939.7 kJ

2HCl(g) H2(g) + Cl2(g) H° = −184.6 kJ

Ti(s) + 2Cl2(g) TiCl4(l) H° = −804.2 kJ
a. 233.7 kJ
b. −233.7 kJ
c. −320.1 kJ
d. 504.7 kJ
e. 320.1 kJ
15. A bomb calorimeter has a heat capacity of 675 J/°C and contains 925 g of water. If the combustion of 0.500 mole of a
hydrocarbon increases the temperature of the calorimeter from 24.26°C to 53.88°C, determine the enthalpy change per
mole of hydrocarbon.
a. −229.3 kJ
b. −269.3 kJ
c. −94.78 kJ
d. −134.6 kJ
e. −802.3 kJ

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Practice Exam 2
Answer Key
1. e
2. c
3. d
4. e
5. b
6. a
7. a
8. a
9. a
10. c
11. d
12. a
13. c
14. b
15. b

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5. The first stage in extracting aromatic hydrocarbons from coal is called

6. In gas chromatography, volatile compounds in a mixture are separated by their

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8. Which statement about energy is false?

9. Thermal energy in matter is a result of

Calculate the H° for the reaction below.

14. Determine the heat of reaction for the process

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