1. The document provides a material safety data sheet for a scale inhibitor product.
2. The product contains trisodium phosphate and ethylene glycol. Repeated or prolonged exposure may cause irritation of eyes and skin.
3. The product is a liquid that is clear to yellow in color and odorless. It is soluble in water and stable under recommended storage conditions.
1. The document provides a material safety data sheet for a scale inhibitor product.
2. The product contains trisodium phosphate and ethylene glycol. Repeated or prolonged exposure may cause irritation of eyes and skin.
3. The product is a liquid that is clear to yellow in color and odorless. It is soluble in water and stable under recommended storage conditions.
1. The document provides a material safety data sheet for a scale inhibitor product.
2. The product contains trisodium phosphate and ethylene glycol. Repeated or prolonged exposure may cause irritation of eyes and skin.
3. The product is a liquid that is clear to yellow in color and odorless. It is soluble in water and stable under recommended storage conditions.
1. The document provides a material safety data sheet for a scale inhibitor product.
2. The product contains trisodium phosphate and ethylene glycol. Repeated or prolonged exposure may cause irritation of eyes and skin.
3. The product is a liquid that is clear to yellow in color and odorless. It is soluble in water and stable under recommended storage conditions.
Main physical hazards: No classified physical hazards.
Main health hazards: Repeated or prolonged exposure may cause irritation of eyes and skin. Precautions: Avoid contact with the skin and the eyes. Wear suitable protective equipment. Keep container tightly closed. HMIS classification: Health: 1 Flammability: 0 Physical hazard: 0
Form: Liquid Color: Clear to hazy yellow Odor: None
Eye contact: Immediately flush eyes with water for 5 minutes while holding eyelids open. Seek medical attention if irritation occurs. Skin contact: Rinse with water. If symptoms persist, call a physician. Ingestion: Do not induce vomiting without medical advice. Obtain medical attention. Inhalation: Move to fresh air in case of accidental inhalation of vapors. Consult a physician if necessary.
5. FIRE-FIGHTING MEASURES
Flash point: >100 °C / >212 °F
________________________________________________________________________________________ 110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 1 of 7 Product Code: B317 Revision date: 18 August 2010
Method: Pensky-Martens CC Autoignition temperature: No data available. Flammability limits in air: Lower: No information available. Upper: No information available. Oxidizing properties: No data available
Suitable extinguishing media:
Use extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasons:
Not applicable.
Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases: Carbon oxides.
Special protective equipment for firefighters:
Wear self-contained breathing apparatus and protective suit.
Main physical hazards: No classified physical hazards.
Personal precautions: Avoid contact with skin and eyes. Wear suitable protective equipment. Methods for cleaning up: Dam up. Put into suitable containers for disposal. Environmental precautions: Prevent product from entering drains. Prevent entry into sewage.
7. HANDLING AND STORAGE
Handling: Precautions: Avoid contact with the skin and the eyes. Wear suitable protective equipment. Keep container tightly closed. Safe handling advice: Wear suitable protective equipment. Technical measures/ Keep away from direct sunlight. Keep container tightly closed. storage conditions: Packaging requirements: Keep in properly labelled containers. Incompatible products: No information available.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures Control the source. Enclosure of the process. Other suitable methods. to reduce exposure: Hygiene measures: Avoid prolonged or repeated contact with skin. Wear suitable protective equipment. Respiratory protection: None normally needed Eye protection: Tightly fitting safety goggles. Hand protection: Neoprene. Nitrile. Butyl. PVC. Skin and body protection: Chemical resistant apron. ________________________________________________________________________________________ 110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 2 of 7 Product Code: B317 Revision date: 18 August 2010
ACGIH - TLVs OSHA - PELs Com ponent TWA / Ceiling STEL ACGIH - Skin TWA / C STEL Final PELs - Skin Trisodium ortho phosphate - - - - - - Ethane-1,2-diol 100 mg/m3 C - - - - -
Particles Not Otherw ise Regulated/Specified [PNOR or PNOS] (insoluble or poorly soluble): - OSHA PEL's for Inert or Nuisance Dust are covered by PNOR limits: respirable fraction: 5 mg/m3; total dust 15 mg/m3. - ACGIH PNOS Recommendations: airborne concentrations should be kept below 3 mg/m3, respirable particulate, and 10 mg/m3, inhalable particles.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: Liquid Color: Clear to hazy yellow Odor: None Odor threshold: No information available. pH: 4 Boiling point/range: No data available. Flash point: >100 °C / >212 °F Method: Pensky-Martens CC. Flammability limits in air: Lower: No information available. Upper: No information available. Bulk density: Not applicable. Melting point/range: No data available. Decomposition temperature: No data available. Solubility: Water solubility: Soluble. Fat solubility: No information available. Partition coefficient Not applicable. (n-octanol/water): Relative density: No information available Vapor pressure: Similar to water. Vapor density: No data available. Viscosity: No data available. Evaporation rate: Similar to water. % Volatile (VOC): No data available.
10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.
Conditions to avoid: Freezing.
Incompatibility with other substances:
None known.
Hazardous decomposition products:
Carbon oxides.
________________________________________________________________________________________ 110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 3 of 7 Product Code: B317 Revision date: 18 August 2010
Hazardous polymerization: Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
PRODUCT TOXICOLOGICAL INFORMATION
Information given is based on data on the components and the toxicology of similar products.
Acute Health Hazard
Eye contact: May be mildly irritating.
Skin contact: Prolonged skin contact may cause skin irritation. Ingestion: Swallowing large amounts may be harmful. Inhalation: No effect expected. Sensitization - lung: Not known to cause allergic reaction. Sensitization - skin: Not known to cause allergic reaction.
Chronic Health Hazard
Carcinogenic effects: Not listed by IARC, USA NTP, or USA OSHA.
Mutagenic effects: See COMPONENT TOXICOLOGICAL INFORMATION below. Teratogenic effects: Not known to cause birth defects or have a deleterious effect on a developing fetus. Reproductive toxicity: Not known to adversely affect reproductive functions and organs. Target organ effects: See COMPONENT TOXICOLOGICAL INFORMATION below.
Com ponent IARC Group 1 or 2: ACGIH - OSHA Listed NTP:
Carcinogens: Carcinogens Trisodium ortho phosphate - - - - Ethane-1,2-diol - A4 - Not Classifiable - - as a Human Carcinogen (aerosol)
Com ponent OTHER TOXICOLOGICAL INFORMATION
Ethane-1,2-diol Mutagen - somatic cells. Long term exposure by inhalation in controlled animal studies show ed sense organ effect, especially eyes, w ith corneal damage. Large oral doses caused liver, kidney, ureter and bladder effects in animal studies. Fetotoxic and teratogenic effects observed in controlled animal studies. Skin sensitivity: tw o cases of sensitization to ethylene glycol in occupational setting have been reported. Central nervous system (CNS) depressant.
12. ECOLOGICAL INFORMATION
PRODUCT INFORMATION
________________________________________________________________________________________ 110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 4 of 7 Product Code: B317 Revision date: 18 August 2010
Ethane-1,2-diol Bioaccum ulation: Does not bioaccumulate Persistence / degradability: Readily biodegradable. Freshw ater Fish Species EC50 96 h (Selenastrum capricornutum) = 6500 - 13000 mg/L Data Freshw ater Fish Species LC50 96 h (Oncorhynchus mykiss) = 41000 mg/L Data LC50 96 h (Oncorhynchus mykiss) = 14-18 ml/L LC50 96 h (Lepomis macrochirus) = 27540 mg/L LC50 96 h (Oncorhynchus mykiss) = 40761 mg/L LC50 96 h (Pimephales promelas) = 40000-60000 mg/L LC50 96 h (Poecilia reticulata) = 16000 mg/L LC50 96 h (Oncorhynchus mykiss) = 41000 mg/L Water Flea Data EC50 48 h (w ater flea) = 46300 mg/L Other inform ation: Listed on PLONOR list of OSPAR
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
Dispose of in accordance with local regulations.
Contaminated packaging: If reusable containers are used, send them back to the product supplier, after the required rinsing.
EPA RCRA Hazardous Waste Code:
None
14. TRANSPORT INFORMATION
DOT: CERCLA RQ: None
Hazard class: Not regulated.
Proper shipping name: Not regulated Label(s): None required.
IMDG/IMO Shipping name: Not regulated.
UN number: None
ICAO/IATA Shipping name: Not regulated.
UN number: None
TDG (Canada): Shipping name: Not regulated. PIN: None
________________________________________________________________________________________ 110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 5 of 7 Product Code: B317 Revision date: 18 August 2010
Note 1: For the applicab le placard selection refer to the appropriate transport regulations; the selection may vary depending on the cargo size and categories of other hazardous materials in the cargo.
15. REGULATORY INFORMATION
International Chemical Inventories
USA, Toxic Substances Control This product complies with TSCA requirements. Act inventory (TSCA): Canada, Domestic Substance This product complies with DSL requirements. List (DSL): U.S.A. Regulations
OSHA Hazard Communication Standard:
(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)
EPA RCRA Hazardous Waste Code:
None
EPA, Sections 311 and 312 - Material Safety Data Sheet Requirements (40 CFR 370):
Immediate (Acute) Health Hazard: None
Delayed (Chronic) Health Hazard: None Fire Hazard: None Sudden Release or Pressure Hazard: None Reactive Hazard: None
EPA, Sections 313 - List of Toxic Chemicals (40 CFR 372):
This product contains the following substance(s), which appear(s) on the List of Toxic Chemicals:
Additional Regulatory Information
Trisodium ortho phosphate EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): None CERCLA/SARA - Hazardous Substances and their RQs: 2270 kg final RQ 5000 lb final RQ EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None California Proposition 65: None Ethane-1,2-diol EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): Listed CERCLA/SARA - Hazardous Substances and their RQs: 2270 kg final RQ 5000 lb final RQ EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None California Proposition 65: None
International Hazard Class
WHMIS Hazard Class: Non-controlled product.
________________________________________________________________________________________ 110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 6 of 7 Product Code: B317 Revision date: 18 August 2010
Current references: 1. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. American Conference of Governmental Industrial Hygienists, Cincinnati OH. 2. IARC Monograms on the Evaluation of the Carcinogenic Risk of Chemicals to Man. World Health Organization, International Agency for Research on Cancer. Geneva, Switzerland. 3. Annual Report on Carcinogens. National Toxicology Program. U.S. Department of Heath and Human Services, Pub lic Health Service. 4. NIOSH Registry of Toxic Effects of Chemical Substances (RTECS). National Institute for Occupational safety and Health. Cincinnati, OH. 5. LOLI Database.
Explanation of terms: ACGIH: American Conference of Governmental Industrial Hygienist ACGIH-TL: Threshold Limit Value DSL: Domestic Substance List HMIRC: Hazardous Materials Information Review Commission IARC: International Agency for Research on Cancer NTP: National Toxicology Program NIOSH: National Institute of Occupational Safety & Health NIOSH-REL: Recommended Exposure Limit OSHA: Occupational Safety & Health Administration OSHA-PEL: Permissible Exposure Limit TSCA: Toxic Substance Control Act (Inventory)
Occupational Exposure Limits indicators: TWA - Time Weighted Average; STEL - Short Term Limit; C - Ceiling Limit;units: [mg/m 3]
ACGIH Notations: "Skin" refers to the potential significant contribution to the overall exposure by the cutaneous route, including mucous membranes and the eyes, either by contact with vapors or by direct skin contact with the substance. "A" notation indicates carcinogenicity as follows: ACGIH classification: A1 - Confirmed Human Carcinogen; A2 - Suspected Human Carcinogen; A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans; A4 - Not Classifiable as a Human Carcinogen; A5 - Not suspected as a Human Carcinogen. "SEN" refers to the potential for an agent to product sensitization as confirmed by human and animal data.
Section(s) revised: 2, 4, 11
Prepared by: Chemical Regulatory Compliance (CRC)
Revision date: 18 August 2010
The information and recommendations contained herein are based upon tests believed to be reliable. How ever, Schlumberger does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. Schlumberger assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits arising from the use of these data. No w arranty against infringement of any patent, copyright or trademark is made or implied.
End of the Material Safety Data Sheet
________________________________________________________________________________________ 110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 7 of 7
A Consumerýs Dictionary of Household, Yard and Office Chemicals: Complete Information About Harmful and Desirable Chemicals Found in Everyday Home Products, Yard Poisons, and Office Polluters
A Consumerýs Dictionary of Household, Yard and Office Chemicals: Complete Information About Harmful and Desirable Chemicals Found in Everyday Home Products, Yard Poisons, and Office Polluters
