MATERIAL SAFETY DATA SHEET

# 111 ULTRASONIC WATCH CLEANING SOLUTION

PCN(s): 112, 275 Publication Date: 11 / 11 /02 REV: E
1. SUPPLIER AND EMERGENCY INFORMATION Emergency Phone Numbers:
L&R Manufacturing Company Product Information For emergencies involving a spill, leak,
577 Elm Street, P.O. Box 607 Call: 201-991-5330 fire or accident contact:
Kearny, NJ 07032 - 0607 USA CHEMTREC - 800-424-9300
within the United States or
703-527-3887 for international collect calls.
2. COMPOSITION/INFORMATION ON INGREDIENT
Component CAS Number Percentage
Stoddard Solvent 8052-41-3 60-70
VM&P Naphtha 8032-32-4 15-20
Oleic Acid 112-80-1 5 -10
Isopropanolamine 78-96-6 1-5
2 Propoxyethanol 2807-30-9 1-5
Ammonium Hydroxide 1336-21-6 1-5
3. HAZARDS IDENTIFICATION
Physical appearance and odor: Pale Amber liquid with ammonia type odor
A: WARNING STATEMENT:
Good industrial hygiene practices should be used when handling this product.
Acute Eyes: Direct contact causes irritation, redness and possible tearing.
Acute Skin: Prolonged or repeated contact causes redness, and drying of the skin.
Acute Inhalation: Breathing high concentrations of vapors or mists may cause irritation to the nose and drowsiness.
Acute Ingestion: Expected to cause nausea dizziness, drowsiness, irritation of the digestive tract.
B: POTENTIAL HEALTH EFFECTS:
Chronic Effects: This product does not contain any ingredient designated by IARC, NTP, ACGIH or OSHA as probable or
suspected human carcinogens.
4. FIRST AID MEASURES
Eye Exposure: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek medical attention.
Skin Exposure: Wash thoroughly with water. If irritation or redness develops, seek medical attention.
Inhalation: If respiratory irritation or distress occurs, move victim to fresh air. Seek medical attention if respiratory irritation or
distress continues.
Ingestion: Seek immediate medical attention. DO NOT INDUCE VOMITING.
MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE: Skin contact may aggravate existing skin disease.

5. FIRE FIGHTING MEASURES

FIRE HAZARD DATA:
FLASH POINT: 82 o F ( 27.8o C) METHOD USED: Tag Closed Cup
Flammability limits ( vol/vol% ) : Lower: No Data Upper: No Data
Extinguishing Media: Extinguish with dry chemical, CO2 or a BC/ABC extinguisher
Special Fire Fighting Procedures: None known
Unusual Fire and Explosion Hazards: Product will burn under fire conditions. Closed containers may explode due to build up of
pressure when exposed to extreme heat.
Hazardous Decomposition Materials: ( under fire conditions ) Oxides of nitrogen and carbon.
6. ACCIDENTAL RELEASE MEASURES
Cleanup and Disposal of Spill: Ventilate area of spill, use non-reactive material to pick up spill. Dispose of in accordance with
local, state and federal regulations.
Environmental and Regulatory Reporting: Not required
7. HANDLING AND STORAGE
Minimum/Maximum Storage Temperatures: 39 to 100 o F. Protect from freezing. Freezing may cause separation of the
product. If product is allowed to return to room temperature and shaken, it may return to its original
state.
HANDLING: AVOID CONTACT WITH SKIN, EYES OR CLOTHING
8. EXPOSURE CONTROL/PERSONAL PROTECTION
General: These recommendations provide general guidance for handling of this product. Because specific work environments and
material handling practices vary, safety procedures should be developed for each intended application. When
developing safe handling procedures, do not overlook the need to clean and dispose of the material. Waste resulting
from the use of this product should be handled in accordance with Section 13: Disposal Considerations.

Exposure Guidelines: Exposure limits are recommended worker breathing limits. The following limits apply to this material:

INGREDIENTS LIMITS INGREDIENTS LIMITS

Stoddard Solvent 100 ppm OSHA/ TWA 2-Propoxyethanol None established
VM&P Naphtha 300 ppm OSHA/ ACGIH TWA Ammonium Hydroxide 25o Be 50 ppm (as ammonia)
Oleic Acid None established Isopropanolamine None established
8. EXPOSURE CONTROL PERSONAL PROTECTION, CONTINUED
Engineering Controls: Normal room ventilation
Respiratory Controls: For reasonable uses of this material, respiratory protection should not be necessary.
Eye/Face Protection: Safety glasses to protect from splashing
Skin Protection: Rubber or plastic gloves to avoid drying and irritation to the skin.
Work Practice Control: Normal hygiene in the work area should be taken when working with or handling this product.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical Appearance: Pale yellow to amber Freezing Point Range: < 32 O F
Odor: Ammonia Boiling Point: > 212o F
pH: 10.5 Vapor Pressure: N/E
Specific Gravity: 0.79 Vapor Density: N/E
Water Solubility: Forms an emulsion Percent Volatile: Approx. 70%
Melting Point Range: N/A V.O.C. (Calculated): 5.67 lbs/gal or 679.7 g/l

10. STABILITY AND REACTIVITY

Chemical Stability: This material is stable under normal handling and storage conditions as described in Section 7.
Conditions to be avoided: Heat, open flame. Materials/Chemicals to be avoided: Strong acids.
Decomposition type: Thermal Oxides of carbon and nitrogen Hazardous Polymerization: WILL NOT OCCUR
Avoid the following to inhibit hazardous polymerization: NOT APPLICABLE
11. TOXICOLOGICAL INFORMATION
Acute Eye Irritation: Irritating to eyes. Acute Skin Irritation: No test data found for
product
Acute Dermal Toxicity: No test data found for product. Acute Respiratory Irritation: No test data found for product
Acute Inhalation Toxicity: No test data found for product.
Acute Oral Toxicity: LD50 (rat) Stoddard Solvent .> 5 gm/kg 2-Propoxyethanol = 3089 mg/kg
VM&P Naphth > 5 gm/kg Ammonium Hydroxide 25o Be = 350 mg/kg
Oleic Acid > 5 gm/kg Isopropanolamine = 2098 mg/kg
Chronic Toxicity: This product does not contain any substances that are considered by OSHA, NTP, IARC OR ACGIH to be a
probable or suspected human carcinogens. No additional test data was found for this product.
12. ECOLOGICAL INFORMATION
Ecotoxicological Information: No data found.
13. DISPOSAL CONSIDERATIONS
This material is a flammable liquid and must be disposed in accordance with all local, state and federal regulations.
IT CAN NOT BE DISPOSED OF IN A SANITARY SEWER SYSTEM.
14. TRANSPORTATION INFORMATION
For domestic ground shipments of containers of 1 gallon or less, this material is listed as ORM-D. For all other containers :
FLAMMABLE LIQUID n.o.s. ( Contains Naphtha, Petroleum ), 3, UN 1993, Packing group III.
Do not stack cartons more than five high.

15. REGULATORY INFORMATION

Inventory Issues: All components of this product are listed on the U.S. TSCA and Canadian DSL, chemical listings.

16. OTHER INFORMATION

National Fire Protection Association Hazard Rating, NFPA
Health Flammability Reactivity General
2 3 0 --

MSDS CHANGES
REV DATE DESCRIPTION OF CHANGE
A 02/02/99 Changed to ANSI MSDS format
B 08/08/99 Changed wording of section 3 A
C 04/17/00 Revised wording of section 15
D 02/20/01 Revised shipping description section 14
E 09/21/01 Updated Corporate Logo

Disclaimer: The information herein is given in good faith but no warranty expressed or implied is made.
Prepared By: L&R Manufacturing Company Date: 03/01/99
Product Name: # 111 ULTRASONIC WATCH CLEANING SOLUTION