Cambridge IGCSE Notes Chemistry Topic 2

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YOUR NOTES
IGCSE Chemistry CIE 
2. Atoms, Elements & Compounds
CONTENTS
2.1 Atomic Structure & the Periodic Table
2.1.1 Elements, Compounds & Mixtures
2.1.2 Atomic Structure
2.1.3 Electronic Configuration
2.1.4 Isotopes
2.2 Ions & Ionic Bonds
2.2.1 Ions & Ionic Bonds
2.2.2 Ionic Bonds & Lattice Structure
2.2.3 Properties of Ionic Compounds
2.3 Simple Molecules & Covalent Bonds
2.3.1 Covalent Bonds
2.3.2 Molecules & Compounds
2.3.3 Properties of Simple Molecular Compounds
2.4 Giant Structures
2.4.1 Diamond & Graphite
2.4.2 Silicon(IV) Oxide
2.4.3 Metallic Bonding
Page 1 of 45
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2.1 Atomic Structure & the Periodic Table YOUR NOTES

2.1.1 Elements, Compounds & Mixtures
Elements, Compounds & Mixtures

Elements, compounds and mixtures
All substances can be classified into one of these three types
Element
A substance made of atoms that all contain the same number of protons and cannot be
split into anything simpler
There are 118 elements found in the Periodic Table
Compound
A pure substance made up of two or more elements chemically combined
There is an unlimited number of compounds
Compounds cannot be separated into their elements by physical means
E.g. copper(II) sulfate (CuSO4), calcium carbonate (CaCO3), carbon dioxide (CO2)
Mixture
A combination of two or more substances (elements and/or compounds) that are not
chemically combined
Mixtures can be separated by physical methods such as filtration or evaporation
E.g. sand and water, oil and water, sulfur powder and iron filings
Particle diagram showing elements, compounds and mixtures
Page 2 of 45
2.1.2 Atomic Structure YOUR NOTES
Atomic Structure
All substances are made of tiny particles of matter called atoms which are the building
blocks of all matter
Each atom is made of subatomic particles called protons, neutrons, and electrons
The protons and neutrons are located at the centre of the atom, which is called the nucleus
The electrons move very fast around the nucleus in orbital paths called shells
The mass of the electron is negligible, hence the mass of an atom is contained within the
nucleus where the protons and neutrons are located
The structure of the carbon atom
Page 3 of 45
Protons, Neutrons & Electrons YOUR NOTES
The size of atoms is so tiny that we can't really compare their masses in conventional units 
such as kilograms or grams, so a unit called the relative atomic mass is used
One relative atomic mass unit is equal to 1/12th the mass of a carbon-12 atom.
All other elements are measured relative to the mass of a carbon-12 atom, so relative
atomic mass has no units
Hydrogen for example has a relative atomic mass of 1, meaning that 12 atoms of hydrogen
would have exactly the same mass as 1 atom of carbon
The relative mass and charge of the sub-atomic particles are shown below:
Table of Subatomic Particles
 Exam Tip
Knowing the exact mass of an electron is not in the specification and saying it is
almost nothing or negligible will be sufficient. It does, however, sometimes appear in
particle identification questions, but you can usually deduce that it is the electrons
from other information in the question.
Defining Proton Number

The atomic number (or proton number) is the number of protons in the nucleus of an atom
The symbol for atomic number is Z
It is also the number of electrons present in a neutral atom and determines the position of
the element on the Periodic Table
Page 4 of 45
Defining Mass Number YOUR NOTES
The Nucleon number (or mass number) is the total number of protons and neutrons in the 
nucleus of an atom
The symbol for nucleon number is A
The nucleon number minus the proton number gives you the number of neutrons of an
atom
Note that protons and neutrons can collectively be called nucleons.
The atomic number and mass number of an element can be shown using atomic notation
The Periodic Table shows the elements together with their atomic (proton) number at the
top and relative atomic mass at the bottom - there is a difference between relative atomic
mass and mass number, but for your exam, you can use the relative atomic mass as the
mass number (with the exception of chlorine)
Diagram showing atomic notation
Atomic notation for carbon
 Exam Tip
Both the atomic number and the relative atomic number (which you can use as the
mass number) are given on the Periodic Table but it can be easy to confuse them.
Think MASS = MASSIVE, as the mass number is always the bigger of the two
numbers, the other smaller one is thus the atomic / proton number. Beware that
some Periodic Tables show the numbers the other way round with the atomic
number at the bottom!
Deducing protons, neutrons & electrons

Finding the protons
Page 5 of 45
The atomic number of an atom and ion determines which element it is YOUR NOTES
Therefore, all atoms and ions of the same element have the same number of protons 
(atomic number) in the nucleus
E.g. lithium has an atomic number of 3 (three protons) whereas beryllium has atomic
number of 4 (four protons)
The number of protons equals the atomic (proton) number
The number of protons of an unknown element can be calculated by using its mass number
and number of neutrons:
Mass number = number of protons + number of neutrons
Number of protons = mass number – number of neutrons
Finding the electrons
An atom is neutral and therefore has the same number of protons and electrons
Finding the neutrons
The mass and atomic numbers can be used to find the number
of neutrons in ions and atoms:
Number of neutrons = mass number – number of protons
 Worked Example
Determine the number of protons, electrons and neutrons in an atom of element X
with atomic number 29 and mass number 63
Answer:
The number of protons of element X is the same as the atomic number
Number of protons = 29
The neutral atom of element X therefore also has 29 electrons
The atomic number of an element X atom is 29 and its mass number is 63
Number of neutrons = mass number – number of protons
Number of neutrons = 63 – 29
Number of neutrons = 34
Page 6 of 45
2.1.3 Electronic Configuration YOUR NOTES
Page 7 of 45
Electronic Configuration YOUR NOTES
Electronic configuration 
We can represent the structure of the atom in two ways: using diagrams called electron
shell diagrams or by writing out a special notation called the electronic configuration (or
electronic structure or electron distribution)
Electron shell diagrams
Electrons orbit the nucleus in shells (or energy levels) and each shell has a different amount
of energy associated with it
The further away from the nucleus, the more energy a shell has
Electrons fill the shell closest to the nucleus
When a shell becomes full of electrons, additional electrons have to be added to the next
shell
The first shell can hold 2 electrons
The second shell can hold 8 electrons
For this course, a simplified model is used that suggests that the third shell can hold 8
electrons
For the first 20 elements, once the third shell has 8 electrons, the fourth shell begins to
fill
The outermost shell of an atom is called the valence shell and an atom is much more stable
if it can manage to completely fill this shell with electrons
A simplified model showing the electron shells

The arrangement of electrons in shells can also be explained using numbers
Instead of drawing electron shell diagrams, the number of electrons in each electron shell
can be written down, separated by commas
This notation is called the electronic configuration (or electronic structure)
E.g. Carbon has 6 electrons, 2 in the 1st shell and 4 in the 2nd shell
Its electronic configuration is 2,4
Electronic configurations can also be written for ions
E.g. A sodium atom has 11 electrons, a sodium ion has lost one electron, therefore has
10 electrons; 2 in the first shell and 8 in the 2nd shell
Page 8 of 45
Its electronic configuration is 2,8 YOUR NOTES
The Electronic Configuration of the First Twenty Elements 
Note: although the third shell can hold up to 18 electrons, the filling of the shells follows a more
complicated pattern after potassium and calcium. For these two elements, the third shell holds
8 and the remaining electrons (for reasons of stability) occupy the fourth shell first before filling
the third shell.
Page 9 of 45
Exam Tip YOUR NOTES
 You need to be able to write the electronic configuration of the first twenty elements

and their ions. You may see electronic configurations using full stops or '+' signs
instead of commas. You would not be penalised for using full stops.
Page 10 of 45
Electron Shells & The Periodic Table YOUR NOTES
There is a clear relationship between the electronic configuration and how the Periodic 
Table is designed
The number of notations in the electronic configuration will show the number of occupied
shells of electrons the atom has, showing the period in which that element is in
The last notation shows the number of outer electrons the atom has, showing the group
that element is in (for elements in Groups I to VII)
Elements in the same group have the same number of outer shell electrons
The electronic configuration for chlorine
Period: The red numbers at the bottom show the number of notations which is 3, showing that a
chlorine atom has 3 occupied shells of electrons and is in Period 3
Group: The final notation, which is 7 in the example, shows that a chlorine atom has 7 outer
electrons and is in Group VII
The position of chlorine on the Periodic Table
Page 11 of 45
In most atoms, the outermost shell is not full and therefore these atoms react with other YOUR NOTES
atoms in order to achieve a full outer shell of electrons (which would make them more 
stable)
In some cases, atoms lose electrons to entirely empty this shell so that the next shell below
becomes a (full) outer shell
All elements wish to fill their outer shells with electrons as this is a much more stable
configuration
The noble gases
The atoms of the Group VIII elements (the noble gases) all have a full outer shell of electrons
All of the noble gases are unreactive as they have full outer shells and are thus very stable
The noble gases are on the Periodic Table in Group 8/0
 Exam Tip
The electrons in the outer shell are also known as valency electrons.
Page 12 of 45
2.1.4 Isotopes YOUR NOTES

Defining Isotopes
Isotopes are different atoms of the same element that contain the same number of
protons but a different number of neutrons
The symbol for an isotope is the chemical symbol (or word) followed by a dash and then the
mass number
So C-14 ( or carbon-14) is the isotope of carbon which contains 6 protons, 6 electrons and
14 - 6 = 8 neutrons
It can also be written as 14C or 146 C
The Atomic Structure and Symbols of the Three Isotopes of Hydrogen
Page 13 of 45
Why Isotopes Share Properties YOUR NOTES
EXTENDED 
Isotopes of the same element display the same chemical characteristics
This is because they have the same number of electrons in their outer shells and, therefore,
the same electronic configuration and this is what determines an atom's chemistry
The difference between isotopes is the number of neutrons which are neutral particles
within the nucleus and add mass only
The difference in mass affects the physical properties, such as density, boiling point and
melting point
Isotopes are identical in appearance, so a sample of C-14 would look no different from C-
12
Water made from deuterium oxide is known as 'heavy' water, and has a relative formula of
mass 20, compared to 18 for water, so it is 20% heavier, but it would look, taste and feel just
like normal water
However, it wouldn't be a good idea to drink it because it is toxic as it interferes with
biochemical reactions in your cells!
Page 14 of 45
Calculating Relative Atomic Mass YOUR NOTES
EXTENDED 
Relative Atomic Mass

The symbol for the relative atomic mass is Ar
The relative atomic mass for each element can be found in the Periodic Table along with the
atomic number
The atomic number is shown above the atomic symbol and the relative atomic mass is
shown below the atomic symbol
Atoms are too small to accurately weigh but scientists needed a way to compare the
masses of atoms
The carbon-12 is used as the standard atom and has a fixed mass of 12 units
It is against this atom which the masses of all other atoms are compared
Relative atomic mass (Ar) can therefore be defined as:
the average mass of the isotopes of an element compared to 1/12th of the mass of
an atom of 12C
The relative atomic mass of carbon is 12
The relative atomic mass of magnesium is 24 which means that magnesium is twice as
heavy as carbon
The relative atomic mass of hydrogen is 1 which means it has one-twelfth the mass of
one carbon-12 atom
The relative atomic mass of an element can be calculated from the mass number and
relative abundances of all the isotopes of a particular element using the following
equation:
( % of isotope 1 x mass number of isotope 1) + ( % of isotope 2 x mass number of isotope 2)
Ar =
100
The top line of the equation can be extended to include the number of different isotopes of
a particular element present.
Example
The table shows information about the isotopes in a sample of rubidium
(72 x 85) + (28 x 87)

Ar = = 85 . 6
100
Page 15 of 45
Is mass number and relative atomic mass the same thing? YOUR NOTES
On the Periodic Table provided in your exam you will see that lithium has a relative atomic 
mass of 7
Although it seems that this is the same as the mass number, they are not the same thing
because the relative atomic mass is a rounded number
Relative atomic mass takes into account the existence of isotopes when calculating the
mass
Relative atomic mass is an average mass of all the isotopes of that element
For simplicity relative atomic masses are often shown to the nearest whole number
The relative atomic mass of lithium to two decimal places is 6.94 when rounded to the
nearest whole number, the RAM is 7, which is the same as the mass number shown on this
isotope of lithium
Page 16 of 45
2.2 Ions & Ionic Bonds YOUR NOTES

2.2.1 Ions & Ionic Bonds
Page 17 of 45
The Formation of Ions YOUR NOTES
An ion is an electrically charged atom or group of atoms formed by the loss or gain of 
electrons
An atom will lose or gain electrons to become more stable
The loss or gain of electrons takes place to gain a full outer shell of electrons which is a
more stable arrangement of electrons
The electronic configuration of an ion will be the same as that of a noble gas – such as
helium, neon and argon
Formation of positively charged sodium ion
Page 18 of 45
YOUR NOTES
Formation of negatively charged chloride ion

Ionisation of metals and non-metals
Metals: all metals can lose electrons to other atoms to become positively charged ions,
known as cations
Non-metals: all non-metals can gain electrons from other atoms to become negatively
charged ions, known as anions
Page 19 of 45
The Formation of Ionic Bonds YOUR NOTES
Ionic compounds are formed when metal atoms react with non-metal atoms 
Metal atoms lose their outer electrons which the non-metal atoms gain to form positive
and negative ions
The positive and negative ions are held together by strong electrostatic forces of
attraction between opposite charges
This force of attraction is known as an ionic bond and they hold ionic compounds together
Dot-and-cross diagrams
Dot and cross diagrams are diagrams that show the arrangement of the outer-shell
electrons in an ionic or covalent compound or element
The electrons are shown as dots and crosses
In a dot and cross diagram:
Only the outer electrons are shown
The charge of the ion is spread evenly which is shown by using brackets
The charge on each ion is written at the top right-hand corner
Electrostatic forces between the positive Na ion and negative Cl ion
Page 20 of 45
Ionic Bonds between Group I & Group VII Elements YOUR NOTES
Example: Sodium Chloride, NaCl 
Sodium chloride ionic bonding

Explanation
Sodium is a Group I metal so will lose one outer electron to another atom to gain a full outer
shell of electrons
A positive sodium ion with the charge 1+ is formed
Chlorine is a Group VII non-metal so will need to gain an electron to have a full outer shell of
electrons
One electron will be transferred from the outer shell of the sodium atom to the outer shell of
the chlorine atom
A chlorine atom will gain an electron to form a negatively charged chloride ion with a charge
of 1-
Page 21 of 45
The oppositely charged ions are held together by strong electrostatic forces of attraction YOUR NOTES
The ionic compound has no overall charge 

Formula of ionic compound: NaCl
Page 22 of 45
2.2.2 Ionic Bonds & Lattice Structure YOUR NOTES
The Lattice Structure of Ionic Compounds

EXTENDED
Lattice structure
Ionic compounds have a giant lattice structure
Lattice structure refers to the arrangement of the atoms of a substance in 3D space
In lattice structures, the atoms are arranged in an ordered and repeating fashion
The lattices formed by ionic compounds consist of a regular arrangement of alternating
positive and negative ions
The lattice structure of NaCl
Page 23 of 45
Ionic Bonds between Metallic & Non-Metallic Elements YOUR NOTES
EXTENDED 
Ionic compounds
Ionic compounds are formed when metal atoms and non-metal atoms react
The ionic compound has no overall charge
Example: Magnesium Oxide, MgO
Diagram showing the dot-and-cross diagram of magnesium oxide

Explanation
Magnesium is a Group II metal so will lose two outer electrons to another atom to have a full
outer shell of electrons
A positive ion with the charge 2+ is formed
Oxygen is a Group VI non-metal so will need to gain two electrons to have a full outer shell
of electrons
Two electrons will be transferred from the outer shell of the magnesium atom to the outer
shell of the oxygen atom
Oxygen atom will gain two electrons to form a negative ion with charge 2-
Magnesium oxide has no overall charge
Formula of ionic compound: MgO
 Exam Tip
When drawing dot and cross diagrams, you only need to show the outer shell of
electrons. Remember to draw square brackets and include a charge for each ion.
Make sure the overall charge is 0; you may need to include more than one positive or
negative ion to ensure the positive and negative charges cancel each other out.
Page 24 of 45
2.2.3 Properties of Ionic Compounds YOUR NOTES

Properties of Ionic Compounds
Ionic compounds are usually solid at room temperature
They have high melting and boiling points
Ionic compounds are good conductors of electricity in the molten state or in solution
They are poor conductors in the solid state
Explaining the Properties of Ionic Compounds

EXTENDED
Ionic substances have high melting and boiling points due to the presence
of strong electrostatic forces acting between the oppositely charged ions
These forces act in all directions and a lot of energy is required to overcome them
The greater the charge on the ions, the stronger the electrostatic forces and the higher the
melting point will be
For example, magnesium oxide consists of Mg2+ and O2- so will have a higher melting
point than sodium chloride which contains the ions, Na+ and Cl-
For electrical current to flow there must be freely moving charged particles such as
electrons or ions present
Ionic compounds are good conductors of electricity in the molten state or in solution as
they have ions that can move and carry a charge
They are poor conductors in the solid state as the ions are in fixed positions within the
lattice and are unable to move
Molten or aqueous ions move freely but cannot in solid form
Page 25 of 45
2.3 Simple Molecules & Covalent Bonds YOUR NOTES

2.3.1 Covalent Bonds
Page 26 of 45
The Formation of Covalent Bonds YOUR NOTES
Covalent compounds 
Covalent compounds are formed when pairs of electrons are shared between atoms
Only non-metal elements participate in covalent bonding
As in ionic bonding, each atom gains a full outer shell of electrons, giving them a noble gas
electronic configuration
When two or more atoms are covalently bonded together, we describe them as
‘molecules’
Dot-and-cross diagrams can be used to show the electric configurations in simple
molecules
Electrons from one atom are represented by a dot, and the electrons of the other atom are
represented by a cross
The electron shells of each atom in the molecule overlap and the shared electrons are
shown in the area of overlap
The dot-and-cross diagram of the molecule shows clearly which atom each electron
originated from
Diagram showing how a covalent bond forms between two chlorine atoms
Page 27 of 45
Exam Tip YOUR NOTES
 When drawing dot-and-cross diagrams for covalent compounds, make sure that

the electron shell for each atom is full (remember that the 1st shell can only hold 2
electrons).
Page 28 of 45
Single Covalent Bonds YOUR NOTES
Many simple molecules exist in which two adjacent atoms share one pair of electrons, also 
known as a single covalent bond (or single bond)
Common Examples of Simple Molecules
Hydrogen:
Chlorine:
Water:
Methane:
Page 29 of 45
YOUR NOTES
Ammonia:
Hydrogen chloride:
Page 30 of 45
2.3.2 Molecules & Compounds YOUR NOTES
Page 31 of 45
Covalent Bonds in Complex Covalent Molecules YOUR NOTES
EXTENDED 
Some atoms need to share more than one pair of electrons to gain a full outer shell of
electrons
If two adjacent atoms share two pairs of electrons, two covalent bonds are formed, also
known as a double bond
If two adjacent atoms share three pairs of electrons, three covalent bonds are formed, also
known as a triple bond
Nitrogen:
When 2 nitrogen atoms react they share 3 pairs of electrons to form a triple bond
Ethene:
In ethene, the 2 carbon atoms share 2 pairs of electrons
This is known as a double bond
Methanol:
Page 32 of 45
YOUR NOTES
Carbon Dioxide:
 Exam Tip
Be careful when drawing dot-and-cross diagrams, it is a common mistake for
students to draw the wrong type of diagram. Remember, if the compound contains
metal and non-metal, it is an ionic compound and you need to draw the ions
separated, with square brackets around each ion, together with a charge. If the
compound contains non-metal atoms only, it is a covalent compound, the shells
should overlap and contain one or more pairs of electrons.
Page 33 of 45
2.3.3 Properties of Simple Molecular Compounds YOUR NOTES

Properties of Simple Molecular Compounds
Small molecules are compounds made up of molecules that contain just a few
atoms covalently bonded together
They have low melting and boiling points so covalent compounds are usually liquids or
gases at room temperature
As the molecules increase in size, the melting and boiling points generally increase
Small molecules have poor electrical conductivity
Page 34 of 45
Explaining the Properties of Simple Molecular Compounds YOUR NOTES
EXTENDED 
Small molecules have covalent bonds joining the atoms together, but intermolecular forces
that act between neighbouring molecules
They have low melting and boiling points as there are only weak intermolecular forces
acting between the molecules
These forces are very weak when compared to the covalent bonds and so most small
molecules are either gases or liquids at room temperature
As the molecules increase in size the intermolecular forces also increase as there are more
electrons available
This causes the melting and boiling points to increase
The bonds between hydrogen and oxygen in water are COVALENT, and the attractions
between the molecules are INTERMOLECULAR FORCES which are about one tenth as strong
as covalent bonds
 Exam Tip
The atoms within covalent molecules are held together by covalent bonds while the
molecules in a covalent substance are attracted to each other by intermolecular
forces.
Electrical Conductivity
Molecular compounds are poor conductors of electricity as there are no free ions or electrons
to carry the charge.
Most covalent compounds do not conduct at all in the solid state and are thus insulators
Common insulators include the plastic coating around household electrical wiring, rubber
and wood
Page 35 of 45
YOUR NOTES
The plastic coating around electrical wires is made from covalent molecules that do not
allow a flow of charge
Page 36 of 45
2.4 Giant Structures YOUR NOTES

2.4.1 Diamond & Graphite
Page 37 of 45
Structure of Graphite & Diamond YOUR NOTES
Diamond and graphite are allotropes of carbon which have giant covalent structures 
Both substances contain only carbon atoms but due to the differences in bonding
arrangements they are physically completely different
Giant covalent structures contain billions of non-metal atoms, each joined to adjacent
atoms by covalent bonds forming a giant lattice structure
Diamond
In diamond, each carbon atom bonds with four other carbons, forming a tetrahedron
All the covalent bonds are identical, very strong and there are no intermolecular forces
Diagram showing the structure and bonding arrangement in diamond

Graphite
Each carbon atom in graphite is bonded to three others forming layers of hexagons,
leaving one free electron per carbon atom which becomes delocalised
The covalent bonds within the layers are very strong, but the layers are attracted to each
other by weak intermolecular forces
Page 38 of 45
YOUR NOTES
The structure and bonding in graphite
Page 39 of 45
Uses of Graphite & Diamond YOUR NOTES
Properties of Diamond 
Diamond has the following physical properties:
It does not conduct electricity
It has a very high melting point
It is extremely hard and dense
All the outer shell electrons in carbon are held in the four covalent bonds around each
carbon atom, so there are no freely moving charged particles to carry the current thus it
cannot conduct electricity
The four covalent bonds are very strong and extend in a giant lattice, so a very large amount
of heat energy is needed to break the lattice thus it has a very high melting point
Diamond ́s hardness makes it very useful for purposes where extremely tough material is
required
Diamond is used in jewellery due to its sparkly appearance and as cutting tools as it is
such a hard material
The cutting edges of discs used to cut bricks and concrete are tipped with diamonds
Heavy-duty drill bits and tooling equipment are also diamond-tipped
 Exam Tip
Diamond is the hardest naturally occurring mineral, but it is by no means the
strongest. Students often confuse hard with strong, thinking it is the opposites of
weak. Diamonds are hard, but brittle – that is, they can be smashed fairly easily with a
hammer. The opposite of saying a material is hard is to describe it as soft.
Properties of Graphite
Each carbon atom is bonded to three others forming layers of hexagonal-shaped forms,
leaving one free electron per carbon atom
These free (delocalised) electrons exist in between the layers and are free to move through
the structure and carry charge, hence graphite can conduct electricity
The covalent bonds within the layers are very strong but the layers are connected to each
other by weak forces only, hence the layers can slide over each other making graphite
slippery and smooth
Graphite thus:
Conducts electricity
Has a very high melting point
Is soft and slippery, less dense than diamond
Graphite is used in pencils and as an industrial lubricant, in engines and in locks
It is also used to make non-reactive electrodes for electrolysis
Page 40 of 45
Exam Tip YOUR NOTES
 Don’t confuse pencil lead with the metal lead – they have nothing in common. Pencil

lead is actually graphite, and historical research suggests that in the past, lead
miners sometimes confused the mineral galena (lead sulfide) with graphite; since
the two looked similar they termed both minerals ‘lead’. The word graphite derives
from the Latin word ‘grapho’ meaning ‘I write’, so it is a well named mineral!
Page 41 of 45
2.4.2 Silicon(IV) Oxide YOUR NOTES

Structure of Silicon(IV) Oxide
EXTENDED
Silicon(IV) oxide (also known as silicon dioxide or silica), SiO2, is a macromolecular
compound which occurs naturally as sand and quartz
Each oxygen atom forms covalent bonds with 2 silicon atoms and each silicon atom in turn
forms covalent bonds with 4 oxygen atoms
A tetrahedron is formed with one silicon atom and four oxygen atoms, similar to diamond
Diagram showing the structure of SiO2 with the silicon atoms in blue and the oxygen atoms in
red
Page 42 of 45
Comparing Diamond & Silicon(IV) Oxide YOUR NOTES
EXTENDED 
SiO2 has lots of very strong covalent bonds and no intermolecular forces so it has similar
properties to diamond
It is very hard, has a very high boiling point, is insoluble in water and does not conduct
electricity
SiO2 is cheap since it is available naturally and is used to make sandpaper and to line the
inside of furnaces
Page 43 of 45
2.4.3 Metallic Bonding YOUR NOTES

Metallic Bonding
EXTENDED
Metal atoms are held together strongly by metallic bonding in a giant metallic lattice
Within the metallic lattice, the atoms lose the electrons from their outer shell and become
positively charged ions
The outer electrons no longer belong to a particular metal atom and are said to be
delocalised
They move freely between the positive metal ions like a 'sea of electrons'
Metallic bonds are strong and are a result of the attraction between the positive metal ions
and the negatively charged delocalised electrons
Diagram showing metallic lattice structure with delocalised electrons
Page 44 of 45
Properties of Metals YOUR NOTES
EXTENDED 
Metals have high melting and boiling points
There are many strong metallic bonds in giant metallic structures between the
positive metal ion and delocalised electrons
A lot of heat energy is needed to break these bonds
Metals conduct electricity
There are free electrons available to move through the structure and carry charge
Electrons entering one end of the metal cause a delocalised electron to displace itself
from the other end
Hence electrons can flow so electricity is conducted
Metals are malleable and ductile
Layers of positive ions can slide over one another and take up different positions
Metallic bonding is not disrupted as the outer electrons do not belong to any particular
metal atom so the delocalised electrons will move with them
Metallic bonds are thus not broken and as a result metals are strong but flexible
They can be hammered and bent into different shapes or drawn into wires without
breaking
 Exam Tip
When explaining why metals can conduct electricity, be careful of the terminology
you use. Don't get confused with ionic compounds. Metals can conduct electricity
as they have free electrons that can carry charge whereas molten or aqueous ionic
compounds can conduct electricity because they have free ions that can carry
charge.
Page 45 of 45

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IGCSE Chemistry CIE 

2. Atoms, Elements & Compounds

2.1 Atomic Structure & the Periodic Table YOUR NOTES

Elements, Compounds & Mixtures

Particle diagram showing elements, compounds and mixtures

2.1.2 Atomic Structure YOUR NOTES

The structure of the carbon atom

Protons, Neutrons & Electrons YOUR NOTES

Defining Proton Number

Defining Mass Number YOUR NOTES

Diagram showing atomic notation

Atomic notation for carbon

Deducing protons, neutrons & electrons

2.1.3 Electronic Configuration YOUR NOTES

Electronic Configuration YOUR NOTES

A simplified model showing the electron shells

Its electronic configuration is 2,8 YOUR NOTES

The Electronic Configuration of the First Twenty Elements 

Exam Tip YOUR NOTES

Electron Shells & The Periodic Table YOUR NOTES

The electronic configuration for chlorine

The position of chlorine on the Periodic Table

The noble gases are on the Periodic Table in Group 8/0

2.1.4 Isotopes YOUR NOTES

The Atomic Structure and Symbols of the Three Isotopes of Hydrogen

Why Isotopes Share Properties YOUR NOTES

Calculating Relative Atomic Mass YOUR NOTES

Relative Atomic Mass

(72 x 85) + (28 x 87)

2.2 Ions & Ionic Bonds YOUR NOTES

The Formation of Ions YOUR NOTES

Formation of positively charged sodium ion

Formation of negatively charged chloride ion

The Formation of Ionic Bonds YOUR NOTES

Electrostatic forces between the positive Na ion and negative Cl ion

Example: Sodium Chloride, NaCl 

Sodium chloride ionic bonding

The ionic compound has no overall charge 

2.2.2 Ionic Bonds & Lattice Structure YOUR NOTES

The Lattice Structure of Ionic Compounds

The lattice structure of NaCl

Ionic Bonds between Metallic & Non-Metallic Elements YOUR NOTES

Diagram showing the dot-and-cross diagram of magnesium oxide

2.2.3 Properties of Ionic Compounds YOUR NOTES

Explaining the Properties of Ionic Compounds

Molten or aqueous ions move freely but cannot in solid form

2.3 Simple Molecules & Covalent Bonds YOUR NOTES

The Formation of Covalent Bonds YOUR NOTES

Exam Tip YOUR NOTES

Single Covalent Bonds YOUR NOTES

2.3.2 Molecules & Compounds YOUR NOTES

Covalent Bonds in Complex Covalent Molecules YOUR NOTES

2.3.3 Properties of Simple Molecular Compounds YOUR NOTES

Explaining the Properties of Simple Molecular Compounds YOUR NOTES

2.4 Giant Structures YOUR NOTES

Structure of Graphite & Diamond YOUR NOTES

Diagram showing the structure and bonding arrangement in diamond