Acids, Bases and Salts - Done
Acids, Bases and Salts - Done
Acids, Bases and Salts - Done
2. Test to distinguish between acids and bases – substance which show one colour (or odour) in
acidic medium and a different colour (or odour) in the basic medium are called acid – base
indicators. These are of two types:
(i) Indicators showing different in the acidic and basic medium e.g. litmus solution,
phenolphthalein, methyl orange etc.
The colour of some natural indicators are summed up in the Table below:
Indicators Colour in the Colour in the Colour in the
neutral solution acidic solution basic solution
Litmus Purple Red Blue
Red cabbage leave extract Red Red Green
Flowers of hydrangea plant Blue Blue Pink
Phenolphthalein Colourless Colourless Pink
Methyl orange Orange Red Yellow
(ii) Indicators giving different odours in the acidic and basic medium e.g. onions, vanilla, essence,
clove oil etc
4. Reaction mark – acids react with active metals like zinc, magnesium etc generally with the
evolution of hydrogen gas.
5. Reaction with metal carbonates and metal hydrogen carbonate – acids react with metal carbonates
and bicarbonates to give out carbon dioxide togive out carbon dioxide with effervescene and
forming the corresponding salt and water. For example
(i) NaCO3 + H2SO4 ----> Na2SO4 + H2O + CO2
(ii) NaHCO3 + HCl -----> NaCl + H2O + CO2
(iii) CaCO3 + 2 HCl -----> CaCl2 + H2O + CO2
7. Reaction with bases – when an acid reacts with a base, t form salt and water. As a result, the
acidic properties of the acid disappear. The process is called neutralization.
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8. Reaction with metallic oxides – metal oxides like quick lime i.e. calcium oxide (CaO), copper (II)
oxide (CuO), magnesium oxide (MgO) etc react with acid to form salt and water.
10. Organic and inorganic acids -Acids present in plants and animals are called organic acids while
acids obtained from the minerals of the earth are called inorganic acids.
(i) Acetic acid is used as a preservative in making pickles
(ii) Tartaric acid is an ingredient of baking powder
(iii) Carbonic acid is present in the soft drinks and soda water
12. Acids are the substances which contain hydrogen and which when dissolved in water give
hydrogen ions (H+) in the solution
13. Rain water conducts electricity but distilled water does not – distilled water does not contain any
acid, base or salt which may dissociate to produce ions. Hence, it does not conduct electricity.
Rain water contain dissolved gases of the air like CO2, SO2, NO2 etc. these gases dissolve in
water to form acids e.g., CO2 dissolves in H2O to form H2CO3 which dissociate to give H+ ions
and carbonate ions. Hence, it conducts electricity.
14. Role of water in the solution of an acid – HCl gas or solution of HCl gas in benzene or toluene
does not show acidic properties. However, solution of HCl gas in water shows acidic properties.
Thus, aids give H+ ions only in presence of water. These H+ ions combine with H2O molecules
and exist as H3O+ or H+ (aq). Thus, the properties of an acid are due to H+ (aq) or H3O+ ions
which it gives in the aqueous solution.
15. Dilution of concentrated acid – dilution of concentrated acid with water is highly exothermic.
Hence, for dilution, we always add acid into water and not water into acid.
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16. Effects of dilution on acids – on dilution, the concentration of H+ (aq) ions per unit volume
decreases. Hence, acidic strength decreases.
17. Use of mineral acids in industry
(a) Sulphuric acid – it is used in a number of industries like fertilizers, paints, explosives, dyes,
drugs etc. hence it is called ‘King of Chemicals’
(b) Nitric acid is used in manufacture of fertilizers, explosives, artificial silk.
(c) Hydrochloric acid is used in cleaning the surface of metals before electroplating as well as in
textile, food, leather and dye industries.
18. Properties of bases
(a) bitter taste- bases possess a bitter taste
(b) slippery or soapy touch – they possess a slippery touch like soaps.
(c) Action on litmus paper – they turn read litmus blue.
(d) Action on phenolphthalein – they turn phenolphthalein solution pink.
(e) Corrosive nature – some bases like caustic soda, caustic potash etc. produce a burning
sensation on the skin.
(f) Reaction with acid –some bases like sodium hydroxide and potassium hydroxide react with
active metals like zinc and aluminium to liberate hydrogen gas along with formation of a
salt.
(g) Reaction with non – metals – bases react with non – metal oxides (like CO2, SO2, SO3, P2O5)
to form salt and water.
19. Difference between a base and an alkali – the bases which are soluble in water and give
hydroxide ions in the aqueous solution are called alkali. Thus, all alkalies are bases but all bases
are not alkalies.
20. Neutralization reaction between an acid and base- it may be defined as the reaction between H+
ions given by the acid with the OH- ions given by the base to form water and salt. Neutralization
is always an exothermic process
21. Uses of some common bases
Name Commercial Chemical Uses
name formula
Sodium hydroxide Caustic soda NaOH In manufacture of soaps, artificial fibres
like rayon and in paper industry.
Potassium hydroxide Caustic potash KOH In manufacture of soft soaps, in nickel –
iron storage battery and for absorbing CO2
In manufacture of bleaching powder, in
Calcium hydroxide Slaked lime Ca(OH)2 white washing and testing CO2 gas
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22. Chemical nature of base – a base is a substance which when dissolved in water gives hydroxide
(OH-) ions in the solution, hence, the properties of abase are due to OH- ions which it gives in the
aqueous solution.
23. Strong and weak acids – acids like HCl and H2SO4 which dissociate completely in the aqueous
solution to produce a large amount of H+ ions and hence conduct electricity to a large extent are
called strong acids.
On the other hand, acids likes acetic acids (CH3COOH), oxalic acid (COOH)2, carbonic acid
(H2CO3) etc., which dissociate only partially in the aqueous solution to produce a small amount of
H+ ions and hence conduct electricity to a small extent are called weak acids.
24. Strong and weak bases – bases like NaOH, KOH etc., which dissociate completely in the aqueous
solution to produce a large amount of OH- ions and hence conduct electricity to a large extent are
called strong bases.
On the other hand, bases like NH4OH, Ca(OH)2 etc., which dissociate only partially in the
aqueous solution to produce a small amount of OH- ions and hence conduct electricity in a small
extent are called weak bases.
25. pH of a solution – the acidity or alkalinity of a solution is expressed in terms of pH. The pH of a
solution is the magnitude of the negative power to which 10 must be raised to express the H + ion
concentration in moles per litre e.g., if H+ ion concentration of a solution = 10-x mol L-1, then
pH = x
26. pH scale – an acidic , basic or neutral solution contain both H+ ions and OH- ions. If the solution
is neutral, [H+] = [OH-] = 10-7M. In a solution, [H+] can from 100 to 10-14 M. Hence, solution can
have pH from O to 14. This is called pH scale. Neutral solution have pH = 7. Acidic solutions
have pH < 7 and basic solution have pH > 7. Lesser is the pH than 7, more acidic is the solution.
Greater is the pH than 7, more basic is the solution.
29. Salt and their formation – salts are ionic compounds consisting of two parts, one parts carrying a
positive charge and other part carrying a negative charge.
32. pH of salt solution – when salt is dissolved in water, it reacts to give back the acid and base. It is
called salt hydrolysis. It is reverse of neutralization.
a. Salts of strong acids and strong bases like NaCl, KNO3 etc. give neutral solution with pH =
7.
b. Salt of strong acids and weak base like CuSO4, NH4Cl etc. give acidic solution with pH < 7
c. Salts of weak acids and strong base like Na2CO3 five basic solution with pH >7
34. Table salt – it used as a food material is iodized salt containing a small amount of potassium
iodide which protects us from thyroid disorders.
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39. Manufacture of caustic soda – by electrolysis o an aqueous solution of sodium chloride. The
method is called chlor – alkali process because it gives chlorine and the alkali, NaOH. Hydrogen
and chlorine are obtained as by – products. They can be combined to produce HCl gas which can
be dissolved in water to produce hydrochloric acid.
42. Manufacture – bleaching powder is manufactured by action of chlorine on dry slaked lime.
46. Manufacture – It is prepared by passing CO2 through NaCl solution saturated with NH3. It can
also be prepared by passing CO2 through aqueous Na2CO3 solution.
47. Properties - It is white crystalline solid, stable in air, sparingly soluble in water. On heating, it
decomposes to give Na2CO3 and CO2. It reacts with acids with effervescence to give out CO2 gas.
48. Uses – it is used in medicines as antacid, as a constituent of baking powder for preparing fluffy
food stuff like cake, bread etc. and in fire extinguishers.
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51. Sodium carbonate exists in three forms : NA2CO3, 10H2O, Na2CO3.H2O and Na2CO3
55. Crystalline salts like Na2CO3. 10 H2O, CaSO4.2 H2O, CaSO4.½ H2O, CuSO4.5H2O etc. which
seem to be dry contain water of crystallization. Water of crystallization is a fixed number of water
molecules present in one formula unit of the salt.
58. It is white powder. Mixed with water, it sets to a hard mass. His is due to rehydration to from
gypsum
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