rate = 3.0×10-4 [ 0.26 ] [ 0.

080]
=
0.62×10-5 Mls

Pof reactant
First order C- K) second order ( + K )
Pf Pi
-

zero order (a)

I ' '

Y : th (15.7-6)=2.757 Y mmhg
= =
0.06345
0 45.9-6 ygiy,

18.88-15.76=3-12 45.76-6.24=12.64 Y : In ( 12.64 ) = 2.537 Y =

11.64=0.09-911
-
k ,
k , 1
y= In (8.7-3)=2.167
-

22.79-75.76=7.03 22.79-74.06=8.73 Y =
g.gg
= 0.1145

Y = In (4-44)=1.491 !
27.08-15.76=11.32 27.08-22.64=4.44
b
Y
Y =
q ,
= 0.2252

It is a second order of reaction as the slope is positive

which met the condition of second order of reaction

slope : Ay =
K
✗

0.2252-0.06345
=

1164 -

=
0.1618

1164
'
rate const .
- K = 139×10-6 g-

0 181 513 7164

In =
(÷ ÷ ) -

1h
(4.60×10-457)=10440*1%1
(8.80×15451) 8.314T/Kmt Ti
-

÷,

(%
^
0.649=12545) )
-

-
623

-
519×157-1 623
1
=
¥
755 ✗ 15£ =
¥
,

-12--645 Is = 372°C
 PX.in/RT
2N 20 → 2
Nz -102 2.10 : M

'

E.
=
% Neo Nz 0 After 1 half life
,

I 2.70 O o PNZO =
{ (2-10)=2.10 -
2x
3 1h2
3. 58×10 =
C 1- 2X 1- ✗
K -
2X 2x : 2.10 -1.05

1<=3.23×15%-1 F 2.10-2 ✗ 2X ✗ ✗ = 0.525

In [ A) In [ A) Kt
Pt :( 2.10-2*2×-1
-
=
◦ ✗

In P = In Po -
Kt =
2.10+11
i
1h2 .to -
3.23×10%(3.58×103) Pf
:
2.10-10.525
=
0.02181 : 2.63 atm
Preactant -_
7.04937 mmhg = 1.05 atm

P 1.05 3--1.57 atm

product = ✗

Pt =
1.051-1-57=2.62 atm

EE it produce first , consume

later

↳ consume first , produce later

↳ same

↳ diff

2Ce -1T /
" +
→ 243++1-13-1

a.
Catalyst : Mn2t

Intermediates = Mn
"
,Mn4t
>+
:(e'
+
Mnzt Must
determining step Ce
rate -
+ → +

b. The use of catalyst is to decrease the Ea of

the reaction Without it .

,
the F- a of the reaction

will remain the same as if F-a is

high the reaction

will undergo slower

c.
Catalysis is
homogeneous