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Heaven’s Light is Our Guide

Rajshahi University of Engineering & Technology


Department of Electronics & Telecommunication Engineering

Title: Resonant and Non-resonant plasmonic nanoparticle


enhancement for thin-film silicon solar cells.

Presented By: Supervised By:


Anik Halder Sham Datto
Roll:1704057 Assistant professor
Dept. of ETE Dept. of ETE,
RUET, Rajshahi-6204, Bangladesh RUET, Rajshahi-6204, Bangladesh
Introduction

❑ The field of plasmonic photovoltaic has a attractive approach for use scattering
from metallic nanostructures deposited on top of thin-film solar cells to improve
light trapping and energy conversion efficiency of the cells.

❑There are many kinds of nanoparticle that can enhancement the performance of
thin film silicon solar cells.

❑The nanoparticle are mainly two types such as resonant and non-resonant.

❑For resonant nanoparticle Ag(silver) is gaining popularity in the making of thin


film silicon solar cells. On the other hand Al(aluminium) in non-resonant.
Literature Review

Authors Considerations Limitations


Stuart H R and Hall D G [2] Improving the cell’s optical Low efficiency nanopartical
absorption and giving rise to a selection.
stronger photocurrent response

Catchpole K R and Polman A[3] The crucial role in the observed This limit is determined by optical
enhancements is due to the proper properties of the nanoparticle
selection of the nanoparticle material.
parameters.

Nie S and Emory S R [4] various plasmonic applications, Low parasitic degradation.
from enhanced fluorescence and
Raman scattering.
Moulin E, Sukmanowski J, Schulte Ag is also the material of choice. High plasmon-induced losses.
M, Gordijn A, Royer F X and Stiebig It exhibits lower parasitic
H[5] absorption and better coupling
Motivations

❑ The enhancement for thin film silicon solar cell is proposed with a
view to :

1. Higher optical absorption in the photoactive region than only aluminium


nanoparticles.
2. To maintain a net positive enhancement of the optical absorption .
3. To get a negative effect by silver nanoparticles, when the nanoparticles are
oxidized.
Effectiveness and Absorption rate
of silicon solar cell

The full set of 3D Maxwell’s equations: Where,


∇ × E = iωμ0H , ∇ × H = −iωε0εE (1) A(ω)= Spectral absorption rate
Qinc = SF(ω) is the spectral power
The spectral absorption rates coming from the Sun over the solar
A(ω) = Qabs(ω) /Qinc(ω), (2) cell surface S;
Qabs(ω) is the spectral power absorbed
The integral over the element volume V : by each element
Qabs(ω) = ωε0 /2 ∫vIm[ε(ω)]|E|2dV. (3) Qtotabs =total power absorbed by the
photoactive region
Total power absorbed by different components
Qtot abs =∫ A(ω)F(ω) dω. (4)
Simulation and Result

a)ω > 2.75 eV


a)ultravoilet

Figure 1. Spectral absorption rate A(ω) of the Figure 1(b) shows the comparison
a-Si:H photoactive region (solid lines) and the of the resonant and non-resonant
nanoparticle array (dashed lines) in a cell coupling effects for the Ag and Al
enhanced and as a function of frequency w. nanoparticle arrays of R = 80 nm
and η = 11%.
Simulation and result

This figure shows the maximum


enhancement that can be achieved by using
Ag and Al nanoparticles with the radius R
and the corresponding optimum surface
coverage ηmax,

Figure 2. (a) Maximum enhancement of the optical


absorption in the a-Si:H region (as compared to the
reference cell), as a function of nanoparticle radius
R and (b) corresponding optimum coverage ηmax to
attain the maximum enhancement, as a function of
radius R.
Conclusion

❑Al is a very good candidate among the commonly used


metals.
❑Ag is very good among the resonant used metal
References

❑[2] Stuart H R and Hall D G 1998 Appl. Phys. Lett. 73 3815


❑[3] Catchpole K R and Polman A 2008 Opt. Express 16 21793
❑[4] Nie S and Emory S R 1997 Science 275 1102
❑[5] Moulin E, Sukmanowski J, Schulte M, Gordijn A, Royer F X and
Stiebig H 2007 Thin Solid Films 516 6813
❑[6] Pillai S, Catchpole K R, Trupke T and Green M A 2007 J. Appl. Phys.
101 093105
❑ [7] Rockstuhl C and Lederer F 2009 Appl. Phys. Lett. 94 213102
❑[8] Nakayama K, Tanabe K and Atwater H A 2008 Appl. Phys. Lett. 93
121904
Thank You for Your
Attention

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