Aits 2223 FT Viii Jeea Paper 1 Sol

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2023
FULL TEST – VIII
PAPER –1
TEST DATE: 07-05-2023
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. A, D
Sol. In case of smooth wall there is no change in vertical component of velocity during collision and
therefore time of flight of ball is unchanged
2. A, C
Sol. At open end pressure amplitude is zero while at closed end pressure amplitude is maximum.
3. A, D
Sol. If  decreases, force between earth and the satellite will also decrease and therefore satellite will
drift away from earth and vice versa.
4. A, C, D
Sol. In case hydrogen atom is free to move then to conserve linear momentum of the system it will
gain some energy and therefore energy of the photon emitted will be less then the case when
hydrogen atom was at rest.
A particle having zero rest mass can not travel with speed less then speed of light in free space
5. A, C, D
Sol. System will not loose any energy as there are no drag forces. Energy lost by battery will be partly
stored in capacitor and partly will go into kinetic energy of sheet when sheet is entering into gap.
Sheet will undergo oscillatory motion.
6. A, C, D
Sol. Current in solenoid can be resolved along length of solenoid (iii ) and along curvature of solenoid
(i ) . (iii ) will produce field at mid point even if solenoid is long.
7. D
Sol. Basic concept of SHM
8. A
Vi
Sol. Final volume of right part =
8
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2
AITS-FT-VIII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
Vi 15Vi
Final volume of left part = 2Vi  
8 8
For right part using Pi Vi  Pf Vf

V 
Pi Vi  Pf  i 
8
P
 f  32 …(i)
Pi
PV
For left part using  cons tan t
RT
 15Vi 
Pf 
Pi Vi 8  T
   f  60 …(ii)
RTi RTf Ti
For left part
Q = W + U
P V  Pi Vi 5 9 Pi Vi 5
= f i  n0 R(Tf  Ti )  PVi i   R(60Ti  Ti )
 1 2 2 RTi 2
Q = 152PV
i i …(iii)
Q 152PV i i 152Ti 152
    2.5
n0RTf PV
i i Tf 60
RTf
RTi
9. C
Sol. Conserving angular momentum about point just below centre of mass of A
rod.
4ML2
3Mux   
12 v
9xu x
 2 …(i)
L
Conserving linear momentum
B
3u
3Mu = 4Mv  v  Just after collision
4
Velocity of end A
L  3u 9u x 
vA  v     
2  4 2 L 
For vA = 0
3u 9xu

4 2L
x = L/6
10. C
Sol. Information Based
3
Section – B
11. 0.00
Sol. No force is required to hold the barometric tube at equilibrium
12. 2.00
Sol. Potential at O due to circular ring of width dx
kdq 1   2rdx
dV   (  surface change density)
x 40 x
 x sin dx + +
 + +Q
20 x + +
L + +O
 sin 
 dV 
2 0 dx
 + + q
+ +
0
R
Q R + x
L +
L sin  RL L Q +
V   + dx
20 20 20L
Qq
 work done = qV =
20L
13. 1000.00
Sol. At steady state let temperature of stick at distance x
x from A is T. T
A B
KA(100  0) KA(100  T)
  100C dx 0C
L x
100x
  100  T
L
 100x 
T   100 
 L 
Heat absorbed by part dx
2 
dQ   dx   10  (T  0)
L 
20  100x 
 dx  100 
L  L 
2000  x
dQ  1 dx
L  L 
L L
2000  x 2000  x2 
 Q
L
0

 1   dx 
 L L 
x  
2L 
0
2000  L
L    1000 J
L  2
14. 0.42
mv 2
Sol. TA  mgsin  
R
1 (4)2
TA   1 10  sin30
1
TA = 16  5 = 11 N …(i)
4
Using conservation of mechanical energy between points P A

and Q
1 1
m(4)2  mg  R sin   m(v Q )2 4 m/s
2 2
2 P
16  20  1sin30  vQ
R = 1m
v 2Q  26 …(ii) O
m  26
TQ   26 N
1  = 30
TP 11 B
  0.42
TQ 26
15. 14.00
 
Sol. r  R  1  1
 2 
 
 L0 / 2 
 10   1  2 
 5L0 
 
 12 
E
Also,  6  E = 12 volt
2
16. 1.00
 P 
Sol. If source is at rest. Energy spread out in length c and area of cross section A is  A
 4 a2 
 P 1 
 Extra energy received by observer per second =  2
A  u
 4 a c 
P P u P  u
Total energy received by observer in one second per unit area = 2
 2
= 2  1 
4a 4 a c 4a  c
Power P P u P  u
Intensity received by observer =  2
 2 c
 1 c 
Area 4a 4a 4  a2  
17. 0.60
Sol. Conservation of linear momentum
mv0 = mv + 2mv1

v + 2v1 + v0 …(i)
Conserving angular momentum about point on the ground v1
just below centre of the disc
2mR2
mv0R  mvR  
2 m v0
Or v0 = v + R …(ii)
v = R + v1 …(iii)
2v 0 v0
Solving,   , v1 
5R 5
2 v 3v 0
v A  R  v 1  v 0  0 
5 5 5
5
18. 9.76
V A B
Sol. i

10 32 68
At resonance, i   0.1A
100
1 1  105 
0   
 7  rad/s
4.9  103  106
LC  
1 7
XC    70
0C 105  10 6
Z A  (32)2  (70)2  76.97
VA  iz A  0.1 76.97  7.7 Volt
105 490
XL  L   4.9  10 3   70
7 7
ZB  (68)2  (70)2  97.6
VB = 0.1  97.6 = 9.76 volt
6
Chemistry PART – II
Section – A
19. A, C
Sol. An increase in chelate ring size beyond six membered ring produces a fairly uniform decrease in
complex stability. Which does not show any strong dependence on the size of the metal ion.
20. A, C, D
Sol. CH3
A Cl
H2C Br
B Cl
H2C SH
C Cl
21. A, B, C
1 1 0
Sol. rate  k  Acetone H  Br2  .
22. A, C, D
Sol. H2 O  H  OH
C
C 1    0.1 C
K W  H  OH 
 0.1  55.5  3.6  1015
 2  1014
Hence, T must be > 25oC.
7
23. A, B
Sol. 4LiNO3  2Li2 O  4NO2  O2
2KMnO4  K 2MnO4  MnO2  O2
NH4 NO3  N2 O  H2 O
1
NaNO3  NaNO2  O2
2
24. A
Sol. Trimethylsilyl group (Me3Si) shows a strong electron withdrawing effect from the ortho and para
positions due to the resonance effects involving the 3d orbital of the silicon atom.
NH2 NH2
Si(CH3)3 Si(CH3)3
25. A
Sol. Oxidation always takes place at anode.
In electrolytic cell G  0 .
Fuel cell based breath alcohol sensor oxidizes the alcohol in a breath sample and produces an
electric current.
26. A
Sol. All Monosaccharides are reducing sugars.
(I) is Mannose and is a C-2 epimer of glucose.
The formation of osazone involves C-1 and C-2.
Glucose, Mannose and Fructose have identical configuration at C-3, C-4 and C-5. Hence, they
form the same osazone.
27. B
Sol. 
(I) is Ascorbic acid (Vitamin C) is a diprotic acid K a1  9  103 . 
(III) is a Squaric acid and also a diprotic acid. Both are stronger acid than H2 CO3 and produce
effervescence on addition of NaHCO3.
28. C
Sol. O O O
Cr ;
Cr Cr
O O O O O
O O O
O O
O
Cr
O O
; O O
Cr O
O O
O O O
8
Section – B
29. 26.67
Sol. A is NH4NO3

NH4 NO3  NaOH   NaNO3  NH3   H2 O 
NH3  HCl  NH4 Cl
NaNO3  4Zn  7NaOH  NH3  4Na2 ZnO2  2H2 O

NH4 NO3   N2 O   2H2 O 
30. 11.00
Sol. Na2 CO3  HCl  NaHCO3  NaCl
20 10
10  10
pH  pK a2  11
31. 6.40
3
Sol. K 3 Fe  oxalate 3   t 2g eg2 HS complex
5
K 3 Ru  oxalate 3   t 2g ego LS complex
 s of K 3 Fe  oxalate 3   35 BM
 s of K 3 Ru  oxalate 3   3 BM
x  y 35  3
   6.40
5 5
32. 19.75
Sol. dE
S  nF
dT
 2  96500  5  105
1
 2  5  965 
1000
2
 965  10
G  nFE
 2  96500  1.02
H  G  TS
G  H  TS
 2  965  102  300  965  102
 965  204  3 
 965  207
 199755
 19.75 kJ mol1
9
33. 5.67
Sol. H O H HO O
C O C
A B
O
C O
O O HO
C D
Nuber of C atoms – 14 (x)
Nuber of O atoms – 3 (y)
Nuber of N atoms – 0 (z)

x + y + z 17
 =  5.67
3 3
34. 12.00
Sol. Fullerene has 12 five membered rings
x = 12
C O O C
B y=2
C O O C
cis diol-boric acid complex

2-
z=5
x  y  z 12  2  5
   12
10 10
10
35. 149.85
k
Sol. A  B 
1
P
k
P 
1
A B
k
P 
2
Q
Rate  k 2 P  … (1)
Applying steady state assumption on [P]
d P 
 k1  A B   k 1 P   K 2 P   0
dt
 k1  A B   k 1 P   k 2 P 
k1  A B 
P  k 1  k 2
… (2)
From (1) and (2)

k 2 k1  A B 
Rate 
k 1  k 2
k 2 k1
k overall 
k 1  k 2
10  1.5  105

10 4  10
1.5  106

10010
= 149.85
36. 4.05
Sol. Mixture is containing 70%. Racemic mixture and 30% R-2-methylbutan-1-ol.
11
Mathematics PART – III
Section – A
37. A, B, C, D
2
Sol. The equation x2 + y2 + 2gx + 2fy + c = 0 can be reduced to z   g  if  z   g  if  z  c  0 by
putting z = x + iy  z  x  iy
2
(i) Radius of c1  a c
(ii) If c1 and c2 touch extremely, then distance between centres = r1 + r2
2 2
 ab  a c  b c
(iii) Let a = g1 + if 1 ; b = g2 + if 2
c1c2 will cut orthogonally if 2g1g2 + 2f 1f2 = c + d
Now, ab  ba =  g1  if1  g2  if2    g2  if2  g1  if1  = 2g1g2  2f1f2
(iv) Radical axis can be obtained by subtracting the equations
38. A, C, D
Sol. Put x = , 2
(i) 1 = a0 + a1 + a22 +a33 + ..... (1)
(ii) 1 = a0 + a12 + a24 + a36 + ..... (2)
By adding equation (1) and (2), we get 2 = 2a0 – a1 – a2 + 2a3 – a4 – a5
a a a a
 1  a0  1  2  a3  4  5  .....
2 2 2 2
39. A, B, C, D
Sol. The given equation can be written as 3 + 2 cos( – ) cos( – ) + cos( – )
Also, 3 = 1 + 1 + 1 = cos2  + sin2  + cos2  + sin2  + cos2  + sin2 
Hence, the equation may be
 2cos 2
  cos2   cos2   2cos  cos   2cos  cos   2cos  cos  + 
 sin 2 2 2
  sin   sin   2 sin  sin   sin  sin   sin  sin  = 0 
2 2
Hence, (cos  + cos  + cos ) + (sin  + sin  + sin ) = 0
  cos   0   sin   0 and   cos   sin    0
40. A, B, C
 sin  x     sin  x     sin  x    cos  x    cos  x    cos  x   
Sol. f   x   sin  x    sin  x    sin  x     cos  x    cos  x    cos  x   
sin      sin      sin      sin     sin      sin     
 f(x) = 0  f(x) is a constant function  f() = f() = f()
41. B, D
Sol. Let f(x) = xn  f(x) = nxn – 1  f(x) = n(n – 1)xn – 2
For (n > 1 or n < 0 and x > 0) f(x) > 0 (a, f(a)) (c, f(c))
 Convexity downward
(b, f(b))
 a  b  c  f  a   f b   f  c 
 f 
 3  3
12
42. A, B
Sol. For 1  j  k
n n  j 1 1 1
  
n  j ! n  j ! n  j  1! n  j !
k
1 1 1 1 1
n    lim T  n, k   
j 1  n  j  ! n! n  k ! k  n! n n!
1 1 1
Now, T  n, n     ..... 
  
n  1 ! n  2  !  !
2n
1 1 1 1
 T  n, h     .....    T(n, k)
n! n! n!  n  1!
43. D
Sol. (I) (a + c)(a + c – 2b) = (a + c)2 – 2b(a + c) = (a + c)2 – 4ac = (a – c)2
 2loge  a  c   loge  a  c   loge a  c  2b   A.P.
(II) (a1 x – a2)2 + (a2 x – a3)2 + ..... + (an–1 x – an)2  0
  
 a12  a22  a32 ..... an2 a22  a32 ..... an21  a1a2  a2a3  a3 a4..... an1an 
a1 a2 a3
 Only equality holds when   .....  G.P.
a2 a3 a3
(III) G.P.
(IV) x18 = y21 = z28  18 ln x = 21 ln y = 28 ln z
7 4 9
 logxy  , logzy  , logzx   A.P.
6 3 14
44. C
Sol. (I) 

1  tan  3 3 tan x  tan x
3

 3 tan4 x – 6 tan2 x + 8 tan x – 1 = 0
1  tan  1  3 tan2 x
(II) Least value exist for equilateral triangle
1
(IV) sin x(sin2 60 – sin2 x) = sin3x
4
sin x + sin2 x + sin3 x = 1  sin x(1 + sin2 x) = 1 – sin2 x = cos2 x
(1 – cos2 x)(4 – 4 cos2 x + cos4 x) = cos4 x  cos6 x – 4 cos4 x + 8 cos2 x = 4
45. B
Sol. (I) Both are rectangular hyperbola  e12  e22  2  2  4
b b
    2
(II) tan 1  a a    b  1  e2  4
 b2  3 a2 3 3
 1 2 
 a 
1 1
2
 2  1  e = 2
e e
(III) OP = r1, OQ = r2, POX = 
P  (r1 cos , r1 sin ) N2
Q P
Q  (–r2 sin , r2 cos )
2 2
P and Q lies on 10x – 3y = 1 
x
1 O
 2  10cos2   3 sin2 
r1
1 1 1
 2
 10 sin2   3 cos2   2  2  7
r2 r1 r2
13
 2 4 3
(IV) Normal at  2t,  is 2t – xt + yt – 2 = 0
 t
2
Let slope of normal is m = t
4 3
Let P be (h, k)  2t – ht + kt – 2 = 0
 2m2 – t(hm – k) – 2 = 0  4m4 – h2m3 + (2hk – 8)m2 – k2m + 4 = 0
h2 2
Sum of slopes = 2  2 h =8
4
46. B
Sol. (I) 54 is multiple of 3 and 2
So, common divisor 2 can be if the other number is multiple of 2 but not multiple of 6
 Total 3000 numbers exist
2024 506 506
(II) 32025  3  3   3  81 = 3 1  80   3 1  506  80  100k 
= 3(1 + 80 + 505  80 + 1001k) = 3(81) + 100k = 243 + 100k
10th place = 4
(III) |z – 2| = 2 is circle with centre (2, 0) and r = 2
z 1  i   z 1  i   4
  z  z   i  z  z   4  2x – i(2iy) = 4
 2x + 2y = r  x + y = 2
i.e., 2 common points (2, 0)
(IV) Counting of terms are 1025  2  21  22  23  .....  2k

2k  1
1025 
2 1
1026  2k  k =11
Section – B
47. 3.00
Sol. Given in the figure
(2, 4) (5, 4)
48. 10.50
Sol. n3 = 5x3, m2 = 2x3
n3  m2 7x3 7  3
   10.5
2 2 2
Since, minimum value of x3 = 3
49. 9.00
Sol. g(x) = f(x) – 2f(2x)
g(1) = f(1) – 2f(2) = 5
g(2) = f(2) – 2f(4) = 7
g(1) + 2g(2) = f(1) – 4f(4) = 19
14
h(x) = f(x) – 4f(4x) – 10

h(1) = f(1) – 4f(4) – 10 = 19 – 10 = 9
50. 0.00
f   x 
Sol. g(f(x)) = x  g(f(x)) f(x) = 1  g  f  x    3
 f  x 
1 43
 g  3   and g  3   3
23 5  23 
51. 0.00
x2
Sol. lim f  x   lim

f  x e 2
 lim
 
f   x   2xf   x   x 2  1 f  x 
 lim f  x   0
x  x  x2
e2
x 
1  x 
2 x 
52. 3.00
Sol. f(x) = 1 – (a cos x + b sin x) – (A cos 2x + B sin 2x)
 f(x) = 1  a2  b2 cos  x     A 2  B2 sin  2x   
  a2  b2
 f      1  A 2  B2 cos  2   
4  2
  a2  b2
 f      1  A 2  B2 cos  2   
 4 2
    2 a2  b2
 f     f     2  0  a2  b2  2
 4  4 2
Similarly, f     f       2  2 A 2  B 2  0  A2 + B2  1
53. 4.00
Sol. Applying R1  R1 – R2, R2  R2 – R3
1 1 0
 0 1 1  [z] + [y] + [x] + 1 = 
 x   y   z  1
Maximum value of  = 2 + 0 + 1 + 1 = 4
54. 0.00
Sol. 2 cos               cos              cos              3  0
 2 cos      cos        cos2       2 sin      sin        sin2     
2 2
   sin          sin      0
 sin( + ) + sin( + ) + sin( + ) = 0
 d sin( + ) d sin( + ) + d sin( + ) = 0
 cos( +) d + cos ( + ) d + cos( + ) d = 0
and sin( + ) d + sin( + ) d + sin( + ) d = 0

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

Using conservation of mechanical energy between points P A

Nuber of C atoms – 14 (x)

Nuber of O atoms – 3 (y)

Nuber of N atoms – 0 (z)

cis diol-boric acid complex

From (1) and (2)

Mathematics PART – III

(IV) Counting of terms are 1025  2  21  22  23  .....  2k

h(x) = f(x) – 4f(4x) – 10

Sol. lim f  x   lim

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