Fiitjee All India Test Series: Concept Recapitulation Test - Iv JEE (Advanced) - 2019
Fiitjee All India Test Series: Concept Recapitulation Test - Iv JEE (Advanced) - 2019
Fiitjee All India Test Series: Concept Recapitulation Test - Iv JEE (Advanced) - 2019
Physics PART – I
SECTION – A
1. AD
Sol. f
N2
mg
N1
mgr fR i
N1 sin f mg ii
N1 cos N 2 iii
Solve i , ii & iii to get N 2 and f
So, force at B f 2 N 22
For minimum value of N, use f N2
2. ABC
3g
Sol. Use g eff g sin 37 instead of g in all standard vertical circle cases
5
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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 2
3. ABD
Sol. The impulse exerted by the string on the cylinder is equal and opposite to the impulse exerted by
the cylinder on the string.
10sin
10
10 cos
J 40000 0.25 10 3 10 ms along the string
For marble,
J 0 2 10cos
final velocity along the string is zero.
Putting J 10ms, we get 60
4. ABC
Sol. The ball has v’ component of its velocity perpendicular to the length of rod immediately after
collision u is the velocity of CM of the rod and is the angular velocity of the rod just after
collision.
Write velocity of separation = velocity of approach for the point of collision.
u
D v'
D
Use, conservation of linear momentum perpendicular to the rod and conserve angular momentum
about point D
5. AC
h a
Sol. tan
c g h
6. ABC
2r 2
Sol. The equation of free surface is y y0 y
2g
y0
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3 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
7. BC
x N
Sol. Net force towards the centre of the earth mg ' mg and
R
mg θ R/2
N mg 'sin
2
8. A
9. B
10. C
11. B
12. A
13. C
SECTION – C
14. 2
3L
Sol. Balancing torque about point O, NI R 2 B LRV 2
4
L
[ force exerted by air on rod 2 R 2 L0 RV 2 ]
2
15. 6
Sol. Use Biot-Savart Law:-
0 qV sin
B
4 r 2
16. 7
Sol. At any distance r from the axis
r dr
a
b
0 i
B
2 r
B2 0 i 2
4B
20 8 2 r 2
[Magnetic energy density]
b
du B uB dv
a
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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 4
17. 8
1 2 1 2 1
Sol. Using energy conservation Cv0 Cv L0 I 2
2 2 2
Putting all given values
I=6A
18. 4
Sol. Make two separate equations, one f V t from 0 to 1 ms and the other from 1 to 2 ms
V1 4, for 0 1ms
And V2 4t 4, for t 1 2 ms
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5 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
Chemistry PART – II
SECTION – A
19. ACD
Sol.
Al OH 3 NaOH
Na Al OH 4
sp 2 sp 3
SiF4 2 HF
H 2 SiF6
sp 3 sp 3d 2
PCl4 PCl6
2PCl5
sp 3d sp3 sp3d 2
20. ABC
Sol. At 104.5 angle, p p p Bp Bp Bp
At 102 angle, i.e. bond angle is decreased so, Bp Bp Bp p p Bp similarly at 106
angle, is bond angle is increased, p p p Bp Bp Bp Bp
Water can form maximum of 4 hydrogen bonds.
21. ABCD
Sol. Salt has equal moles of Na2CO3 and NaHCO3 when phenol phthalein indicator is used, only
reaction occur till end point is
Na2 CO3 HCl
NaHCO3 NaCl
40 mL 40 mL
0.05M 0.05M
x 40 mL
When methyl orange is used in an independent titration, 2x mL of HCl would be required for
Na2CO3 and x mL for original NaHCO3.
y 3x 3 40 120 mL
Hence y x 80 and y x 160
If methyl orange is added subsequently at phenol phthalein end point, x mL of HCl would be
required for NaHCO3 produced from Na2CO3 and x mL for original NaHCO3 i.e. a total of 2x mL of
HCl would be required further.
NaOH NaHCO3
Na2CO3 H 2O
2m mol 2m mol
2 x
Volume of NaOH required 20 mL mL
0.10 2
22. ABC
Sol. (A) Molar volume of ideal gas at STP is 22.4 L
(B) AT critical point, z = 3/8
2
(C) Pc a / 27b , hence large ‘b’ implies low critical pressure.
(D) As p 0, gas approaches ideal behaviour hence PV=const. and PV/RT = 1 .
23. CD
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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 6
Sol. Weak acid and weak base gives less heat in neutralisation hence smaller temperature rise than in
cane of strong acids and bases if all other conditions are same.
24. AB
Sol. (A) As some ammonia is removed by 2nd reaction, some N2H4 would decompose to restore 1st
equilibrium.
(B) As K1 <K 2 , less ammonia will be formed than it is decomposed.
(C) Partial pressure of N2 will increase but it cannot be predicated with guarantee that it would be
doubled.
25. ABCD
Sol. Pb CH 3COO 2 +K 2 CrO 4
PbCrO 4 +K CH3COO
Yellow
Pb NO3 2 +K 2 CrO 4
PbCrO 4 +KNO3
Yellow
AgNO3 +KI
AgI+KNO3
Yellow
H 2S+CdSO 4
CdS+H 2SO 4
Yellow
26. C
27. D
28. C
29. C
30. B
31. A
SECTION – C
32. 4
Sol. H + +HCO3-
H 2 CO3 Ka1 4.0 107
H + +CO32-
HCO3- Ka 2 5 1011
On adding above two equilibria
2H + +CO32- Ka=2.0×10-17 1
H 2 CO3
K sp = M +2 CO32-
2- K sp 2×10-12
CO3 minimum
= = =2×10-11M
M +2 0.1
For equation (1)
2
H + CO32-
Ka =
H2CO3
2
H + ×2×10-11
2×10 -17
0.01
H 10
+ 4
pH=4
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7 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
33. 3
Sol. w 3320 p0 V nR T
3320
T 200
2 8.3
q 14.94 kJ nC p T
19.94 1000
And C p 37.35 jK 1 mol 1
2 200
3
Also C p x R, where x = atomicity.
2
C p 3 37.35
x 1.5 3
R 2 8.3
34. 7
Sol. 0.0591
ECl / AgCl / Ag E Ag
/ Ag
10 g K sp
1
0.0591
0.209 0.80 10 g K sp
1
K sp 1010
Let solubility of AgCl in 0.01 M
Ag Cl
AgCl
1010 x x 0.01
x 108
Moles of AgCl dissolved in 10 L = 10-8×10=10-7
y 7
35. 6
Sol. KC
AB2 1 x 1 x x 2
A B 2 4 2 2 2 4 2 4
AB 2 2
Now let y moles of AB2 is added
KC
2 y
1
2
2 2 2 4
2 y 1
2
2 4 4
2 y
1
8
y 82
y6
36. 6
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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 8
SECTION – A
37. ABD
3
Sol. sin 3 x cos 3 y 2 3.sin x cos y 2
sin x cos y 2 0
sin x cos y 2
sin x 1 & cos y 1
x and y 0, 2
2
38. AD
Sol. tan sin cot cos
2 2
tan sin tan cos
2 2 2
sin n cos
2 2 2
sin cos 2n 1
sin cos 1, 1
1
sin
4 2
n
n 1
4 4
3
0, , , , 2
2 2
3
But & are not in domain
2 2
3
sin 0,
3 2
39. ACD
Sol. a cos i sin
b cos i sin
c cos i sin
then a b c 1 i
Where a, b, c are complex numbers on the unit circle. Now to minimise cos , consider a triangle
with vertices a,1 i and the origin. We want a as far away from 1 i as possible while
maintaining a nonnegative imaginary part. This is achieved when b and c have the same
argument, so b c 1 i a 2 .
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9 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
cos
12 2 22
2 1 2
1
2 2
and cos cos
4
cos cos sin sin
4 4
1 7
4
40. AB
1
Sol. Substituting x y
2
4 3 2
1 1 1 1
8 y 16 y 16 y 8 y a 0
2 2 2 2
3
8 y 4 4 y2 a 0
2
2
Let y z
3
8 z 2 4 z a 0
2
Case I:
3
If a
2
All roots are non-real
sum 2
Case II
3
If a
2
2
8z 4 z 0
2z2 z 0
1
z 0; z
2
1
y 2 0; y 2
2
2 2
1 1 1
x 0; x
2 2 2
1 1
x , ; 2 non real roots
2 2
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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 10
1 1
sum 2
2 2
1
Case III
3
a
2
Let z k1 & k2
y 2 k1 y k1
1 1
x y k1
2 2
1
x k1
2
1 1
sum 2 k1 k1
2 2
1
41. ABC
Sol.
c
iˆ 2 ˆj kˆ
6
ˆ ˆ
Let a i j 2kˆ and b iˆ 2 ˆj kˆ
A vector coplanar to a and b and perpendicular to c
a b c a c b b c a
6
1 2 2 i 2 ˆj kˆ 1 4 1 iˆ ˆj 2kˆ
ˆ
6
3i 4 ˆj 5kˆ
6
For 6, 3 and
3
42. ABCD
Sol. (A) x y 1
x y 2 xy 1
x 2 2 xy y 2 2 x 2 y 1 0 is a parabola
1 1
(B) 1 xy x y 0 is a hyperbola
x y
1 1 1
(C) 0 x 2 3 xy y 2 0 pair of straight lines
x y x y
1 2
(D) x y 0 x y 1 0 pair of straight lines
x y
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11 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
43. ACD
n 2n
3n 2 n
Sol. As A
0 3n
a d 210 310 45 95 multiple of 13
10 10
Also d b 2 , a b c d 2 3
44. B
45. C
46. C
Sol. (for Q. 44 to Q. 46)
3
(I)
3 1 3 3
x 1 x 3
4
4 x2 4 x2
(II) u sin ln cos ln
1 x 1 x
4 x2
0
1 x
4 x2
ln
1 x
So, 2 u 2
1 1
(III) Let x 5 t ; g t 0,
2 4
t 2
g t
t 2 t 2
1
(IV) 0 cos x
ln cos 1 x ln 2
47. B
48. A
49. C
Sol. (for Q. 47 to Q. 49)
Point 1, a1 ,1 lies on P1 and P2
2 3a1 4 9 a1 1
b1 , b2 ,1 is to normal of planes P1 , P2 & P3
2b1 3b2 4 0
4b1 5b2 6 0
b1 1, b2 ... a 2, b 3
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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 12
SECTION – C
50. 5
Sol. First note that out of the 8 selected cards, one pair of cards have to share the same number and
another pair of cards have to share the same colour. Now, these 2 pairs of cards cannot be the
same or else there will be 2 cards which are completely same.
Then WLOG let the numbers be 1,1, 2,3, 4,5, 6 and 7 and the colours be
a, a, b, c, d , e, f and g . We therefore obtain only 2 cases:
Case I: 1a 1b 2a ,3c, 4 d , 5e,6 f , 7 g . In this case, we can discard 1a
There are 2 6 12 situation in this case
Case II: 1b,1c, 2 a ,3a , 4 d ,5e, 6 f and 7g . In this case, we cannot discard. There are
6
C2 15 situations in this case.
12 4
Probability pq 5
12 15 9
51. 1
e n 1 1 e n 1
n
y
Sol. f y e lim n
n 1 e 1 e
n 1
n 1
n
1 1
e y lim n n 1
n
n 1 e e 1
ey
e 1
1 1
1
f x dx e x dx 1
0 e 1 0
52. 0
3 3
Sol. x 1 y 1 16
3 1/3
y 1 16 x 1 f x
3 1/3
x 1 16 y 1
3 1/3
f x 1 16 x 1 g x
1
f x g x
f 1 3 15 g 1 3 15 0
2
f x g x .g x f x f x f x
d 2
dx
f x f x 2 f x f x . f ' x f x . 1 f ' x
d 2
dx
f x f x at x 1 3 15 0
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13 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
53. 1
Sol. Since 23 1 mod 7
1.2 2.3 3.4 2011.2012
2 2 2 2
Let S 2 2 2 ........ 2
2 20 20 21 ........ 20 21 mod 7
1
2010 1 0
3
2 2 20 21 mod 7
670 4 2 mod 7
1 mod 7
54. 1
1
x 1 1 2
x2 1 x
2 x 1 x2 1
Sol.
1 x4
x2 1
x2 1
1
2
4 2
x 1 1
x
2
x3 x 4
1
x4 2
4
x
1
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