Fiitjee All India Test Series: Concept Recapitulation Test - Iv JEE (Advanced) - 2019

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FIITJEE

ALL INDIA TEST SERIES


CONCEPT RECAPITULATION TEST – IV
JEE (Advanced)-2019
PAPER – 1

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

SECTION – A

1. AD
Sol. f

N2

 mg
N1
mgr  fR    i 
N1 sin   f  mg    ii 
N1 cos   N 2     iii 
Solve  i  ,  ii  &  iii  to get N 2 and f
So, force at B f 2  N 22
For minimum value of N, use f   N2

2. ABC
3g
Sol. Use g eff  g sin 37  instead of g in all standard vertical circle cases
5

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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 2

3. ABD
Sol. The impulse exerted by the string on the cylinder is equal and opposite to the impulse exerted by
the cylinder on the string.

10sin 

10

10 cos 

J  40000  0.25  10 3  10 ms along the string
For marble,
J  0   2 10cos  
 final velocity along the string is zero.
Putting J  10ms, we get   60

4. ABC
Sol. The ball has v’ component of its velocity perpendicular to the length of rod immediately after
collision u is the velocity of CM of the rod and  is the angular velocity of the rod just after
collision.
Write velocity of separation = velocity of approach for the point of collision.
u

D v'
D
Use, conservation of linear momentum perpendicular to the rod and conserve angular momentum
about point D

5. AC
h a
Sol. tan   
c g h

6. ABC

 2r 2
Sol. The equation of free surface is y   y0 y
2g

y0

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3 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19

7. BC
x N
Sol. Net force towards the centre of the earth  mg '  mg and
R  
mg θ R/2
N  mg 'sin   
2

8. A
9. B
10. C
11. B
12. A
13. C

SECTION – C

14. 2
3L
Sol. Balancing torque about point O, NI  R 2  B   LRV 2
4
 L 
[ force exerted by air on rod    2 R   2   L0 RV 2 ]
 2 
15. 6
Sol. Use Biot-Savart Law:-
0 qV sin 
B
4 r 2

16. 7
Sol. At any distance r from the axis

r dr

 a

b
0 i
B
2 r
B2 0 i 2
4B  
20 8 2 r 2
[Magnetic energy density]
b

 du B   uB dv
a

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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 4

17. 8
1 2 1 2 1
Sol. Using energy conservation Cv0  Cv  L0 I 2
2 2 2
Putting all given values
I=6A

18. 4
Sol. Make two separate equations, one f V  t  from 0 to 1 ms and the other from 1 to 2 ms
V1  4, for 0  1ms
And V2  4t  4, for t  1  2 ms

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5 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19

Chemistry PART – II

SECTION – A

19. ACD
Sol.
Al  OH 3  NaOH 
 Na  Al  OH 4 
sp 2 sp 3
SiF4  2 HF 
 H 2 SiF6
sp 3 sp 3d 2
 PCl4  PCl6
2PCl5 
sp 3d sp3 sp3d 2
20. ABC
Sol. At 104.5 angle, p  p  p  Bp  Bp  Bp
At 102 angle, i.e. bond angle is decreased so, Bp  Bp  Bp  p  p  Bp similarly at 106
angle, is bond angle is increased, p  p  p  Bp  Bp  Bp  Bp
Water can form maximum of 4 hydrogen bonds.
21. ABCD
Sol. Salt has equal moles of Na2CO3 and NaHCO3 when phenol phthalein indicator is used, only
reaction occur till end point is
Na2 CO3  HCl 
 NaHCO3  NaCl
40 mL 40 mL
0.05M 0.05M
x  40 mL
When methyl orange is used in an independent titration, 2x mL of HCl would be required for
Na2CO3 and x mL for original NaHCO3.
 y  3x  3  40  120 mL
Hence y  x  80 and y  x  160
If methyl orange is added subsequently at phenol phthalein end point, x mL of HCl would be
required for NaHCO3 produced from Na2CO3 and x mL for original NaHCO3 i.e. a total of 2x mL of
HCl would be required further.
NaOH  NaHCO3 
 Na2CO3  H 2O
2m mol 2m mol
2 x
Volume of NaOH required   20 mL  mL
0.10 2
22. ABC
Sol. (A) Molar volume of ideal gas at STP is 22.4 L
(B) AT critical point, z = 3/8
2
(C) Pc  a / 27b , hence large ‘b’ implies low critical pressure.
(D) As p  0, gas approaches ideal behaviour hence PV=const. and PV/RT = 1 .

23. CD

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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 6

Sol. Weak acid and weak base gives less heat in neutralisation hence smaller temperature rise than in
cane of strong acids and bases if all other conditions are same.
24. AB
Sol. (A) As some ammonia is removed by 2nd reaction, some N2H4 would decompose to restore 1st
equilibrium.
(B) As K1 <K 2 , less ammonia will be formed than it is decomposed.
(C) Partial pressure of N2 will increase but it cannot be predicated with guarantee that it would be
doubled.
25. ABCD
Sol. Pb  CH 3COO  2 +K 2 CrO 4 
 PbCrO 4 +K CH3COO
 Yellow 
Pb  NO3  2 +K 2 CrO 4 
 PbCrO 4 +KNO3
 Yellow 
AgNO3 +KI 
 AgI+KNO3
 Yellow 
H 2S+CdSO 4 
 CdS+H 2SO 4
 Yellow 
26. C
27. D
28. C
29. C
30. B
31. A
SECTION – C
32. 4
Sol.  H + +HCO3-
H 2 CO3  Ka1  4.0 107
 H + +CO32-
HCO3-  Ka 2  5  1011
On adding above two equilibria
 2H + +CO32- Ka=2.0×10-17    1
H 2 CO3 
K sp =  M +2   CO32- 
2- K sp 2×10-12
 CO3  minimum
= = =2×10-11M
 M +2  0.1
For equation (1)
2
 H +  CO32- 
Ka =
 H2CO3 
2
 H +  ×2×10-11
2×10  -17

0.01
  H   10
+ 4

pH=4

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7 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19

33. 3
Sol.  w  3320  p0 V  nR T
3320
 T   200
2  8.3
 q  14.94 kJ  nC p T
19.94  1000
And C p   37.35 jK 1 mol 1
2  200
3 
Also C p    x  R, where x = atomicity.
2 
C p 3 37.35
x    1.5  3
R 2 8.3
34. 7
Sol. 0.0591
ECl  / AgCl / Ag  E Ag


/ Ag
 10 g K sp
1
0.0591
0.209  0.80  10 g K sp
1
 K sp  1010
Let solubility of AgCl in 0.01 M
  Ag   Cl  
AgCl    
1010  x  x  0.01
x  108
Moles of AgCl dissolved in 10 L = 10-8×10=10-7
y 7

35. 6

Sol. KC 
 AB2   1  x  1  x  x  2
 A B 2 4 2   2 2 4 2  4
 AB 2  2
Now let y moles of AB2 is added

 KC 
2  y 
1
2
2  2  2 4
2 y 1
 2

2   4 4
2 y
 1
8
y 82
y6
36. 6

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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 8

Mathematics PART – III

SECTION – A
37. ABD
3
Sol. sin 3 x  cos 3 y   2   3.sin x cos y  2 
 sin x  cos y  2  0
 sin x  cos y  2
sin x  1 & cos y  1

x and y  0, 2
2
38. AD
   
Sol. tan  sin    cot  cos  
2  2 
    
tan  sin    tan   cos  
2  2 2 
  
 sin   n   cos 
2 2 2
 sin   cos   2n  1
 sin   cos   1,  1
  1
 sin      
 4 2
 n 
   n   1
4 4
 3
  0, ,  , , 2
2 2
 3
But   & are not in domain
2 2
 3
 sin  0,
3 2
39. ACD
Sol. a  cos   i sin 
b  cos   i sin 
c  cos   i sin 
then a  b  c  1  i
Where a, b, c are complex numbers on the unit circle. Now to minimise cos  , consider a triangle
with vertices a,1  i and the origin. We want a as far away from 1  i as possible while
maintaining a nonnegative imaginary part. This is achieved when b and c have the same
argument, so b  c  1  i  a  2 .

Now a, O and 1  i form a triangle having side lengths 1, 2, 2

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9 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19

 cos  
12   2  22
2 1  2
1

2 2
 
and cos   cos    
4 
 
 cos cos   sin sin 
4 4
1  7

4
40. AB
1
Sol. Substituting x  y 
2
4 3 2
 1  1  1  1
8  y    16  y    16  y    8  y    a  0
 2  2  2  2
 3
 8 y 4  4 y2   a    0
 2
2
Let y  z
 3
8 z 2  4 z   a    0
 2
Case I:
3
If a 
2
All roots are non-real
sum  2
Case II
3
If a 
2
2
8z  4 z  0
 2z2  z  0
1
 z  0; z  
2
1
 y 2  0; y 2  
2
2 2
 1  1 1
  x    0;  x   
 2  2 2
1 1
 x  , ; 2 non real roots
2 2

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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 10

1 1
sum  2     
2 2
    1
Case III
3
a
2
Let z  k1 &  k2
 y 2  k1  y   k1
1 1
x y   k1 
2 2
1
x    k1
2
1  1 
 sum  2    k1     k1     
2  2 
   1
41. ABC

Sol.

c

iˆ  2 ˆj  kˆ 
6
 ˆ ˆ 
Let a  i  j  2kˆ and b  iˆ  2 ˆj  kˆ
  
 A vector coplanar to a and b and perpendicular to c
        
   
  a  b  c   a  c b  b  c a  


6
   
 1  2  2  i  2 ˆj  kˆ   1  4  1 iˆ  ˆj  2kˆ 
 ˆ

6

3i  4 ˆj  5kˆ 
6
For    6,    3 and  
3
42. ABCD
Sol. (A) x  y 1
 x  y  2 xy  1
 x 2  2 xy  y 2  2 x  2 y  1  0 is a parabola
1 1
(B)   1  xy  x  y  0 is a hyperbola
x y
1 1 1
(C)    0  x 2  3 xy  y 2  0 pair of straight lines
x y x y
1 2
(D) x  y   0   x  y   1  0 pair of straight lines
x y

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11 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19

43. ACD
n 2n
3n  2 n 
Sol. As A   
0 3n 
a  d  210  310  45  95 multiple of 13
10 10
Also d  b  2 , a  b  c  d  2  3

44. B
45. C
46. C
Sol. (for Q. 44 to Q. 46)
3

(I)
 3  1 3 3
 x 1  x  3  
4
  4  x2     4  x2  
(II) u  sin  ln     cos  ln  
  1 x    1 x  
     
4  x2
0  
1 x
 4  x2 
  ln  
 1 x 
 
So,  2  u  2
 1 1
(III) Let x  5  t ; g  t    0,    
 2 4
t 2
g t  
 t  2  t  2
1
(IV) 0  cos x 
  ln  cos 1 x   ln   2

47. B
48. A
49. C
Sol. (for Q. 47 to Q. 49)
Point 1, a1 ,1 lies on P1 and P2
2  3a1  4  9  a1  1
 b1 , b2 ,1 is  to normal of planes P1 , P2 & P3
2b1  3b2  4  0
4b1  5b2  6  0
 b1  1, b2  ... a  2, b  3

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AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 12

SECTION – C
50. 5
Sol. First note that out of the 8 selected cards, one pair of cards have to share the same number and
another pair of cards have to share the same colour. Now, these 2 pairs of cards cannot be the
same or else there will be 2 cards which are completely same.
Then WLOG let the numbers be 1,1, 2,3, 4,5, 6 and 7 and the colours be
a, a, b, c, d , e, f and g . We therefore obtain only 2 cases:
Case I: 1a 1b 2a ,3c, 4 d , 5e,6 f , 7 g . In this case, we can discard 1a
There are 2  6  12 situation in this case
Case II: 1b,1c, 2 a ,3a , 4 d ,5e, 6 f and 7g . In this case, we cannot discard. There are
6
C2  15 situations in this case.
12 4
Probability    pq 5
12  15 9
51. 1
  e n 1  1   e n  1 
n
y
Sol. f  y   e lim   n 
n 1   e  1 e 
n 1
n   1 
 
n
1 1 
 e y lim   n  n 1 
n
n 1  e e 1 
ey

e 1
1 1
1
  f  x dx   e x dx  1
0 e 1 0

52. 0
3 3
Sol.  x  1   y  1  16
3 1/3

y  1  16   x  1   f  x
3 1/3
x  1  16   y  1 
3 1/3
 f  x   1  16   x  1   g  x 
1

 f  x  g  x

  
f 1  3 15  g 1  3 15  0 
2
 f  x  g  x   .g  x  f  x    f  x  f  x    
d 2

dx

f  x  f  x    2 f  x  f  x   . f '  x  f  x   . 1  f '  x  
d 2

dx

f  x  f  x   at x  1  3 15  0

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13 AITS-CRT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/19

53. 1
Sol. Since 23  1 mod 7 
1.2 2.3 3.4 2011.2012
2 2 2 2
Let S  2  2  2  ........  2
  2  20  20  21  ........  20  21   mod 7 
1

 2010 1 0 

 3
 2  2  20   21   mod 7 

  670  4  2  mod 7 
 1 mod 7 

54. 1
1
  x 1 1  2
     
 x2  1  x
2 x  1  x2  1 
Sol.
  1  x4 
  x2 1   
  x2 1 
 
1
2
  4  2
x  1 1
 x 
2
  
  x3  x 4 
   
1
 x4  2
 4
x 
1

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