Aits 2223 PT II Jeea TD Paper 2 Sol

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2023
PART TEST – II
PAPER –2
TEST DATE: 11-12-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. C
Sol. 
i  i0 1  e t/  
di i  t/ 
 e
dt 
1
U  Li2
2
dU 1  di 
 L  2i   ke t (1  e t )
dt 2  dt 
dU
at t = 0, 0
dt
du
t  , 0
dt
2. A
k 0 A
Sol. dC 
dx
1 1 1
CeV

dC 
  k A dx
0
d
1
 k e
0 0
x
0 A
dx
 k 0 0 A
Ceq 
1  ed
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AITS-PT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 2
3. B
d
Sol. H  kA
dx
The heat current decreases from the end P and Q through the rod hence slope of (T-x) graph
also decreases.
4. C
kq0 (2q)
Sol. U
z2  2a2
5. A, B, D
Sol. At time ‘t’ (10  q) (10 + q)
q 8 10  q
 i  0 5F
4 3 5
q t i
dq 3

0 2
9

q 0
8dt
+q q
20
27 
40   t
4F
(8/3)
q 1  e 160  ,
9  

27
dq 3  t
 i  e 160
dt 4
(10)2
Ui 
25
(40 / 9)2 (50 / 9)2
Uf  
24 25
40
U  Ui  Uf  J
9
6. B, C
Sol. Current in the circuit
5 20
i 
R 3R
R
2
20
 Potential drop across PS = iR = V
3
R 10
Potential drop across SQ = i   = V
2 3
20 / 3 4
 Potential q radiant for PS =  V/m
5 3
10 / 3 2
Potential q radiant for SQ =  V/m
5 3
5
 Length required for 5V = V= 3.75 m
4/3
20
8
Length required for 8V = 5  3  7m
2/3
3 AITS-PT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023
7. A, C
Sol. When charge particle is moved from ‘S’ to infinity then induced electric field is perpendicular to
the displacement hence work done by external agent is zero.
From P to infinity
Work done = q(change in potential difference)
r 2 dB 55
= q  J
4 dt 8
8. A, C, D
Sol. Before switch is closed 2F S
10V
q
10  q0  0  0
2
5V +q0 q0 Before switch
20
q0  C is closed
3 q0 +q0
After switch is closed 2F 10V

From KVL,
q  q1 q0  q + 
5  0 5V q0 + q q0 q1 After switch
2 1
1F 2F is closed
q  q q0  q q0 q q0 + q1
10  0  0
1 2 q
On solving,
q  q1 q1
2 4
q   C, q1  C
3 3
1 (20 / 3)2 1 (20 / 3)2 100
Ui    J
2 1 2 2 3
1 (6)2 1 (8)2 1 (2)2
Uf     35 J
2 1 2 2 2 2
4 10
WB  5( 2)  10   J
3 3
5
So, heat required = J
3
9. A
kQ R
Sol. Potential at ‘C’ = 
R 20
Flat surface of hemispherical shell is on equipotential surface.
10. B, C
Sol. ff  mg
a  g
v t

v0

dv  g dt
0
v  v0  gt
v  v 0  gt
 dm 
 L   ff v  mg(v 0  gt)
 dt 
m t
 dm  g

m0

 m  0 L 
   (v 0  gt)dt
m g  gt 2 
n    v0t  
m0 L  2 
g  gt 2 
  v0t  
L  2 
m  m0 e
Section – B
11. 4
1 R C
Sol. mv 2C  qE  …(i)
2 2 
1 E
mvB2  qE  R …(ii)
2
v2 qE
At C, aC  C  A B
R m
2
v 2qE
At B, aC  B 
R m
2 2
 qE   qE 
a1     
 m   m 
2 2
 qE   2qE 
a2     
 m   m 
a1 1  2

a2 1  4 2
12. 2
30
Sol. 1 = L11T = (1.7  10 5 )  100  0.51 mm
100
 2  (1.91  0.51)  1.4 mm
So,  2  L2  2 T
 2  2  10 5 /C
13. 2

Sol. B  4iˆ  ˆj  kˆ

v  ˆi  2ˆj  3kˆ
  
So, F  q(v  B)  q( 5iˆ  11jˆ  9k)
ˆ
| F | q 227
| v |2
R  2  103 m = 2 km
aC
14. 2
1 1 1 1
Sol.   
Req R1 R2 R3
k eq A  k1A1  k 2 A 2  k 3 A 3
k1  k 2  k 3
k eq   2 W/mK
3
15. 3
d dB dx
Sol. emf   x 2 (dN)
dt dt x
b
N  dB  2 14 O
 
b  a  dt 
x dx 
a
3
volt
emf
i 3A
R
16. 7
Sol. Req between points x and z
28
Req  
13
r 10V
3
x 3
z
3 3
3
18
3 18
w y
x y w z
12 3 12
z 6
3
17. 6
Sol. Immediately after the switching, current in the branch of inductor will not change and charge on
capacitor will be zero.
18. 3
Sol. T1cos60 + T2 cos60 = mg
T1 + T2 = 2mG …(i) P
Taking torque about ‘O’
   
(T2 cos60)R  |   B | (T1 cos60)R …(ii)
T1 T1 T2
On solving 3 T1cos60
 T2cos60
T2 i 
S O T x


mg
z
Chemistry PART – II
Section – A
19. D
Sol. Option (D) has longest chain of 5C-atom which is same as in the compound given
5 4 1
H3C CH3 H2C CH2
3
2
2 3
H2C CH3 H3C CH3
4 5
1
20. C
Sol. O R2 O R2
R1 C OH R1 C OH
N C HNO2 N C


NH2 H O N2 H O
Hydrolysis
O R2
R1 OH
OH  H2N
OH O
Lactic acid [y]
(R1 = CH3)
R2 O
OH NH
H2N 
 
O HN
O
2,5-diketopiperazine(R2 = H)
21. B
Sol.
Me Me Me
S 1
I  Me CH Me N

H O

2
Me CH Re arrange
Me   Me C CH Me
 
 CH shift 
Me Br Me  3  Me
Me Me
II Me CH Ph N

S 1
H O
 Me CH Ph (No rearrangement further)
2
Me Br Me
22. C
Sol. H2C OH
O
H OH
H gives positive Tollen's test and

OH H
NH2OH/H+ due to presence of
Hemiacetal linkage.
OH H
H OH
  D  Glucopyranose
23. A, B, D
Sol. O OH
Et2 O
C  MeMgBr   Ph C Ph
H /H O
Ph Ph 2
Me
O OH
2 Et O
C  PhMgBr 
NH Cl
 Ph C Ph
4
Ph Me
Me
O OH
Et 2O
C  Ph  CH2  MgBr   Ph CH CH2 Ph
H / H O
Ph H 2
O OH
Et 2O
C  2PhMgBr   H3C C Ph
H /H O
H3C OEt 2
Ph
24. A, C
Sol. OH OH
Br Br
Br  excess 
2

H O

2
SO 3H Br
(Major)
OH OH
Br /CS
2 2
o 
0 C
Br
(Major)
OH OH
Br Br
KBrO  KBr
3

H O

2 KBrO 3  KBr  H2 O  Br2 
Br
(Major)
NO 2
Br Br
1. aq. KOH
   No reaction
2. H
Br
25. C, D
Sol. [F]
CH3 O
O O CH CH2 CH3
C OH [G]
CH3

H /H2 O/ 
   HO CH CH2 CH3
E 1. NH3 ,  Liberate CO2

P  PBr3 or HBr
2. NaOH  Br2
with NaHCO3
OH 3. NaNO2  dil. HCl CH3

4. H2 O, warm Br CH CH2 CH3
[I]
Q MF
[M] N/D Q 
C Mg / dry ether
Na
CH3 CH3
NC CH CH2 CH3 MgBr CH CH2 CH3

[J]
H3 O /  R  1. CO2 , 2. H
O CH3
CH3
HO C CH CH2 CH3
HOOC CH CH2 CH3
K 
K 
M , H
M , H
O CH3
CH3
O C CH CH2 CH3
O C CH CH2 CH3
O
L  is metamer of E 
26. A, B, D
Sol. O O
[P] can be H2C O and H3C O
(Two structural isomers)

O OH O O O
H2C
1. aq.NaOH
O   H2C C CH2 C OH H3C C CH2 C OH
2. H
Q 
P
,  CO2
H3C C CH3 [R]

O
NaOH 
CH3 O
H3C C CH C CH3
[S]
O OH O O O
H3C
1. aq.NaOH
O   H3C C CH C OH H3C C CH2 C OH
2. H
Q 
P
,  CO2
O
H3C C CH3 R 
NaOH 
CH3 O
H3C C CH C CH3
S 
27. B, C, D
Sol. C N H2C NH2
CONH2 P2 O5 Re duction
 
LiAlH4
P
N C HN CH3
 i Br2  KOH
Re duction
  
 ii  CHCl3  OH LiAlH4
 Q
C N COOH
O O
H /H2O Ca  OH2
   C O 
 
2 Ca C
Hydrolysis
P 
Benzophenone
NC +
NH2 N2 Cl
2H /H O NaNO
2
  
HCl

Q
Mild basic OH
HO N N
Orange red dye

CONH2 NH2 N C

2Br  KOH CHCl3  O H

Hoffman bromamide deg radation
  
Carbyla min e reaction
 Cl
CHCl3  O H  C  dichlorocarbene 
Cl
28. A, B, C
Sol. Ph O Ph OH O
H /H2 O Ph OH

  Ph  H3C C CH3
O O OH
OH
O
O
Ph C H
Ph C H
O O O O
dil.NaOH
Ph C H  Ph C H  H3C C CH3  
 Ph CH CH C CH CH Ph
P 
NH2  OH
OH
N
Ph CH CH C CH CH Ph
Number of stereoisomers  4 
Section – B
29. 9
Sol. H
N 1. CH3 Cl/ AlCl3 I
2. NaOH, H O/ 
2

3. Br /CH COOH mono bromination 

2 3
O 4. NaNO 2 /dil.HCl 273 K 
5. KI H3C Br
P 
H I
N 1. Br2 /Fe  mono bromination 
2. Cl /Fe mono chlorination 
2

3. ICl/AlCl mono halogenation 

3
O 4. NaOH, H2O/ 
5. NaNO2 /dil. HCl 273 K  Br Cl
5. H3PO2
 Q
Br Cl
Cl 1. HNO3  H2SO 4

2. H2 /Pd  C

3. Br2 /H2 O
4. NaNO2 /dil. HCl 273 K  I
5. KI
Br
R
30. 3
Sol. I, III and VI compounds satisfy the conditions
31. 2
Sol. General formula of isomeric ketone of MW = 100 is C6H12O possible structures:
O O
(A) (B)
H3C CH2 CH2 C CH3 H3C CH2 CH2 C CH2 CH3
O
O
H3C CH CH2 C CH3
(C) H3C CH2 CH C CH3
CH3 (D)
CH3
O
CH3 O
H3C CH CH CH2 CH3
(E) H3C C C CH3
CH3 (F)
CH3
Compound B and E will give racemic mixture.
32. 4
Sol. CHO COOH
Br
2
(CHOH)4 
H O
 (CHOH)4
2
H2C OH H2C OH
D-Glucose Gluconic acid
33. 7
Sol. Statements 1, 2, 4, 5, 6, 7 and 10 are correct.
34. 9
Sol. 6.HBr /ROOR/ 
10. t BuOK / 

4. BH .THF

3
9.H2 O2 , aq. NaOH OH
35. 5
Sol. CH3 CH3
HBr 1 eq.
H2C C CH CH2   H3C C CH CH2
1,4  addition at 298 K 
[A] [B] Br
[Major]
36. 2
Sol. OH
H /  aq. dilute KMnO 4  excess 
  273K

HO
HO H3C OH
H3C OH
P   Q
Mathematics PART – III
Section – A
37. A
cos A  b2  c 2  a2  b c
  
sin A cos A sinB sinC  2bc  2R 2R 57a2 bc 57
Sol.  =   
 cosB sinC  sinB cos C  2
sin A a 2
8  2bc a 2 16
sinB sinC 4R 2
38. B
2 2 C3
Sol. DE  AK  r1  r2    r2  r1   2 r1r2 C2
C1
Similarly, BL = EF = 2 r2r3
A B C
Let APD =  and PD = x, then P  K L
AD BE CF
tan     D
PD PE PF E
r r2 r3 F
 1  = k (say)
x x  2 r1r2 x  2 r1r2  2 r2 r3
r2  r1 r3  r2
r1  kx, r2  kx  2k r1r2 , r3  kx  2k r1r2  2k r2r3 ;   r2  r1r3  4  9  6
2 r1r2 2 r2r3
39. C
x2 y2
Sol.   1  S is (4, 0)
25 9
Let image of S in any tangent be P(h, k),
Midpoint of SP will lie on auxiliary circle
( foot of perpendicular from focus on any tangent lies on auxiliary circle)
h4 k  2 2 2 2
  ,  lies on x + y = 25  locus of image is (x+ 4) + y = 100
 2 2
0  8  22 2
It touches ky – 2x + 22 = 0   10  k + 4 = 9  k =  5
k2  4
40. C
Sol. AOB = 90 (as AB is diameter) A  2t12 , 4t1 
 Slope of OA  Slope of OB = –1
2 2
  1  t1t2 = –4
t1 t 2
Point of intersection of tangent at A and B is O
C(2t1t2, 2(t1 + t2)) = C(–8, 2(t1 + t2))
If perpendicular tangents are drawn from C to
y2 = kx, then C must be on its directrix  k = 32
B  2t 22 , 4t 2 
41. A, B, C
2 4 6 2 4 8
Sol. f  3   cos  cos  cos and g  3   cos  cos  cos
7 7 7 7 7 7
6 8
 cos  cos  f(3) = g(3)
7 7
2 4 6 8 10 12
f  6   cos  cos  cos  cos  cos  cos =
7 7 7 7 7 7
 2 4 6 
2  cos  cos  cos   2f  3 
 7 7 7 
( cos  = cos(2 – ))
2 4 8 16 32 64
g  6   cos  cos  cos  cos  cos  cos
7 7 7 7 7 7
 64  8  32  4  16  2  
 cos  cos , cos  cos , cos  cos   g(6) = 2g(3)
 7 7 7 7 7 7 
42. A, B, C, D
4 B P(, 2)
Sol. B(0, 2) and C is (0, –2). Slope of PQ =
 
4
Equation of PQ y – 2 =  x  
 
y( – ) – 2( – ) = 4x – 4 A(a1, a2)
4x – y( – ) – 2( + ) = 0
0  0  2    C Q(, –2)
 it touches x2 + y2 = 4  2
2
16      
4 3 a 3
  = 4  If  = 4 slope of PQ   Slope of OA    2  
3 4 a1 4
43. A, D
dy dy x  dy 
Sol. X2 = 4ky  2x  4k     1
dx dx 2k  dx  2k, k 
 Slope of normal at (2k, k) = –1 (2k, k)
 Equation of normal y – k = –1(x – 2k)  x + y = 3k
If k = 1, equation of normal x + y = 3
 Shortest distance lies along the common normal
 It passes through (, –3) ;  – 3 = 3   = 6 (, –3)
 If k = 2, x + y = 6 passes through (, –3)   = 9
 If  = 20  x + y = 3k passes through (20, –3)
17
 k
3
44. B, C
s  q s r p qr
Sol. sp    k  say   s   q + r – p = 2k ; p + r – q = 8k ; p + q – r = 12 k
4 6 2
 p = 10k, r = 5k, q = 7k  S = 11k    s  s  p  s  q  s  r 
pqr 175 5k  7k  10k
   11k  k  4k  6k  2 66 k 2 ; Circumradius =   k=1
4 4 66 4  2 66 k 2
P Q R
 Area = 2 66 inradius = 4(Circumradius) sin sin sin
2 2 2
6 175 P Q R
 2  4  sin sin sin
11 4 66 2 2 2
45. A, C, D
Sol. Area of inscribed rectangle x2 y2
= 2a cos   2a sin  = 2ab sin 2  1
a2 b2
(Here, a  4 2 ; b  2 2 ) (–a cos , b sin ) A(a cos , b sin )
Maximum value = 2ab when  = 45
 Area of R1 = 2ab
and sides of r1 are a 2 ; b 2
Let major axis and minor axis of E2
be 2a2, 2b2
(–a cos , b –sin ) B(a cos , b –sin )
a b
 2a2  a 2  a2  ; b2 
2 2
a b
 Area of R2  2    ab and sides are of R2 are a and b
2 2

2ab 2a 2b
Similarly area of Rn  n 1 and sides of Rn are n 1
; n 1
2  2  2
2a 2b
Similarly major axis and minor axis of En are n 1
; n 1
 2  2
ab ab 2ab
 Sum of areas of rectangles R1, R2, R3 ..... is 2ab + ab +   .....   4ab
2 4 1
1
2
 Sum of areas is always less than 4  4 2  2 2  64
Eccentricities does not change  E10 = E12
46. A, C, D
 2  2 2 
 4t  t 2t  4t  R  ; 2t 
Sol. Centroid :  ;  ; h t ; k  2t t  y=x
 3 3 3 3
3k 4
 t  3h  6k   9hk = 18k2 + 4  2
2 3k P  2t; 
Circumcentre is (0, 0)  t
 2 
 Orthocentre :  4t  ; 2t  y=0
 t 
 Locus hk = 2k2 + 4
 2
Q  2t;  
 t
Section – B
47. 2
r 1 r
Sol. Tr 
1
r 1
sin3  3r 1   
1
r 1
 3 sin3r 1   sin3r  = 1  sin3r 2   sin3
r 1
 1
   Vr  Vr 1 
3 43 4 3 3  4
1 1 1 sin310  
 S10   V1  V2  V2  V3  ..... V10  V11  =  V1  V11   f      3 sin   9 
4 4 4 3 
48. 8
Sol. Let E be (5 cos , 3 sin )  5 cos  E
c
 c  cos   F is (5 cos , –3 sin )
5
x cos  y sin  H (c, 0) G
Tangent at E :  1
5 3
F
x cos  y sin   5 
Tangent at F :   1  G is  , 0
5 3  cos  
1 1  5 
Area of EFG =  GH  EF     5 cos    6 sin 
2 2  cos  
 3 1/2 3/2 
  c 25  c 2    2c    25  c 2 
1  25  c2 3  3/2 3  
=   c   6  1  25  c 2       c    2 
2  c   25 5c  5 c2 
Which is always negative (–ve)  (c) is always decreasing
If 1  c  3, then minimum value of (c) is at c = 3
3
 3  16 3 /2  3  26  64
53 53 5
49. 5
Sol.  Area of PSQ =  5  1 area of RSQ P
1 1
 PQ  QS  sin    5  1  QR  QS  sin 108    54
2 2
S
PQ QR
 
sin18 sin54 
 sin  sin18   5  1 sin54 sin 108    108 –  18
R
Q
5 1 5 1 sin 108    1 5 1
 sin    5  1   sin 108      
4 4 sin  5 1 4
5 1
sin 108 cot  – cos 108 =  cot  = 0   = 90
4
50. 8
Sol. Let A be (12 sec 1, 12 tan 1)
B be (12 sec 2, 12 tan 2)
C be (12 sec 3, 12 tan 3) and
D be (12 sec 4, 12 tan 4)
Let centroid of ABC be (h, k) D A
 h = 4 sec 1 + 4 sec 2 + 4 sec 3 and
K = 4 tan 1 + 4 tan 2 + 4 tan 3 C B
12sec 1  12sec 2  12sec 3  12sec 4 6  0

4 2
3h  12sec 4  12  4 sec  4  4  h
12 tan 1  12 tan 2  12 tan 3  12 tan 4 12  0

4 2
3k + 12 tan 4 = 24  4 tan 4 = 8 – k  (h – 4)2 – (k – 8)2 = 16   = 4,  = 8,  = 4
51. 3
Sol. Equation of chord of contact AB ky = 2(x + h)
2x 2h x2 y 2
y   it touches  1
k k 9 16 A
4h2 9  4 2 2
 2  16 ; h + 4k = 9
k2 k
x2 y2 P(h, k)
 locus is  1
9 9/4 B
9 3
 9 1  e2   e 
4 2
52. 2
a b
Sol.  It is equilateral   x1   cos   cos   cos   ; y1   sin   sin   sin  
3 3
9x12 9y12 2 2
 2   cos   cos   cos     sin   sin   sin  
a2 b
= 3 + 2(cos  cos  + cos  cos  + cos  cos  + sin  sin  + sin  sin  + sin  sin )
53. 6
a2  b2
Sol.  C1 : x2 + y2 = a2 – b2  C2 : x2 + y2 =
3
a2  b2
Director circle of C1 is x2 + y2 = 2(a2 – b2)  2(a2 – b2) =
3
 6a2 – 6b2 = a2 + b2  5a2 = 7b2
2 12
5a2 = 7a2 1  e12   e12  and 5a2 = 7a2  e22  1  e22 
7 7
54. 7
a a
Sol. (a – 2b)2 + (a – 3c)2 = 0  a = 2b, a = 3c  b  , c
2 3
a2 a2
2 2 2 a2  
a c b 9 4  31
cosB   cosB 
2ac a 24
2a
3

Aits 2223 PT II Jeea TD Paper 2 Sol

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

After switch is closed 2F 10V

H gives positive Tollen's test and

E 1. NH3 ,  Liberate CO2

OH 3. NaNO2  dil. HCl CH3

NC CH CH2 CH3 MgBr CH CH2 CH3

(Two structural isomers)

H3C C CH3 [R]

Orange red dye

Mathematics PART – III

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