Class 11 PT1

KENDRIYA VIDYALAYA No.
1, RAIPUR
PERIODIC TEST-II; 2022-23
CHEMISTRY-XI
TIME: 1.30 Hrs
MM: 40 M.
Instructions for students:
(a) All questions are compulsory; however 1 internal choice is given in a question of 3 marks (Q-17) and
in a question of 5 marks (Q-19), writes only one in each.
(b) Perform all the calculations for the numerical questions, in a margin on the right side of the solution.
(c) Follow sign convention, rules of punctuations and write units of the quantities especially while
reporting final solution.
Qu1. According to Lewis concept, an acid is:
(a) Proton donor
(b) Electron pair donor
(c) Electron pair acceptor
(d) Proton acceptor
Q2. Ostwald’s dilution law is applicable to:
(a) Strong electrolytes only
(b) Weak electrolyte only
(c) Non-electrolytes
(d) Strong and weak electrolytes
Q3. The pH of a solution of hydrochloric acid is 4. The molarity of the solution is:
(a) 4.0
(b) 0.4
(c) 0.0001
(d) 0.04
Q4.For the reversible reaction
N2 (g) + 3H2(g) ⇋ 2NH3 + Heat
The equilibrium shifts in forward direction
(a) by increasing the concentration of NH3(g)
(b) by decreasing the pressure
(c) by decreasing the concentration of N2 and H2
(d) by increasing pressure and decreasing temperature
Q5.Oxidation number of P in PO43-, of S in SO42- and that of Cr in Cr2O72- are respectively:
(a) +3, +6 and +5
(b) +5, +3 and +6
(c) +3, +6 and +6
(d) +5, +6 and +6
Q6. Consider the following reaction:
Zn + Cu2+ → Zn2+ + Cu
With reference to the above, which one of the following is the correct statement?
(a) Zn is reduced to Zn2+ ions.
(b) Zn is oxidized to Zn2+ ions.
(c) Zn2+ ions are oxidized to Zn.
(d) Cu2+ ions are oxidized to Cu.
Q7.. Reduction never involves:
(a) Gain of electrons
(b) Decrease in oxidation number
(c) Loss of electrons
(d) Decrease in valence of electropositive component
Q8.In the reaction
3Br2 + 6CO32- + 3H2O → 5Br – + BrO3– + 6HCO3–
(a) Bromine is oxidized and carbonate is reduced.
(b) Bromine is reduced and water is oxidized.
(c) Bromine is neither reduced nor oxidized.
(d) Bromine is both reduced and oxidized.
Assertion reason question
(a) Both A and R are true and R is correct explanation of A.
(b) Both A and R are true but R is not correct explanation of A.
(c) A is true but R is false
(d) Both A and R are false
Q9. Assertion (A): The ionisation of hydrogen sulphide in water is low in the presence of hydrochloric acid.
Reason (R : Hydrogen sulphide is a weak acid.
Q10. Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of
disproportionate reaction.
Reason (R) : The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in
O2 and –2 oxidation state in H2O.
Qu 11.The concept of electron transfer is found unable to explain the redox changes or electron shift in case
of covalent compounds. To explain these changes a new concept called oxidation number is
introduced .oxidation number is defined as the charge that an atom of the element has in its ion or appear to
have when present in the combined state with other atoms.
In other words, it is also defined as the charge that an atom appear to have in the compound when all
other atoms are as ions from the compound.
1. the oxidation number of K in KO2 is
i) 0 ii) 2 iii) -1 iv) -1/2
2. the element which never has positive oxidation number in any of its compound
i) F ii) Cl iii) O iv) N
3. if three electron are lost by a metal ion M3+ , then the final oxidation state of metal is
i) 3 ii) 2 iii) 1 iv) 4
4. When KMnO4 is reduced with oxalic acid in acidic medium the oxidation number of Mn from
i) +7, +2 ii) +7,+4 iii) +4, +2 iv) +7, +5
Qu12. Write the expression for the equilibrium constant, Kc, for each of the following reaction:
2NOCl (g)↔2NO(g)+Cl2(g)
Qu13. at 450 K, Kp= 2.0 × 10 10 bar for the given reaction at equilibrium.
2SO2(g) +O2(g) ⇌ 2SO3(g)
What is Kc at this temperature? R = 0.0831 bar L bar K–1 mol–1
Qu14.Assign oxidation number to Mn in K2MnO4 and S in H2S2O7
Qu15. Consider the elements: K, Ar, Br, F
(i) Identify the element that exhibits –ve oxidation state
(ii) Identify the element that exhibits +ve oxidation state
(iii) Identify the element that exhibits both –ve and +ve oxidation state
(iv) Identify the element that exhibits neither –ve nor +ve oxidation state
Qu16. The following species can act both as an acid and a base, for each case write down the corresponding
conjugate acid/base.: , NH3, HSO4-
Qu17.a) The pH of a sample of vinegar is 3.76. Calculate the concentration of hydrogen ion in it
b) Define buffer solution. ( anti log .76= 5754 )
OR
A) What is meant by ionic product of water (kw)?
B) The concentration of hydrogen ion in a sample of soft drink is 3.8 ×10-3 M. what is its pH
( log 38 =5798)
Qu18. Balance the following redox reaction: (any 1)
(i) Cl2O7(g) + H2O2(aq) → ClO2-(aq) + O2(g) + H+ (in basic medium)
(ii) MnO4-(aq) + SO2 → Mn2+(aq) + HSO4- (in acidic medium)
Qu.19 a) State Le Chatelier’s principle.
b) For the following reaction at equilibrium,
N2 + H2 → 2NH3 (g) H= -22.4 kcal
Predict the shift in the direction of equilibrium with
(a)Increase in temperature (b) Increase in pressure (c) Decrease in concentration of Nitrogen
OR
At 473 K, the equilibrium constant Kc for the decomposition of phosphorus pentachloride (PCl5) is 8.3 × 10-
3
. If decomposition proceeds as:
PCl5 (g) ⇌ PCl3(g) + Cl2(g) ; ∆H = + 124.0 kJ mol-1
(a) Write an expression for Kc for the reaction.
(b) What is the value of Kc for the reverse reaction at the same temperature?
What would be the effect on Kc if
(i) more PCl5 is added
(ii) pressure is increased
(iii) the temperature is increased?
Qu20. A) Given the standard electrode potentials,
K+/K = -2.93 V, Ag+/Ag = 0.80 V, Hg2+/Hg = 0.79 V, Mg2+/Mg = -2.37 V,
Cr3+/Cr = -0.74 V. Arrange these metals in increasing order of their reducing power.
b) Depict the galvanic cell in which the reaction, Zn(s) + 2Ag+(aq) ————> Zn2+(aq) + 2Ag(s)
takes place. Further show:
(i) which of the electrode is negatively charged.
(ii) the carriers of current in the cell and
(iii) individual reaction at each electrode.

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KENDRIYA VIDYALAYA No.

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