Remedial

ENAT COLLEGE Chemistry Test for Remedial Students in 2016 E.
C
1. What is the energy of the electronic transition associated with the sodium-D line having a wavelength of 589 nm?
a. 6.63 × 10-34 J b. 1.13 × 10-27 J c. 3.38 × 10-19 J d. 5.82 × 102 J
2. Which of the following sets of quantum numbers are not allowed in the hydrogen atom?
a. n = 3, ℓ = 2, mℓ = 2 b. n = 4, ℓ = 3, mℓ = 4 c. n = 1, ℓ = 0, mℓ = 0 d. n = 2, ℓ = 1, mℓ = -1
3. Which of the following has the lowest electro negativity? a. Carbon b. Magnesium c. Beryllium d. Boron
4. Which of the following is not a property of ionic bonds? a. loss of electrons b. gain of electrons
c. sharing of electrons d. transferring of electrons
5. In which of the following molecule is a co-ordinate covalent bond present? a. F2 b. O3 c. NH3 d. CCl4
6. A neutral molecule having the general formula AB3 has two unshared pair of electrons on A. What is the hybridization of A?
a. sp b. sp2 c. sp3 d. sp3 d
7. A quantity of gas has a volume of 25 L at 17 °C and 3 atm of pressure. To what volume must the gas be increased for a gas to be
under STP conditions? a. 79.7 L b. 26.6 L c. 70.6.0 L d. 75.0 L
8. The equilibrium partial pressures of SO2 , O2 and SO3 are 0.1 atm, 0.25 atm and 0.5 atm respectively.
The equilibrium constant for the reaction SO3 (g) ⇌ SO2 (g) + ½O2 (g) is: a. 0.1 b. 10 c. 0.05 d. 20
9. Which one is the least soluble in water? a. methanol b. hexane c. butanal d. hexanedioic acid
10. The compounds CH3 OH and CH3 COOH react in the presence of an acid catalyst to form:
a. a carboxylic acid b. an aldehyde c. a ketone d. an ester
11. What is the oxidation number of chromium in the ionic compound ammonium dichromate? (NH 4)2Cr2O7? a. +3 b. +4 c. +5 d. + 6
12. What was oxidized and what was reduced in the following reaction? 2Hg2+ + N2H4 → 2Hg + N2 + 4H+
a. Hg2+ was oxidized; N2 H4 was reduced b. Hg2+ was reduced; N2 H4 was oxidized
c. Hg2+ was oxidized; N2 H4 was oxidized d. Hg2+ was reduced; N2 H4 was reduced
13. Which statement regarding voltaic cells is not correct? a. Reduction occurs at the cathode.
b. Anions move through the barrier/bridge toward the electrode where oxidation is occurring.
c. The electrode where reduction is occurring is represented by a positive sign
d. Electrons flow in the external circuit from the cathode to the anode.
14. The electrochemical reaction shown below is given, if the standard reduction potential of Zn 2+--> Zn is – 0.76 V, what is
the standard reduction potential of Mg+2 → Mg ? Mg |Mg+2 (aq) || Zn+2 (aq )|Zn E˚ = + 1.61 V
a. – 0.85 V b. + 0.85 V c. + 2.37 V d. – 2.37 V
15. In the Brønsted–Lowry definition of acids and bases, an acid ___ a. is a proton donor. b. breaks stable hydrogen bonds.
c. is a proton acceptor. d. corrodes metals.
16. Which one of the following is not a conjugate acid–base pair? a. NH3 and NH4+ b. HS– and H2S c. NH3 and NH2– d. H3O+ and OH–
17. A solution with an [OH– ] concentration of 1.20 × 10–7 M has a pOH and pH of __________
a. 6.92 and 7.08 b. 7.08 and 6.92 c. 1.00 and 13.00 d. 5.94 and 8.06
18. Which of the following substances are not readily miscible within each other? a. C 6H6 and CCl4 c. C2H5OH and H2O
b. H2O and CCl4 d. CH3OH and H2 O
19. The reaction 2X +Y Z was studied and the following data were obtained
Experiment [X] [Y] Rate (mol

. L-S-)
1 3.0 3.0 1.8
2 3.0 1.5 0.45
3 1.5 1.5 0.45
What is the proper rate expression?
A. Rate = K[X] B. Rate =K[Y] C. Rate = K[Y]2 D. Rate =k[X]2[Y]
20. Which one of the following factors does not affect the rate of a chemical reaction?
A. Concentration B. Humidity C. Temperature D. Nature of reaction.
ENAT COLLEGE CHEMISTRY ASSIGNMENT FOR REMEDIAL IN 2016 E.C

1. What is the half-life of the irreversible first order reaction A B if 75% of A is converted to 60 minutes?
2. Thiosulfate ion is oxidized by iodine according to the following reaction. 2S 2O3-2 (aq) + I2 S4O6-2(aq) +2I-(aq)
If in a certain experiment, 0.006mol of S2O3-2 is consumed in 1.0L of solution each at second, at what rate are S4O6-2 and I-
produced in this solution?
3. Explain on the basis that “like dissolves like” why glycerol, CH2OHCHOHCH2OH, is miscible in water but benzene, C6H6,
has very limited solubility in water.

4. The concentrated sulfuric acid we use in the laboratory is 98.0% H2SO4, by mass. Calculate the molality and molarity of
the acid solution. The density of the solution is 1.83 g/mL.
5. According to the Lewis theory, each of the following is an acid base reaction. Which species is the acid and which is the
base? a. BF3 + F− → BF4 − b. OH-(aq) + CO2(aq) → HCO3−(aq)
6. Calculate the percent ionization of a 0.125 M solution of nitrous acid (a weak acid), with a pH of 2.09
7. The Ka for acetic acid, HC2H3O2, is 1.8 × 10-5.What is the pH of a buffer prepared with 1.0 M HC2H3O2 &1.0 M C2 H3O2 - ?
HC2H3O2 (aq) + H2O (aq) ↔ H3O+(aq) + C2H3O2- (aq)
8. Define each of the following terms: a. oxidation b. reduction c. Galvanic cell d. electrolytic cell e. corrosion
9. Balance each of the following chemical equations in basic and acidic medium, using ion-electron method.
a. ClO3− + SO2 → SO42- + Cl− b. H2S + HNO3 → NO + S + H2 O
10. When an aqueous solution of copper (II) sulfate, CuSO4, is electrolyzed, copper metal is deposited. 2 Cu2+ + 2e− → Cu(s)
(The other electrode reaction gives oxygen: (2H2O → O2 + 4H+ + 4e−) If a constant current was passed for 5.00 h and
404 mg of copper metal was deposited, what was the current?
11. Predict whether the following reaction would proceed spontaneously as written at 298 K:
Co(s) + Fe2+ (aq) → Co2+ (aq) + Fe(s) , given that [Co2+] = 0.25 M and [Fe2+] = 0.94 M.
12. for the reaction at equilibrium: 2SO2 (g) + O2 (g) ⇌ 2SO3 (g) ∆H = -196 kJ/mol. Predict the direction of the change on:
a. Removal of SO2 b. Addition of noble gas (argon) at constant pressure c. Decreasing volume of the system
d. Increasing temperature of the system e. Addition of a catalyst
13. for the reaction at 200 °C: 2A (g) + B (g) ⇌ 3C (g) the equilibrium constant is 3.0. Given the following information, Species
Concentration [A] 2.0 M [B] 3.0 M [C] 2.0 M predict the direction in which the reaction should proceed to reach
equilibrium.
14. If 140 cm3 of methane diffuse into air in 72 seconds, how long will it take 210 cm3 of sulphur dioxide
to diffuse under the same conditions?
15. Iridium has two naturally occurring isotopes. 191 Ir and 193 Ir have atomic masses of 1 90.9609 amu & 1 92 .9633 amu,
respectively. The average atomic mass for iridium is 192.22 amu. What is the percent natural abundance for each isotope?
16. Calculate the wavelength of the light emitted when an electron falls from n = 3 to the n = 1 state in hydrogen atom.
17. Write the number and the letter for the orbital that corresponds to the following pairs of n and l quantum numbers:
a. n = 3, l = 1 b. n = 4, l = 0
18. Write the ground-state electron configurations for the following elements: a. Br (Z = 35) b. W (Z =74)

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ENAT COLLEGE Chemistry Test for Remedial Students in 2016 E.

Experiment [X] [Y] Rate (mol

1 3.0 3.0 1.8

2 3.0 1.5 0.45

3 1.5 1.5 0.45

What is the proper rate expression?

A. Rate = K[X] B. Rate =K[Y] C. Rate = K[Y]2 D. Rate =k[X]2[Y]

ENAT COLLEGE CHEMISTRY ASSIGNMENT FOR REMEDIAL IN 2016 E.C

has very limited solubility in water.

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