31. a Derive Gibbs-Helmhotz equation. Give its applications- , Reg. No.

(oR)
b. With a neat sketch explain Pourbaix diagram for kon. B.Tech. DEGREE EXAMINATION, NO\EMBER 2018
First Semester
32. a Explain in detail the conformational analysis of n-butane with potential erer5/ diagam.
l8CYBlOIJ - CHEMSTRY
(oR) (For the candidates admitted during the academic year 20lB-2019)
b. How is isomerism exhibited in transition metal compounds? Explain the types with an Note:
example each? ..(l) Part - A should be answered in OMR sheet within first 45 minutes and OMR sheet should be hmded
over to hall invigilator at the end of 45fr minute.
rirl.*** (ii) Part - B and Part - C should be answered in answer booklet.

Time: Three Hours Mo<. Marks: 100

PART-A (20 x 1= 20 Marks)

AnswerALL Questions
l. Two electrons occupying the sarne orbital me distinguished by
(A) Azimuthal quantum number (B) Spin quantum number
(C) Magnetic quantum number @) Orbital quantum number
2. Ttrc de-Broglie hypothesis is associated with
(A) Wave nature of electrons only (B) Wave nature ofprotons only
(C) Wave nature of radiation @) Wave nanre of all material particles
3. For a homonuclear diatomic niolecule the bonding orbital is
(A) orof lowest enerry @) o,of second lowest enerry
(C) arof lowest enerry @) z,of lowest ener5/

4. Organic compounds which contain more than one benzene rings are terrned
(A) Arenes (B) Aryls
(C) Acyls @) Benzenes
5. The crystal field splitting enersr for ockrhedral (4) and tetrahedral (A,) complexes is
related as
(A) L,=4l9Lo (B) A, =l l2yo
(C) Ao =24, (D) Ao = 419L,
6. The number of unpaired electons in d6, low spin octahedral complex is
(A) 0 (B) I
(c) 2 (D) 3
7. The vibrational rotational spectnrm is obseried in _ region
(A) NearIR @) Microwave region
(C) Visible regron (D) Radio frequency region

8. In a rotational spectrum transitions are only observed between rotational levels of A.I =
(A) *t - (s) t2
(c) 0 @) tr
Pagc d of4 l7Nr118CrBl0lJ Page 1 of4 .IMIFUSCYB1O1J
 19. The Er mechanism proceeds via formation of
is dependent upo-n the energr of the (B) Carbocation
9. The kinetic eners/ of the ejected photoelectron (A) Carbanion
tal I"* **i" @) Photons around
(D) ImPingingPhoton
(Ci PorUte Uona @) Free radical
tcj urroia following reagents'
20. Reduction of ketone to hydroxyl group takes place by one of the
10. Compute the miller indices for the intercepts * = yZ,y = /rona' - L (A) NaBII4 (B) Oz
(C) KIvInO4 @) CrOr
(A) 110 (B) 101
(c) 100 (D) 210 PART-B (5 x 4=20 Marks)
Answer ANY FM Questions
11. The smallest interplanar spacing in a ctystal which
will give ntr order Bragg's reflection is
i;;-i;r=" (B) dnr=% 2t. Discuss the radial wave functions of hydrogen atom'

(C) dna:% @) a* -/o ,,",

Discuss the enerry levet diagram of Oz molecule'

enerry because the

23. Explainbriefly about high spin and low spin complexes with
examples'
12. The second ionization enerry is always higher than the firstionization to the
(A) Elector ir Xtru"t"a mire by t1i corJ @) Electron is more tightly bound
electrons nucleusinanion )4. Discuss the criteda for absorption in the IR region'
(C) Stability increases on attaining an @) Atomic size is larger
periods and groups'
octet or duPlet configuration 25. Write a note on the variatioa in atomic and ionic sizes across the
13. First law of thermodynamics states that
(A) LU=q-w (B) LU -q+w 26- Define: Entropy. Give its sigrrificance'
(C) LU=q+Lw @) M=Aq+w
27. Briefly explain Dieckmann condensation'

ici 2." (D) R€srins consd Alsw.t AII Qu€sti@s

potential @), standard . a Discuss in detail the schrodinger wave equation of a particle
in a box'
15. The name of the equation showing rylation between electrode 28.
potential urd concentration of ions in solution is
("E)
(oR)
(A) Kohlrausch's law @) Nemst equation orbital
(C) Faraday's equation (D) Ohm's law b. what is Linear combination of atomic or6itasr Draw and explain the molecular
energi level diagram for hydrogen molecular ion and calculate the bond ordet'
[r{i ]
16. Corrosion of metals involves
(A) reactions
Electrochemical @) Chemical reactions
29. a.i. Give the salient features of crystal field theory'
(4 Marks)

iC; fomaanan (D) Therrralreactions

(8 Marks)
ii. Discuss thd crysul freld splitting in a octahedral complex
17. Enantiomers are
(A) Molecules that have a mirror image (B) Molecules ttrat have atleast one stereogenic (oR)
center harmonic
(D) Non-super imposable molecules that are b. Discuss the vibrational spectrum of a diatomic molecule undergoing simple
(C) Non-super imposable molecules motion
mirror images of each other
x & Y can be represented as 30. a--Discuss the principle, instumentation and applications
of )(PS'
18. In the Newmann projection of 2,2- dimethyl butane

(oR)
b.i. Write a note on Vander Waal's interactions' Marks)

ii. Discuss in detail Bragg's law forthe diftaction of crystals with aneat sketch'
(s Marks)
Y
(A) H&CH3 (B) CH: & CHr
(c) H& CzIIs (D) BothB & C
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