Acid Sulfuric

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Sulfuric acid

Sulfuric acid is a very important commodity chemical, and indeed a nation's sulfuric
acid production is a good indicator of its industrial strength. The major use (60% of
total worldwide) for sulfuric acid is in the "wet method" for the production
of phosphoric acid, used for manufacture of phosphate fertilizers as well
as trisodium phosphate for detergents. In this method phosphate rock is used, and
more than 100 million tonnes is processed annually. This raw material is shown
below as fluorapatite, though the exact composition may vary. This is treated with
93% sulfuric acid to produce calcium sulfate, hydrogen fluoride (HF)
and phosphoric acid. The HF is removed as hydrofluoric acid. The overall process
can be represented as:

Ca5F(PO4)3 + 5 H2SO4 + 10 H2O → 5 CaSO4·2 H2O + HF + 3 H3PO4

Sulfuric acid is used in large quantities in iron and steel making principally as
pickling-acid used to remove oxidation, rust and scale from rolled sheet and billets
prior to sale into the automobile and white-goods business. The used acid is often
re-cycled using a Spent Acid Regeneration (SAR) plant. These plants combust the
spent acid with natural gas, refinery gas, fuel oil or other suitable fuel source. This
combustion process produces gaseous sulfur dioxide (SO2) and sulfur trioxide (SO3)
which are then used to manufacture "new" sulfuric acid. These types of plants are
common additions to metal smelting plants, oil refineries, and other places where
sulfuric acid is consumed on a large scale, as operating a SAR plant is much cheaper
than purchasing the commodity on the open market.

Ammonium sulfate, an important nitrogen fertilizer is most commonly produced as


a by-product from coking plants supplying the iron and steel making plants, Reacting
the ammonia produced in the thermal decomposition of coal with waste sulfuric acid
allows the ammonia to be crystalised out as a salt (often brown because of iron
contamination) and sold into the agro-chemicals industry.

Another important use for sulfuric acid is for the manufacture of aluminium sulfate,
also known as papermaker's alum. This can react with small amounts of soap
on paper pulp fibres to give gelatinous aluminium carboxylates, which help to
coagulate the pulp fibres into a hard paper surface. It is also used for
making aluminium hydroxide, which is used at water treatment plants to filter out
impurities, as well as to improve the taste of the water. Aluminium sulfate is made
by reacting bauxite with sulfuric acid:

Al2O3 + 3 H2SO4 → Al2(SO4)3 + 3 H2O

Sulfuric acid is used for a variety of other purposes in the chemical industry. For
example, it is the usual acid catalyst for the conversion of cyclohexanoneoxime
to caprolactam, used for making nylon. It is used for making hydrochloric
acid from salt via the Mannheim process. Much H2SO4 is used
in petroleum refining, for example as a catalyst for the reaction of isobutane
with isobutylene to give isooctane, a compound that raises the octane rating
of gasoline (petrol). Sulfuric acid is also important in the manufacture of dyestuffs.

A mixture of sulfuric acid and water is sometimes used as the electrolyte in various
types of lead-acid battery where it undergoes a reversible reaction
where lead and lead dioxide are converted to lead(II) sulfate. Sulfuric acid is also
the principal ingredient in some drain cleaners, used to clear blockages consisting of
paper, rags, and other materials not easily dissolved by caustic solutions.

Sulfuric acid is also used as a general dehydrating agent in its concentrated for
dehydrating agent in its concentrated form.

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