Document No.

: PSM/HSE/MSDS/16
Revision No. : 00 Nov 2016
MATERIAL SAFETY Issue No. : 01 Nov 2016
DATA SHEET Revision due : Oct 2019
Page No. : 1 of 6
Engro Power Gen, Thar. (Reductant) Orig. Prep. by : MAN –SB

Department: HSE Unit / Section: ALL Area : ALL

Section 1. Product and Manufacturer Identification

Product Name: Reductant

Chemical Name Sodium bisulfite

Section 2. Composition and Common Information

Name: Reductant
CAS#: 7631-90-5
Chemical Name Sodium bisulfite.
Chemical Formula: NaHSO3

Section 3. Physical and Chemical Properties

State and Appearance Solid.

Odor: Sulfurous. (Slight.).
Molecular Weight 104.07 g/mole.
Color White. Off-white
Boiling Point: -
Melting Point Decomposes.
Critical Temperature: -
Specific Gravity 1.48 (Water = 1)
Vapor Pressure -
Vapor Density -
Dispersion Properties See solubility in water.
Solubility Easily soluble in hot water. Soluble in cold water. Soluble in 3.5 parts cold water.
Soluble in 2 parts boiling water. Soluble in 70 parts alcohol Insoluble in liquid
chloride, ammonia.

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 Document No.: PSM/HSE/MSDS/16
Revision No. : 00 Nov 2016
MATERIAL SAFETY Issue No. : 01 Nov 2016
DATA SHEET Revision due : Oct 2019
Page No. : 2 of 6
Engro Power Gen, Thar. (Reductant) Orig. Prep. by : MAN –SB

Department: HSE Unit / Section: ALL Area : ALL

Section 4. Stability and Reactivity

Stability The product is stable

Reactivity Under normal conditions of storage and use, hazardous reactions will not occur.
Possibility of hazardous Slowly oxidized to sulfate on exposure to air.
reactions
Conditions to avoid Incompatible materials.
Incompatible materials Reactive with oxidizing agents, acids
Hazardous Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.
Hazardous Under normal conditions of storage and use, hazardous polymerization will not
polymerization occur.

Section 5. Handling and Storage

Handling:
Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the
label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, alkalis.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 6. Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 7. Toxicological Information

Skin / eye contact and Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Acute
inhalation: Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation.
Inhalation: Can cause respiratory tract irritation with cough, wheezing, and shortness

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 Document No.: PSM/HSE/MSDS/16
Revision No. : 00 Nov 2016
MATERIAL SAFETY Issue No. : 01 Nov 2016
DATA SHEET Revision due : Oct 2019
Page No. : 3 of 6
Engro Power Gen, Thar. (Reductant) Orig. Prep. by : MAN –SB

Department: HSE Unit / Section: ALL Area : ALL

of breath. It can produce anaphylaxis or other hypersensivity reactions in some

sensitized individuals.
Ingestion Ingestion: May be harmful if swallowed. It may cause nausea, vomiting, diarrhea,
abdominal pain, gastric hemorrhage. Extremely large amounts may affect
behavior/central nervous system and may produce central nervous system
stimulation, irritation, seizures and may also cause, cyanosis, respiratory depression,
apnea, circulatory disturbances, hypotension and cardiovascular collapse. May cause
asthmatic reaction in sensitized individuals. Chronic Potential Health Effects:
Inhalation: Prolonged or repeated inhalation may cause bronchitis to develop with
cough, phlegm, and/or shortness of breath. It can cause an asthma-like allergy or
other hypersensivity reactions such as anaphylaxis,
angioedema, bronchoconstriction, flushing, diaphoresis, urticarial, tachycardia, and
hypotension in sensitized individuals. Futures exposures may cause shortness of
breath, wheezing, cough, and/or chest tightness. Skin: Prolonged or repeated skin
contact can cause dermatitis. Ingestion: Prolonged or repeated ingestion may affect
the liver, and blood.

Section 8. Ecological Information

Product and Toxicity of Possibly hazardous short term degradation products are not likely. However, long
Biodegradation term degradation products may arise. The products of degradation are less toxic
than the product itself.

Section 9. Hazards Identification

Potential Health Effects

Potential Acute Health Effects:
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
Slightly hazardous in case of inhalation (lung irritant). CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by
IARC. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to lungs, skin. Repeated or prolonged
exposure to the substance can produce target organs damage.

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 Document No.: PSM/HSE/MSDS/16
Revision No. : 00 Nov 2016
MATERIAL SAFETY Issue No. : 01 Nov 2016
DATA SHEET Revision due : Oct 2019
Page No. : 4 of 6
Engro Power Gen, Thar. (Reductant) Orig. Prep. by : MAN –SB

Department: HSE Unit / Section: ALL Area : ALL

Section 10. Exposure Control / Personal Protection

Appropriate engineering controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure
to airborne contaminants below the exposure limit.
Individual protection measure
Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator
or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist before
handling this product.

Section 11. Emergency / First Aid Measures

First-aid measures after If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
inhalation breathing is difficult, give oxygen. Get medical attention immediately.
First-aid measures after skin In case of contact, immediately flush skin with plenty of water. Cover the
contact irritated skin with an emollient. Remove contaminated clothing and shoes. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-
bacterial cream. Seek immediate medical attention.
First-aid measures after eye Check for and remove any contact lenses. In case of contact, immediately flush
contact eyes with plenty of water for at least 15 minutes. Cold water may be used. Get
medical attention.
First-aid measures after Do not induce vomiting unless directed to do so by medical personnel. Never
ingestion give anything by mouth to an unconscious person. If large quantities of this
material are swallowed, call a physician immediately. Loosen tight clothing such
as a collar, tie, belt or waistband.

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 Document No.: PSM/HSE/MSDS/16
Revision No. : 00 Nov 2016
MATERIAL SAFETY Issue No. : 01 Nov 2016
DATA SHEET Revision due : Oct 2019
Page No. : 5 of 6
Engro Power Gen, Thar. (Reductant) Orig. Prep. by : MAN –SB

Department: HSE Unit / Section: ALL Area : ALL

Section 12. Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is
not present at a concentration level above TLV.

Section 13. Fire Fighting Measures / Fire and Explosion Data

Flammability of the Product

Non-flammable.
Products of Combustion
Oxides of Sulfur
Fire Hazards in Presence of Various Substances:
Slightly combustible in presence of open flames and sparks.
Explosion Hazards in Presence of Various Substances
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the
product in presence of static discharge: Not available.
Fire Fighting Media and Instructions
Use the media in relevant of surrounding material.

Section 14. Transportation Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.
Special Provisions for Transport: Not applicable.

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 Document No.: PSM/HSE/MSDS/16
Revision No. : 00 Nov 2016
MATERIAL SAFETY Issue No. : 01 Nov 2016
DATA SHEET Revision due : Oct 2019
Page No. : 6 of 6
Engro Power Gen, Thar. (Reductant) Orig. Prep. by : MAN –SB

Department: HSE Unit / Section: ALL Area : ALL

Section 15. Regulatory Information

Federal and State Regulations:

Connecticut hazardous material survey.: Sodium bisulfite Illinois toxic substances disclosure to employee act: Sodium
bisulfite Illinois chemical safety act: Sodium bisulfite New York release reporting list: Sodium bisulfite Pennsylvania RTK:
Sodium bisulfite Minnesota: Sodium bisulfite Massachusetts RTK: Sodium bisulfite Massachusetts spill list: Sodium bisulfite
New Jersey: Sodium bisulfite New Jersey spill list: Sodium bisulfite Louisiana spill reporting: Sodium bisulfite California
Director's List of Hazardous Substances: Sodium bisulfite TSCA 8(b) inventory: Sodium bisulfite TSCA 8(a) PAIR: Sodium
bisulfite TSCA 8(d) H and S data reporting: Sodium bisulfite: Effective date: 1/26/94; Sunset date: 6/30/98 CERCLA:
Hazardous substances.: Sodium bisulfite: 5000 lbs. (2268 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC):
R22- Harmful if swallowed. R31- Contact with acids liberates toxic gas. S25- Avoid contact with eyes. S46- If swallowed, seek
medical advice immediately and show this container or label.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate
respirator when ventilation is inadequate. Splash goggles.

Section 16. Other Information

Not available

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