AITS 2122 FT X JEEA Paper 2 Sol

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2022
FULL TEST – X
PAPER –2
TEST DATE: 21-08-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. B, C
Q  t /RC 3Q/2 3Q/2 B R A
Sol. Q t 
2
e   C
Q  t /RC –Q/2 +Q/2
lt  e (from B to A)
2RC
2
Q / 2  Q2
Total heat dissipated  =
2C 8C
2. A, D
2
Dx 9
Sol.   
 D  x  1
Dx
3
Dx
D  x  3D  3x
4x = 2D
D 120
x   60 cm
2 2
x = 60 cm
D2  x 2 (120  120)  (60  60)
Now, f  
4D 4  120
f = 22.5 cm
3. B, C
Sol. The two springs have different spring constants. Also energy remains conserved during the
motion as no friction is present.
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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22 2
4. B, D
Sol. From equation, PV = nRT 2 B P = KV
2
PC < PB, VC = VB and TB > TC PV = C

W AB > W AC; (TB – TA) > (TC – TA) P
st
So, by 1 law, Q = U + W
QAB > QAC.
A C
VC VS
V
5. A
Sol. Fcos   mg
mv 2 F v
F sin   
R
2
2  mv 2  mg
F  mg  
 R 
F  2 N.
6. B, D
Sol. Case I:
Since there is no relative motion,
F F F 8
a  1 f  f  F1 max   Ff
5 3 3
Case II:
F F  Ff 8
a f  2  F2 max   Ff
5 3 5
F1max  5
Clearly, F1(max  F2max  and  .
F2 max  3
7. D
v 332
Sol.    0.332m.
n 1000
8. C
Sol. The apparent frequency for reflecting surface as observer is
 332  64 
n  1000    1320 Hz
 332  32 
9. C
10. B
Sol. (for Q. 9 to 10):
The maximum acceleration with which the blocks can move together without slipping
mg 0.3  1 10 2
amax    0.5 m/s
3M 32
Fmax  2(M  m)amax  6  0.5  3 N
The friction force between the front blocks,
FS = (M + 2m) amax = 4  0.5 = 2 N
3 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22
Section – B
11. 4
2
Sol. a + R = A cos t …(i)
f = ma …(ii)

1
fR = mR2  …(iii)
2 a
f + 2f = mA2 cos t
1
f  mA2 cos t f
3
1 1
(max)  mA2R   6  2  1  4 N-m
3 3
12. 20
2  m1F2  m2F1  2  2  27  4  9  2 90
Sol.  max      150  6  0.20 m  20 cm
k  m1  m2  150  24 
13. 3
 m  3r 3mv 2 F
Sol. F    2 =
2 8 16r
Section – C
14. 03.40
15. 04.74
Sol. (for Q. 14 to 15): y
Using conservation of momentum
P = P2 cos  …(i) P1
P1 = P2 sin  …(ii) P
Squaring and adding, we get  x
P2  P12  P22
2mk + 2m1k1 = 2m2K2 P2
4k + k1 = 10k2
10k2  k1 = 4k
 10k2  k1 = 44. …(iii)
Also, k1 + k2 = k  |Q|
k1 + k2 = 11.  2.86
k1 + k2 = 8.14 …(iv)
Adding (iii) and (iv), we get
11k2 = 52.14
 k2 = 4.74 MeV
 k1 = 8.14  4.74
k1 = 3.40 MeV
16. 03.00
17. 01.00
Sol. (for Q. 16 to 17):
3a
4TaB  3TaA = 0  aB  M=3
4
3a a
2TaB  TaA  TaP = 0  aP  2aB  aA  a 
2 2
a
aP  K=1
2
18. 180.00
19. 02.00
Sol. (for Q. 18 to 19):
At the instant shown both particles are at their mean positions and moving in opposite direction.
Phase difference = 180
As  is same for both the particles
 GM 
   the phase difference will be maintained throughout and they can never meet.
 R3 
vmax  A  For a particle undergoing S.H.M
v1 R 2
So,  
v2 R / 2 1
Chemistry PART – II
Section – A
20. B, C
Sol. The V.D. and molar mass of the emergent gas will always be greater than that of pure gas.
  
In case of CH3 OH molar mass 32 g mol1 and acetone (molar mass 58 g mol1 )
 Molar mass of N2 being 28 g mol1
 Molar mass of H2 O being 18 g mol1 .
 Molar mass of D2 O being 20 g mol1 .
21. B
Sol. HO
HO
NaOH
O 2N N2  
Fa int ly basic medium
 O 2N N N
22. A, B, C
Sol. (A) Below critical micelle concentration soap behaves like normal electrolyte; no micillisation
of the anions.
(B) In water-in-oil emulsion, oil forms external (continuous) phase.
(C) SnO2  2NaOH  Na2 SnO3  H2 O
(D) Cations will be effective in coagulation of negatively charged sol formed in option (C).
23. A, B, D
Sol. 1. S(entropy) is not the measure of available energy.
2. S between the two states is not path dependent whether reversible or irreversible
S  S2  S1 .
3. Heat supplied into the isothermal reversible expansion of ideal gas is equal to work of
expansion of the gas.
4. G is equal to the available energy of the system to do useful work.
24. A, B, C, D
Sol. 1. Ethers have much lower boiling point than alcohol of similar molecular mass, alcohols
undergo molecular association through intermolecular hydrogen bonding.
2. Intramolecular hydrogen bonding makes ortho-isomer weaker acid than para-isomer.
3.  
At lower temperature 20o C , the reaction between phenol and conc. H2 SO 4 is
kinetically controlled and product composition depends on relative rate of formation.
4. Owing to intramolecular H-bonding in ortho-nitrophenol, its boiling point is less than that
of p-nitrophenol (molecular association due to inter molecular H-bonding).
25. A, B, C
Sol. Brass – Cu + Zn
Bell metal – Cu + Sn
Nickeloy – Al + Cu + Ni
Magnalium – Al + Mg + Ni
26. D
27. B
Sol. (for Q. 26 and 27):
O
 3
1 O

 2 Zn H O 
2
CHO
X
OH N2 H4 / 
O
O O N N
,
CHO ,
CHO CHO
E 
F  G  Z
Possible enolates  Cyclic hydrazene 
CHO
Aldol
 E  

Aldol
F  

OH
O
Aldol
 G  

28. B
29. D
Sulphur excess of HCl
ZnO  X  
 ZnS  P    H2 S R   ZnCl2  S 
Philosopher 's wool  White substance  Foul smell gas  Solution 

SO2  Q  Aq. NaOH
Zn  OH2  T 
 white ppt.
Excess of NaOH
Na2 ZnO 2
Sol. 28. (A) ZnO – is an amphoteric oxide.
(B) ZnO is white powder which on heating turns yellow but again on cooling becomes white.
(C) Lithopone is mixture of ZnS  BaSO4
(D) ZnO  CoO  CoZnO2 or CoO.ZnO

Rinmann's green
Sol. 29. 3

AgNO
 Ag2 S 
Black 
KMnO 4  Acidic 
H2 S   K 2 SO 4  MnSO 4  S  H2 O
3  CH
2
COO  Pb
PbS 

Black 
3 CH
2
COO  Cd
 CdS 
 Yellow 
Section – B
30. 16
Sol. O O
 3   3   5   0   0   5 
N H4 N O2 O S S S S O have difference of oxidation states
O O greater than 2.
 Total compounds  4  P
2
S
 3   5 
N H4 N O3  6 
O S O
O
Hydrazine NH2 NH2   Both nitrogen have same oxidation state of  2  
Calcium cyanamide  CaNCN  Both nitrogen have same oxidation state of  3  

P
Urea NH2 CONH2   Both nitrogen have same oxidation state of  3  
Cr2 O72  both chromium have same oxidation state  6 
 
O O
HO S S OH
 5   3 
O
 P  Q  4  4  16
31. 92
Sol.  1
AgNO3   Ag  NO2  O2
2
 0.5 mole   0.5 mole 
 1
2LiNO3   Li2 O  2NO2  O2
2
 0.5 mole   0.5 mole 
 1
Ca  NO3 2   CaO  2NO2  O2
2
 0.5 mole  0.5  2  1 mole 


NH4 NO3   N2 O  2H2 O 

5
2NaNO3 
 Na2 O  N2  O2  No NO2  g  evolved
2 
5 

2KNO3   K 2 O  N2  O2 
2 
 Total number of moles evolved 0.5  0.5  1  2 mole

Total weight  2  46  mol. mass of NO2   92 g
32. 6
Sol. O
O O
COOH
O
OH ; ;
H3C C CH2 COOH ;
HOOC
O
  keto acid decarboxylates on simple heating
COOH
COOH
; H2C
COOH
COOH
Ge min al diacids also decarboxylates on heating

O
H2C CH CH2 C OH  ,   unsaturated acid decarboxylates simply on heating
CH2 COOH
H2C COOH
; H2C ;
H2C COOH
CH2 COOH
1,, 4 and 1,, 5  diacid dehydrates on heating.
Section – C
33. 00.10
34. 04.00
1 2
Partial pressure of X2 before reaction pX2   0.4 atm
23
23
Partial pressure of Y2 before reaction pY2   1.2 atm
23
0.6
Atm of X2  g  and Y2  g each reacted   0.3 atm
2
pX2  at equilibrium   0.4  0.3  0.1 atm
pY2  at equilibrium   1.2  0.3  0.9 atm
2
2
pXY  0.6 
Kp  KC    4.0
pX2  pY2 0.1  0.9
35. 02.00
36. 11.00
2.0  0.05  3.0   2  0.05 
CN  in the resulting solution 
  23
0.4
  0.08 M
5
K W  H  OH   2  10 7  2  107
 4.0  10 14 M2
CN  H2 O  HCN  OH K b  2  104 
14
KW 4  10
K a  of HCN    2  1010
Kb 2  104
KW 4  1014
‘X’ – Hydrolysis constant K H of CN   10
 2.0  104
Ka 2  10
1
‘Y’ – pH =
2
pK W  pK a  log C
1
   log 4  10 14  log 2  10 10  log 0.08 
2 
1 3
 14  2log 2  10  log 2  log  2   102 
2   
1
  24  3 log 2  2  3 log 2
2
= 11
37. 01.05
38. 03.43
(3.42 – 3.43)
Let Po be initial partial pressure of NO.
2Po be initial partial pressure of NO2.
2NO2  N2 O 4 K P1  6.8 atm 1
2Po  3.4  P 1.7
NO  NO 2  N2 O3
o o
P P 2P  3.4  P P
1.7
K P  for 1st equilibrium  6.8  2
 2P o
 3.4  P 
or, 2Po  3.4  P  0.5
or, 2Po  P  3.9 …. (1)
Also, total pressure (at equilibrium) PNO2  PN2 O4  PNO  PN2O3
5.05  0.5  1.7  Po  P  P
Po  2.85 atm
Now from Equation (1) 2Po  P  3.9
2  2.85  P  3.9  P  1.8 atm
 Equilibrium pressure of NO  Po  P  2.85  1.80 = 1.05 atm.
PN2O3 1.8
K P2    3.42 atm 1 .
PNO  PNO2  1.05  
0.5
Mathematics PART – III
Section – A
39. A, D
Sol.  a  666,  a   a  0
aB aC aD
40. A, B, C
2 2 2
Sol. C:x +y =b
S : x + y = a where a2 = 2b2
2 2 2
41. A, B, C, D
Sol. if k = 0  P = 0 and if k = r  P = 2022!
42. A, C
4
Sol. Area of R = 6
2/3
2 2
Equation of R : x + 2y + (2 + )z – 30 – 15 = 0 where    = –4
3 2
  4  9
 Equation of R: x + 2y – 2z + 30 = 0
43. A, C, D
Sol. ai represent vertices of a regular octagon so
8 8    
 ai  a j  0 ;  ai  a j  4
i  j j1 1 i  j 8
8   8  
  ai  a j   0 ;
i  j j1
 a  a
1 i  j 8
i j 4  
2 1
44. A, C
Sol. P(t) is clearly continuous  t but non-differentiable whenever the person turns
1 9 4
limP  t   1 
t  9 16 5
1
16
45. D
Sol. Make cases based on denominator
46. A
20
Sol. Probability is
255
47. B
Sol. a = 50, b = 25, c = 50
48. D
Sol. None of the functions are periodic as local extrema keeps on decreasing after every 4 seconds
Section – B
49. 4
Sol. 2c sin(A – B) cos(A + B) = b sin B – a sin A
 c[sin 2A – sin 2B] = b sin B – a sin A
 2 c sin A cos A + a sin A = b sin B + 2c sin B cos B
1 1
c cos A  a  b   c cosB
2 2 1 5 3
   cosC   5 sinC 
sinB sin A 2 2
50. 6
3 3 3
Sol. () =  and  +  =  +    = 0, 1, –1
3
If  = 0  ( + ) =  +    =  = 0, 1 –1
2 2
Corresponding equation are x = 0 ; x  x = 0
3
If  = 1  ( + ) = 4( + )   +  = 0, 2, –2
Corresponding equation are x2  2x + 1 = 0
3
If   = –1  ( + ) + 2( + ) = 0  +  = 0
Corresponding equation is x2 – 1 = 0
51. 8
2
x 2 y 2  4  4xy  2y 2  2xy 2  4y  xy  2   2y 2  2y  xy  2  xy  2 2y
Sol. = =  2 2 2 2
xy 2  2y y  xy  2  y xy  2
Section – C
52. 01.57
/ 2
2ln  sec y   1 1
 /2
 2lnsec y  1   2ln  cosec y   1
Sol. Let ex – 1 = tan2 y  I1   dy =  dy
0
ln  tan y  2 0 ln tan y
 /2
1 2ln tan y 
=  dy 
2 0 ln tan y 2
53. 00.00
Sol. Let x = 2 + y  I2 
2
ln  2  y 
dy 
2

ln 4  y 2  dy

2 4y 2 
0 4y 2
Also, let x = 4 – t2  I2  2
2

ln 4  t 2
 dt  I 2
 I2 = 0
0 4t 2 2
54. 01.41
kz2  1  k  z 3
Sol. zi equals 1, -1, i ; a = min. of z1  = 2
k  1  k 
55. 02.67
i 8
Sol. z  b
3 3
56. 01.41
57. 03.16
Sol. (for Q. 56 to 57):
PA  5 ; PB  2 ; PC  10

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

PC < PB, VC = VB and TB > TC PV = C

Hydrazine NH2 NH2   Both nitrogen have same oxidation state of  2  

Calcium cyanamide  CaNCN  Both nitrogen have same oxidation state of  3  

 Total number of moles evolved 0.5  0.5  1  2 mole

Ge min al diacids also decarboxylates on heating

1,, 4 and 1,, 5  diacid dehydrates on heating.

Mathematics PART – III

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