CHEM Model Question

Model Question
Class -12 Chemistry

Group A : Multiple choice Question (11x1=11)
Tick the correct answer.

1. The equivalent weight of K2 Cr2O7 in acidic medium is
(a) Mol. Wt. (b) Mol. Wt/3 (c) Mol wt./5 (d) Mol. Wt/6
2. Which of the following solution cannot act as a buffer?
(a) NaH2PO4+H3PO4 (b) CH3COOH+CH3COONa
(c) HCI+ NH4CI (d) H3PO4+Na2HPO4
3. The reaction in which the rate of reaction is equal to rate constant is of …….. order.
a) Zero b) One (c) Two (d) Three
4. The strongest oxidizing agent among the following is
(a) EoZn+2/Zn=-0.76V (b) EoCu+2/Cu=+0.34V
(c) E0 Au+3/Au=1.42V (d) E0Ag+/Ag = +0.80V
5. Which is the following transition metal icons is colourless?
(a) V2+ (b) Ti4+ (c) Fe2+ (d) Mn2+
6. Iron becomes passive when treated with conc. HNO3 due to the formation of
(a) Fe2O3 (b) FeO (c) Fe(NO3)3 (d) Fe3O4
7. Nitration of nitrobenzene yields
(a) Picric acid (b) TNT (c) 1,4 - dinitrobenzene (d) 1,3-dinitrobenzene
8. Which of the following is not an organometallic compound?
(a) C2H5ONa (b) RMgX (c) Ferrocene (d) Zeise's salt
9. Which cement is used to construct buildings near sea shore?
(a) OPC (b) PPC (c) White cement (d) Grade – 33
10. Chemical pulping mostly uses
(a) NaNO3 (b) KOH (c) CaCO3 (d) NaOH
11. 30
15𝑃 →
30
14𝑆𝑖 , this nuclear change takes place by emission of
(a) 𝛼-particles (b) 𝛽-particles (c) Positron (d) Neutron
Attempt all the questions:
Group B : Short Answer Questions (8x5=40)
1. Primary standard solution is prepared by dissolving known weight of primary standard substance in
water.
(a) What are the requisites for the substance to become primary standard? [2]
(b) A commercial sample of sulphuric acid has specific gravity 1.8 g/ml. 10 ml of this acid was diluted
upto 1 litre with water. 10 ml of the diluted acid required 30 ml of N/10 NaOH for complete
neutralization. Calculate the percentage purity of H2SO4 in the commercial sample. [3]
OR
(a) Differentiate between order and molecularity of reaction. (2)
(b) Show that the half life period for zero order reaction is dependent of the initial concentration of
reactant. (1)
(c) What will be the initial rate of reaction if its rate constant is 1x10 -3 min-1 and the concentration of the
reactant is 0.2 mol L-1 ? How much of the reactant will be converted into the product in 500 minutes? (2)
2. (a) Discuss the effect of temperature on the spontaneity of a process for exothermic and
endothermic process in terms of free energy change. (2)
(b) How is standard free energy change related to equilibrium constant? (1)
(c) Calculate the equilibrium constant (K) for the following reaction at 400 K.
2NOCl (g) 2NO (g) + Cl2 (g)
Given that ∆H0 = 80 KJ mol-1 and ∆S0 = 120 JK-1 at 400 K.
3. (a) Discuss the shape of [Fe (CN)6]3- on the basis of crystal field theory. (2)
(b) Why is [Fe(CN)6]3- ion colored? [1]
(c) What is the magnetic property of this complex ion and why? [2]
4. A metal ‘M’ is used to make magnets and is also used for the manufacture of steel.
(a) Write the reaction during roasting of chief ore of M. [1]
(b) Write the action of M with carbon monoxide at 120oC and 200 atm. [1]
(c) Discuss the theory of corrosion of M and its prevention. [3]
5. (a) If a primary haloalkane (X) is allowed to react with KCN, it yields a compound (Y) which on acidic
hydrolysis gives propanoic acid. Identity X and Y. [2]
(b) What happens when X is treated with sodium metal in presence of dry ether? What is this reaction
called? [2]
(c) Compare the melting point and boiling point of X with ethanol. [1]
OR
(a) Why is haloarene less reactive than haloalkanes towards nucleophilic substitution reactions? [2]
(b) What happens when the haloarene (C6H5CI) is treated with
(i) CH3CI in presence of anhydrous AlCI3?
(ii) Chloral in presence of conc. H2SO4? [2]
(c) How can C6H5CI be obtained from Sandmeyer reaction? [1]
6. (a) Why are aliphatic amines stronger bases than ammonia? [1]
(b) What happens when aliphatic primary amines are warmed with chloroform and alc. KOH? [1]
(c) How methyl amine and dimethyl amine can be separated by Hoffmann’s method ? [2]
(d) What product is formed when nitrobenzene is reduced in presence of Na3AsO3/NaOH? [1]
7. (a) Why is phenol more acidic than aliphatic alcohol? [2]
(b) What product is formed when phenol is heated with chloroform in presence of aqueous NaOH
at 60-70oC? [1]
(c) Name the compound X and Y. [2]
OH
Na CH3I
X Y
8. (a) Define addition polymerization. Write the reaction to show formation of polyvinyl chloride (PVC)
from its monomer. [1+2]
(b) What are the raw materials used in cement production? [2]
Group-C Long answer Question (3x8=24)

9. Selection of indicator has special importance during titration.
a) Define indicator. [1]
b) How is suitable indicator selected for the titration between strong acid and weak base? (2)
c) Discuss Bronsted-Lowry concept of acid & base [2]
(d) Given that the solubility product of BaSO4 is 1x10-10. Will a precipitate form when equal volume
of 2x10-8M BaCl2 solution and 2x10-3 M Na2SO4 solution are mixed together? [3]
OR
(a) Define bond energy. [1]
(b) Given the bond energy of H-H, O-H and O=O are 435, 460 and 500 KJ mol-1 respectively.
Calculate the enthalpy of combustion of hydrogen. [2]
(c) Define electrochemical series and give its two applications. (1+2)
(d) Construct a galvanic cell & calculate the standard emf of the cell by using following data. [2]
EoZn/Zn++=0.76V EoCu++/Cu=0.34V
10. A primary alcohol (A) with molecular weight 46 is commonly used as alcoholic beverage.
(a) How can A be prepared from fermentation of sugar? (2)
(b) Convert A into ethyl acetate. (1)
(c) Give a suitable test to distinguish A from methanol. (1)
(d) Compare boiling point of A with methanol. (1)
(e) Identify X, Y and Z in the following reaction sequence. (3)
𝑁𝑎𝑁𝑂2 +𝐻𝐶𝑙 𝐻2 0/𝐻 + 𝑎𝑞.𝐵𝑟2

Aniline → X → Y → Z
𝑐𝑜𝑙𝑑 ∆
11. (a) An organic compound C2H4O, gives a red precipitate with Fehling's solution. It also undergoes
aldol condensation in the presence of dilute alkali. Write IUPAC name of the compound and give the
reactions involved. (3)
(b) Convert above compound C2H4O to methanal. (2)
(c) What happens when benzaldehyde reacts with. (3)
(i) Acidified KMnO4
(ii) Lithium aluminum hydride
(iii) RMgX
OR
An organic compound C2H4O2 which can be obtained by treating CH3 MgCl with CO2 in presence
of dry ether changes blue litmus to red.
(a) Give the reaction for the formation of C2H4O2 from above reaction. (1)
(b) Compare the boiling point of C2H4O2 with other organic compounds of comparable molecular
weight. (2)
(c) Compare the acidic strength of CH3COOH, ClCH2COOH & Cl2CHCOOH. (2)
(d) Starting from C2H4O2, how would you prepare 2-hydroxy propanic acid ? (3)
The End
Answer Key:
1.d 2.c 3.a 4.c 5.b 6.d 7.d 8.a 9.b 10.d 11.c

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Model Question

Class -12 Chemistry

Tick the correct answer.

Group-C Long answer Question (3x8=24)

𝑁𝑎𝑁𝑂2 +𝐻𝐶𝑙 𝐻2 0/𝐻 + 𝑎𝑞.𝐵𝑟2

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