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Safety Data Sheet

acc. to OSHA HCS
Printing Date 05/29/2019 Revision Number 3 Revision Date 05/29/2019

* 1 Identification
· Product identifier
· Trade name: 55137 (Hardman Epocap 25137 Part B)
· Article number: 55137
· CAS Number:
112-24-3
· EC number:
203-950-6
· Index number:
612-059-00-5
· Relevant identified uses of the substance or mixture.
Industrial Use Only.
Activator
· Application of the substance / the mixture Activator
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Royal Adhesives And Sealants, LLC
2001 W. Washington Street
South Bend IN 46628-2023
Information Phone Number: 574-246-5000
· Information department: Global Regulatory Department.
· Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)

* 2 Hazard(s) identification
· Classification of the substance or mixture

GHS08 Health hazard

Repr. 1B H360 May damage fertility or the unborn child.

GHS05 Corrosion

Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Acute Tox. 4 H312 Harmful in contact with skin.
Skin Sens. 1 H317 May cause an allergic skin reaction.
(Contd. on page 2)
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Safety Data Sheet
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Printing Date 05/29/2019 Revision Number 3 Revision Date 05/29/2019

Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 1)

· Label elements
· GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS05 GHS07 GHS08

· Signal word Danger

· Hazard statements
Harmful if swallowed or in contact with skin.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May damage fertility or the unborn child.
· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dusts or mists.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 3
1 Fire = 1
3 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH *3 Health = *3
FIRE 1 Fire = 1
PHYSICAL HAZARD 0 Physical Hazard = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
(Contd. on page 3)
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Safety Data Sheet
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Printing Date 05/29/2019 Revision Number 3 Revision Date 05/29/2019

Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 2)
· vPvB: Not applicable.

* 3 Composition/information on ingredients
· Chemical characterization: Substances
· CAS No. Description
112-24-3 Triethylenetetramine
· Identification number(s) N/A
· EC number: 203-950-6
· Index number: 612-059-00-5
· Description: Mixture: consisting of the following components.
· Hazardous components:
Aliphatic Amine ≤2.5%

* 4 First-aid measures
· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin becomes irritated seek medical attention.
· After eye contact: Rinse opened eye for 20 minutes under running water. Call a Doctor immediately.
· After swallowing:
Rinse mouth with water.
Do not induce vomiting; immediately call for medical help.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

* 5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
Firefighters use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA.
· Protective equipment: Protective clothing and respiratory protective device.

* 6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
(Contd. on page 4)
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Safety Data Sheet
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Printing Date 05/29/2019 Revision Number 3 Revision Date 05/29/2019

Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 3)
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Protective Action Criteria for Chemicals
· PAC-1:
Substance is not listed.
· PAC-2:
Substance is not listed.
· PAC-3:
Substance is not listed.

* 7 Handling and storage

· Handling:
· Precautions for safe handling
Open and handle receptacle with care.
Open containers in a well ventilated area and avoid breathing headspace vapors.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location away from direct heat.
· Information about storage in one common storage facility: Store away from oxidizing agents.
· Further information about storage conditions: Keep receptacle tightly sealed.
· Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment (see listings below)
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
(Contd. on page 5)
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Safety Data Sheet
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Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 4)
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
· Material of gloves
Nitrile rubber, NBR
Chloroprene rubber, CR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

Face Shield
· Body protection: Protective work clothing

* 9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Color: Light
· Odor: Amine-like
· Odor threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point: 12 °C (53.6 °F)
Boiling point: Undetermined
· Flash point: 135 °C (275 °F)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 335 °C (635 °F)
· Decomposition temperature: Not determined.
· Auto igniting: Not determined.
· Danger of explosion: Product does not present an explosion hazard.
· Flammable limits:
Lower: Not Available
Upper: Not Available
· Vapor pressure at 20 °C (68 °F): 0.01 hPa (0 mm Hg)
· Specific gravity at 20 °C (68 °F): 0.98236 g/cm³ (8.19779 lbs/gal)
(Contd. on page 6)
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Safety Data Sheet
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Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 5)

· Relative density Not determined.

· Vapor density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Organic solvents: 0.0 %
· Other information No further relevant information available.

* 10 Stability and reactivity

· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid Avoid high temperatures. Avoid freezing.
· Incompatible materials: Reacts with oxidizing agents.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide

* 11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
112-24-3 Triethylenetetramine
Oral LD50 2,500 mg/kg (rat)
Dermal LD50 805 mg/kg (rabbit)
Aliphatic Amine
Dermal LD50 660 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: Caustic effect on skin and mucous membranes.
· on the eye:
Vapors may be severely irritating to the eyes.
Strong caustic effect.
· Sensitization: Skin Contact - Sensitization possible through skin contact.
· Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
Substance is not listed.
· NTP (National Toxicology Program)
Substance is not listed.
(Contd. on page 7)
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Safety Data Sheet
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Printing Date 05/29/2019 Revision Number 3 Revision Date 05/29/2019

Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 6)
· OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.

* 12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes: At present there are no ecotoxicological assessments.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

* 13 Disposal considerations
· Waste treatment methods
· Recommendation: Must be specially treated adhering to official regulations.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· UN-Number
· DOT, IMDG, IATA UN2259
· UN proper shipping name
· DOT Triethylenetetramine
· IMDG, IATA TRIETHYLENETETRAMINE
· Transport hazard class(es)
· DOT

· Class 8 Corrosive substances

(Contd. on page 8)
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Safety Data Sheet
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Printing Date 05/29/2019 Revision Number 3 Revision Date 05/29/2019

Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 7)

· Label 8
This product meets the criteria
· IMDG, IATA

· Class 8 Corrosive substances

· Label 8
· Packing group
· DOT, IMDG, IATA II
· Environmental hazards: Not applicable.
· Special precautions for user Warning: Corrosive substances
· EMS Number: F-A,S-B
· Segregation groups Alkalis
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
· Segregation Code SG35 Stow "separated from" SGG1-acids
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": UN 2259 TRIETHYLENETETRAMINE, 8, II

* 15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
Substance is not listed.
· Section 313 (Specific toxic chemical listings):
Substance is not listed.
· TSCA (Toxic Substances Control Act):
112-24-3 Triethylenetetramine
· Hazardous Air Pollutants
Substance is not listed.
· Proposition 65
Please contact H.B. Fuller for more information regarding Proposition 65 on this product:
[email protected] .
· (DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
· New Jersey Right-to-Know List:
Substance is not listed.
· New Jersey Special Hazardous Substance List:
Substance is not listed.
(Contd. on page 9)
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Safety Data Sheet
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Printing Date 05/29/2019 Revision Number 3 Revision Date 05/29/2019

Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 8)
· Pennsylvania Right-to-Know List:
Substance is not listed.
· Pennsylvania Special Hazardous Substance List:
Substance is not listed.
· Cancerogenity categories
· EPA (Environmental Protection Agency)
Substance is not listed.
· TLV (Threshold Limit Value established by ACGIH)
.
· MAK (German Maximum Workplace Concentration)
Substance is not listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
· National regulations:
· Water hazard class: Water hazard class 2 (Assessment by list): hazardous for water.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
· Department issuing SDS:
Global Regulatory Department.
[email protected]
· Creation Date: 05/29/2019
· Date of preparation / last revision 05/29/2019 / 2
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity – Category 4
(Contd. on page 10)
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Trade name: 55137 (Hardman Epocap 25137 Part B)

(Contd. of page 9)
Skin Corr. 1A: Skin corrosion/irritation – Category 1A
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Repr. 1B: Reproductive toxicity – Category 1B
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