Bondic MSDS Sheet

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Safety Data Sheet


acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

* 1 Identification

Product Name Bondic 5998443

dentified uses Adhesives

Manufacturer Supplier
Laser Bonding Tech, Inc. Laser Bonding Tech, Inc.
235 Industrial Parkway S.#21 235 Industrial Parkway S.#21
Aurora, ON L4G 3V5 Aurora, ON L4G 3V5
-855-Not-A-Glue 1-855-Not-A-Glue
1-855-668-2458 1-855-668-2458

Information department: North American Safety Department @ 1-860-482-101


European Safety Department @ +49-(0) 611-962-790

Emergency telephone number North America: Chemtrec @ 1-800-424-9300 (24hrs)

* 2 Hazard(s) identification
· Classification of the substance or mixture

GHS08 Health hazard

Repr. 2 H361 Suspected of damaging fertility or the unborn child.


STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.


Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Label elements
· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms GHS07, GHS08
· Signal word Danger
· Hazard-determining components of labeling:
Vinylmonomer
· Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure.
· Precautionary statements
Wear protective gloves / eye protection.
Wear protective gloves.
Wear eye protection / face protection.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
(Contd. on page 2)
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Page 2/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

Trade name: Bondic 5998443

(Contd. of page 1)
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
IF ON SKIN: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 1
1 Fire = 1
1 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH 1 Health = 1
FIRE 1 Fire = 1
REACTIVITY 0 Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* 3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
2235-00-9 Vinylmonomer 25-50%
STOT RE 1, H372; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4,
H332; Eye Irrit. 2A, H319; Skin Sens. 1, H317
5888-33-5 Isobornylacrylat 2,5-10%
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335
75980-60-8 diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide < 1,0%
Repr. 2, H361
· Additional information: For the wording of the listed risk phrases refer to section 16.

* 4 First-aid measures
· Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
(Contd. on page 3)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

Trade name: Bondic 5998443

(Contd. of page 2)
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Immediately call a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

* 5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire fighting measures that suit the environment.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment:
Mouth respiratory protective device.
Do not inhale explosion gases or combustion gases.

* 6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective clothing.
· Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

* 7 Handling and storage


· Handling:
· Precautions for safe handling
Store in cool, dry place in tightly closed receptacles.
Keep away from heat and direct sunlight.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: Protect from heat.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
(Contd. on page 4)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

Trade name: Bondic 5998443

(Contd. of page 3)
· Further information about storage conditions: Keep receptacle tightly sealed.
· Storage class: 6.1 C
· Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use respiratory protective device that is independent of circulating air.
Use suitable respiratory protective device in case of insufficient ventilation.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Tightly sealed goggles

* 9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Color: Yellowish
· Odor: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
(Contd. on page 5)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

Trade name: Bondic 5998443

(Contd. of page 4)

Boiling point/Boiling range: Undetermined.


· Flash point: > 100 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature:
Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapor pressure: Not determined.
· Density at 20 °C: 1.1 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic at 20 °C: 5000 mPas
Kinematic: Not determined.
· Solvent content:
Organic solvents: 0.0 %
Water: 0.0 %
VOC content: 0.0 %
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide

* 11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
2235-00-9 Vinylmonomer
Oral LD50 1860 mg/kg (rat) (OECD 401)
Dermal LD50 1700 mg/kg (rabbit) (OECD 402)
5888-33-5 Isobornylacrylat
Oral LD50 4350 mg/kg (rat) (see ECHA data)
(Contd. on page 6)
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Page 6/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

Trade name: Bondic 5998443

(Contd. of page 5)
Dermal LD50 * > 3000 mg/kg (rabbit) (see ECHA data)
75980-60-8 diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide
Oral LD50 * > 5000 mg/kg (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Harmful
Irritant

* 12 Ecological information
· Toxicity
· Aquatic toxicity:
2235-00-9 Vinylmonomer
LC50/96h 318 mg/l (fish) (OECD 203)
EC50/48h* > 100 mg/l (daphnia) (79/831/EWG)
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· UN-Number
· DOT, ADR, ADN, IMDG, IATA Void
· UN proper shipping name
· DOT, ADR, ADN, IMDG, IATA Void
(Contd. on page 7)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

Trade name: Bondic 5998443

(Contd. of page 6)

· Transport hazard class(es)


· DOT, ADR, ADN, IMDG, IATA
· Class Void
· Packing group
· DOT, ADR, IMDG, IATA Void
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Remarks: No hazardous material as defined by the prescriptions.
· IMDG
· Remarks: No hazardous material as defined by the prescriptions.
· IATA
· Remarks: No hazardous material as defined by the prescriptions.
· UN "Model Regulation": Void

* 15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· TSCA (Toxic Substances Control Act):
All ingredients of this material are listed on the TSCA Inventory or are exempt.
· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms GHS07, GHS08
· Signal word Danger
· Hazard-determining components of labeling:
Vinylmonomer
· Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure.
· Precautionary statements
Wear protective gloves / eye protection.
Wear protective gloves.
Wear eye protection / face protection.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
(Contd. on page 8)
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Page 8/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 11/27/2015 Reviewed on 11/27/2015

Trade name: Bondic 5998443

(Contd. of page 7)
Get medical advice/attention if you feel unwell.
IF ON SKIN: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· National regulations:
· Information about limitation of use:
Employment restrictions concerning pregnant and lactating women must be observed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing SDS: Environment protection department.
· Contact: Frau Dr. Jutta Lörzer
· Date of preparation / last revision 11/27/2015 / 13
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
Repr. 2: Reproductive toxicity, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
STOT RE 1: Specific target organ toxicity - Repeated exposure, Hazard Category 1
· * Data compared to the previous version altered.
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