Material Safety Data Sheet

PURESPRAY GREEN

1. Product and company identification

Common name : PURESPRAY GREEN
Code : PSGREEN, 440-198
Material uses : PureSpray Green is a Spray Oil that is registered as "Organic" with USEPA and OMRI and
used in Organic farming operations.
EPA registration number: 69526-9
Manufacturer : PETRO-CANADA
P.O. Box 2844
150 –6th Avenue South-West
Calgary, Alberta
T2P 3E3
In case of emergency : Petro-Canada: 403-296-3000
Canutec Transportation:
613-996-6666
Poison Control Centre: Consult local telephone directory for emergency number(s).

2. Hazards identification
Physical state : Viscous liquid.
Odor : No odour or slight petroleum oil like.
OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the
safe handling and proper use of the product. This MSDS should be retained and
available for employees and other users of this product.
Emergency overview : No specific hazard.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eyes : Slightly irritating to the eyes.
Skin : Slightly irritating to the skin.
Inhalation : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Medical conditions : Repeated or prolonged contact with spray or mist may produce chronic eye irritation and
aggravated by over- severe skin irritation. Repeated skin exposure can produce local skin destruction or
exposure dermatitis.
See toxicological information (section 11)

3. Composition/information on ingredients
Name CAS number %
Mixture of severely hydrotreated and hydrocracked base oil (petroleum). Mixture -

4. First aid measures

Eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention if irritation occurs.
Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser. Get medical
attention if irritation occurs. Remove contaminated clothing and shoes. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Inhalation : If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. Get medical attention.
Ingestion : Do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If potentially dangerous quantities of this
material have been swallowed, call a physician immediately.

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4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

5. Fire-fighting measures
Flammability of the product : May be combustible at high temperature.
Products of combustion : Carbon oxides (CO, CO2), smoke and irritating vapours as products of incomplete
combustion.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : In a fire or if heated, a pressure increase will occur and the container may burst.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special remarks on fire : Low fire hazard. This material must be heated before ignition will occur.
hazards
Special remarks on : Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or
explosion hazards sources of ignition.

6. Accidental release measures

Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see section
1 for emergency contact information and section 13 for waste disposal.

7. Handling and storage

Handling : Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire
risk. Evaporate the residue under a fume hood. Ground all equipment containing
material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective
clothing. If ingested, seek medical advice immediately and show the container or the
label. Keep away from incompatibles.
Storage : Keep container tightly closed. Store away from incompatible materials (see section 10).
Keep container in a cool, well-ventilated area.

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8. Exposure controls/personal protection

Product name Exposure limits
Mixture of severely hydrotreated and ACGIH TLV (United States). Notes: (oil mist)
hydrocracked base oil (petroleum). TWA: 5 mg/m³ 8 hour(s).
STEL: 10 mg/m³ 15 minute(s).
Consult local authorities for acceptable exposure limits.
Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to
control worker exposure to airborne contaminants. If this product contains ingredients
with exposure limits, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any recommended or statutory
limits.
Personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Recommended: organic vapor filter
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Recommended: neoprene, nitrile, polyvinyl alcohol (PVA), Viton.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.

9. Physical and chemical properties

Physical state : Viscous liquid.
Flash point : Open cup: 174°C (345.2°F) [Cleveland.]
Auto-ignition temperature : Not available.
Flammable limits : Not available.
Color : Colorless to light yellow.
Odor : No odour or slight petroleum oil like.
pH : Not available.
Boiling/condensation point : Not available.
Pour point : Not available.
Melting/freezing point : Not available.
Relative density : 0.855 kg/L @ 15ºC (59ºF)
Vapor pressure : Not available.
Vapor density : Not available.
Volatility : Not available.
Odor threshold : Not available.
Evaporation rate : Not available.
Viscosity : 13.6 cSt @ 40ºC (104ºF), 3.18 cSt @ 100ºC (212ºF)
Solubility : Insoluble in water. Easily dispersed in water.
LogKow : Not available.

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9. Physical and chemical properties

Softening Point : Not available.
Dropping Point : Not available.

Penetration : Not available.

Physical/chemical : Not available.
properties comments

10 . Stability and reactivity

Stability and reactivity : The product is stable.
Conditions of instability : Not available.
Incompatibility with various : Reactive with oxidizing agents.
substances
Hazardous decomposition : May release COx, smoke and irritating vapours when heated to decomposition.
products
Hazardous polymerization : Will not occur.

11 . Toxicological information
Toxicity data
Product/ingredient name Test Result Route Species
Mixture of severely hydrotreated LD50 >5000 mg/kg Oral Rat
and hydrocracked base oil LD50 >2000 mg/kg Dermal Rabbit
(petroleum). LC50 >2500 mg/m³ (4 Inhalation Rat
hours)
Specific effects
Carcinogenic effects : Not listed as carcinogen by OSHA, NTP or IARC.
Mutagenic effects : No known significant effects or critical hazards.
Teratogenicity / : No known significant effects or critical hazards.
Reproductive toxicity
Sensitization
Ingestion : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Eyes : Slightly irritating to the eyes.
Skin : Slightly irritating to the skin.
Synergistic products : Not available.

12 . Ecological information
Ecotoxicity data
Product/ingredient name Species Period Result

Environmental precautions : This product is inherently biodegradable.

Bioconcentration factor Not available.
BOD and COD Not available.
Biodegradable/OECD Not available.
Mobility Not available.
Special remarks on the Not available.
products of biodegradation

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13 . Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

Waste disposal : The generation of waste should be avoided or minimized wherever possible. Dispose of
surplus and non-recyclable products via a licensed waste disposal contractor. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

14 . Transport information
Regulatory UN number Proper shipping Class PG* Label Additional
information name information
TDG Classification Not - - - -
regulated.
DOT Classification Not available. Not available. Not - -
available.
PG* : Packing group

15 . Regulatory information
United States
HCS Classification : Not regulated.
Canada
WHMIS (Canada) : Not controlled under WHMIS (Canada).
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
International regulations
International lists
CANADA INVENTORY (DSL) : Listed
EC INVENTORY (EINECS/ELINCS) : Listed
TSCA 8(b) inventory : Listed

16 . Other information
Hazardous Material : Health 1
Information System (U.S.A.)
Fire hazard 1
Reactivity 0

Personal protection B

National Fire Protection :

1 Flammability
Association (U.S.A.)
Health 1 0 Instability
Special

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16 . Other information
References : Available upon request.
TM/MC Marque de commerce de Petro-Canada - Trademark

Date of printing : 6/2/2008.

Date of issue : 6/2/2008.
Date of previous issue : No previous validation.
Responsible name : Product Safety - JDW
Version : 1
For Copy of (M)SDS : Internet: lubricants.petro-canada.ca/msds

Lubricants:
Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564
Ontario & Central Canada, telephone: 1-800-268-5850 and (905) 822-4222; fax: 1-800-
201-6285
Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 1-800-201-6285

For Product Safety Information: (905) 804-4752

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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