General Chemistry 2: Types of Catalyst

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SHS

STEM
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General Chemistry 2
Quarter 2- Week 4 (Module 20)
Types of Catalyst
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General Chemistry 2 (SHS-STEM)
Quarter 2 – Week 4 (Module 20): Types of Catalyst

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Regional Director: Gilbert T. Sadsad

Asst. Regional Director: Jessie L. Amin

Development Team of the Module

Writer: Merlita Cardano

Editors/Reviewers: Arlen B. Bertiz


Tomasa R. Camu
Ronaldo C. Reyes
Noel V. Ibis
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Dear learners,

I hope you will enjoy using this Self-directed Module in General Chemistry 2.
In this module you will be able to cite and differentiate the types of catalyst.

A catalyst is a substance added to a reaction that changes the speed of


chemical process (but most of the time increases the reaction rate) without getting
consumed in the process. Catalysts typically speed up a reaction by reducing the
activation energy or changing the reaction mechanism. Enzymes are proteins that act
as catalysts in biochemical reactions.

In this module, you will learn how a catalyst increases the rate of reaction
without being used up itself in the reaction and you will able to identify the different
types of catalyst. Be ready to learn how catalyst work in a chemical reaction.

MOST ESSENTIAL LEARNING COMPETENCY

Cite and differentiate the types of catalyst.

YOUR LEARNING TARGET

Specifically, you will be able to:

1.Identify the different types of catalyst.


2.Describe the characteristics of catalyst and catalyzed reaction
3. Explain the various types of catalyst

Are you ready to learn more? You can now proceed to the next
page of your manual

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https://www.google.com/search?q=ANIMATED+picture

Direction: Read carefully and answer each question below. Write the letter of the
correct answer in your notebook.

1. Which of the following is not a characteristic of a catalyst?


a) It participates in the reaction
b) It enhances the equilibrium rate
c) It activates equilibrium
d) It initializes the reaction
2. Which is a homogeneous catalyst?
a. Those which exist in the same phase (gas or liquid) as the reactant
b. Those that are not in the same phase as the reactants
c. Those that involves the use of solid catalysts place in a liquid
reaction mixture
d. Those that are in different phase than the reactant.

3. Which is an example of heterogeneous catalyst?


a. catalytic converter in gasoline or diesel fueled car
b. organometallic catalysis
c. acid catalysis
d. enzymatic catalysis

4. What type of catalyst decreases the activation energy by accepting an


alternative path for the reaction to occur?
a. Positive catalyst
b. Negative catalyst
c. Auto-catalyst
d. Induced catalyst
5. In which of the following sample will there be an increase in the rate of
reaction?
a. without enzyme c. inhibitors
b. with enzyme d. all of the above

Please check your answer at the answer key section. If you got
perfect score of 5, it will be easy for you to continue with this module
but if your score is 4 or lower, I suggest you need to study more.

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A. Engage

Have you ever known that sugar can be fermented and turned into ethyl
alcohol in the presence of yeast? The substance in yeast that converts the
sugar to alcohol is an enzyme, which is an example of a catalyst.

Get ready! Let’s learn and do some engaging activities to know more
about the topics.

There are four pictures, all of them share a word in common. Your role
is to figure out the common word based on word length. You need to arrange
the letter that describes the image.
1.

A
T A L C Y S T
_______ _______ ________ ________ _________ _______ _____ ______
https://www.google.com/search?q=what+are+the+example+of+catalyst&rlz

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2. Major types of catalyst.

M G U N H O
Di
d
O O E E S
yo
u
_____ _____ ____ ____ _____ _____ _____ _____ _____ ____ ______
kn
and
ow
th
E E E E O OU S N T R G H
at?

catalyst.

https://www.google.com/search?q=FINISHED+PRODUCT+OF+HOMOGENEOUS+CATALYST+IMAGE&r
lz=1C1CHBD_enPH784PH784&tbm=isch&source=iu&ictx=1&fir=MVSRMPWA79G
N
4
N
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3.

I B O S MZ N E Y E
____ ____ ______ _____ _______ ______ _______ ________ ________ ___
_https://www.google.com/search?q=PICTURE+/IMAGE+OF+BIOENZYMES&rlz=1C1CHBD_enPH784P
H784&tbm=isch&source=iu&ictx=1&fir=17tPeBNKcL76NM%252CVfcJRjhaUc80JM%

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4.

Auto-catalyst

Induced fit enzyme model

R O U F E T P S Y
___ ______ ______ _______ _______ _______ ________ _______ ________
of catalyst
https://www.google.com/search?q=induced+catalysis+examples&rlz=1C1CHBD_enPH784PH784&so
urce

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5.

A A T I O N V I T C Y R N E E G

___ ___ ____ ___ ___ ___ ___ ___ ___ ____ ___ ____ ____ ___ ___ ___

https://www.google.com/search?q=activation+energy&source=lnms&tbm=isch&sa=X&ved=2ahUKEwj7usi9wJ7qAhWDHHAKHcHTDgUQ

Good work! In the next activity, you will explore the different types of catalyst.

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B. Explore

Activity 1: Match Me

This activity contains statements about types of catalyst given in two columns.
Identify the correct description of each catalyst by matching Column A with Column
B

Column A Column B
1. The type of catalyst that
decreases the activation energy
by accepting an alternative path Positive catalyst
for the reaction to occur.
2. The catalyst that slows down
chemical reaction like aging and Auto-catalyst
rusting.
3. The catalyst that retards the rate
of reaction. Induced catalyst
4. The substance that accelerates
the activity of catalyst . Negative catalyst
5. A phenomenon when a reaction
influences the rate of other Inhibitors
reaction
Check your answer in the answer key. If you got a score of 5, congratulations
for having a stocked knowledge on the topic. For those who got 4 and below you need
to read more about catalyst.

google.com/search?q=gestu

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Work it out
Activity 2: Tell Me

This activity is a continuation of Activity 1. In questions 1 to 3, tell me if the


statement labelled A and B is Auto- catalyst and Induced catalyst. You may refer to
the set of information in the definition found at the end of this module. Write capital
“A” if the statement is Auto- catalyst and small "i" if statement is induced catalyst. For
questions 4-5 answer what is being ask. Write your answers in your notebook

1. A. One of the products formed in the reaction acts as a catalyst for the reaction
to proceed.
B. A substance that influences the speed of a reaction which is not possible
under ordinary conditions.

2. A. Is a single chemical reaction wherein reaction product is itself the catalyst.


B. Is a chemical reaction that increases the rate of another chemical reaction.

3. A. Example: Sodium arsenite solution is not oxidized by air.


B. Example: The oxidation of a solution of ethanedioic acid (oxalic acid) by an
acidified solution of potassium manganate(VII) (potassium permanganate).
https://www.google.com/search?q=what+is+auto+catalyst+give+example&rlz=

4. Cite the difference between auto-catalyst and induced catalyst.


_______________________________________________________

5. Differentiate Positive catalyst from Negative catalyst.


_______________________________________________________

https://www.google.com/search?q=awesome+image

: Check your answer in the answer key. If you got 5 you’re excellent, below
4 needs more readings about the topic catalyst

https://www.google.com/search?q=ANIMATED+picture

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B. Explain

ACTIVITY 3: LABEL ME!

Direction: Shown below are the two main types of catalyst. Observe the difference
between the two pictures, identify which picture is homogeneous catalyst and
heterogeneous catalyst by labelling. Write your answer in your notebook.

A.________________________ B.________________________
https://www.google.com/search?q=homogeneous+catalyst+example&tbm=isch&rlz=1C1CHBD
Direction: Observe the difference between the two reactions written in the box, identify
which reaction is homogeneous catalyst and heterogeneous catalyst. Explain.

2. NO(g) Fe (s)
N 2SO2(g) + O2 (g) 2SO3 (g) N2(g) + 3H2 (g) 2NH3 (g)

A.________________________ B.________________________
https://www.slideshare.net/ShikhaPopali1/homogeneous-catalysis-mpharm-msc-bpharm-bsc
Direction: Observe the difference between the two statements written in the box that
describe the two types of catalyst. Identify which statement is Biocatalyst and
Heterogenization methods of homogeneous catalyst.

3. The phenomenon that “breaks” the A substance such as enzymes or


hormone, that initiates or increase the
uniformity of the catalyst and product.
rate of chemical reaction.

A.________________________ B.________________________
N

https://depositphotos.com/stock-photos/job-well-done.html?qview=16317151

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ACTIVITY 3: LET’S ANALYZE MY UPSHOTS!

https://www.google.com/search?q=critical+thinking+images&rlz=1

Situational Analysis: Read related technology brought about by catalyst and answer
what is being asked?

1. USING TECHNOLOGY: Catalytic Converter

https://www.google.com/search?q=image+of+catalytic+converter

The exhaust systems of cars today are equipped with catalytic


converters that uses rhodium and platinum as catalysts. No more than 4-9
grams of these precious metals are used in a single converter. This catalyst
speeds up reaction of three types of toxic compounds given off the cars. The
rhodium and platinum as catalysts do not enter into a chemical reaction, but
the rough surface of the catalyst provides a high-surface area for the reaction
to occur. Catalytic converters change unburned hydrocarbons, carbon
monoxide, and nitrogen oxides into harmless compound.

Why is it not necessary to add more rhodium and platinum to a catalytic


converter as these substances are used?

Comment: _________________________________________________
_________________________________________________

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2. Science and Arts: Fresco Painting

https://www.google.com/search?q=fresco+painting&rlz
Fresco Painting is a mural painting technique that involves painting with
water-based paint directly onto wet plaster so that the paint becomes an
integral part of the plaster. The word fresco is an Italian for “fresh”. Fresco
painting makes use of chemical reaction that causes color pigment to
crystalize within the plaster as it dries. As the plaster dries, carbon dioxide in
the air turns the lime to calcium carbonate, crystalizing the pigments. The color
then becomes part of the plaster itself.
The process of forming a carbonate is sometimes referred to as
“carbonation”, this term usually refers to the process of dissolving carbon
dioxide in water. Calcium carbonate and natural pigments make the medium
of Fresco the most environmentally safe medium. Only pigments that resist the
action of lime can be used. The pigments are usually earth color. Frescoes
have been painted for hundreds and hundreds of years.
What is the role of carbon dioxide in air in Fresco Painting? What type
of catalytic mechanism exist in Fresco painting? Why?
Comment: _________________________________________________

3. Agricultural Industry: Haber’s Process/Haber–Bosch

https://www.google.com/search?q=image+Haber%27s+process&rl

The Haber process, also called the Haber–Bosch process, is an artificial


nitrogen fixation process and is the main industrial procedure for the production
of ammonia today. In agriculture, ammonia is produced with the help of
iron catalysts. The ammonia is most commonly used in the field to make
fertilizers which are essential for plant growth.
What type of catalytic mechanism is involved in Haber’s or Bosch process
in producing ammonia? Explain why? Please refer to the information given on
page 16, types of catalyst.
Comment: _________________________________________________

https://www.google.com/search?q=image+congratulations&source

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C. Elaborate

https://www.google.com/search?q=elaborate+image&rlz

A catalyst is a substance that speeds up a reaction and does not appear in the
overall chemical equation. A catalyst offers an alternative pathway by which a reaction
occurs. The effect of catalysts can be understood in terms of the collision theory. The
presence of catalyst lowers the activation energy needed to overcome the reaction to
occur and forms another activated complex. For the reaction

A2+B2 A2B2 2AB.


activated complex

The reaction is the ordinary pathway by which A2 and B2 react to form 2AB. The
activated complex is A2B2. If the collision is ineffective A2B2 reverts back to the
reactant. If there is a sufficient energy of the reacting molecules, A 2B2 is formed
immediately. The higher the energy needed to form the activated complex, the slower
the rate of reaction. In the presence of catalyst (C), the reaction proceeds in different
pathway as shown below.

A2 + C A 2 C + B2 2AB + C

The catalyst C is generated at the end of the reaction. The alternative pathway
will need a lower activation energy. At lower activation energy, more collision will have
sufficient energy to pass over the energy barrier. The reaction proceeds faster
because a greater fraction of collision is effective at any given point.

1. What type of catalyst is presented in the previous discussion/lecture? Why?


• ____________________________________________________________

2. Why activation energy is important to start a chemical reaction?


• ____________________________________________________________

3. What is the relationship between catalyst and activation energy?


• ____________________________________________________________

4. How do you call the catalyst that slows down chemical reaction?
• ______________________________________________________________

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There are four other types of catalyst:
1. Homogeneous catalysis refers to reactions where the catalyst is in the same
phase as the reactants. An example of this type of catalysis ivolving liquid in the
conversion of persulphate and iodine into sulphate ion and iodine:
( S2O82- + 2I- 2SO42 + I2)
2. Heterogeneous catalysis, when the catalyst and the reactant are in different
phases. For example, the catalyst might be in solid phase while the reactant is in liquid
or gas phase, like the catalytic converter in gasoline or diesel-fueled cars (Oxidation
of hydrocarbons (unburnt and partially burned fuel) to carbon dioxide and water.

3.Heterogenization method of homogeneous catalytic system is the


application of two liquid phases with no limited or temperature regulated miscibility of
two phases or a solid phase in the liquid phase. It is a modification of homogeneous
catalyst to “break” the uniformity among the molecules of catalyst and the product(s)
by rendering them in separable phases to allow their separation.
An example of heterogenized homogeneous catalytic reaction.

Immobilization of a water soluble phosphine by hydrogen bonding of the hydrated


sodium-sulfonate groups to the surface of silica.
https://pubs.rsc.org/en/content/articlehtml/2011/cy/c1cy00174d
4.Biocatalyst is a substance, such as enzymes or hormone, that initiates or increases
the rate of chemical reaction. An enzyme is a biological catalyst that accelerates a
chemical reaction without altering its equilibrium. Enzymes are present in the body and
are responsible for reaction that extract energy from food we eat. They increase the
speed of reaction essential to life. Without these enzymes, reactions would occur
extremely slowly and life may not be possible. General example of biocatalyst being
the yeast-mediated transformation of sugar into alcohol, acids, or gases. However, the
most frequent example of biocatalyst are as follows:

https://www.google.com/search?q=most+frequent+example+of+biocatalyst&rlz

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Other types of catalyst are the following:

1. Positive catalyst, decreases the activation energy by accepting an alternative


path for the reaction to occur. The rate of reaction is decreased. Some reaction
uses positive catalyst. Example: 2KClO3 2KCl(s) + 3O2(g).

2. Negative catalyst, decreases or slows down the rate of reaction in rusting, or


decomposition of certain substances and aging. The negative catalyst is known
as inhibitors. Example: 2H2O(l) 2H2O(l) + O2(g).

3. Auto-catalyst-the products formed in the reaction act as a catalyst for the


reaction to proceed. Example:
Process Catalyst

ammonia synthesis iron

sulfuric acid manufacture nitrogen(II) oxide, platinum

cracking of petroleum zeolites

hydrogenation of unsaturated hydrocarbons nickel, platinum, or palladium

4.Induced catalyst is a substance that influences the speed of reaction which is


not possible under ordinary condition. A chemical reaction that increases the
rate of another chemical reaction is called induced catalysis.( Example:
Sodium arsenite solution is not oxidized by air). Thus the oxidation of
sodium arsenite is induced by oxidation of sodium sulphite. Examples are:
Air
• NA2SO3 Na2SO4
Air
• Na2 SO3 No reaction

Air
• NA2SO3 + Na2 AsO3 Na2AsO4 + NaSO4
https://www.topperlearning.com/answer/explain-with-the-help-of-example-induced-
catalyst/58sagptt

https://www.google.com/search?q=image+now+you+know&rlz

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D. Evaluate: Write the letter of your answer in your science notebook.

https://www.123rf.com/stock-photo/evaluation.html
1. A catalyst is
a. A reactant in a chemical reaction
b. A product in a chemical reaction
c. A substance the speeds up a reaction without being consumed
d. A substance that increases the energy of the product

2. Which of the following is present in a reaction where in the catalyst exist in a


different phase from the reactants molecules?
a. homogeneous b. heterogeneous catalyst
c. heterogenized homogeneous catalyst d. enzymes

3. Which statement is incorrect about auto-catalyst?


a. Slows down the decomposition of a certain substance
b. The reaction product is itself the catalyst for that reaction
c. One of the product act as catalyst for the same or coupled reaction
d. The product formed in the reaction act as catalyst for the reaction to
proceed.

4. Which statement regarding enzymes is false?


a. Enzymes are protein that function as catalyst
b. Enzymes also acts as catalyst in biological process
c. Enzymes provide activation energy for the reaction
d. Enzymes maybe used many times for specific reaction

5. Look at the diagram, which depicts the energy diagram for a chemical reaction.
Which point on the diagram represent the point in which the transition state
exists?

https://www.google.com/search?q=5.+Look+at+the+diagram

a. A b. B c. C d. D

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https://www.google.com/search?q=signs+image+vocabulary&rl

• Activation energy is the minimum quantity of energy which the reacting species
must possess in order to undergo a specified reaction

• Catalyst is a substance added to reaction that changes the speed of chemical


process (but most of the time increases the reaction rate) without itself
undergoing any permanent chemical change.

• Enzyme is a type of protein that speeds up metabolic reactions in plants and


animals without permanently changed or destroyed.
• Homogeneous catalysis occurs when the reactants, products and catalyst are
all in the same phase. Often the reactants, products and catalyst areall
dissolved in the same solvent. Due to environmental considerations, the solvent
is often water. This is then reduced back to the original form by reaction with
the other reactant.

• Heterogeneous catalysis is catalysis in which the catalyst does not take part
in the reaction that it increases. With heterogeneous catalysis, the catalyst
and the reactants may be in different phases, for example gas-phased
reactions which are catalyzed by solids.

• Heterogenization of homogeneous catalytic system is a modification of


homogeneous catalysts to “break” the uniformity among the molecules of the
catalyst and the product by rendering them in separate phases to allow their
separation.

• Biocatalyst is the substance, such as enzymes or hormones, that initiates or


increases the rate of chemical reaction.

• Positive catalyst decreases the activation energy by accepting an alternative


path for the reaction to occur.

• Negative catalyst decreases or slows down chemical reaction by increasing


activation energy needed for the reaction to occur.

• Auto-catalyst the product formed in the reaction act as catalyst for the
reaction to proceed.

• Induced catalyst is a substance that influences the speed of a reaction which


is not posible under ordinary condition.

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.

https://www.google.com/search?q=image+post+test&source

Direction: True or False? Analyze the statement carefully, write True if the
statement is correct and False if the statement is wromng. Write your answer
in your answer sheet.

1. A catalyst increases the rate of forward reaction without influencing that of


reverse reaction.
2. Positive catalyst is a type of catalyst that increases the activation energy
by accepting alternative path for the reaction to occur like slowing down
aging and rusting of iron.
3. Negative catalyst is a type of catalyst that enhances the rate of reaction
like ripening of banana.
4. When one of the products formed in the reaction act as catalyst for the
reaction to proced is known as auto-catalyst.
5. Enzymes act as catalyst in biological process. It is also use to convert
sugar into alcohol with the use of yeast.
Direction: This is a short answer type question. Each correct answer will earn 20
points with a total of 100 points. Write your answer in your notebook.
1. Why is catalyst more effective in a finely grinded state?

2. What is the differnce between homogeneous catalyst and


heterogenous catalyst?

3. What is the differnce between positive catalyst and negative catalyst in


terms of rate of reaction.

4. Differentiate auto-catalyst from induced catalyst in terms catalytic


performance.

5. How is catalyst and activation enrgy related to each other?

google.com/search?q=image+fantastic&source

Now, you have learned about the different the types of catalyst!

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https://www.google.com/search?q=image+answer+key+sign&rlz

ANSWER KEY:

Pretest:
1. a
2. a
3. a
4. a
5. b

Engage
1. CATALYST
2. TWO TYPES
3. BIOENZYMES
4. FOUR TYPES
5. ACTIVATION ENERGY

Explore
Activity 1. Match Me
1. Positive catalyst
2. Inhibitors
3. Negative catalyst
4. Auto-catalyst
5. Induced catalyst

Activity 2. Tell Me
1. A. A
B. i
2. A. A
B. i
3. A. i
B. A
4. Auto-catalyst act as a catalyst for the reaction to proceed while induced
catalyst influences the speed of reaction which is not possible under ordinary
condition.
5. The positive catalyst decreases activation energy by accepting an alternative
path for the reaction to occur while negative catalyst slows down the rate of
chemical reaction, an inhibitor.

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Activity 3. Label Me
1. A. heterogeneous catalyst
B. homogeneous catalyst
2. A. homogeneous catalyst (all gas phase)
B. Heterogeneous catalyst (2phase 1-solid and 1 liquid)
3. A. Heterogenization of homogeneous catalyst
B. Biocatalyst

Activity 4. Let’s Analyze My Upshots


1. Platinum and Rhodium is very expensive
2. Carbon dioxide in the air turns the lime to calcium carbonate, crystalizing the
pigments. Therefore, the catalyzing agent is the Carbon dioxide in air. It is an
example of negative catalyst.
3. Auto-catalyst. Ammonia is a product out of iron as catalyst producing
ammonia fertilizer used by farmers.

C. Elaborate
1. Positive catalyst
2. It is the minimum energy needed to start a reaction
3. A catalyst increases the rate of reaction by lowering the activation energy
so that more reactant molecules collide with enough energy
4. Negative catalyst/ inhibitor

Evaluate
1. c
2. b
3. a
4. c
5. b

Post Test
1. False
2. False
3. False
4. True
5. True

If in case you got a poor rating in the assessment, try again! You
need to repeat reading and answering the activities in the module until
you got a passing score in the assessment. Just go back to the
module from the top until such time that you master the concepts and
skills. Congrats for acquiring more knowledge on citing and identifying
catalyst!

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Bibliography

1McLaughlin,Charles W. et. Al (1999). Physical Science. Glencoe/MacGraw-Hill


Companies, 8787 Orion Place Columbus, OH 43240.

2Ayson, Marissa F. et. Al ( 2016). General Chemistry 2 for Senior High School.
Vibal Group, Inc. 1253 G. Araneta Avenue, Quezon City, Metro Manila

3Phillips,
Johnson S. et, AL ( 1997). Chemistry Concept and Application.
Glencoe/MacGraw-Hill Companies, 936 Eastwind Drive Weaterville,Ohio
43081

Electronic Sources

https://www.saralstudy.com/study-eschool-ncertsolution/chemistry/surface-chemistry/1865-give-
four-examples-of-heterogeneous-catalysis

https://www.saralstudy.com/study-eschool-ncertsolution/chemistry/surface-chemistry/1865-give-
four-examples-of-heterogeneous catalysis

https://www.google.com/search?q=differentiate+homogeneous+catalyst&rlz=1C1CHBD_enPH784P
H784&oq

https://www.google.com/search?rlz=1C1CHBD_enPH784PH784&q=What+are+biocatalysts+give+an
+example%3F&sa=X&ved=2ahUKEwj_97fj8pjqAhWRdd4KHc2IB_cQzmd6BAgNEAw&

https://www.google.com/search?q=heterogeneous+catalyst+example&rlz=1C1CHBD_enPH784PH78
4&oq=HETEROGENEOUS+CATAKYST+

https://www.quora.com/How-would-one-explain-the-phrase-all-proteins-are-enzymes-but-not-all-
enzymes-are-proteins

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References cited

https://www.google.com/search?q=image+of+catalyst+symbol&tbm

https://www.google.com/search?q=ANIMATED+picture
https://www.google.com/search?q=induced+catalysis+examples&rlz=1C1CHBD_en
PH784PH784&source

https://www.google.com/search?q=PICTURE+/IMAGE+OF+BIOENZYMES&rlz=1C1
CHBD_enPH784PH784&tbm=isch&source=iu&ictx=1&fir=17tPeBNKcL76NM%252C
VfcJRjhaUc80JM%

https://www.google.com/search?q=activation+energy&source=lnms&tbm=isch&sa=X
&ved=2ahUKEwj7usi9wJ7qAhWDHHAKHcHTDgUQ

https://www.google.com/search?q=image+of+catalytic+converter

https://iliafresco.com/medium-of-fresco/fresco-painting.htm

https://www.google.com/search?q=image+Haber%27s+process&rl

https://pubs.rsc.org/en/content/articlehtml/2011/cy/c1cy00174d

https://www.topperlearning.com/answer/explain-with-the-help-of-example-induced-
catalyst/58sagptt

https://www.google.com/search?q=image+post+test&source
google.com/search?q=image+fantastic&source

https://www.google.com/search?q=signs+image+vocabulary&rl

https://www.google.com/search?q=image+answer+key+sign&rlz

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