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    Chemical Kinetics - DPP-02 (Of Lec-03) - DPP - 02

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    Shanks
    The document contains 10 multiple choice questions regarding order of reaction and rate laws. The questions cover topics such as determining rate laws from experimental data, effects of changing concentrations on reaction rates, identifying rate expressions, calculating rate constants, and units of rate constants. An answer key is provided with the correct response for each question.

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    Chemical Kinetics - DPP-02 (Of Lec-03) - DPP - 02

    Uploaded by

    Shanks
    78 views3 pages
    The document contains 10 multiple choice questions regarding order of reaction and rate laws. The questions cover topics such as determining rate laws from experimental data, effects of changing concentrations on reaction rates, identifying rate expressions, calculating rate constants, and units of rate constants. An answer key is provided with the correct response for each question.

    Original Title

    Chemical Kinetics _ DPP-02 (of Lec-03) - DPP - 02

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    The document contains 10 multiple choice questions regarding order of reaction and rate laws. The questions cover topics such as determining rate laws from experimental data, effects of changing concentrations on reaction rates, identifying rate expressions, calculating rate constants, and units of rate constants. An answer key is provided with the correct response for each question.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    78 views3 pages

    Chemical Kinetics - DPP-02 (Of Lec-03) - DPP - 02

    Uploaded by

    Shanks
    The document contains 10 multiple choice questions regarding order of reaction and rate laws. The questions cover topics such as determining rate laws from experimental data, effects of changing concentrations on reaction rates, identifying rate expressions, calculating rate constants, and units of rate constants. An answer key is provided with the correct response for each question.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    ORDER Of REACTION DPP-02

    𝑑[𝐴] 𝑑[𝐵]
    1. 𝐴 + 2𝐵 → 𝐶 + 𝐷, If − 𝑑𝑡 = 5 × 10−4mol l–1 s–1, then − 𝑑𝑡 is:
    (A) 2.5 × 10–4 mol l–1 s–1 (B) 5.0 × 10–4 mol l–1 s–1
    –3 –1 –1
    (C) 2.5 × 10 mol l s (D) 1.0 × 10–3 mol l–1 s–1

    2. The data for the reaction A + B → C is:


    Exp. [A]0 [B]0 Initial rate
    (1) 0.012 0.035 0.10
    (2) 0.024 0.070 0.80
    (3) 0.024 0.035 0.10
    (4) 0.012 0.070 0.80
    The rate law corresponds to the above data is:
    (A) Rate = k[B]3 (B) Rate = k[B]4
    (C) Rate = k[A][B]3 (D) Rate = k[A]2[B]2

    3. The experimental data for the reaction 2A + B2 → 2AB is:


    Exp. [A]0 [B2]0 Rate (mole s–1)
    (1) 0.50 0.50 1.5 × 10–4
    (2) 0.50 1.00 3.0 × 10–4
    (3) 1.00 1.00 3.0 × 10–4
    The rate equation for the above data is:
    (A) Rate = k[B] (B) Rate = k[B2]
    (C) Rate = k[A]2[B2]2 (D) Rate = k[A]2[B2]
    4. The reaction 2𝑁𝑂(𝑔) + 𝑂2 (𝑔)→2𝑁𝑂2 (𝑔) is of first order. If volume of reaction vessel is reduced to 1/3, the rate
    of reaction would be:
    (A) 1/3 times (B) 2/3 times
    (C) 3 times (D) 6 times

    5. For a reaction 2A + B → Products, doubling the initial concentration of both the reactants increases the rate by a
    factor of 8, and doubling the concentration of B alone doubles the rate. The rate law for the reaction is:
    (A) 𝛾 = 𝑘[𝐴][𝐵]2 (B) 𝛾 = 𝑘[𝐴]2 [𝐵]
    (C) 𝛾 = 𝑘[𝐴][𝐵] (D) 𝛾 = 𝑘[𝐴]2 [𝐵]2
    6. Velocity constant K of a reaction is affected by
    (A) Change in the concentration of the reactant (B) Change of temperature
    (C) Change in the concentration of the product (D) None of the above

    7. For a reaction A + B → Product, it was found that rate of reaction increases four times if concentration of ‘A’ is
    doubled, but the rate of reaction remains unaffected, if concentration of ‘B’ is doubled. Hence, the rate law for the
    reaction is:
    (A) Rate = k[A][B] (B) Rate = k[A]2
    2 1
    (C) Rate = k[A] [B] (D) Rate = k[A]2[B]2
    8. In a first order reaction the concentration of reactant decreases from 800 ml/dm3 to 50 mol/dm3 in 2 × 102 sec. The
    rate constant of reaction in sec–1 is:
    (A) 2 × 104 (B) 3.45 × 10–5
    –2
    (C) 1.386 × 10 (D) 1.386× 10–4

    9. For a reaction A → B, the rate of reaction quadrupled when the concentration of A is doubled. The rate expression
    of the reaction is 𝑟 = 𝐾(𝐴)𝑛 , when the value of 𝑛 is
    (A) 1 (B) 0
    (C) 3 (D) 2

    Note - If you have any query/issue mail at [email protected]& whatsapp on these numbers from 1pm to 7pm- 9205494559/ 7757879130.
    𝐾
    10. For the following reaction scheme (elementry), the rate constant has units: A + B → C:
    (A) sec–1 mole (B) sec–1
    –1 –1
    (C) sec litre mole (D) sec

    Note - If you have any query/issue mail at [email protected]& whatsapp on these numbers from 1pm to 7pm- 9205494559/ 7757879130.
    ANSWER KEY
    1. (D)
    2. (A)
    3. (B)
    4. (C)
    5. (B)
    6. (B)
    7. (B)
    8. (C)
    9. (D)
    10. (C)

    Note - If you have any query/issue mail at [email protected]& whatsapp on these numbers from 1pm to 7pm- 9205494559/ 7757879130.

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