H S (H S) : Ydrogen Ulfide

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HYDROGEN SULFIDE (H2S)

FAST FACTS

Hydrogen Sulfide
Hydrogen sulfide (H2S) is a colorless, flammable and extremely hazardous gas
with a distinctive “rotten egg” smell at low concentrations. It occurs naturally
in crude oil and natural gas, and can be produced by the breakdown of
organic matter and human/animal waste (e.g., sewage). It is heavier than air
and can collect in low lying and enclosed, poorly ventilated areas, such as
pipeline trenches, valve boxes, sumps, sewers, excavations and low areas
around rig platforms.

Detection by Smell
• At low concentrations, H2S can be detected by its “rotten egg” smell.
• Continuous low-level exposure and high concentrations of H2S rapidly
deaden the ability to smell the gas.
• DO NOT rely on a sense of smell to detect the presence of H2S or to warn
of hazardous concentrations. Odor is not a reliable warning.

Health Effects
Health effects vary with how long and at what concentration (measured in
parts per million [ppm]) a person has been exposed:
• For exposure to <10 ppm — Irritation of eyes, nose, throat or respiratory
system; these effects can be delayed. The maximum acceptable exposure
limit for an eight-hour day during a 40-hour work week is 10 ppm.
• For exposure from 10 to 100 ppm — Severe eye and respiratory effects,
headache, dizziness, nausea, coughing, vomiting and difficulty breathing.
A concentration of 100 ppm is considered immediately dangerous to life
or health (IDLH).
• For exposure to >100 ppm — Shock, convulsions, inability to breathe,
coma, death; the effects can be extremely rapid (e.g., within a few
breaths).

Before Entering Areas Possibly Containing Hydrogen Sulfide


The only reliable way to detect the presence of H2S is to measure its
concentration using either fixed or portable calibrated detectors:
• Fixed detection systems are installed in all areas where H2S may be
present. When levels exceed preset limits, an alarm sounds in the control
room and locally in the vicinity of the detector.
• Gas testing using portable monitoring equipment (e.g., TMX412 or MX4
gas monitors) by a certified gas tester is necessary where H2S or
hydrocarbons may be present, in all confined space entries and for work
in low lying areas.
• In addition to personal protective equipment (PPE) recommended in
Chemical Hazard Bulletin (CHB) #155, appropriate respiratory protection
(self-contained breathing apparatus [SCBA] or supplied-air breathing
apparatus [SABA]) and rescue and communication equipment are
necessary.
• These actions are required as per company applicable standards:
 Low concentrations (<10 ppm) — It is safe to work but gas tests must
be conducted periodically because conditions may change.
 Moderate concentrations (10 to 100 ppm) — SCBA or SABA must be
worn and the superintendent must countersign the work permit.
 High concentrations (>100 ppm) — No work or entry is permitted.

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