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    BT tuần 2

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    Đặng Nhung
    The document describes a study that synthesized Bi2O3@NaBi(MoO4)2 hybrid composite materials using a hydrothermal method. The materials were characterized using powder X-ray diffraction (XRD) and transmission electron microscopy (TEM) to analyze their crystalline structure and composition. The results showed that Bi2O3@NaBi(MoO4)2 with reaction times of 1 hour and 3 hours were formed, with XRD peaks corresponding to the crystal planes of Bi2O3 and NaBi(MoO4)2. Electron diffraction patterns further supported the identification of crystalline phases present in the materials.

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    BT tuần 2

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    Đặng Nhung
    105 views2 pages
    The document describes a study that synthesized Bi2O3@NaBi(MoO4)2 hybrid composite materials using a hydrothermal method. The materials were characterized using powder X-ray diffraction (XRD) and transmission electron microscopy (TEM) to analyze their crystalline structure and composition. The results showed that Bi2O3@NaBi(MoO4)2 with reaction times of 1 hour and 3 hours were formed, with XRD peaks corresponding to the crystal planes of Bi2O3 and NaBi(MoO4)2. Electron diffraction patterns further supported the identification of crystalline phases present in the materials.

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    The document describes a study that synthesized Bi2O3@NaBi(MoO4)2 hybrid composite materials using a hydrothermal method. The materials were characterized using powder X-ray diffraction (XRD) and transmission electron microscopy (TEM) to analyze their crystalline structure and composition. The results showed that Bi2O3@NaBi(MoO4)2 with reaction times of 1 hour and 3 hours were formed, with XRD peaks corresponding to the crystal planes of Bi2O3 and NaBi(MoO4)2. Electron diffraction patterns further supported the identification of crystalline phases present in the materials.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    105 views2 pages

    BT tuần 2

    Uploaded by

    Đặng Nhung
    The document describes a study that synthesized Bi2O3@NaBi(MoO4)2 hybrid composite materials using a hydrothermal method. The materials were characterized using powder X-ray diffraction (XRD) and transmission electron microscopy (TEM) to analyze their crystalline structure and composition. The results showed that Bi2O3@NaBi(MoO4)2 with reaction times of 1 hour and 3 hours were formed, with XRD peaks corresponding to the crystal planes of Bi2O3 and NaBi(MoO4)2. Electron diffraction patterns further supported the identification of crystalline phases present in the materials.

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    NGHIÊN CỨU CÁC ĐẶC TÍNH CẤU TRÚC CỦA VẬT LIỆU LAI

    Bi2O3@NaBi(MoO4)2 TỔNG HỢP BẰNG PHƯƠNG PHÁP THỦY


    NHIỆT

    1. Phương pháp tổng hợp vật liệu


    Synthesis of Bi2O3@NaBi(MoO4)2 hybrid composites (HCs) : A mixture A consisted of 0.15 g of

    poly-(2-ethyl-2-oxazoline) (PEtOx, MW = 50,000) and 0.70 g of polyvinylpyrrolidone (PVP, M W

    = 360,000) in 30 ml of triethylene glycol (TEG) was stirred at 90 oC under Ar gas in a three-neck

    round-bottom flask until becoming a homogenous solution. At the same time, the compounds of

    4 mmol of Na2MoO4.2H2O in 30 ml TEG adding 10 ml of 2 M NaOH, and 54 mmol NaBH 4 in

    40 ml TEG were prepared in two separately beakers named B and C, respectively. The solution

    B was added quickly into A once they all obtained the homogenous state. After the mixture was

    uniform completely, the solution C was dropped slowly to it using a glass pressure-equalizing

    funnel. A large amount of gas will be generated during this chemical reaction, which was kept

    for 2 h since the finished drop process and cooled down to room temperature (RT)

    spontaneously. A white precipitate of bipyramid Na2MoO4 was collected by centrifugation at

    9,000 rpm for 10 min and washed with ethanol alternatively several times. The products were

    gathered and dispersed again in 70 ml of TEG by ultrasound (solution D), which later was heated

    to 180 oC in a three-neck round-bottom flask under constant magnetic stirring and Ar gas.

    Meanwhile, a ready mixture called E of 4 mmol of Bi(NO3)3.5H2O in 30 mL TEG was

    homogeneously prepared. We added E drop by drop using a glass pressure-equalizing funnel to

    the solution D, while the temperature was maintained as a constant at 180 °C during reaction for

    different reaction times (1 h and 3 h). The examined samples of Bi 2O3@NaBi(MoO4)2 HCs were

    cooling to RT before collected by centrifugation for 10 min at 9,000 rpm, and washing with a
    mixture of deionized water and ethanol (1:1 in volume) thrice. Next, the powder substances were

    collected and dried at 70 °C in a vacuum oven for 4 h, followed by annealing for 12 h under Ar

    gas at 200 °C. These powders, named as Bi2O3@NaBi(MoO4)2-1h and Bi2O3@NaBi(MoO4)2-3h,

    were used for materials characterization and electrochemical measurements.

    (Kèm theo sơ đồ khối mô tả các bước thí nghiệm)

    2. Phương pháp xác định các đặc tính cấu trúc vật liệu

    Materials characterization: The crystalline phase and component of the powder samples were

    determined by powder X-ray diffraction (XRD, Bruker-AXS-D8). The electron diffraction was

    investigated by transmission electron microscopy (TEM, Talos-F200X).

    3. Kết quả và bàn luận

    - Giải thích về cách hình thành vật liệu, viết phương trình phản ứng liên quan.

    - Vẽ phổ XRD và thảo luận về các peak trong phổ XRD (kèm chỉ số hkl, và ký hiệu của

    từng chất chuẩn).

    - Xác định các vòng nhiễu xạ trong phổ electron diffraction tương ứng với kích thước d

    của mặt (hkl) nào.

    - Dựa vào phổ XRD: đánh giá sơ về khả năng tồn tại dạng amorphous hay crystalline hay

    là hỗn hợp của cả amorphous và crystalline; tính d ứng với các peaks, tính kích thước hạt;

    tính lattice strain; tính hằng số mạng a,b,c của Bi2O3 và NaBi(MoO4)2 .

    - Tham khảo các bài báo liên quan để biết cách giải thích các peaks trong phổ XRD.

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