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Safety data sheet

according to 1907/2006/EC, as ammended by Regulation (EU) no.
2015/830
Printing date 04.12.2020 Version: 1.1 Revision: 04.12.2020

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: SICCATIVE HARLEM (DARK) 085
· Article number: 24285085
· UFI: YE20-X0HN-U00Y-669M
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use: Siccative for artists' oilcolour
· 1.3 Manufacturer/Supplier:
Royal Talens
P.O.Box 4
NL-7300 AA Apeldoorn Tel. +31 (0)55 5274700
· Further information obtainable from:
Regulatory Affairs
[email protected]
· 1.4 Emergency telephone number:
Great Britain: National Poisons Information Service (Birmingham) tel. (44) (0) 1215074123
Ireland: National Poisons Information Centre (Dublin) tel. 35 3 18379966

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Flam. Liq. 3 H226 Flammable liquid and vapour.

GHS07

STOT SE 3 H336 May cause drowsiness or dizziness.

Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS02 GHS07

· Signal word Warning

· Hazard-determining components of labelling:
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, as ammended by Regulation (EU) no.
2015/830
Printing date 04.12.2020 Version: 1.1 Revision: 04.12.2020

(Contd. of page 1)
· Hazard statements
H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P271 Use only outdoors or in a well-ventilated area.
P501 Dispose of contents/container to hazardous waste collection point.
· Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with non-hazardous additions.
· Dangerous components:
EC/List number: 919-857-5 Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% 30-50%
Reg.nr.: 01-2119463258-33 aromatics
Flam. Liq. 3, H226; Asp. Tox. 1, H304; STOT SE 3, H336
CAS: 64742-95-6 Hydrocarbons, C9, aromatics 5-10%
EC/List number: 918-668-5 Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2,
Reg.nr.: 01-2119455851-35 H411; STOT SE 3, H335-H336
EINECS: 258-901-1 Calcium isononanoate 1-2.5%
Acute Tox. 4, H302; Eye Irrit. 2, H319
CAS: 106705-37-7 Strontium neodecanoate 1-2.5%
Acute Tox. 4, H302
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed May cause drowsiness or dizziness.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water spray
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases/vapours is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.
GB
(Contd. on page 3)

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Safety data sheet
according to 1907/2006/EC, as ammended by Regulation (EU) no.
2015/830
Printing date 04.12.2020 Version: 1.1 Revision: 04.12.2020

(Contd. of page 2)

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Keep away from ignition sources.
· 6.2 Environmental precautions: Do not allow product to reach sewage system or any water course.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Protect from heat and direct sunlight.
· Storage class: -
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· DNELs
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics
Oral DNEL,long term (chronic) - systemic effects 125 mg/kg bw/day (Consumer)
Dermal DNEL,long term (chronic) - systemic effects 125 mg/kg bw/day (Consumer)
208 mg/kg bw/day (Employee)
Inhalative DNEL,long term (chronic) - systemic effects 185 mg/m3 (Consumer)
871 mg/m3 (Employee)
64742-95-6 Hydrocarbons, C9, aromatics
Oral DNEL,long term (chronic) - systemic effects 11 mg/kg bw/day (Consumer)
Dermal DNEL,long term (chronic) - systemic effects 11 mg/kg bw/day (Consumer)
25 mg/kg bw/day (Employee)
Inhalative DNEL,long term (chronic) - systemic effects 32 mg/m3 (Consumer)
150 mg/m3 (Employee)
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, as ammended by Regulation (EU) no.
2015/830
Printing date 04.12.2020 Version: 1.1 Revision: 04.12.2020

(Contd. of page 3)
· Respiratory protection: Not required.
· Protection of hands:

If prolonged or repeated contact is likely, chemicalresistant gloves are recommended.

· Material of gloves Nitrile rubber, NBR

· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Safety glasses if risk of splashes.

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· pH-value: Not applicable.
· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: 154-193 °C
· Flash point: 41 °C
· Flammability (solid, gas): Not applicable.
· Decomposition temperature: Not determined.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
· Explosion limits:
Lower: 0.7 Vol %
Upper: 6 Vol %
· Oxidising properties No further relevant information available.
· Vapour pressure at 20 °C: 2 hPa
· Density at 20 °C: 0.91 g/cm³
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 40 °C: >20.5 mm²/s
· 9.2 Other information No further relevant information available.
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Safety data sheet
according to 1907/2006/EC, as ammended by Regulation (EU) no.
2015/830
Printing date 04.12.2020 Version: 1.1 Revision: 04.12.2020

(Contd. of page 4)

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability Stable under recommended storage and handling conditions (see section 7).
· 10.3 Possibility of hazardous reactions
Dangerous reactions are not expected if the product is handled according to its intended use.
· 10.4 Conditions to avoid Keep away from sources of ignition - No smoking.
· 10.5 Incompatible materials: Strong oxidising agents.
· 10.6 Hazardous decomposition products: No decomposition if used according to specifications.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics
Oral LD50 >5,000 mg/kg (rat)
Dermal LD50 >5,000 mg/kg (rabbit)
Inhalative LC50/4 h >5,000 mg/l (rat)
64742-95-6 Hydrocarbons, C9, aromatics
Oral LD50 2,000-5,000 mg/kg (rat)
Dermal LD50 >2,000 mg/kg (rabbit)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Additional toxicological information:
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
64742-95-6 Hydrocarbons, C9, aromatics
EC50, acute 1-10 mg/l (algae)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes: Harmful to aquatic organisms
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
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Safety data sheet
according to 1907/2006/EC, as ammended by Regulation (EU) no.
2015/830
Printing date 04.12.2020 Version: 1.1 Revision: 04.12.2020

(Contd. of page 5)

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN1263
· 14.2 UN proper shipping name
· ADR 1263 PAINT RELATED MATERIAL
· IMDG, IATA PAINT RELATED MATERIAL
· 14.3 Transport hazard class(es)
· ADR, IMDG, IATA

· Class 3 Flammable liquids.

· Label 3
· 14.4 Packing group None.
· ADR, IMDG, IATA III
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Flammable liquids.
· Hazard identification number (Kemler code): 30
· EMS Number: F-E,S-E
· Stowage Category A
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 3
· Tunnel restriction code D/E
· IMDG
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· UN "Model Regulation": UN 1263 PAINT RELATED MATERIAL, 3, III
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(Contd. on page 7)

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Safety data sheet
according to 1907/2006/EC, as ammended by Regulation (EU) no.
2015/830
Printing date 04.12.2020 Version: 1.1 Revision: 04.12.2020

(Contd. of page 6)

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 5,000 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50,000 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and
electronic equipment – Annex II
None of the ingredients is listed.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids – Category 3
Acute Tox. 4: Acute toxicity - oral – Category 4
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
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