Safety Data Sheet according to Regulation (EC)

No. 1907/2006 (REACH)

Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

! SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Name of product pH-Minus / pH-Senker
Rec Nr : 900105
UFI : 41UD-YKT2-R20K-Q9Q2
Name of substance sodium hydrogensulphate
Index No 016-046-00-X
EC No 231-665-7
REACH registration number 01-2119552465-36-XXXX
CAS No 7681-38-1

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended intended purpose(s)
pH regulator for swimming pool water
1.3. Details of the supplier of the safety data sheet
Manufacturer/distributor BAYROL Deutschland GmbH
Robert-Koch-Str. 4, D-82152 Planegg
Phone +49 (0) 89 85701-0
Advice
E-mail (competent person):
[email protected]
1.4. Emergency telephone number
NCEC, Phone (+44)(0)1865407333

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]
Hazard classes and Hazard Hazard Statements Classification procedure
categories
Eye Dam. 1 H318

Hazard Statements
H318 Causes serious eye damage.

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]

GHS05

Signal word
Danger
Hazard Statements
H318 Causes serious eye damage.

Page 1/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

Precautionary Statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P280 Wear protective gloves/eye protection.
P305 + P351 + IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
P338 easy to do. Continue rinsing.
P308 + P311 IF exposed or concerned: Call a POISON CENTER/doctor.
P501 Dispose of contents/ container to an approved waste disposal plant.

Hazardous ingredients for labelling

sodium hydrogensulphate
2.3. Other hazards
Results of PBT and vPvB assessment
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

SECTION 3: Composition/ information on ingredients

3.1. Substances
CAS No 7681-38-1 sodium hydrogensulphate
EC No 231-665-7
Index No 016-046-00-X
REACH registration number 01-2119552465-36-XXXX
3.2. Mixtures
not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
Remove contaminated soaked clothing immediately and dispose it safely.
Symptoms of poisoning may not occur for hours, therefore medical supervision for at least 48 hours necessary.
Adhere to personal protective measures when giving first aid.
In case of inhalation
Remove the casualty into fresh air and keep him immobile.
In the event of symptoms refer for medical treatment.
In case of skin contact
In case of contact with skin wash off immediately with plenty of water.
Refer for medical treatment.
In case of eye contact
Rinse immediately with plenty of water for at least 15 minutes.
Call for a doctor immediately.
In case of ingestion
Do not induce vomiting.
Call for a doctor immediately.
Rinse out mouth and give plenty of water to drink.

4.2. Most important symptoms and effects, both acute and delayed
Physician's information / possible dangers
risk of strong eye injuries

Page 2/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

4.3. Indication of any immediate medical attention and special treatment needed
Treatment (Advice to doctor)
Treat symptoms.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Product does not burn, fire-extinguishing activities according to surrounding.
Alcohol-resistant foam
Dry fire-extinguishing substance
Carbon dioxide
water mist
Unsuitable extinguishing media
Strong water jet

5.2. Special hazards arising from the substance or mixture

In the event of fire the following can be released:
Sulphur dioxide (SO2)

5.3. Advice for firefighters

Special protective equipment for fire-fighters
Use breathing apparatus with independent air supply.
Wear full protective clothing.
Additional information
Cool endangered containers with water spray jet.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

For non-emergency personnel
Avoid dust formation.
Use personal protective clothing.

6.2. Environmental precautions

Do not discharge into the drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up

Flush away residues with water.
Use chemical neutralizers.
Take up mechanically.

6.4. Reference to other sections

Safe handling: see section 7
Disposal: see section 13
Personal protection equipment: see section 8
Emergency telephone number: see section 1

Page 3/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling
Avoid the formation and deposition of dust.
General protective measures
Avoid contact with eyes and skin
Hygiene measures
Do not eat or drink when working.
Keep away from food and drink.
Wash hands before breaks and after work.
Advice on protection against fire and explosion
The product is not combustible.
No special measures necessary.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage rooms and vessels
Keep only in original container.
Advice on storage compatibility
Do not store together with animal feedstuffs.
Do not store together with food.
Further information on storage conditions
Storage: cool and dry
Protect from atmospheric moisture and water

Protect from sun.

Information on storage stability
Storage time: 5 years.
Storage group 13

7.3. Specific end use(s)

Recommendation(s) for intended use
See section 1.2

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No information available.
8.2. Exposure controls
Respiratory protection
Particle filter P2
In case of dust formation wear micro dust mask.
Hand protection
Protective gloves
chemical-resistant gloves
Suitable materials (recommended: protection index 6, >480 minutes permeation time according to EN 374)
Nitrile-butadiene rubber (NBR) - 0.4 mm layer thickness
Butyl rubber (butyl) - 0.7mm layer thickness
In view of the many different types, the manufacturers' directions for use must be followed
Eye protection
Safety goggles

Page 4/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Colour Odour
pearl (drop) yellowish odourless
Odour threshold
not determined
Important health, safety and environmental information
Value Temperature at Method Remark
pH value ca. 1 20 °C 50 g/l

Boiling temperature / not determined

boiling range

melting point 315 °C

Flash point not determined

Vapourisation rate not determined

Flammable (solid) not determined

Flammability (gas) not determined

Ignition temperature not determined

Self ignition temperature not determined

Lower explosion limit not determined

Upper explosion limit not determined

Vapour pressure not determined

Relative density not determined

Bulk density ca. 1400

kg/m3

Vapour density not determined

Solubility in water ca. 1080 g/l 25 °C

Solubility/other not determined

Partition coefficient n- not determined

octanol/water (log P O/W)

Decomposition not determined

temperature

Viscosity not determined

Page 5/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

Oxidising properties
No information available.
Explosive properties
No information available.
9.2. Other information
No information available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No information available.
10.2. Chemical stability
Decompostion takes place from temperatures above:
ca. 300 °C

10.3. Possibility of hazardous reactions

Reactions with alkalies.

10.4. Conditions to avoid

No information available.
10.5. Incompatible materials
Substances to avoid
Alkali (lye)

10.6. Hazardous decomposition products

Sulphur dioxide

Thermal decomposition

Remark No decomposition if used as directed.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity/Irritation/Sensitization

Value/Validation Species Method Remark

LD50 acute oral 2140 mg/kg rat

LC50 acute > 2,4 mg/l (4 h) rat

inhalation

Skin irritation low irritant effect - not

necessary to label

Eye irritation risk of strong eye

injuries

Subacute Toxicity - Carcinogenicity

Page 6/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

Value Species Method Validation

Mutagenicity No information available.

Reproduction- No information available.

Toxicity

Carcinogenicity No information available.

Experiences made from practice

After swallowing: burns in mouth, throat, oesophagus and gastrointestinal tract. Risk of perforation in the oesophagus
and stomach.

SECTION 12: Ecological information

12.1. Toxicity
No information available.

12.2. Persistence and degradability

No information available.

12.3. Bioaccumulative potential

No information available.

12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB assessment

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
12.6. Other adverse effects
Behaviour in sewage plant
The product is an acid. Neutralization is normally necessary before a waste water is discharged into sewage treatment
plants.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste code No. Name of waste
16 05 09 discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16 05 08

Recommendations for the product

Remove in accordance with local official regulations.
Dispose of as hazardous waste.
The product should not be allowed to enter drains, water courses or the soil.
Recommendations for packaging
Uncontaminated packaging may be taken for recycling.
Recommended cleansing agent
Water

Page 7/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

SECTION 14: Transport information

ADR/RID IMDG IATA-DGR
14.1. UN number - - -

14.2. UN proper shipping - - -

name

14.3. Transport hazard - - -

class(es)

14.4. Packing group - - -

14.5. Environmental hazards - - -

14.6. Special precautions for user

No information available.
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No information available.

Transport/further information
No dangerous goods as defined by the transport regulations - ADR/RID, IMDG, ICAO/IATA-DGR.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Authorizations

Other regulations (EU)

Regulation (EU) 1272/2008 (CLP), Regulation (EU) 1907/2006 (REACH), DECISION 2000/532/EG (list of wastes)

VOC standard
VOC content 0%

National regulations
Restriction of occupation
Observe employment restrictions for young people.
Observe employment restrictions for mothers-to-be and nursing mothers.
Other regulations, restrictions and prohibition regulations
ZH 1/81 "Data Sheet for hazardous chemical substances"
ZH 1/124 "Plant instructions for working with hazardous substances (A 010)"
ZH 1/132 "Data Sheet: Skin protection (M 042)"
ZH 1/175 "Data Sheet for First Aid due to inluence of hazardous chemical substances"
ZH 1/192 "Data Sheet for eye protection"
ZH 1/129 "Data Sheet: Irritating substances / corrosive substances (M 004)"
Water hazard class 1

15.2. Chemical Safety Assessment

For this substance a chemical safety assessment has not been carried out.

Page 8/9
 Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Revision 13/05/2020 (GB) Version 12.3
pH-Minus / pH-Senker
900105

SECTION 16: Other information

Recommended uses and restrictions
National and local regulations concerning chemicals shall be observed.
Further information
Refer to product information paper.
The information contained herein is based on the state of our knowledge. It characterizes the product with regard to the
appropriate safety precautions. It does not represent a guarantee of the properties of the product.
Indication of changes: "!" = Data changed compared with the previous version. Previous version: 12.2
Sources of key data used
Results of own researches and examinations
Literature informations
Toxicity studies, NIOSH-Tox-Data
National legislation and regulation

Page 9/9