SAFETY DATA SHEET

PPR-290 PART B

Section 1. Product and Company Identification

Product Name: PPR-290 Part B

Supplier: CSNRI | 621 Lockhaven Drive. Houston, TX 77073 | +1 281.590.8491
Emergency Phone Number: 800.424.9300 (CHEMTREC)
+1 703.741.5970 (Outside the US)
Product Description: Hardener for epoxy resin
Product Use: Anticorrosive coating component
Chemical Name or Synonym: N/A

Section 2. Hazards Identification

Classification of the substance or mixture:

Acute toxicity/oral – Category 4
Skin corrosion/irritation – Category 1B
Skin sensitization - Category 1
Eye damage/irritation – Category 1
Acute toxicity/inhalation – Category 4
STOT (RE) – Category 2

Label Elements:

Hazard Statements:
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H332 Harmful if inhaled
H373 May cause damage to organs

Signal Word: Danger

Precautionary Statement:
P264 Wash thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P302+P352 IF ON SKIN: Wash with plenty water.
P333+P313 If skin irritation or rash occurs: Get medical advice
P301+P312 IF SWALLOWED: Call a Poison Center/doctor if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if
present and easy to do. Continue rinsing
P312 Call a POISON CENTER if you feel unwell.

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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PPR-290 PART B

Section 3. Composition/ Information on Ingredients

Chemical Name CAS-No Weight %

Methyleneoxide, polymer with benzenamine, Mixture
12 – 24
hydrogenated
Benzyl Alcohol 100-51-6 5 – 10
Organic acid N/A 1–3
4,4'Methylenebiscylcohexanamine 1761-71-3 1–2

Section 4. First Aid Measures

First Aid Measures for Accidental:

Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately.
Ingestion: Do not induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious
person. If symptoms persist, call a physician.
Inhalation: Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie,
belt or waistband. Get medical attention immediately.
Most important symptoms/effects, acute and delayed: Skin/eye irritation. May cause an allergic skin irritation.
Indication of immediate medical attention and special treatment needed: Treat symptomatically.

Section 5. Fire Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, foam, dry chemical, water fog, limestone powder. Use water
spray to cool fire exposed containers.
Unsuitable Extinguishing Media: Do not use high pressure water jet as this may spread the area of the fire.
Special Protective Equipment and Precautions for Fire-fighters: Use personal protective equipment. Wear
self-contained breathing apparatus for firefighting if necessary, with a full face-piece operated in positive
pressure mode to protect against potential harmful and/or irritating fumes.
Specific Hazards Arising from the Chemical (Under Fire Conditions): Exposure to decomposition products
may be harmful to health; combustion products may include but are not limited to: carbon monoxide, carbon
dioxide, nitrogen oxides, ammonia, nitric acid. The formation of hydrocarbon fragments is possible in the initial
states of fire (especially between 400 0C ad 700 0C); smoke may contain particles of the original material as well.

Section 6. Accidental Release Measures

Personal Precautions, Protective Equipment and Emergency Procedures: Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering. Do not walk through spilled material. Shut off all
ignition sources. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8). Avoid breathing mist, vapors, spray. Avoid contact
with skin, eyes and clothing.
Environmental Precautions: Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas.

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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PPR-290 PART B

Methods and Materials for Containment and Cleaning Up: Halt the flow of material as soon as practical using
barriers. Turn containers leak-side up to stop the escape of liquid. Prevent from spreading or entering into drains,
ditches, waterways by using sand, earth or appropriate barriers. Dispose of in accordance with applicable local
and federal environmental control regulations.

Section 7. Handling and Storage

Precautions for Safe Handling: Put on appropriate personal protective equipment (see Section 8). Eating,
drinking and smoking should be prohibited in areas where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and
protective equipment before entering eating areas. Avoid breathing vapor or mist. Keep in the original container
or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse
empty container.
Conditions for safe storage including any incompatibilities: Store between 5 and 40°C in a dry well
ventilated place away from sources of heat, ignition and direct sunlight. Store away from oxidising agents and
strongly alkaline and acid materials. Store away from heat and open flame.

Section 8. Exposure Controls / Personal Protection

Control Parameters (Exposure Limits): No data available

Appropriate Engineering Controls: Ventilation must be adequate for most operations.

Personal Protective Equipment:
Respiratory Protection: In case of inadequate ventilation wear respiratory protection. Use a NIOSH approved
organic vapor cartridge respirator. Self-contained breathing apparatus should also be available in case of
emergency.
Eye / Face Protection: Wear safety glasses with side shields or chemical splash goggles when exposure is
more likely.
Skin Protection: Wear chemical resistant gloves (nitrile-butyl rubber, neoprene, butyl rubber or natural rubber)
and full body-covering clothing.
Additional protective measures: Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed
out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

Section 9. Physical and Chemical Properties

Physical State: Liquid

Colour: Green
Odour: No data available
Melting Point/ Freezing Point: No data available
Boiling point: No data available
Flammability (solid, gas): No data available
Lower and Upper Explosion limits/
Flammability Limits: No data available
Flash Point: >219 ⁰F Method: IN 51758 (Pensky-Martins Closed Cup)

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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PPR-290 PART B

Auto-ignition Temperature: No data available

Decomposition Temperature: No data available
pH: No data available
Viscosity: 100 – 250 Poise Method: S3900 Part A7
Solubility: Immiscible in water
Evaporation rate (ether=1): No data available
Flammability Limits in Air: No data available
Solubility in other solvents: No data available
Partition coefficient (n-octanol/water): No data available
Vapour Pressure: No data available
Density and/or Relative Density: 1.7Kgs/ Ltr Method: S3900 Part A19
Relative Vapour Density: No data available
Particle Characteristics: No data available
VOC content: Essentially zero under normal conditions

Section 10. Stability and Reactivity

Reactivity: Stable
Chemical Stability: Stable under standard normal conditions.
Possibility of Hazardous reactions: Mixtures with strongly acidic or strongly alkaline materials may produce
an exothermic reaction. Hazardous polymerization will not occur.
Conditions to Avoid: Avoid elevated temperatures and sources of ignition.
Incompatible Materials / Chemicals: Keep uncured material away from strong acids, strong bases, oxidizing
agents. Reacts with epoxy.
Hazardous Decomposition Products: In a fire, hazardous decomposition products such as smoke, acrolein,
carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced.

Section 11. Toxicological Information

Information in the likely route of exposure:

Potential Acute Health Effects:
Based on the properties of the epoxy constituents and considering toxicological data on similar
preparations:
May be a skin sensitizer and an irritant.
It contains low molecular weight epoxy constituents which are irritating to eyes, mucous membrane and
skin.
Repeated skin contact may lead to irritation and to sensitization, possibly with cross-sensitisation to other
epoxies. Skin contact with the preparation and exposure to mist and vapour should be avoided.

Symptoms related to the physical, chemical and toxicological characteristics:

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PPR-290 PART B

Mutagenicity: No information available.

Carcinogenicity: No information available.
Reproductive Toxicity: No information available.
Tetratogenicity: No information available.
Specific Target Organ Toxicity - single exposure (STOT-se): No data available
Specific Target Organ Toxicity - repeated exposure (STOT-re): No data available
Over-exposure signs / symptoms: Repeated or prolonged exposure may cause an allergic skin
reaction; once sensitized, a severe allergic reaction may occur.

Delayed and immediate effects and also chronic effects from short- and long-term exposure:
Short term exposure: No specific data.
Long term exposure: No specific data

Numerical measures of toxicity:

Acute toxicity:
Acute Oral Toxicity: LD50 (rat): >5,000mg/Kg.
Acute Dermal Toxicity: LD50 (rabbit): 20,000mg/Kg.

Section 12. Ecological Information

Ecotoxicity Effects:
Aquatic ecotoxicity: No information available
Persistence and degradability: No information available.
Bioaccumulative potential: No information available.
Mobility in soil: No information available.
Other adverse effects: No information available.

Section 13. Disposal Considerations

Waste treatment methods: Do not dump to ground, sewers or watercourses. Dispose of at a licensed waste
disposal facility utilizing methods that are in compliance with all applicable federal, state and local laws
regulations. Waste characterization and compliance with applicable laws are the responsibility solely of the waste
generator.
Uncleaned packaging: Empty containers should be taken to an approved waste handling site for recycling or
disposal.

Section 14. Transport Information

DOT:
Proper Shipping Name: Amines, liquid, corrosive n.o.s (cycloaliphatic amine)
UN number: UN2735
Hazard Class: 8
Packing Group: PG III
ERG No 153
IMDG:
Proper Shipping Name: Amines, liquid, corrosive n.o.s (cycloaliphatic amine)
UN number: UN2735

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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PPR-290 PART B

Hazard Class: 8
Packing Group: PG III
EmS No.: F-A, S-B

IATA:
Proper Shipping Name: Amines, liquid, corrosive n.o.s (cycloaliphatic amine)
UN number: UN2735
Hazard Class: 8
Packing Group: PG III
EmS No.: F-A, S-B

Section 15. Regulatory Information

SARA Title III section 311/312 (40CFR370): Acute health hazard

SARA Title III section 313 (40CFR372): No reportable components
CERCLA status (40CFR302): No reportable quantity components
TSCA inventory status: Reported/included
Canadian DSL Status: Reported/included
REACH Annex XIV (SVHC): No listed components
REACH Annex XIVII: No listed components
REACH status (EC 1907/2006): This material has been registered, pre-existed or is otherwise exempted from
registration under the Registration, Evaluation and Authorisation of Chemical Substances.
Chemical safety assessment: Not available

Section 16. Other Information

Key Legend Information:

N/A – Not Applicable
OSHA – Occupational Safety and Health Administration
NIOSH – National Institute for Occupational Safety and Health

The information contained herein is based on the data available to us and is believed to be accurate. The data is offered in good
faith as typical values and not as product specification. The information in this data sheet was compiled from information
supplied by the vendors of the components of this compound. CSNRI makes no warranty either expressed or implied regarding
the accuracy of these data or the results to be obtained from the use thereof. The recommended industrial hygiene and safe
handling procedures are believed to be genuinely applicable. However, each user should review these recommendations in the
specific context of the intended use and determine whether they are appropriate. CSNRI assumes no responsibility for injury
from the use of the product described herein. The information is intended only to assist in the safe handling of this material.
CSNRI DISCLAIMS ALL EXPRESS AND IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE, OR FREEDOM FROM PATENT INFRINGEMENT. CSNRI WILL NOT BE LIABLE FOR ANY
SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES.

Date of issue: 05.07.21 Revision date: 09.15.22 Supersedes: 06.17.22 Version: 3

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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