Chemistry Class 10 Chapter 10
Chemistry Class 10 Chapter 10
Chemistry Class 10 Chapter 10
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UNIT 10
ACIDS, BASES AND SALTS
SHORT QUESTIONS:
Q1. When a clear liquid is placed in a beaker. How can you identify whether it as an acid, base or
neutral?
Ans: Different methods is used to determine the whether the given solution/ liquid is acidic, basic or
neutral.
Litmus paper:
One of them is litmus paper test. In this method litmus paper is dipped in a beaker. If it turns the blue
litmus paper to red then the given liquid will be acidic. If it turns red litmus paper then the given liquid
will be basic. If the litmus paper remains unchanged it will be neutral liquid.
pH scale:
We can also use pH scale to measure the acidity or basicity of a solution. pH scale is a number from 0 to
14. From 0 to 7 are acids. From 7 to 14 are bases while if a liquid has a pH of 7. It will be neutral
Q2.justify H+ ion as a Lewis acid?
Ans: H+ ion as a Lewis acid:
According to Lewis concept a positively charged ions that can accept an electron pair can act as Lewis
acid.
As H+ is positively charged ion and it has tendency to accept lone pair of electrons so it acts as a Lewis
acid.
H+ + :NH3 ⟶ NH4+
(Acid) (Base) (Ammonium ion)
Q3. Distinguish strong acids from weak acids? Give two example of each.
Strong acid:
Those acids which ionizes completely in aqueous solutions and give higher concentration of H+ ions are
called strong acids”. A strong acid is strong electrolyte.
HCI, H2SO4 and HNO3 are the examples of strong acids because they completely ionize in water.
HCI (aq)⟶ H+ + CI-
H2SO4 (aq)⟶ H+ + SO4-
HNO3 (aq)⟶ H+ + NO3-
Weak acids:
“Those acids which do not completely ionize in aqueous solutions and give lower concentration of H+
ions are called weak acids”. A weak acid is weak electrolyte.
Examples:
CH3COOH (aq) ⇌ H++ CH3COO-
Acetic acid (CH3COOH) is a weak acid because when it is added into water, very few molecules of
CH3COOH are dissociated. Some other weak acids are H2S, H2CO3, H2SO3 and HNO2 etc.
Q4. Compare the physical properties of acid and bases.
Ans:
Acids Bases
iv. Acids solution have PH values less iv. Basics solution have PH values
than 7. greater than 7.
Q5 A carbonated drink has [H+] = 3.2 × 10-3 M, classify the drink as neutral acidic or basic with
reason.
Ans: Solution:
Data: hydrogen ion concentration = [H+] = 3.2 × 10-M
Determination of PH
PH = -log [H+]
Putting the value of [H+] we get:
PH = - log [3.2x10-3]
=PH=-(log3.2+log10-3) ∵ log mn = logm + logn
=PH=-[log3.2-log10-]3
=PH= - (0.5051) –(-3) log 10 ∵ logmn = n log m
=PH = - 0.5051 + 3log10
=PH= -.0.5051 +3 (1) ∵ log10=1
=PH= 0.5051 +3
=PH= 2.49
As the pH is less than 7 so the carbonated drink is acidic solution.
OR
We can also solve this problem by comparing the given [H] + of the solution with that of neutral water.
As we know that [H]+ = [OH]- = 1×10-7
If [H ]+ ˃ 1×10-7 the solution will be acidic.
If [OH] - ˃ 1×10-7 the solution will be basic.
As in the given solution [H] += 3.2×10-3 M ˃ 1×10-7 the solution is acidic.
Q6. Write the chemical name of an acid present in the following.
Ans: (a). Apple juice: Malic acid
(b).Grape: Tartaric acid
(c). Lemon juice: Citric acid
(d). Sour milk: Lactic acid.
Q7.What determine the strength of a base? Give one example of each solution of strongly acidic
and weakly acidic.
Ans: Strong bases:
“Those bases which completely dissociate in aqueous solution and give a higher concentration of OH-
are called strong bases”.
Strong bases completely ionize in water and almost no unionized molecule is left behind.
Examples:
Examples of some of the strong bases are given below:
NaOH (aq)⟶ Na+ OH-
KOH (aq) ⟶ K+ + OH-
LiOH (aq)⟶ Li + OH-
Weak bases:
“Those bases which do not dissociate completely in aqueous solution and give a lower concentration of
OH- are called weak bases”.
Examples:
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Some bases which do not completely ionize in water are given below:
NH4OH (aq)⇌ NH4+ + OH-
Ba(OH)2(aq) ⇌ Ba+2+2OH-
Mg(OH)2(aq)⇌ Mg+2+20H-
Q8. Calculate the pH and pOH of O.5 M solution of HCl.
Calculate the PH and POH of 0.5M HCL solution.
Given:
Molarity of hydrochloric acid (HCI) solution= 0.05M
Required:
To calculate the PH and PH
Solution:
Chemical equation for ionization of hydrochloric acid is:
HCI → H+ + CI-
0.5M 0.05M
5
Hydrogen ion concentration [H+] = 0.5 = = 5x10-1 M
10
Determination of PH
PH = -log [H+]
Putting the value of [H+] we get:
PH = - log [5x10-1]
=PH=-(log5+log10-1) ∵ log mn = logm + logn
=PH=-log5-log10-1
=PH= - (.06989) – (-1) log 10 ∵ logmn = n log m
=PH = - 0.6989+1log10
=PH= -.06989 +1 (1) ∵ log10=1
=PH= -.06989 +1
=PH= 0.301
Determination of POH:
We know that:
PH + POH = 14
POH = 14 - PH
Putting the value of PH we get:
POH = 14-0.3o1
⟹POH = 13.
Result:
PH = 0.301 and POH = 13.69
Q9. Calculate the PH and POH of 0.005M H2SO4 solution.
Given:
Molarity of H2SO solution= 0.005M
Required:
To calculate the PH and PH
Solution:
Chemical equation for ionization of nitric acid is:
H2SO → 2H+ + SO4-2
0.005M 0.005M
5
Hydrogen ion concentration [H+ ]:0.005 = = 5x10-3 M
1000
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Determination of PH
PH = -log [H+]
Putting the value of [H+] we get:
PH = - log [5x10-3]
=PH=-(log5+log10-3) ∵ log mn = logm + logn
=PH=-log5-log10-3
=PH= - (.06989) – (-3) log 10 ∵ logmn = n log m
=PH = - 0.6989+3og10
=PH= -.06989 +3 (1) ∵ log10=1
=PH= -.06989 +3
=PH= 2.301
Determination of POH:
We know that:
PH + POH = 14
POH = 14 - PH
Putting the value of PH we get:
POH = 14- 2.301
⟹POH = 11.699
Result:
PH = 2.301 and POH = 11.699
10. Calculate the PH of 0.2M NaOH solution?
Given:
Concentration of NaOH solution = 0.2M
Required:
POH =?
Solution:
Chemical equation for ionization of sodium hydroxide is:
NaOH → Na+ + OH-
0.2M 0.2M
1
Hydroxide ion concentration [OH-]: 0.2M = = 10-1M
10
Determination of POH
POH = -log [OH-]
Putting the value of [OH-] we got:
POH = - log [2x10-1]
POH =-(log2+log10-1) ∵ log mn = logm + logn
POH =-log5-log10-3
POH = - (0.301) –(-1) log 10 ∵ logmn = n log m
POH = - 0.301+ 1 log10
POH = -.0.301+1 (1) ∵ log10=1
POH = 0.699
Determination of PH:
We know that:
PH + POH = 14
PH = 14 – POH
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LONG QUESTIONS:
Q1, (a). What is salt?
Salt:
“The substance obtained due to neutralization reaction of an acid base reaction is called salt”.
Composition of salt:
A salt consists of positive ions combined with negative ions. Positive ions come from a base while
negative ions come from an acid i.e. In NaCI Na+ is from NaOH while CI- is from HCI.
Examples of some salts:
Examples of salts are given below:
ii. Silver bromide (AgBr)
iii. Potassium sulphate (K2SO4)
iv. Ferric phosphate (FePO4).
Q1. (b). write down the different types of salts with example?
Ans: Types of salts:
There are three types of salts i.e. neutral salt, acidic salts and basic salts their detail is given below:
i. Neutral salts:
“The salts formed when hydrogen atom of an acid is completely replaced by a metal ion or group of
atoms behaving like metal ion are called normal salts”.
Neutral salts are formed when a strong acid react with strong base.
Examples:
NaOH + HCI →NaCI + H2O
Base Acid Normal Salt
Some other examples of normal salts are given below:
i. Potassium sulphate (K2SO4)
ii. Sodium phosphate (Na3PO4)
iii. Ammonium sulphate [(NH4)2SO4]
iv. Sodium carbonate (Na2CO3)
ii. Acidic salts:
“The salts formed when hydrogen atom of a polyprotic acid is partially replaced by a metal ion or group
of atoms behaving like metal ion are called acidic salts”.
Examples:
H2SO4 + KOH →KHSO4 + H2O
These acids can further react with bases forming neutral salt
KHSO4 + KOH →K2SO4 + H2O
Some other examples of acidic salts are given below:
i. Ammonium bi phosphate [NH4) H2PO4]
ii. Potassium bicarbonate (KHCO3)
ii. Sodium bicarbonate [(NaHCO3] etc.
iii. Basic salts:
“The salts formed when hydroxide ions (OH-) of a base are partially neutralized by an acids are called
basic salts”.
Basic salts are formed by poly acid bases only e.g.
Examples:
Pb(OH)2, Mg(OH)2, AI(OH)3 etc.
Pb(OH)2 + HCI →Pb(OH)CI + H2O.
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Q2. (a). Define the auto-ionization of water. How can you find the pH of Water?
Ans: Auto-ionization of water:
The reaction in which two water molecules produce ions is called as the self-ionization or auto-
ionization of water.
Explanation:
In order to understand the concept of self-ionization or auto ionization of water, we take one molecule of
water and its dissociation at 250C, as
H2O(l) →H+(aq) + OH-(aq)
Equilibrium constant expression for this reaction is:
�𝐻𝐻 + ] [𝑂𝑂𝑂𝑂 − ]�
Kc= [𝐻𝐻2 𝑂𝑂]
As concentration of H2O remains constant and the above equation can be written as:
Kc [H2O] = [H+] [OH-]
Kw = [H+] [OH-]
where Kw= Kc [H2O]
Dissociation constant of water (Kw):
Kw is called dissociation constant or ionization constant of water. It is defined as “ the product of molar
concentration of H+(H3O+) and OH- ions is called dissociation constant of water”. The value of Kw of
water at 250C is 1.0x10-14 i.e.
Kw = [H+] [OH-] =1x10-14 mol/dm3 of water at 250C
As one molecule of water produces one H+ and oneOH- ion on dissociation.
Therefore, we can say that,
[H+] [OH-] = 1x10-14
[H+] = [OH-]
Or [H+] [H+] = 1x10-14
(H+)2 = 1x10-14
(H+)2 = 1x10-14
Therefore
(H+)= 1x10-7
And [OH-] = 1.0× 10-7
In water at 250C, (H+)= 1x10-7Mand [OH-] = 1.0× 10-7M
Kw = [H+] [OH-]
Kw = 1x10-7M × 1x10-7M
Kw = 1x10-14 M2
pH Definition:
PH can also be defined as:
“The negative logarithm of molar concentration of H+ ions is called PH”.
PH = -log [H+]
PH of Water:
According to this scale, pH of water is calculated as,
pH = -log [H+]
putting values of [H+],
pH = -log[1.0× 10-7]
pH = - (-7.0) log10 log10= 1
pH = 7.0
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Q.2(b). Why some acids are called monoprotic, diprotic and polyprotic acids. Explain your answer
with suitable examples.
Ans: Acids can be classified in term of number of protons that can be given by per molecule of an acid
when added to water. Acids are classified as,
i. Mono-protic acids
ii. Poly-protic acids
Monoprotic or monobasic acids:
“Those acids which give one proton per molecule are called monoprotic acids or monobasic acids”.
Examples:
HCI, HNO3, CH3COOH, HBr, HCN etc are some of the examples of monoprotic acids because they give
only one portion per molecule.
HCI (aq)⟶ H+ + CI-
HNO3 (aq) ⟶ H+ + NO-
CH3COOH (aq)⟶ H++CH3COO-
HBr (aq)⟶ H++ Br-
HCN (aq)⟶ H+ + CN-
Polyprotic acids:
“Those acids which give more than one proton per molecule are called polyprotic acids or polybasic
acids”.
These are further divided into the following subgroups:
i. Diprotic acids:
“Those acids which give two protons per molecule are called diprotic acids or dibasic acids”.
Examples:
H2SO4H2CO3 etc. are the examples of diprotic acids because they give two protons per molecule.
H2SO4 (aq)⟶ 2H+ + SO-2
H2CO3 (aq) ⟶ 2H+ + CO3-2
ii. Triprotic acids:
“Those acids that give three protons per molecule are called Triprotic acids or tribasic acids”.
Example:
Phosphoric acid is an example of triprotic acid as clear from the following chemical equation:
H3PO4(aq)⟶3H+ + PO4-2
Q3. (a). Discuss the concept of lewis acids and bases with examples.
Ans: The Lewis concept:
Introduction:
G.N Lewis presented his own concept of acids and bases in 1923.
Definitions of acids and bases:
Acids:
According to this concept an acid is a species that can accept an election pair.
Base: Base is a species which can donate electron pair.
An acid is electrophile (electron loving) while a base is a nucleophile (nucleus loving).
Species which acts as Lewis acids:
Those compound in which central atom has less than eight electrons in valance shell or positively
charged ions that can accept an electron pair act as Lewis acids. e.g. BF3, AICI3,H+ etc.
Species which acts as Lewis Base:
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Those compounds in which central atom has lone pair of electrons in valance shell or negatively charged
ions that can donate an electron pair can act as Lewis bases. act as Lewis bases e.g. NH3, H2O,CN-,CI-
Example:
Q3. (b) Give the bronsted-lowery definition of acids and bases. Write equation that explain the
definition.
Ans: Introduction:
Bronsted and Lowry presented a broader concept about acids and bases in 1923.
Definitions of acids and bases:
According to Bronsted-Lowry concept.
Acids: Acids are defined as the substances which donate or tend to donate protons (H+ ions).
Bases: Bases are defined as the substances which accept or tend to accept protons.
Examples:
i. When ammonia (NH3) is added to water, the following reaction occurs:
+
HCl (aq) + NH3 (aq)⟶ N𝑯𝑯𝟒𝟒(𝒂𝒂𝒂𝒂) + Cl-(aq)
(Acid) (Base)
In the above example the ammonia accepts a proton from HCI, therefore, it acts as a base while HCI
donates a proton and therefore it acts as an acid.
ii.HCl + H2O ⟶ H3O+ + Cl-
Acid Base
In this example water act as a bronsted-lowery base and HCl act as bronsted-lowery acid?
+
iii. H2O (l) + NH3 ⟶ N𝑯𝑯𝟒𝟒(𝒂𝒂𝒂𝒂) + OH
In the above example the ammonia accepts a proton from H2O, therefore, it acts as a base while H2O
donates a proton and therefore it acts as an acid.
Q4. Below are two equations showing how two alkalis react with water.
NaOH (aq) + H2O (i) ⇌ Na+ (aq) + OH-
NH3 (aq) + H2O ⇌NH4+ (aq) + OH-(aq)
A). name both alkalis.
Ans: NaOH = sodium hydroxide
NH3 = ammonia
B. which is classified as weak alkali and why?
NaOH is a strong base while NH3 is weak base.
c. What is the likely pH of each alkali?
PH of NaOH is13 while that of NH3 is 11.6
Q5. Write the balanced neutralization reaction of,
It is also called as baking soda because it is used in baking of cakes and other confectionaries. It is also
as antacids in medicines and in toothpastes.
v. Copper sulphate (CuSO4.5H2O) (Blue vitriol):
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It is used as electrolyte in copper electroplating process. It is also used to kill algae in water reservoirs
and in agriculture spray.
vi. Magnesium sulphate (MgSO47H2O) (Epsom Salt):
It is used as antacid and laxative in medicines. It is also used in dye industries.
vii. Potash alum (K2SO4.AI2 (AO4)3, 24H2O):
It is used for water purification to remove suspended impurities. It is also used in textile industry and
as blood coagulant in small injuries.
viii. Potassium nitrate (KNO3):
It is used as a fertilizer and for the manufacture of flint glass.
ix. Calcium Carbonate (CaCO3):
It is used in the preparation of cement and in ceramics industry.
x. Sodium sulphate:
It is used in the manufacture of paper, detergents and glass etc.