Fiitjee All India Test Series: Concept Recapitulation Test - Iii

FIITJEE
ALL INDIA TEST SERIES

CONCEPT RECAPITULATION TEST – III
JEE (Advanced)-2021
PAPER –1
TEST DATE: 04-07-2021
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. B
Sol. Velocity of point ‘A’ v A  v 2  2R 2  v 2
2R 450
C A
 a
450
a 450 450
R
Normal acceleration of point A,

a A  n   2Rcos 450  Rcos 450  acos 450
2R v2
a A(n)  
2 2R
 radius of curvature of trajectory of point ‘A’ relative to the ground is
2
v 
r A
2

v 2  2 2R
a A(n) v2
2R
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2
AITS-CRT-III (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
2. A
Sol. mg  r  R sin    MgR sin 
mr   M  m  R sin 
mr 1
sin   
M  m  R 2
   300
3. B
Sol. At the resonance source voltage and source current in same phase Hence “B”
4. C
Sol. Angle between normal x-axis and incident ray is
1  3 2  2

P r x
n̂P n̂r
5  
2iˆ  5ˆj  5kˆ . î  10.1.cos 
1
cos      450
2
Applying snell’s Law at P
1 sin   2 sin r
1
3.  2 sin r
2
r  600
The unit vector along the refracted ray
nˆ r  cos riˆ  sin rnˆ P
 ˆj  kˆ 
n̂r  cos600 î  sin 600  
 2 
1ˆ 3
n̂r 
2
i
2 2

ˆj  kˆ 
2iˆ  3ˆj  3kˆ
n̂r 
8
5. B
Sol. Apparent wavelength
1
 ' vT  aT 2
2
Apparent frequency received by the observer
source observer
a S O vo
3
v  v0  v  v0 
f'  
' 1 2
vT  aT
2
 v  v0  2 v  v0  f 2
 
v a
 2  2vf  a 
f 2f
6. D
Sol. Work done is moving a unit positive charge from infinity to a point on the circumference will be
numerically equal to the potential at that point.

P

dr
dA
So we need to calculate potential at any point on the circumference of this charged disc.
Let choose an element of area dA in the form of a ring of radius r and width dr, where dA = 2r dr
r  2R cos   dr  2R sin d
Potential at point P due to the charge on this element is
R
dV    sin d
0
0
R R 0 R
 V   dV    sin d    cos   sin  /2 
 0 /2  0  0
7. AC
Sol. To find F draw the F.B.D of the mass. then apply work energy theorem to get maximum speed.
8. ABCD
Sol. (A) when S1, S2 both are open capacity of the system is C1, Then C1.
4 0  4R  2R 
 4 0 6R 
 4R  2R 
C1 
40  4R  2R 
 40 6R
 4R  2R 
480R
C1 
5
(B) When S1 is closed but S2 is open capacity is C2. Find C2.
C2 
 480R  240R   16 R
0
 240R  240R 
(C) When S2 is closed but S2 is open capacity is C3. Find C3.
C3 
 24 0R  240R   12 R
0
 240R  240R 
(D) when both S1 and S2 are closed. Capacity is C4 is. Then C4 is equal to
C4  240R
4
9. ABCD
Sol. When only S2 is open
2  4 
     20cm
3  120 
When only S1 is open
 4 
2      60 cm
 120 
When all three are closed
4
2     60 cm
120
When only S1 is closed
4
2      60 cm
120
10. ABCD
Sol. Xmax  2.5 mm
2.5  103
nmax   5000
5000  1010
For 3000th order bright fringe, n = 3000
dcos    3000  
3000 3
cos   
5000 5
D 3

2
y D 2 5
900

C
S1 S2 D
8
Solving y    m
3
For 5th bright fringe from ‘C’ n = 4996
5000 cos   4996
sin   0.04
tan   y / D  0.04
y  8  102 m
For 2500th order bright fringe, n = 2500
cos   1/ 2
D 1

2
y D 2 2
4D2  y 2  D2
y  3D
y2 3 m
5
11. ABCD
P  dV  T  2
Sol. C  CY  T 0 V
n  dT   V0 
2
3  nRT   V0  dT T0
 R    2V
2  V.n   2VT0  dV V02
3 RTV02
 R
2 2T0 V 2
3 R 4
 R   R  2R
2 2 2
 T0  2
Tf   2   2V0   4T0
V
 0 
Q  nCT  1 2R  4T0  T0   6RT0
12. ACD
Sol. mA  m  0.3kg
mB  2m  0.6kg
F
N1  2mg  ...(i)
2
F
 2ma ...(ii)
2
F
N2  ...(iii)
2
F
mg   ma ...(iv)
2
F R
450
450 N2
A R
a R2
N1
mg
a
B 450
450
F
2mg
From (ii) and (iv)

mg  3ma  a  g / 3
F 2mg
from (ii),  2ma  2
2 3
 F  2 2N
F
 N2   2N  N2  2N
2
F 2mg 8mg
From(i)N1  2mg   2mg    8N
2 3 3
 N1  8N
6
SECTION – C
13. 00012.50
Sol. Impulse,  Fdt  m 2gh
 iB dt  m 2gh ...(i)
 idt  q ...(ii)
m 2hg 20 2  10  5
q    12.50 Coulomb
B 28
14. 00014.80
dN
Sol.  r  N
dt
N t
dN

N0 r   N
 0 dt
dN
 r  N   r  N0  et
dt
 105   t/20 5000  104 
  104  e   
 20  7.4  14.8 
15. 00002.20
Sol. E  T 4
E T4
 2  22  256  4 4
E1 T1
 T2  4T1
1 0
Also, 1T1   2 T2 gives 2   1000 A
4
hC 12400
KEmax      12.4   ...(i)
2 1000
1 1 3
E2 4  13.6  22   2  2   13.6  4   10.2eV ...(ii)
2 4  16
From (i) and (ii) 12.4    10.2
   2.2 eV
16. 00003.25
1 1
Sol. rAB   dx 
0
 1  2x dx  2
0
0.5
3
rAC   1  2x dx  4 
0
Potential difference between X and Y = 4V = potential difference between A and C when iG  0

28 3
4    r  3.25
r  2 4
7
17. 00012.00
Sol. v 0 cos 30 0  v cos 450
3
 v  v0
2
Now using conservation of energy
1
2
 
m v 2  v 20  mgh
3v 20 v2
 v 02  2gh  0  2gh
2 2
 v 0  4gh  4  10  3.6  12 m / s
18. 00625.00
v t v 66 1
Sol. cos   s  s    0.2
vt v 330 5
S Vs O
d = 200 m
D
 v  f0 25
f   f0    600  625 Hz
 v  v s cos    1  24
 1  
 25 
8
Chemistry PART – II
SECTION – A
19. D
Sol. Fact, on heating with concentrated NaOH solution in an inert atmosphere of CO2, white
phosphorus gives PH3 gas.
20. B
Kt t/10
Sol.   Temperature coefficient 
K0
Kt  t0 
  TC  10 
K0
t
In K t  In K 0   lnTC 
10
On comparing
t t
Now,  lnTC    ln2 
10 10
TC  2
21. B
2
Sol. (A) Be  OH2  2OH  Be  OH4 
pK a1  pK a2 pK a2  pK a3
(B) Isoelectric point can be calculated by using relation PI  and PI 
2 2
(C) Fact
(D) BeF2  2NaF  Na2 BeF4 
22. A
Sol. To stop the unwanted reaction
NH 2
N2Cl
H+
+
N N NH 2
This reaction is suppressed by adding excess of HCl which will convert free aniline to protonated
aniline.
23. A
rx My My 22 1
Sol.     ......... i 
ry Mx Mx 4 2 4
Wy
3
 Given that ........  ii 
Wx 2
Dividing equation (ii) by (i)
Wy Mx 3 4
  
My Wx 2 1
ny 6

nx 1
9
nx 1 x 1
Now   x 
ny 6 xy 6
24. C
3
Sol. Room energy  RT
2
3
  8.314  265 J/mol
2
=3.3 kJ mol1
25. ABC
Sol.
NH 2 N2
HNO2 CHO
N2
OH
O
Flipping Possible H
H
HNO2 Hydride
OH O H shift O H
NH2 N2
O
26. ABC
Sol.
CHCl3 Cl
Cl
C2H5ONa
N Cl HCl
N N
H
H
[CHCl3 + RONa : CCl 2 + R OH + NaCl]

dichloro methylene
27. BC
Sol. SO2 Cl2  2H2 O  2HCl  H2SO 4
x
10
SO2 Cl2  KOH  2KCl K 2 SO 4

x y z
KCl AgNO3  AgCl  KNO3

y white ppt.
K 2SO4  BaCl2  BaSO4  2KCl

z white ppt
28. AC
Sol. (i) To show enantiomers molecule must be chiral with or without chiral centers.
(ii) Selective reduction of double bounds in compounds containing other reducible groups except
   , Aromatic nitro groups and acyl halides, can be achieved by Pd.
29. ABCD
Sol. (a) dE  nCV dT, (b) dH  nCP dT
(c) G  H  TS , H  E  PV
Differentiating we get
dG  d  E  PV   d  TS 
 dE  PdV  VdP  TdS  SdT.......... i 
From 1st law dq = dE + PdV  work of expansion
dq
and dS=  entropy change
T
dq  TdS
Form eq (i) dG  dq  VdP  dq  SdT
dG  VdP  SdT ...........  ii
Equation (ii) at const. pressure
 dG 
   S
 dT p
And at const. Temperature
 dG 
  V
 dP T
30. ABCD
Sol. H2 A  NaOH 
 NaHA  H2 O
Amphiprotic anionic salt
NaHA  NaOH  Na 2 A  H2 O

As from titration curve  V2  volume of strong base required at 1st equivalence point i.e point B.
nd
And V4 = volume of strong base required at 2 equivalence point i.e. point D. Hence at
V 3V2
V1  2 and V3  indicating 1st half and 2nd half equivalence point.
2 2
 Therefore at 1st half equivalence point

NaHA   1, pH  pK
a1
H2 A 
pH = 4
and similarly, at 2nd half equivalence point at C,

Na2 A   1, pH  pK
a
NaHA  2
At point D, only salt Na2A will exist hence pH can be calculated by using salt hydrolysis
phenomena.
11
SECTION – C
31. 00010.50
 
Sol. 3B2H6  6NH3  3 BH2  NH3 2  BH4  = x
 heat
2B3N3H6  12H2
‘y’

Steric factor (f) of BH4   4
2  4  15
a
2
 10.5
32. 00001.26
Sol. For multielectron species
Z2
I.E  I.EH  eff , Li = 1s2 2s1
n2
n  2  for outer electron 
Z 2eff
5.40  13.6 
22
5.40
Zeff  2
13.6
Zeff  1.26
33. 00272.64
Tb K b
Sol. 
Tf K f
RTb2 1000  L fus
 
1000  L vap RTf2
Tb2 L fus
 
Tf2 L vap
2
Tb  373   80
  Tb  373 K
Tf  273 2  540
 Tf  273 K
 Tb  0.1
Tf  0.361
or 273  Tf  0.361
Tf  272.639 K
34. 00003.92
Sol. By Kohlrausch law,
oNH4 OH  NH
o
4
 oOH
12
o o o
NH4 Cl
 NaOH  NaCl
 129.8  217.4  108.9
 238.3 scm2 mol1
C  9.33 scm2 mol1  Given 
C
 % Degree of dissociation =  100
O
9.33
  100
238.3
 3.92%
35. 00027.43
E2 K 2  tert  butyl bromide  OH
Sol. 
E1  E2 K 2  tert  butyl bromide OH  K1  tert  butyl bromide
 
7.1 105  5

7.1 105  5  1.5  105
 0.96
x  96%
x 96
Now 
3.5 3.5
 27.428
36. 00001.26
z1  atomic mass
Sol. Density of Fcc=
NA  V1
z 2  atomic mass
Density of BCC=
NA  V2
dfcc z V
  1 2
dBcc z 2 V1
3
4 3
 
2  3.5 3
 1.259  a
2
And number of unpaired e in NiF6  is zero as it is low spin complex.
Hence y = 0
Therefore n  1.259  0
=1.259
13
Mathematics PART – III
SECTION – A
37. B
Sol. Using LMVT in [1, 2]
f  2   f 1
f ' c    2  f 2  4
2 1
Again using in 2, 4
f  4   f  2
f '     2  f 2  4  f 2  4
42
38. A
Sol. x 2  3x  4  0  x  R,  a  1 x2   a | a  1| 2  x  1  0
2
a  1  0 and  a  | a  1| 2   4  a  1  0  a  
39. B
Sol.  GM  H.M  ac  b
a101  c101
And  2b101  product of roots is  ve.
2
40. C
Sol. a  | b || a  b | a.b  0
 sin 1
 
x  x . x 2  5x  6  cos 1 x  0  sin 1 x  x
 x   0,1
41. D
Sol. An odd function
 point  3, 2  &  5, 4  will also lie on the curve for minimum number of roots f(x) has atleast
three real roots.
42. C
Sol. 
P n, 1  n2 
n  n2  1
dn 
2
1
 lim  n.dn  
n 
2 2
43. BCD
Sol. f(x) has minimum and maximum on  3,4 by IVT.
f "  x   0  f  x  is concave up.
If f(3) = f(4) then Rolle’s theorem  f '  c   0 and c   3,4  .
14
44. AC
x 1 y  4 z  3
Sol. Let line    2a  b  4c  0, 3a  2b  2c  0
a b c
x 1 y  4 z  3
 line is      357  100  256  1  2
10 16 1
   1  point s  9,20,4  or 11, 12,2 
Hence a1  a2  a3  15 or 1.
45. ABD
Sol. No. of function = 81 No. of onto functions = 30
 No. of functions which are not surjective = 45.
46. CD
Sol. f(x) is discontinuous where sin2 x  sin x  1  0
1 5
 sin x 
2
For four points of discontinuity n can be 4 or 5.
47. ABC
sin x
Sol. f  x 
x
48. AD
1
Sol. f '  x   ex   0  f  g  x   x
x
1 1
f '  g  x  .g'  x   1  g'  e   
f ' 1 e  1
f " 1 1 e
g"  e   3
 3
 f " 1  1  e 
SECTION – C
49. 00005.33
Sol. Let f '  x   kx 2  x  2  1  x 2  ,k  0  f '  x   k  x 5  2x 4  x 3  2x 2 
kx3 f  2  8  26 
f  x 
60

10x3  24x 2  15x  40 
f 1

 39 
  5.33
50. 00033.54
 
Sol. Let a  3iˆ  4ˆj  10k, ˆ b  f  x  î  g  x  ˆj  h  x  kˆ
 
a. b  3f  x   4g  x   10 h  x   9  16  100. f 2  g2  h2 cos
 3f  x   4g  x   10 h  x   max
 125. 9  33.54
51. 00008.00
p pq q r
Sol.  injective   and   p,r,q are in G.P
r qr r p
15
Let r = p, q = p 2 solving   2,1

  p, 2p,4p  ,  p,p,p  Here  p,p,p  is not possible.
 p  2p  4p  6  p  2.
52. 00000.00
x 
Sol. Let A = aij  , B =  y  and BT AB  0
33
 z 
  a11x 2  a 22 y 2  a 33 z 2    a12  a 21  xy   a13  a 31  xz   a 23  a 32  yz  0
 if hold for every column rector B
 aii  0 and aij  a ji i  j
 A must be skew symmetric
And C is also skew symmetric
 det  Adj A   det  Adj C   0
53. 00000.25
1
Sol. f ' x  f  x   1  In  x / e   e x f '  x   e x f  x   e x 1/ x  1  In  x / e  
x
 f  x   1  In  x / e   e x  f 1  e    1
1
 Area   x In x dx  1/ 4
0
54. 00032.00
10 10 10 10
Sol.  g  x  dx  8g    
2
  g  x   g    dx    | g  x   g    | dx   | x   | dx
2 2 2
10  10
2
  | x   | dx      n  dn    x    dn     6   16
2 2 
 maximum value is 32.

Fiitjee All India Test Series: Concept Recapitulation Test - Iii

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

Normal acceleration of point A,

From (ii) and (iv)

 iB dt  m 2gh ...(i)

Potential difference between X and Y = 4V = potential difference between A and C when iG  0

[CHCl3 + RONa : CCl 2 + R OH + NaCl]

SO2 Cl2  KOH  2KCl K 2 SO 4

KCl AgNO3  AgCl  KNO3

K 2SO4  BaCl2  BaSO4  2KCl

NaHA  NaOH  Na 2 A  H2 O

 Therefore at 1st half equivalence point

and similarly, at 2nd half equivalence point at C,

Mathematics PART – III

Let r = p, q = p 2 solving   2,1

 maximum value is 32.

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