XI CHEMISTRY - SET - A

Group "A"
Very short answer questions (Attempt any fifteen) [15x2=30]
1. A solution containing 0.7665gm of HCl is mixed with 2.574 gm of decahydrated sodium carbonate crystals. Find the
number of moles of excess reagent left over unreacted.
2. What is molar volume ? Calculate the molecular weight of any gas having volume 5 litres and weight 14.4 gm at NTP
3. Define equivalent weight of an element. A chloride salt of an element X contains 58.68% of chlorine. Find the
equivalent weight of the element X.
4. Why it is difficult for breathing in higher altitudes ?
5. What is meant by aqueous tension ? Why is it substracted from the pressure of a moist gas ?
6. Calculate the oxidation number of Cr in CrO4-- and C in HCN.
7. Natural silicon in silicon containing ores contains 92% Silicon -28, 5% Silicon-29 and 3% Silicon -30. What are the
relative isotopic masses of the Silicon isotopes and what is the relative atomic mass of Silicon ?
8. Define one faraday and Electrochemical Equivalence (ECE)
9. Calculate the no of coulombs required to deposit 40.5g of Al when the electrode reaction is

Al+3 + 3e Al ( At wt of Al = 27)

10. Give two reactions in which ammonia acts as reducing agent.

11. Define allotropy with reference to sulphur. Draw the structure of Rhombic sulphur.
12. How is ozone layer formed ? How is it being depleted ?
13. Why can't be HI prepared by the action of conc H2SO4 on NaI ?
14. Why is H2O a liquid while H2S is a gas ?
15. How many volume of chlorine gas is produced at NTP when 5.5A current is passed through molten NaCl till 5 minutes.
16. What do you mean by the term leaching in metallurgy ?
17. Define the term hydrometallurgy.
18. Ozonolysis of a compound 'A' gives propanone (acetone) and ethanal. Identify compound A and give reactions
involved.
19. Write the isomers of C2H4O2 and give their IUPAC names.
20. Identify the structures A and B in the given reaction:
2 / pd  BaSO4
A alcoholic
  H  C  C  H H
KOH
  B

Group "B"

Short answer questions (Attempt any five) (5x5=25)

21. State the law of multiple proportions. A metal forms two chlorides containing respectively 65.5% and 55.95% chorine.
Show that these results prove the law of multiple proportions.
22. What are the postulates of electronic theory of valency ? Explain with the help of electronic theory of valencty that
'Carbon is a tetravalent element'
23. What are the conclusions of Rutherford's alpha particle scattering experiment ? Write the main drawbacks of this
experiment.
24. State and explain Faraday’s Second law of Electrolysis.
25. State clearly what happen when :
a) Ammonia solution is treated with mercurous nitrate solution
b) Zinc reacts with very dilute nitric acid.
c) Chlorine gas is passed into hot and conc NaOH solution.
d) H2S gas is passed through alkaline solution of zinc chloride
e) Ozone is treated with mercury.
26. How is bromine manufactured from carnallite in pure form ? What happens when bromine reacts with hypo ?
27. Show your familiarity with the following terms with examples
i) Wurtz reaction (ii) Bayer's test (iii) Friedal-crafts alkylation (iv) Polymerization.
Group "C"
Long answer questions (Attempt any two) 2x10=20
28. a) Define oxidation and reduction electronically with suitable examples. Balance the following redox reaction by O.N. or
ion electron method.
HCl +MnO2→MnCl2 + Cl2 + H2O
b) How does diffusion differ from effusion ?
0.16gm of O2 diffuse through a prorous membrane in 100sec. Calculate the time required to diffuse the same amount of
H2 gas through the same porous membrane under similar conditions.
29. Describe with well labeled diagrm how is nitric acid manufactured from Ostwald's process. Write the action of nitric
acid with :
i) Red phosphorous (ii) Calcium carbonate (iii) Hydrogen sulphide (iv) Conc. hydrochloric acid
30. Describe the extraction of sodium by Down's process
What happens when:
a) a piece of sodium is exposed with air.
b) sodium hydroxide is heated with white phosphorous
c) Gypsum is heated progressively
d) Quick lime is heated with ammonium chloride
31. Write note on (any two)
a) Postulates of Kinetic theory of gas
b) Homologous series
c) Homolytic and heterolytic fission

XI CHEMISTRY - SET - B
Group "A"
Very short answer questions (Attempt any fifteen) [15x2=30]
1. What volume of CO2 is produced when 20 gm of 20% pure CaCO3 is completely reacted ?
2. Calculate the mass of :
a) Two atoms of Nitrogen (b) One molecule of hydrogen
3. Define equivalent weight of an element. An oxide of trivalent metal contains 32% of oxygen. Calculate the atomic
weight of the metal.
4. A gas has density 2.41g L -1 at 250 C and 770 mm of Hg. Calculate its molecular mass.
5. What do you mean by 'absolute zero' temperature ? Why is it not attainable ?
6. Find the oxidation numbers of the following underlined elements
i) C6H12O6 (ii) ZnO2- - (iii) Na2SO3 (iv) NH4 +
7. Naturally occurring Boron consists of two isotopes whose isotopic masses are 10.01 amu and 11.01mmu. If the atomic
mass of natural Boron is 10.81 amu, calculate the percentage abundance of the isotopes in the natural Boron.
8. What is octet rule ? Write the Lewis structure of BCl 3
9. What is meant by one Faraday of electricity? Show its value in terms of coulomb.
10. Write down the structure of S8 molecules and Rhombic sulphur.
11. Classify the following oxides with giving reasons ?
i) Al2O3 (ii) NO2
12. Write the names of any two metals which can liberate hydrogen gas from nitric acid.
13. What happens when:
a) a mixture of MnO2 powder, solid NaCl and conc. H2SO4 are heated
b) H2S is passed into aqueous SO2.
14. Distinguish between calcination and roasting
15. What are alkali metals ? Explain why sodium can't be extracted by the electrolysis of aqueous solution of NaCl ?
16. How does carbon dioxide gas react with an ammoniated brine at room temperature ?
17. Define electrophile and nucleophile with suitable example
18. How would you detect unsaturation center in any organic compound
19. Identify A,B and C in the following reaction :
, h
CH 3Cl Na
/     Cl2 
dry ether
 B alc
. KOH

 C
 
20. What happens when :
i) Ethyne is polymerized (ii) Aluminium carbide is treated with cold water
Group "B"
Short Answer questions (Attempt any five) [5x5=25]
21. 160 gm of 75% pure Na2CO3 if treated with 90 gm of HCl to produce NaCl, H2O and CO2
a) Find the limiting reagent and calculate the mole of unreacted reagent left over.
b) What volume of CO2 gas is produced at NTP ?
c) Calculate the mass of NaCl formed.
22. What are the postulates of Bohr's model of atom ?
23. Indicating oxidation half, reduction half, oxidising agent and reducing agent, balance the following redox reaction by
oxidation number or ion electron method.
KMnO4 + H2SO4 + KI K2SO4 + MnSO4 +H2O + I2
24. Write the preparation, properties and uses of Epsom salt
25. State clearly what happens when:
i) Conc. HCl is added to KMnO4
ii) Ammonia solution is treated with Nessler's reagent
iii) Iodine is treated with hypo.
 iv) H2S is passed through acidified CuSO4 solution
v) Chlorine is passed into dry slaked lime at 400C
26. State and explain Faraday’s Second laws of electrolysis.
27. Define isomerism. What are the possible isomers of
a) C3H6O and (b) C2H4O2 ? Write their IUPAC names.
Group "C"
Long answer questions (Attempt any two) [2x10=20]
28. a) State Dalton's Law of partial pressure.
2.2 gm of CO2, 4 gm of O2 and 7 gm of N2 are placed in an evacuated cylinder of 10 litres capacity at 310 K. Find the
partial pressure of each gas and the total pressure exerted by the mixture.
b) State Graham's law of diffusion.
4gm of N2 diffused through a porous membrane in 20 min what volume of CO2 at NTP undergoes diffusion through the
same membrane at the same time under identical conditious ?
29. Describe the principle and draw self explanatory sketch for the manufacture of ammonia by Haber's process. How does
ammonia react with ?
i) Carbon dioxide (ii) Copper sulphute solution (iii) Sodium metal (iv) Chlorine gas in excess
30. How many coulombs are required for the following oxidation?

a) 1mol of H2O to O2 b) 1 mol of FeO to Fe2O3 c) 1 mol of MnO4- to Mn++ d) 3 moles of Cr2O7—to Cr3+ e) 50g of Al
from molten aluminium.
31. Write note on (Any two)
a) Lab preparation of acetylene
b) Markovnikov's rule and peroxide effect
c) Avogadro's hypothesis and its relation with molecular mass of volatile substance
d) Law of reciprocal proportions.

XI CHEMISTRY - SET - C
Group " A "
Attempt anyFifteen questions [15x2=30]
1. How many molecules of H2O and O2 are present in 8.5g of H2O2 ?
2. From 200 mg of CO2, 1021 molecules are removed. How many moles of CO2 are left ?
3. Calculate the volume occupied by
i) 1x1016 molecules of N2 at STP
ii) 16g of O2 at STP
4. Calculate the percentage compositipon of FeSO4. 7H2O (Green vitriol) (Fe=55.8)
5. Define equivalent weight of an element. A divalent metal has atomic weight 24. What is its equivalent weight ?
6. A hydride of nitrogen contains half volume of nitrogen. The vapour density of the hydride is 8.5. Find the molecular
formula of the hydride.
7. Define oxidation number. Find the O.N. of C in HCN
8. Write the formula for substances containing nitrogen in which it shows the oxidation states : +5,+3, O, - 1/3
9. Write the Lewis structure of (i) NH4Cl (ii) SO4 - -
10. Define hydrogen bond. Give an example of intramolecular hydrogen bonding
11. Each carbon-oxygen bond in CO2 is polar but CO2 molecule is non - polar. Give reason
12. Differentiate between ortho and para hydrogen
13. Why do you think depletion of Ozone layer from the atmosphere will be harmful to plant and animal life ?
14. Differentiate between flux and slag
15. Why carbon is generally used in pyrometallurgy ?
16. What is meant by available chlorine of bleaching powder ? How is it obtained ?
17. Define functional group. Write down the functional group of (i) amide (ii) Ester
18. Write the structure of following organic compounds
i) Ethane -1, 2-diol (ii) 4- methyl - 2- pentanone
19. Define carboxylation reaction with an example.
20. What is Grignard's reagent ? How is it prepared ?
Group "B"
Attempt any Five questions [5x5=25]
21. Given the reaction:
Na2CO3 + 2HCl 2NaCl + H2O + CO2. If the reaction is carried out by mixing 2.12 g of Na2CO3 with 1.825g of HCl,
a) Determine the limiting reactant and find the amount of excess reagent left over unreacted.
b) What mass of NaCl is formed ?
c) What volume of CO2 at NTP is produced ?
d) What mass of NaOH is required to absorb the whole CO2 as Carbonate ?
22. 3.6 g of a compound containing carbon, hydrogen and oxygen gave on combustion 5.28 g of CO 2 and 2.16g of H2O.
The relative molecular mass of the compound was found to be 60
a) What are the masses of C,H and O in 3.6g of the compound ?
b) What are the empirical and molecular formulae of the compound ?
23. State Avogadro's Law. Apply the law to deduce the relationship between the molecular mass and the vapour density.
24. Explain with the help of electronic theory of valency that :
a) Carbon is a tetravalent element.
b) Chlorine combines with potassium to give KCl but formation of K2 is unlikely.
c) Ammonium ion contains dative linkage.
d) Helium does not form He2 molecule whilte hydrogen exists as H2.
25. Give the preparation, properties and uses of Epsom salt.
26. What are oxides ? Classify the oxides Na 2O2, CuO, CO and SO2 with reasons
27. Define homologous series. What are the characteristics features of homologous series ?
Group "C"
Attempt any Two questions [2x10=20]
28.a) Define oxidation and reduction with examples interms of electronic concept.
b) Balance the following redox reactions by O.N. or ion-electron method
i) Cl2 + NaOH NaCl + NaClO3 + H2O
ii) MnO-4 + H+ + Fe++  Mn ++ + Fe +++ + H2O
iii) Zn + HNO3  Zn(NO3)2 + N2O + H2O
29. Why is sodium placed in alkali metal group ? What difficulties do arise in extraction of sodium from its ores ? Discuss
how Down's process extract sodium by overcoming all possible difficulties ? What happens when :
a) Washing soda is heated
b) Sodium hydroxide is added to zinc sulphate till saturation
e) Sodium is heated with ammonia.
30. Write note on : (any two) [1+2+4+3]
a) Faraday’s Laws of Electrolysis.
b) Position of hydrogen in periodic table
c) Structural isomerism

XI CHEMISTRY - SET - D
Group A
Attempt any fifteen questions [15x2=30]
1. What is molar volume ? Calculate the molecular weight of any gas having volume 5 litres and weight 14.4 gm at NTP
2. Calculate the mass of :
i) 6x1023 atom of P (P=31)
ii) 0.02 moles of SO2 (S=32,O=16)
3. Define equivalent mass of an element. The oxide of a metal contains 40% by mass of oxygen. Calculate the equivalent
mass of the metal
4. How much gram of sodium is present in 120gm of Na2CO3 ?
5. 0.25 gm of CaCO3 when decomposed thermally gave 0.14 gm of CaO and 56ml of CO2 at NTP. State the low
illustrated by these data
6. Define oxidation and reduction electronically with example
7. Distinguish between oxidation number and valency
8. Calculate the oxidation number of nitrogen in
i) Zn (NO3)2 (ii) N2O4 (iii) N3H (iv) NO2-
9. State the law of multiple proportion.
10. Define one Faraday. What is ECE ?
12. Starting from quick lime, how would you prepare lime water what is meant by milk of lime ?
13. What happens when chlorine gas is passed into a dilute solution of caustic soda
14. What happens when a piece of sodium is exposed to air
15. What happens when ammonium hydroxide is added to a solution of copper sulphate till excess
16. Why carbon monoxide is used a reducing agent in metallurgy but not carbon dioxide
17. How is the moisture present in SO2 gas removed ?
18. What is meant by slag ? Why is it important in metallurgy ?
19. Classify the following oxides with reason Al 2O3 and CO
Group B

Attempt any five questions [5x5=25]

21. Show that oxidation and reduction occur simultaneously in a redox reaction. Give an example to illustrate your answer.
Balance the following redox reactions by ion electron or O N method
a) Br2 + NaOH  NaBr + NaBrO3 + H2O
b) MnO4 - + H++ Fe ++ Mn ++ + Fe+++ + H2O
22. Do the following processes involve oxidation, reduction, both oxidation and reduction or none of these ?
a) 2Hg++ + 2e-  Hg2 ++
b) Cu +  Cu2+ +e-
c) Ag + +Cl-  AgCl
d) NH3 + H+  NH4 +
e) 2Cu +  Cu2+ + Cu4
23. Consider a reaction 4NH3 + 3O2  6H2O + 2N2
a) How many molecules of nitrogen are produced when 0.2 mole of ammonia is completely burnt ?
b) What volume of O2 are required to produce 144 gm of water at STP ?
c) How many molecule of ammonia are used to produce 44.8 litres of nitrogen at STP ?
24. Describe the manufacture of bromine from carnallite.
25. Describe how HI is prepared. Why it cannot be prepared in the same way as HCl ?
26. Describe the steps involved in the manufacture of sodium carbonate by solvary's process.
27. Describe the manufacture of nitric acid by Ostwald's process
Group C

Attempt any two questions [2x10=20]

28. State and illustrate the law of reciprocal proportions. Marsh gas contains 75% carbon 25% hydrogen carbon dioxide
contains 42.86% carbon and 57.14% oxygen. Water contains 11.11% hydrogen and 88.89% oxygen. Show that these
results are in agreement with the law of reciprocal proportions.
29. Write the principle involved along with a self explanatory diagram for the manufacture of sulphuric acid by contact
process. Give two reaction to show concentrated sulpuric acid is
a) dehydrating agent (3+3+2+2)
b) oxidizing agent
30. Write notes on (any two)
a) Bleaching powder
b) Electrolysis and applications of electrolysis.
c) Extraction of sodium by Down's process
d) Oxidising agents and reducing agents.

XI CHEMISTRY - SET - E
Attempt any Fifteen Questions: [2x15 = 30]
1. Which one of the following has greater number of atoms? Show by calculation. 2.3 gm of sodium or 1.3 gm of carbon
2. How much number of H2O molecules is there in 10 litres of water ?
[Density of water = 1gm / cc)
3. Find the weight of 90% H2SO4 required neutralizing 60g of NaOH.
4. Phosphorus and chlorine combine with each other to produce PCl3 & PCl5, which law of stoichiometry do it follow?
State the law.
5. Which one will diffuse faster ammonia or carbon dioxide? Why?
6. Why does the size of an air balloon become larger as it ascends into higher altitudes?
7. 20g of nitrogen gas is enclosed in 1litre flask at 250oC . Calculate the pressure exerted by the gas.
8. Why is the following reaction redox reaction?
Cl2 + 2OH- → Cl- +H2O +ClO-
9. What observation in Rutherford experiment led him to conclude that nucleus of an atom occupy very small space in
atom?
10. Write the quantum numbers n, and l for N-shell and 3d orbital.
11. Ammonia is not dried by using conc. H2SO4. Explain why?
12. What happens when the gas obtained by the action of NH4Cl on Ca(OH)2 is passed to FeCl3 solution.
13. Calculate number of Faraday required to deposit 6.5 moles of Na from Na+.
14. Write the Lewis structure of
(a) Na2CO3 (b) N2O3
15. Distinguish between calcination & roasting.
16. Why do carbon form so many large number of compounds?
17. Write the functional group of following
. a) – COOH b) –CHO
c) –COOP d) – NH2
18. All Ores are minerals but all minerals aren’t Ore.” Justify with examples.
19. Distinguish between organic and inorganic compound.

20. Give IUPAC name of following organic compounds

a. CH 3  CH  CH  CH 3 b. CH 3 C HCOOH
l l l
OH OH Cl

“Group B”
Attempt any five questions. [5x5 = 25]
21. 10.5 gm of copper turning (at wt 63.5) containing 60% pure copper is heated with 12 gm of pure conc. H 2SO4 to
produce copper sulphate, sulphur dioxide & water.
a) Find which one is limiting reagent?
b) Find the number of moles of excess reagent left over un reacted?
c) Calculate the mass of copper sulphate formed.
d) Calculate the volume of sulphur dioxide produced.
22. Describe the hydrogen spectra in light of Bohr's theory. Why do hydrogen show number of spectra although if contain
only one electron.
23. Balance the following equation by oxidation number method or ion electron method.
KMnO4 + HCl → KCl +MnCl2 +H2O +Cl2. Identify oxidant and reductant also.
24. Describe the lab preparation of sulphur dioxide gas. Write its action with H2S.
25. Describe the manufacture of nitric acid by Ostwald’s process.
26. What are general steps for metallurgical operation?
27. Describe homologous series with example.
"Group C"
Attempt any two questions
28. State & explain Graham's law of diffusion. A molten CaCl2 is electrolyzed with the current of 0.8A until 2g of Ca is
deposited at cathode. At another electrode, in series with previous voltameter , there is evolution of hydrogen gas only,
then calculate
a) Time of electrolysis
b) No. of coulombs passed through the solution.
c) Mass of hydrogen liberated.
d) Volume of Hydrogen at NTP.

29. Write the theory with well labeled diagram for the manufacture of sulphuric acid. Explain with two reactions to show
sulphuric acid is a) Dehydrating agent
30. Describe the extraction of sodium by down's cell. Give one reactions each to produce SO 2 as (a) reducing agent
(b) bleaching agent
31. Write short notes on ( any two)
a) Mole concept.
b) Faraday’s laws of electrolysis.
c) Oxidation and Reduction always occurs simultaneously, explain.