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    Foundation Chemistry I - CHM 092 July - November 2020: Tutorial 1 (Topic 1)

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    Aiman Mazlan
    This document provides a tutorial with 30 chemistry problems covering topics such as defining terms related to atoms, isotopes, ions and compounds. It asks students to name and write formulas for various compounds, perform stoichiometric calculations, determine molar masses and concentrations, and calculate yields in chemical reactions.

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    Foundation Chemistry I - CHM 092 July - November 2020: Tutorial 1 (Topic 1)

    Uploaded by

    Aiman Mazlan
    177 views6 pages
    This document provides a tutorial with 30 chemistry problems covering topics such as defining terms related to atoms, isotopes, ions and compounds. It asks students to name and write formulas for various compounds, perform stoichiometric calculations, determine molar masses and concentrations, and calculate yields in chemical reactions.

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    This document provides a tutorial with 30 chemistry problems covering topics such as defining terms related to atoms, isotopes, ions and compounds. It asks students to name and write formulas for various compounds, perform stoichiometric calculations, determine molar masses and concentrations, and calculate yields in chemical reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    177 views6 pages

    Foundation Chemistry I - CHM 092 July - November 2020: Tutorial 1 (Topic 1)

    Uploaded by

    Aiman Mazlan
    This document provides a tutorial with 30 chemistry problems covering topics such as defining terms related to atoms, isotopes, ions and compounds. It asks students to name and write formulas for various compounds, perform stoichiometric calculations, determine molar masses and concentrations, and calculate yields in chemical reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    FOUNDATION CHEMISTRY I– CHM 092

    July – November 2020


    Tutorial 1 (Topic 1)

    1. Define the following terms: atom, ion, atomic element, molecular element, molecular compound, and ionic
    compound. Give an example of all the terms.

    2. Define an isotope. Explain why do isotope of an element exhibit similar chemical behavior.

    3. Write the symbols (mass number, atomic number and chemical symbol) of the following Isotopes. (use a
    periodic table if needed)
    (a) an isotope of silver which contains 60 neutrons :
    (b) an isotope of oxygen which contains 6 neutrons:

    4. An atom of an element has 25 protons in its nucleus.


    (a) Based on the average atomic mass, write the symbol for the element’s most abundant isotope.
    (b) Determine neutrons are in the isotope you described in 4(b)
    (c) Calculate electrons are in an atom of this element.

    5. The chemical symbols given below describe three elements X, Y, Z (not the actual symbols of the
    element)

    14
    7 X3- 272
    92 Y 40
    20 Z2+

    a) Calculate the number of :


    i) electrons in ion X
    ii) electrons in atom Y
    iii) neutron in ion X
    iv) mass number for Z

    b) Write a complete symbol to represent an isotope of Y which contains the number of neutrons twice
    the number of protons.

    6. Write the chemical formula of each compound.


    (a) iron(II) bromide
    (b) calcium fluoride
    (c) magnesium phosphide
    (d) cobalt(II) sulfide
    (e) aluminium sulfate
    (f) ammonium sulfide

    7. Name each of the following compounds


    (a) K2SO4
    (b) NaClO
    (c) BeCl2
    (d) PbO2
    (e) Ti(NO3)2
    (f) CaSO4
    (g) K2CrO4
    8. Name the following compounds
    (a) BrF3
    (b) H2S
    (c) OF2
    (d) SbF5
    (e) PCl3
    (f) N2O3
    (g) SO3
    (h) BBr3

    9. Name the following compounds that has the chemical formula


    (a) KBrO3
    (b) FeCl3. 6H20
    (c) HBrO4

    10. Write the chemical formula for the following compound


    (a) bromic acid
    (b) bromous acid
    (c) copper sulfate pentahydrate

    11. Consider the equation: 3NO2 (g) + H2O(l) → HNO3 (aq) + 2NO(g)
    Is the above equation is balanced?

    12. Balance the following equations


    (a) Ca(OH)2(aq) + HCl(aq) → CaCl2 (s) + H2O(l)
    (b) NaHCO3(l) + H2SO4 (aq) → Na2SO4 (l) + H2O (l) + CO2 (g)
    (c) C4H10 (g) + O2 (g)→ CO2 (g) + H2O(l)
    Tutorial 2 (Topic 1)

    13. Perform the following operation to the correct number of significant figures.

    a) 4.146 + 7.13 - 09.1434


    b) 5.77 x 4.678
    c) 52.734
    4.43
    d) 6.4324 + 3.556 - 8.3000 x 5.0076
    3.56

    e) 43.678 x 4.32 + 4.56 - 2.342 - 6.7


    6.543

    14. An iron nail is composed of four isotopes with the percentage abundances and atomic masses given
    in the following table. Calculate the average atomic mass of iron.

    Isotope Percentage abundance Atomic mass (u)


    54
    Fe 5.80 53.9396
    56
    Fe 91.72 55.9349
    57
    Fe 2.20 56.9354
    58
    Fe 0.28 57.9333
    (Answer: 55.8467)

    15. Determine the moles of sodium atoms corresponds to 1.56 x 1021 atoms of sodium.

    (Answer: 2.59 x 10-3)

    16. Find the volume in L occupied by 10.0 g of CO2 gas at STP.

    (Answer: 5.08 L)
    17. Calculate the molar mass for each of the following

    a) NaHCO3
    b) K2Cr2O7
    c) (NH4)2CO3
    (Answer: 84, 2.9 x 102, 96)

    18. Chlorine is used by textile manufactures to bleach cloth. Excess chlorine is destroyed by its reaction
    with sodium thiosulfate, Na2S2O3, as follows:

    Na2S2O3(aq) + 4Cl2(g)+ 5H2O (l) → 2NaHSO (aq) + 8HCl(aq)

    a) Determine the mole of Na2S2O3 needed to react with 0.12 mol of Cl2.
    b) Identify the amount of HCl that can be formed from 0.12 mol of Cl2.
    c) Calculate the amount of H2O required for the reaction of 0.12 mol of Cl2.

    (Answer: 0.03 mol Na2S2O3 , 0.24 mol HCl, 0.15 mol H2O)
    19. A sample of naturally occurring silicon consists Si-28 (amu = 27.9769), Si-29 (amu = 28.9765) and
    Si-30 (amu = 29.9738). If the atomic mass of silicon is 28.0855 and the natural abundance of Si-29
    is 4.7%, determine the natural abundances of Si-28 and Si-30.

    (Answer: 28Si = 92.2% , 30Si = 3.1% )

    20. When 0.684 g of an organic compound containing only carbon, hydrogen and oxygen was burned
    in oxygen, 1.312 g CO2 and 0.805 g H2O was obtained. Identify the empirical formula of the
    compound.
    (Answer: C2H6O)

    21. A hydrate of copper (II) sulfate with formula CuSO4.xH2O has a molar mass of 250.0 g/mol.

    a) Determine the value of x in the formula of the compound.


    b) A 2.545 g of the hydrate is heated and 63.85 % of the residue is found after heating. Calculate
    the molecular formula of the hydrate.
    (Answer: x = 5, CuSO4.5H2O)
    Tutorial 3 (Topic 1)

    22. Barium sulfate, BaSO4, is made by the following reaction.

    Ba(NO3)2 (aq) + Na2SO4 (s) → BaSO4(s) + NaNO3(aq)

    An experiment was begun with 75.0 g of Ba(NO3)2 and an excess of Na2SO4 After collecting and
    drying the product, 64.45 g of BaSO4 was obtained. Calculate the theoretical yield and percentage
    yield of BaSO4.
    (Answer: 66.97 g, 96.24 %)

    23. Calculate the concentration of solution prepared by dissolving:

    a) 4.00 g of NaOH in 100 mL of solution


    b) 16.0 g of CaCl2 in 250 mL of solution
    (Answer: 1 M, 0.58 M)

    24. Ferrocene, Fe(C5H5)2(s) can be prepared by reacting 3.0 g of FeCl2(s) with an equal mass of
    cyclopentadiene, C5H6(l) and 200.00 mL of 0.200 M KOH solution as shown in the following reaction.

    FeCl2(s) + 2 C5H6(l) + 2 KOH(aq) → Fe(C5H5)2(s) + 2 KCl(l) + 2 H2O(l)

    a) Determine the limiting reactant in this reaction.


    b) Calculate the mass of Fe(C5H5)2 could be produced.
    c) A student who carried out this reaction obtained 2.7 g of ferrocene. Identify the percent yield for
    this reaction.
    (Answer: 3.717 g, 72.6 %)

    25. A 15.0 mL solution of potassium nitrate (KNO3) was diluted to 125.0 mL and 25 mL of this solution
    were then diluted to 1.0 x 103 mL. The concentration of the final solution is 0.00383 M. Calculate the
    concentration of the original solution.
    (Answer: 1.28 M)

    26. When iron (II) hydroxide is mixed with phosphoric acid, iron (II) phosphate is obtained according to
    the following equation:

    3Fe(OH) (aq) + 2H3PO4 (aq) ® Fe3 (PO4 )2 (s) + 6H2O (l)


    2
    In an experiment, 22.5 mL of 2 M Fe(OH)2 is reacted with17.5 mL of 2 M H3PO4.
    a) Determine the limiting reactant.
    b) Calculate the moles of an excess reactant would remain after the reaction is completed
    c) Calculate the mass of Fe3(PO4)2 that could be produced in this reaction.
    d) If the actual mass of Fe3(PO4)2 obtained is 3.5 grams, calculate the percentage yield for this
    reaction.
    (Answer: 0.005 mol, 5.363 g, 65.3 % )

    27. Calculate the atom economy for making hydrogen by reacting coal with steam.

    C(s) + 2H2O(g) → CO2(g) + 2H2(g)


    (Answer: 8.3 %)
    28. A 560.0 mL of 0.610 M sodium bromide, NaBr solution has a density of 1.046 g/cm3. Calculate the
    molality of the solution.
    (Answer: 0.62 mol/kg)

    29. A 4 g sugar cube (Sucrose: C12H22O11) is dissolved in a 350 mL teacup of 80 °C water. Determine
    the molality of the sugar solution. (Density of water at 80° = 0.975 g/mL)

    (Answer: 0.034 mol/kg )

    30. Reaction between manganese (II) chloride with ammonium carbonate solutions produced
    manganese (II) carbonate and ammonium chloride.

    a) Write a balanced chemical equation for the reaction above.


    b) Calculate the number of mol ammonium chloride produced if 5.75 g manganese (II) carbonate
    was obtained from the reaction.
    c) Manganese (II) chloride gives a clear, pink solution when dissolved in water. A 25.2 g manganese
    (II) chloride is dissolved in enough water to give a final volume of 100 mL solution A. 20 mL of
    solution A is then diluted with enough water to give a final volume of 50 mL solution D. Calculate
    the molarity (M) of the solution D.
    (Answer: 0.1 mol, 0.8 M)

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