MDCAT Chemistry Chapter 1 Complete Test

MDCAT Chemistry Chapter 1 complete Test
Q. 1 The No. of covalent bond in 10 g of CH4 are

(a) 6.022 x 1023 (b) 2.062 x 1023 (c) 15.05 x 1024 (d) 1.505 x 1024
Answer:
10
No. of moles = 16 = 0.625
As CH4 has 4 covalent bonds so

Number of moles of covalent bonds = 4 × 0.625 = 2.5
No. of covalent bonds = 2.5 × 6.022 x 1023 = 1.505 x 1024
Q. 2 0.1 mole of Na2CO3 completely dissociates to produce Na+
(a) 1.204 x 1023 (b) 6.02 x 1023 (c) 1.806 x 1023 (d) 1.806 x 1022
Answer:
Na2CO3 → 2Na+ + CO3-2
0.1 0.1 x 2 = 0.2
As when sodium carbonate dissociate it will form 2 Na+. it means if we have 0.1 mole of sodium
carbonate than we will have 2 times of Na+ ions moles.
No. of Na+ ions = 0.2 × 6.022 x 1023 = 1.204 x 1023
Q. 3 In mass spectrometer, increasing the magnetic field with constant electric field results in:
(a) Increase radius ‘r’ (b) Decrease radius ‘r’
(c) Increased ionization (d) None of the above
Answer:
As magnetic field is inversely proportional to radius so by increasing the magnetic field the radius
decreases.
Q. 4 Which of the following is mono isotopic element?
(a) Cl (b) Au (c) H (d) Cd
Q. 5 % of nitrogen in urea (NH4)2SO4
(a) 20.35% (b) 21.6% (c) 21.2% (d) 23.56%
Answer:
28
% of N = 132 × 100 = 21.2 %
Q. 6 100 cm³ of H2 gas at STP contain hydrogen:

(a) 6.02 x 1023 (b) 3.01 x 1022 (c) 2.68 x 1021 (d) 1.34 x 1022
Answer:
1 dm3 = 1000 cm3
22.414 dm3 = 22414 cm3
1 mole = 22414 cm3 = 6.02 × 1023
1 cm3 = 6.02 × 1023/22414
100 cm3 = (6.02 × 1023/22414) × 100 = 2.68 ×1021
Q. 7 A compound contain 63.63% nitrogen and 36.36% oxygen by mass. The empirical formula
of the compound is:
(a) NO2 (b) NO (c) NO3 (d) N2O
Answer:
No. of moles of N = 63.63/14 = 4.545
No. of moles of O = 36.36/16 = 2.27
N:O
4.545 : 2.27
4.545/2.27 : 2.27/2.27
2:1
So the empirical formula is N2O
Q. 8 The volume occupied by 2.8 g of CO at STP
(a) 2.24 dm3 (b) 22.4 dm3 (c) 1.12 dm3 (d) 112 dm3
Answer:
2.8
Volume of CO = × 22.414 dm3 = 2.24 dm3
28
Q. 9 The molarity of 4% w/v NaOH solution is

(a) 1 M (b) 0.25 M (c) 0.05 M (d) 0.5 M
Answer:
As it is w/v solution it means this solution has 4 g of NaOH in 100 cm3 of solution
1 dm3 = 1000 cm3
0.1 dm3 = 100 cm3
4 1
Molarity = 40 × =1M
0.1
Q. 10 What is the molarity of a solution when 49 g of H2SO4 is present in 500 cm3 of solution
(a) 1 M (b) 0.5 M (c) 2.5 M (d) 4 M
Answer:
1 dm3 = 1000 cm3
0.5 dm3 = 500 cm3
49 1
Molarity = 98 × =1M
0.5
Q. 11 In a mixture of 16 g sulphur and 20 g calcium, mole fraction of sulphur is

(a) 0.3 (b) 0.1 (c) 0.25 (d) 0.50
Answer:
16 1
No. of moles of S = =
32 2
20 1
No. of moles of S = 40 = 2
1
2 1
Xs = 1 1 = = 0.5
+ 2
2 2
Q. 12 Molecular ions are produced in mass spectrometer. Which type of molecular ions formed
more abundantly.
(a) Negatively charged (b) H+1 ions
(c) Positively charged (d) Equal positive and negative charge
Q. 13 During combustion analysis, which one is used for absorbing water:
(a) 50% KOH solution (b) 5% KOH (c) Mg(ClO4)2 (d) Silica gel
Q. 14 11.207 dm3 of methane at STP has ________ moles of hydrogen atoms
(a) 4 (b) ½ (c) 8 (d) 16
Answer:
11.207
No. of moles = 22.414 = 0.5
Q. 15 Which of the following solutions of H2SO4 is more concentrated

(a) 2 molar solution (b) 1 molal solution
(c) ½ molal solution (d) All have same concentration
Q. 16 The number of peaks obtained in mass spectrometry shows
(a) Relative abundance (b) Average mass of element
(c) Number of isotopes (d) Relative isotopic mass
Q. 17 Which of the following statements about isotopes is correct?
(a) Isotopes with odd atomic number are abundant
(b) Isotopes with odd atomic number and even mass number are abundant
(c) Isotopes with even atomic number and even mass number are abundant
(d) Isotopes with even atomic number and odd mass no are abundant
Q. 18 Empirical formula of ascorbic acid in which atomic ratio of
C : H : O = 1 : 1.33 : 1
(a) CH1.33O (b) C3H4O3 (c) C2H3O2 (d) CHO
Answer:
The given ratio is called atomic ratio. If we get atomic ratio as integer than this ratio directly give
us empirical formula but as it is not integer so we have to multiply it with number
3 (1 : 1.33 : 1) = 3 : 4 : 3
So the empirical formula is C3H4O3
Q. 19 Avogadro’s number may represent/relate
(a) Volume of particles (b) Number of particles (c) Mass of particles (d) All of the above
Q. 20 Which of the following term is used for the mass of chlorine 35.5
(a) Relative atomic mass (b) Mass number (c) Atomic weight (d) Relative atomic mass
Q. 21 Which of the following statements is wrong about isotopes
(a) They posses different mass number
(b) They posses different physical properties
(c) They posses same chemical properties
(d) They posses different position in the periodic table
Q. 22 For which of the following compounds the term empirical formula cannot be applied
(a) NaCl (b) H2O (c) CCl4 (d) It can be applied to all
Q. 23 Stoichiometry calculations
(a) The reaction can be reversible
(b) Side products can be formed
(c) Law of conservation of mass may not be obeyed
(d) Law of definite proportion is definitely obeyed
Q. 24 Equal volume of CO and N2 are taken in identical conditions, the correct relationship
between masses of two gases is
(a) CO=N2 (b) CO<N2 (c) N2<CO (d) CO<N2
Answer:
AS we have equal volume of both gases in identical conditions so the mass will be same as these
both gases have same molecular mass as well
Q. 25 One mole of CH3OH and one mole of C2H5OH have
(a) Equal number of atoms (b) Equal number of molecules
(c) Equal number of electrons (d) Equal number of protons
Answer:
As both have same number of moles so both will have same number of molecules as well
Q. 26 Which element has same isotopes like palladium
(a) Ni (b) Ca (c) Cd (d) Sn
Q. 27 The number of isotopes of elements with even mass number and even atomic number are
(a) 280 (b) 300 (c) 154 (d) 54
Q. 28 The mass of one mole of CO3-2 is:
(a) 40g (b) 600g (c) 60g (d) 62g
Answer:
𝑀𝑎𝑠𝑠
Moles = 𝐼𝑜𝑛𝑖𝑐 𝑀𝑎𝑠𝑠
Moles × Ionic Mass = Mass

1 × 60 = 60 = Mass
Q. 29 Which one of the following compound does not have the empirical formula CH2O:
(a) HCHO (b) C6H12O6 (c) CH3COOH (d) CH3CH2OH
Q. 30 When solid solute is dissolved in liquid solvent, then the best unit of concentration is
(a) % w/w (b) % v/v (c) % w/v (d) % v/w

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MDCAT Chemistry Chapter 1 Complete Test

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MDCAT Chemistry Chapter 1 complete Test

Q. 1 The No. of covalent bond in 10 g of CH4 are

As CH4 has 4 covalent bonds so

Q. 6 100 cm³ of H2 gas at STP contain hydrogen:

Q. 9 The molarity of 4% w/v NaOH solution is

Q. 11 In a mixture of 16 g sulphur and 20 g calcium, mole fraction of sulphur is

Q. 15 Which of the following solutions of H2SO4 is more concentrated

Moles × Ionic Mass = Mass

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