Version: 1.

1
Revision Date: 10-09-2014

SAFETY DATA SHEET

1. Identification

Product identifier: MERCURY

Other means of identification

Product No.: 2567, 2564, 1280

Recommended use and restriction on use

Recommended use: Not available.
Restrictions on use: Not known.

Manufacturer/Importer/Supplier/Distributor Information

Manufacturer
Company Name: Avantor Performance Materials, Inc.
Address: 3477 Corporate Parkway, Suite 200
Center Valley, PA 18034
Telephone:
Customer Service: 855-282-6867
Fax:
Contact Person: Environmental Health & Safety
e-mail: [email protected]

Emergency telephone number:

24 Hour Emergency: 908-859-2151

Chemtrec: 800-424-9300

2. Hazard(s) identification

Hazard Classification
Health Hazards
Acute toxicity (Inhalation - vapor) Category 2
Toxic to reproduction Category 1B

Environmental Hazards
Acute hazards to the aquatic Category 1
environment
Chronic hazards to the aquatic Category 1
environment
Label Elements
Hazard Symbol:

Signal Word: Danger

Hazard Statement: May damage fertility or the unborn child.

Fatal if inhaled.
Very toxic to aquatic life with long lasting effects.
Causes damage to organs through prolonged or repeated exposure.

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Precautionary
Statement

Prevention: Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Wear protective
gloves/protective clothing/eye protection/face protection. Do not breathe
dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated
area. Wear respiratory protection. Avoid release to the environment. Wash
hands thoroughly after handling.

Response: IF exposed or concerned: Get medical advice/attention. IF INHALED:

Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor/physician.

Storage: Store locked up. Store in a well-ventilated place. Keep container tightly
closed.

Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Other hazards which do not None.

result in GHS classification:

3. Composition/information on ingredients

Substances

Common name CAS

Chemical Identity Content in percent (%)*
and synonyms number

MERCURY 7439-97-6 90 - 100%

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures

General information: Get medical advice/attention if you feel unwell. Show this safety data sheet
to the doctor in attendance.

Ingestion: Call a physician or poison control center immediately. Do not induce

vomiting without advice from poison control center. If vomiting occurs, keep
head low so that stomach content doesn't get into the lungs.

Inhalation: Move to fresh air. Call a physician or poison control center immediately. If
breathing stops, provide artificial respiration.

Skin Contact: Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Call a physician or poison
control center immediately. Wash contaminated clothing before reuse.
Destroy or thoroughly clean contaminated shoes.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention immediately.

Most important symptoms/effects, acute and delayed

Symptoms: Fatal if inhaled. Irritating to eyes, respiratory system and skin.

Indication of immediate medical attention and special treatment needed

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Treatment: Treat symptomatically. Symptoms may be delayed.

5. Fire-fighting measures

General Fire Hazards: In case of fire and/or explosion do not breathe fumes.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

media:

Unsuitable extinguishing None known.

media:

Specific hazards arising from Fire may produce irritating, corrosive and/or toxic gases.
the chemical:

Special protective equipment and precautions for firefighters

Special fire fighting Move containers from fire area if you can do so without risk. Use water
procedures: spray to keep fire-exposed containers cool. Cool containers exposed to
flames with water until well after the fire is out.

Special protective equipment Firefighters must use standard protective equipment including flame
for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.

6. Accidental release measures

Personal precautions, Keep unauthorized personnel away. Use personal protective equipment.
protective equipment and See Section 8 of the MSDS for Personal Protective Equipment. Ventilate
emergency procedures: closed spaces before entering them. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing.

Methods and material for Absorb spill with vermiculite or other inert material, then place in a container
containment and cleaning for chemical waste. Clean surface thoroughly to remove residual
up: contamination. Dike far ahead of larger spill for later recovery and disposal.

Notification Procedures: Dike for later disposal. Prevent entry into waterways, sewer, basements or
confined areas. Stop the flow of material, if this is without risk. Inform
authorities if large amounts are involved.

Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so. Avoid discharge into drains, water courses or onto
the ground.

7. Handling and storage

Precautions for safe handling: Use personal protective equipment as required. Do not breathe mist or
vapor. Do not taste or swallow. Do not eat, drink or smoke when using the
product. Use only with adequate ventilation. Wash hands thoroughly after
handling. See Section 8 of the MSDS for Personal Protective Equipment.
Avoid contact with eyes. Avoid contact with skin. Obtain special instructions
before use. Do not handle until all safety precautions have been read and
understood.

Conditions for safe storage, Keep in a cool, well-ventilated place. Store in a dry place. Store locked up.
including any Keep container tightly closed.
incompatibilities:

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8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source

MERCURY - as Hg TWA 0.025 mg/m3 US. ACGIH Threshold Limit Values (03 2013)
MERCURY - Vapor. - as Hg REL 0.05 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2010)
TWA 0.05 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
MERCURY Ceiling 0.1 mg/m3 US. OSHA Table Z-2 (29 CFR 1910.1000) (02
2006)

Biological Limit Values

Chemical Identity Exposure Limit Values Source
MERCURY (Total inorganic 20 µg/g (Creatinine in urine) ACGIH BEL (02 2013)
mercury: Sampling time:
Prior to shift.)

Appropriate Engineering No data available.

Controls

Individual protection measures, such as personal protective equipment

General information: Good general ventilation (typically 10 air changes per hour) should be used.
Ventilation rates should be matched to conditions. If applicable, use
process enclosures, local exhaust ventilation, or other engineering controls
to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an
acceptable level. An eye wash and safety shower must be available in the
immediate work area.

Eye/face protection: Wear safety glasses with side shields (or goggles) and a face shield.

Skin Protection
Hand Protection: Chemical resistant gloves

Other: Wear suitable protective clothing.

Respiratory Protection: In case of inadequate ventilation use suitable respirator.

Hygiene measures: Provide eyewash station and safety shower. Observe good industrial
hygiene practices. Wash hands before breaks and immediately after
handling the product. Do not eat, drink or smoke when using the product.
Wash contaminated clothing before reuse.

9. Physical and chemical properties

Appearance
Physical state: Liquid
Form: Liquid
Color: Silver
Odor: Odorless
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: -38.87 °C
Initial boiling point and boiling range: 356.73 °C
Flash Point: Not applicable

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Evaporation rate: 4 (butyl acetate=1)

Flammability (solid, gas): Noncombustible Liquid
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: < 0.01 kPa (25 °C)
Vapor density: 7.0 AIR=1
Relative density: 13.55 (20 °C)
Solubility(ies)
Solubility in water: Insoluble in water
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: No data available.

Other information
Molecular weight: 200.59 g/mol (Hg)

10. Stability and reactivity

Reactivity: No dangerous reaction known under conditions of normal use.

Chemical Stability: Material is stable under normal conditions.

Possibility of Hazardous Hazardous polymerization does not occur.

Reactions:

Conditions to Avoid: Heat, sparks, flames. Contact with incompatible materials.

Incompatible Materials: Strong oxidizing agents. Acetylene. Ammonia. Ethylene Oxide Chlorinated
compounds. Metals. Strong oxidizers

Hazardous Decomposition Toxic metal fumes may form when heated to decomposition.
Products:

11. Toxicological information

Information on likely routes of exposure

Ingestion: Harmful if swallowed.

Inhalation: Fatal if inhaled.

Skin Contact: Causes skin irritation.

Eye contact: Causes eye irritation.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)
Oral
Product: No data available.

Dermal
Product: No data available.

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Inhalation
Product: No data available.

Repeated Dose Toxicity

Product: No data available.

Skin Corrosion/Irritation
Product: Causes skin irritation.

Serious Eye Damage/Eye Irritation

Product: Causes eye irritation.

Respiratory or Skin Sensitization

Product: Not a skin sensitizer.

Carcinogenicity
Product: This substance has no evidence of carcinogenic properties.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogenic components identified

US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

No carcinogenic components identified

Germ Cell Mutagenicity

In vitro
Product: No mutagenic components identified

In vivo
Product: No mutagenic components identified

Reproductive Toxicity
Product: May damage fertility or the unborn child.

Specific Target Organ Toxicity - Single Exposure

Product: No data available.

Specific Target Organ Toxicity - Repeated Exposure

Product: Causes damage to organs through prolonged or repeated exposure.

Aspiration Hazard
Product: Not classified

Other Effects: None known.

12. Ecological information

Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Product: No data available.
Specified substance(s):
MERCURY LC 50 (Medaka, high-eyes (Oryzias latipes), 72 h): 1.4 mg/l Mortality
LC 50 (Nile tilapia (Tilapia nilotica), 72 h): 3.71 mg/l Mortality
LC 50 (Snake-head catfish (Channa striata), 72 h): 6.148 mg/l Mortality
LC 50 (Snake-head catfish (Channa striata), 90 d): 1.571 mg/l Mortality

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LC 50 (Snake-head catfish (Channa striata), 90 d): 6.355 mg/l Mortality

Aquatic Invertebrates
Product: No data available.
Specified substance(s):
MERCURY LC 50 (Freshwater prawn (Caridina rajadhari), 24 h): 0.00912 mg/l Mortality
LC 50 (Calanoid copepod (Acartia tonsa), 24 h): 0.0175 mg/l Mortality
LC 50 (Calanoid copepod (Acartia tonsa), 24 h): 0.02 mg/l Mortality
LC 50 (Calanoid copepod (Acartia tonsa), 24 h): 0.022 mg/l Mortality
LC 50 (Rotifer (Brachionus calyciflorus), 24 h): 0.054 - 0.066 mg/l Mortality

Chronic hazards to the aquatic environment:

Fish
Product: No data available.

Aquatic Invertebrates
Product: No data available.

Toxicity to Aquatic Plants

Product: No data available.

Persistence and Degradability

Biodegradation
Product: There are no data on the degradability of this product.

BOD/COD Ratio
Product: No data available.

Bioaccumulative Potential
Bioconcentration Factor (BCF)
Product: No data available on bioaccumulation.

Partition Coefficient n-octanol / water (log Kow)

Product: No data available.

Mobility in Soil: The product is water soluble and may spread in water systems.

Other Adverse Effects: Very toxic to aquatic life with long lasting effects.

13. Disposal considerations

Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local
laws. Dispose of contents/container to an appropriate treatment and
disposal facility in accordance with applicable laws and regulations, and
product characteristics at time of disposal.

Contaminated Packaging: Since emptied containers retain product residue, follow label warnings even
after container is emptied.

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14. Transport information

DOT
UN Number: UN 2809
UN Proper Shipping Name: Mercury
Transport Hazard Class(es)
Class(es): 8, 6.1
Label(s): 8, 6.1
Packing Group: III
Marine Pollutant: No

IMDG
UN Number: UN 2809
UN Proper Shipping Name: MERCURY
Transport Hazard Class(es)
Class(es): 8, 6.1
Label(s): 8, 6.1
EmS No.: F-A, S-B
Packing Group: III
Marine Pollutant: No

IATA
UN Number: UN 2809
Proper Shipping Name: Mercury
Transport Hazard Class(es):
Class(es): 8, 6.1
Label(s): 8, 6.1
Marine Pollutant: No
Packing Group: III

15. Regulatory information

US Federal Regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
None present or none present in regulated quantities.

CERCLA Hazardous Substance List (40 CFR 302.4):

MERCURY Reportable quantity: 1 lbs.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories

X Acute (Immediate) X Chronic (Delayed) Fire Reactive Pressure Generating

SARA 302 Extremely Hazardous Substance

None present or none present in regulated quantities.

SARA 304 Emergency Release Notification

Chemical Identity RQ
MERCURY 1 lbs.

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SARA 311/312 Hazardous Chemical

Chemical Identity Threshold Planning Quantity
MERCURY 500 lbs

SARA 313 (TRI Reporting)

Reporting Reporting threshold for
threshold for manufacturing and
Chemical Identity other users processing
MERCURY 10 lbs

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
None present or none present in regulated quantities.

US State Regulations

US. California Proposition 65

MERCURY Developmental toxin.

US. New Jersey Worker and Community Right-to-Know Act

MERCURY Listed

US. Massachusetts RTK - Substance List

MERCURY Listed

US. Pennsylvania RTK - Hazardous Substances

MERCURY Listed

US. Rhode Island RTK

MERCURY Listed

Inventory Status:
Australia AICS: On or in compliance with the inventory
Canada DSL Inventory List: On or in compliance with the inventory
EINECS, ELINCS or NLP: On or in compliance with the inventory
Japan (ENCS) List: Not in compliance with the inventory.
China Inv. Existing Chemical Substances: Not in compliance with the inventory.
Korea Existing Chemicals Inv. (KECI): On or in compliance with the inventory
Canada NDSL Inventory: Not in compliance with the inventory.
Philippines PICCS: On or in compliance with the inventory
US TSCA Inventory: On or in compliance with the inventory
New Zealand Inventory of Chemicals: On or in compliance with the inventory
Japan ISHL Listing: Not in compliance with the inventory.
Japan Pharmacopoeia Listing: Not in compliance with the inventory.

16.Other information, including date of preparation or last revision

NFPA Hazard ID

0 Flammability
3 0 Health
Reactivity
Special hazard.
Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe

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Issue Date: 10-09-2014

Revision Date: No data available.

Version #: 1.1

Further Information: No data available.

Disclaimer: THE INFORMATION PRESENTED IN THIS MATERIAL SAFETY DATA

SHEET (MSDS/SDS) WAS PREPARED BY TECHNICAL PERSONNEL
BASED ON DATA THAT THEY BELIEVE IN THEIR GOOD FAITH
JUDGMENT IS ACCURATE. HOWEVER, THE INFORMATION PROVIDED
HEREIN IS PROVIDED “AS IS,” AND AVANTOR PERFORMANCE
MATERIALS MAKES AND GIVES NO REPRESENTATIONS OR
WARRANTIES WHATSOEVER, AND EXPRESSLY DISCLAIMS ALL
WARRANTIES REGARDING SUCH INFORMATION AND THE PRODUCT
TO WHICH IT RELATES, WHETHER EXPRESS, IMPLIED, OR
STATUTORY, INCLUDING WITHOUT LIMITATION<(>,<)> WARRANTIES
OF ACCURACY, COMPLETENESS, MERCHANTABILITY, NON-
INFRINGEMENT, PERFORMANCE, SAFETY, SUITABILITY, STABILITY,
AND FITNESS FOR A PARTICULAR PURPOSE, AND ANY WARRANTIES
ARISING FROM COURSE OF DEALING, COURSE OF PERFORMANCE,
OR USAGE OF TRADE. THIS MSDS/SDS IS INTENDED ONLY AS A
GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE
MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT,
AND IS NOT INTENDED TO BE COMPREHENSIVE AS TO THE MANNER
AND CONDITIONS OF USE, HANDLING, STORAGE, OR DISPOSAL OF
THE PRODUCT. INDIVIDUALS RECEIVING THIS MSDS/SDS MUST
ALWAYS EXERCISE THEIR OWN INDEPENDENT JUDGMENT IN
DETERMINING THE APPROPRIATENESS OF SUCH ISSUES.
ACCORDINGLY, AVANTOR PERFORMANCE MATERIALS ASSUMES NO
LIABILITY WHATSOEVER FOR THE USE OF OR RELIANCE UPON THIS
INFORMATION. NO SUGGESTIONS FOR USE ARE INTENDED AS, AND
NOTHING HEREIN SHALL BE CONSTRUED AS, A RECOMMENDATION
TO INFRINGE ANY EXISTING PATENTS OR TO VIOLATE ANY FEDERAL,
STATE, LOCAL, OR FOREIGN LAWS. AVANTOR PERFORMANCE
MATERIALS REMINDS YOU THAT IT IS YOUR LEGAL DUTY TO MAKE
ALL INFORMATION IN THIS MSDS/SDS AVAILABLE TO YOUR
EMPLOYEES.

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