FLOCON-135 Sds

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Revision date: 6/22/2017 Revision: 4.

SAFETY DATA SHEET


FLOCON® 135

1. Identification

Product identifier
Product name FLOCON® 135

Chemical name Phosphinocarboxylic acid

Product number 100496, 100497, 100498, 100499, 100500, 100501, 100502, 100503, 101305, 101306,
101423, 101550

Recommended use of the chemical and restrictions on use


Application Antiscalant

Details of the supplier of the safety data sheet


Supplier BWA Water Additives US LLC
1979 Lakeside Parkway, Suite 925
Tucker, GA 30084 USA
T: +1 800-600-4523
(Technical/commercial enquiries)
F: +1 678-802-3050
E: msds@wateradditives.com

Distributed by:

Emergency telephone number


Emergency telephone Chemtrec Phone: 1-800-424-9300

National emergency telephone For Medical Emergency: 1-303-623-5716


number For Transport Emergency: 1-800-424-9300 (CHEMTREC)

2. Hazard(s) identification

Classification of the substance or mixture


Physical hazards Not Classified

Health hazards Not Classified

Environmental hazards Not Classified

Label elements
Hazard statements NC Not Classified

3. Composition/information on ingredients

Mixtures
Composition comments Aqueous solution of phosphinocarboxylic acid

4. First-aid measures

Description of first aid measures

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FLOCON® 135

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Get medical attention if any discomfort continues.

Ingestion Never give anything by mouth to an unconscious person. Do not induce vomiting. Do not
induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter
the lungs. Rinse mouth thoroughly with water. Get medical attention if any discomfort
continues.

Skin Contact Immediately remove contaminated clothing. Rinse immediately with plenty of water. Continue
to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after
washing.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes. Get medical attention if irritation persists after
washing. Show this Safety Data Sheet to the medical personnel.

Most important symptoms and effects, both acute and delayed


Inhalation No specific symptoms known.

Ingestion No specific symptoms known. May cause discomfort if swallowed.

Skin contact No specific symptoms known. May cause skin irritation/eczema.

Eye contact No specific symptoms known. May cause temporary eye irritation.

Indication of immediate medical attention and special treatment needed


Notes for the doctor Treat symptomatically.

5. Fire-fighting measures

Extinguishing media
Suitable extinguishing media The product is non-combustible. Extinguish with the following media: Water spray, fog or mist.
Foam, carbon dioxide or dry powder.

Special hazards arising from the substance or mixture


Specific hazards The product is non-combustible. Irritating gases or vapors. No unusual fire or explosion
hazards noted.

Hazardous combustion Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and
products other toxic gases or vapors. Oxides of: Phosphorus.

Advice for firefighters


Protective actions during Move containers from fire area if it can be done without risk. Cool containers exposed to
firefighting flames with water until well after the fire is out. Control run-off water by containing and
keeping it out of sewers and watercourses.

Special protective equipment Leave danger zone immediately.


for firefighters

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures


Personal precautions Follow precautions for safe handling described in this safety data sheet.

Environmental precautions
Environmental precautions Avoid release to the environment. To prevent release, place container with damaged side up.

Methods and material for containment and cleaning up

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FLOCON® 135

Methods for cleaning up Avoid the spillage or runoff entering drains, sewers or watercourses. Absorb in vermiculite, dry
sand or earth and place into containers. Collect spillage for reclamation or disposal in sealed
containers via a licensed waste contractor. Containers with collected spillage must be properly
labeled with correct contents and hazard symbol.

Reference to other sections For waste disposal, see section 13.

7. Handling and storage

Precautions for safe handling


Usage precautions Good personal hygiene procedures should be implemented. Avoid spilling. Avoid contact with
skin and eyes.

Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry and cool place. Store at temperatures not
exceeding «Value in °C»°C/«Value in °F»°F. Do not store for extended periods below freezing
point or in direct sunlight. IF FROZEN: once fully thawed, agitate container vigorously to
ensure the product is homogeneous. Store away from the following materials: Alkalis.
Oxidizing materials. Reducing agents. Keep separate from food, feedstuffs, fertilizers and
other sensitive material.

Storage class Unspecified storage.

Specific end uses(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.

8. Exposure Controls/personal protection

Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Observe any occupational exposure
controls limits for the product or ingredients.

Eye/face protection The following protection should be worn: Chemical splash goggles.

Hand protection Selection of a suitable glove depends on work conditions and whether the product is present
on its own or in combination with other substances. Wear protective gloves made of the
following material: Neoprene. Nitrile rubber. Polyethylene. Polyvinyl chloride (PVC). It should
be noted that liquid may penetrate the gloves. Frequent changes are recommended.

Other skin and body Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear apron or
protection protective clothing in case of contact.

Hygiene measures No specific hygiene procedures recommended but good personal hygiene practices should
always be observed when working with chemical products.

Respiratory protection No specific recommendations. Respiratory protection may be required if excessive airborne
contamination occurs.

9. Physical and Chemical Properties

Information on basic physical and chemical properties


Appearance Liquid.

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FLOCON® 135

Color Colorless.

Odor Slight.

Odor threshold Not available. Not available.

pH pH (concentrated solution): 3.5-4.5

Melting point Not available.

Initial boiling point and range 101 - 103 @°C @ 760 mm Hg

Flash point > 93°C PMCC (Pensky-Martens closed cup).

Freezing Point:

Evaporation rate Not available.

Upper/lower flammability or Not applicable.


explosive limits

Vapor pressure Not available.

Relative density 1.17-1.20 @ 20c

Solubility(ies) Miscible with water.

Partition coefficient log Pow: < 0

Auto-ignition temperature Not available.

Decomposition Temperature Not available.

Viscosity 35 - 60 cSt @ 25°C

Oxidizing properties Does not meet the criteria for classification as oxidizing.

Other information Not available.

10. Stability and reactivity

Reactivity Reacts with alkalis and generates heat.

Stability Stable at normal ambient temperatures and when used as recommended.

Possibility of hazardous Will not polymerize.


reactions

Conditions to avoid Avoid excessive heat for prolonged periods of time.

Materials to avoid Strong alkalis. Strong oxidizing agents.

Hazardous decomposition Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and
products other toxic gases or vapors. Oxides of the following substances: Phosphorus.

11. Toxicological information

Information on toxicological effects


Supplemental Toxicological A 90-day oral toxicity study in rats indicated bone damage and kidney effects at high doses.
Information The effect for humans is unknown.

Acute toxicity - oral

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FLOCON® 135

Acute toxicity oral (LD₅₀ 5,000.0


mg/kg)

Species Rat

Inhalation No specific health hazards known.

Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting.

Skin Contact Non Irritant. Not a Skin Sensitiser

Eye contact Non irritant.

12. Ecological Information

Ecotoxicity The product components are not classified as environmentally hazardous. However, large or
frequent spills may have hazardous effects on the environment.

Acute toxicity - fish LC50, 96 hours: > 1000 ,


LC₅₀, 96 hours: >1000 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 320 mg/l, Daphnia magna


invertebrates EC₅₀, 48 hours: 320 mg/l, Daphnia magna

Acute toxicity - aquatic plants IC₅₀, 72 hours: 130 mg/l, Marinewater algae
IC₅₀, 72 hours: 130 mg/l, Algae

Persistence and degradability


Persistence and degradability Not readily biodegradable

Chemical oxygen demand 370 g O2/l

Bioaccumulative potential
Bio-Accumulative Potential The product does not contain any substances expected to be bioaccumulating.

Partition coefficient log Pow: < 0

Mobility in soil
Mobility The product is miscible with water. May spread in water systems.

Other adverse effects


Other adverse effects Not available.

13. Disposal considerations

Waste treatment methods


General information When handling waste, the safety precautions applying to handling of the product should be
considered.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

14. Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, DOT).

Rail transport notes Not classified.

Sea transport notes Not classified.

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FLOCON® 135

Air transport notes Not classified.

UN proper shipping name

Packing group

Environmental hazards

Environmentally Hazardous Substance


No.

15. Regulatory information

US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed.

CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)


None of the ingredients are listed.

SARA Extremely Hazardous Substances EPCRA Reportable Quantities


None of the ingredients are listed.

SARA 313 Emission Reporting


None of the ingredients are listed.

CAA Accidental Release Prevention


None of the ingredients are listed.

FDA - Essential Chemical


None of the ingredients are listed.

FDA - Precursor Chemical


None of the ingredients are listed.

SARA (311/312) Hazard Categories


Threshold Planning Quantity 10,000lbs.

OSHA Highly Hazardous Chemicals


None of the ingredients are listed.

US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
None of the ingredients are listed.

California Air Toxics "Hot Spots" (A-I)


None of the ingredients are listed.

California Air Toxics "Hot Spots" (A-II)


None of the ingredients are listed.

Massachusetts "Right To Know" List


None of the ingredients are listed.

Rhode Island "Right To Know" List


None of the ingredients are listed.

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FLOCON® 135

Minnesota "Right To Know" List


None of the ingredients are listed.

New Jersey "Right To Know" List


None of the ingredients are listed.

Pennsylvania "Right To Know" List


None of the ingredients are listed.

Inventories
EU - EINECS/ELINCS
All the ingredients are listed or exempt.

Canada - DSL/NDSL
All the ingredients are listed or exempt.

US - TSCA
All the ingredients are listed or exempt.

US - TSCA 12(b) Export Notification


None of the ingredients are listed.

Australia - AICS
All the ingredients are listed or exempt.

Japan - MITI
All the ingredients are listed or exempt.

JAPAN- IHSL

Korea - KECI
All the ingredients are listed or exempt.

China - IECSC
All the ingredients are listed or exempt.

Philippines - PICCS
All the ingredients are listed or exempt.

New Zealand - NZIOC


All the ingredients are listed or exempt.

Taiwan -TCSI

16. Other information

General information Flocon 135 is certified by NSF International for use as an antiscalant in reverse osmosis
plants. The maximum approved dose level is 10 mg/l in the feedwater. For advice on chemical
emergencies, spillages, fires or first aid in relation to this product please contact the relevant
emergency number below : EU/English Speakers - +44 (0) 1235 239 670 (NCEC) Arabic
Speakers - +44 (0) 1235 239 671 Asia/Pacific countries - +65 3158 1074 For emergencies
within China - +86 10 5100 3039

Revision comments 4.2 KIWA certification added

Issued by BWA Water Additives Regulatory Group, +44(0)1618646699

Revision date 6/22/2017

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Revision date: 6/22/2017 Revision: 4.2

FLOCON® 135

Revision 4.2

SDS No. 10251

KIWA Certification PLANT AT Trafford Park, Manchester, England. Maximum Dose 10mg/l. K20750.

NFPA - instability hazard Normally stable. (0)

NFPA - special hazard N/A

ACA HMIS Health rating. Minimal Hazard. (0)

NFPA - health hazard No health hazards specifically noted for fire situations. (0)

NFPA - flammability hazard Will not burn. (0)

NSF/ANSI Standard 60 Plant#1 Taiwan Maximum Dose 10mg/L Plant at Manchester, UK Maximum dose: 10 mg/L

ACA HMIS Flammability Will not burn. (0)


rating.

ACA HMIS Physical hazard Normally stable. (0)


rating.

ACA HMIS Personal C


protection rating.

For safety reasons it is IMPERATIVE that customers:-

1. Ensure that all those within their control who use the products are supplied with all relevant information contained within the
Safety Data Sheet and Technical Bulletin concerning the applications for which the product is designed and any instructions
and warnings contained therein.

2. Consult BWA Water Additives before using or supplying the product for any other applications. The information contained
herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety
requirements. It should not therefore be construed as guaranteeing specific properties.

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