SAFETY DATA SHEET

Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

This SDS adheres to the standards and regulatory requirements of India and may not meet the regulatory requirements in
other countries.

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name : Picoxystrobin + Tricyclazole

Recommended use of the chemical and restriction on use

Recommended use : Fungicide
Restrictions on use : Do not use product for anything outside of the above specified uses.

Manufacturer, importer, supplier

Company : E. I. DuPont India Pvt. Ltd.
Street address : 7th Floor, Tower C, DLF Cyber Greens, Sector 25A, DLF City Phase III, Gurgaon -
122002, Haryana
India
Telephone : +91-124-2540900
Telefax : +91-124-2540889 / 90 / 91 / 92

Emergency telephone : +91-124-4092888 / +91-124-2353777

number

2. HAZARDS IDENTIFICATION

Product hazard classification

Acute toxicity (Oral) : Category 4
Specific target organ : Category 2 (Liver)
toxicity - repeated
exposure
Acute aquatic toxicity : Category 1
Chronic aquatic toxicity : Category 2
Endpoints which are not classified, cannot be classified or are not applicable are not shown.

Label content
Pictogram :

Signal word : Warning

Hazardous warnings : Harmful if swallowed.

May cause damage to organs through prolonged or repeated exposure. (Liver)
Very toxic to aquatic life.
Toxic to aquatic life with long lasting effects.

Precautionary : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.

statements Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse

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Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

mouth.
Get medical advice/ attention if you feel unwell.
Collect spillage.
Dispose of contents/ container to an approved waste disposal plant.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Mixture

Components

Chemical name CAS-No. Concentration

Tricyclazole 41814-78-2 20.33 %
Picoxystrobin 117428-22-5 6.78 %
Other Ingredients 72.89 %

4. FIRST AID MEASURES

Have the product container or label with you when calling a poison control center or doctor, or going for treatment.

Inhalation : Remove person to fresh air. If signs/symptoms continue, get medical attention.
Artificial respiration and/or oxygen may be necessary. Call a poison control center
or doctor for treatment advice.

Skin contact : Take off all contaminated clothing immediately. Rinse skin immediately with plenty
of water for 15-20 minutes. Call a poison control center or doctor for treatment
advice.

Eye contact : Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call
a poison control center or doctor for treatment advice.

Ingestion : Call a poison control center or doctor for treatment advice. Have person sip a
glass of water if able to swallow. DO NOT induce vomiting unless directed to do
so by a physician or poison control center. Do not give anything by mouth to an
unconscious person.

Most important : No information available.

symptoms/effects, acute
and delayed

Protection of first-aiders : No information available.

Notes to physician : No information available.

5. FIREFIGHTING MEASURES

Suitable extinguishing : Water spray, Foam, Dry chemical, Carbon dioxide (CO2)
media

Unsuitable extinguishing : High volume water jet, (contamination risk)

media

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Picoxystrobin + Tricyclazole
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Specific hazards : No information available.

Special protective : Wear full protective clothing and self-contained breathing apparatus.
equipment for firefighters

Specific extinguishing : No information available.

methods

Further information : Prevent fire extinguishing water from contaminating surface water or the ground
water system. Collect contaminated fire extinguishing water separately. This must
not be discharged into drains. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.
(on small fires) If area is heavily exposed to fire and if conditions permit, let fire
burn itself out since water may increase the area contaminated. Cool
containers/tanks with water spray.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : No information available.

protective equipment and
emergency procedures

Environmental : Prevent material from entering sewers, waterways, or low areas.

precautions

Methods and materials : Soak up with sawdust, sand, oil dry or other absorbent material. Dispose of in an
for containment and approved container.
cleaning up

Additional advice : Never return spills in original containers for re-use. Dispose of in accordance with
local regulations.

7. HANDLING AND STORAGE

Handling

Technical : Wash hands before breaks and immediately after handling the product. Remove
measures/Precautions and wash contaminated clothing before re-use.

Precautions for safe : Keep away from heat and sources of ignition.
handling

Storage

Suitable storage : Do not contaminate water, other pesticides, fertilizer, food or feed in storage.
conditions Store in original container. Keep tightly closed in a dry, cool and well-ventilated
place. Keep out of the reach of children.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

No occupational exposure limit values are applicable.

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Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

Engineering measures : Use only with adequate ventilation.

Biological occupational : No information available.

exposure limits

Personal protective equipment

Respiratory protection : Where there is potential for airborne exposures in excess of applicable limits, wear
approved respiratory protection with dust/mist cartridge. Provide adequate
ventilation.

Hand protection : Material: Protective gloves

Eye protection : Wear protective eyewear to prevent contact with this substance.

Skin protection : Wear protective clothing such as gloves, apron, boots, or coveralls, as
appropriate.

Hygiene measures : Wash hands thoroughly with soap and water after handling and before eating,
drinking, chewing gum, using tobacco, or using the toilet. Remove clothing/PPE
immediately if material gets inside. Wash thoroughly and put on clean clothing.
Remove personal protective equipment immediately after handling this product.
Wash the outside of gloves before removing. As soon as possible, wash
thoroughly and change into clean clothing.

Protective measures : All chemical protective clothing should be visually inspected prior to use. Clothing
and gloves should be replaced in case of chemical or physical damage or if
contaminated. End users of this product should follow label instructions for
personal protection when using this product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance (Physical state, form, colour, etc.)

Physical state : liquid
Form : liquid
Colour : No information available.

Odour : No information available.

Odour Threshold : No information available.

pH : No information available.

Melting point/freezing point

No information available.

Initial boiling point and boiling range

No information available.

Flash point : No information available.

Evaporation rate : No information available.

Flammability (solid, gas) : No information available.

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Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

Upper/lower flammability or explosive limits

Upper explosion limit : No information available.
Lower explosion limit : No information available.

Vapour pressure : No information available.

Vapour density : No information available.

Density
No information available.

Solubility(ies)
Water solubility : No information available.

Partition coefficient: n- : No information available.

octanol/water

Auto-ignition temperature
No information available.

Decomposition : No information available.

temperature

Viscosity
Viscosity, kinematic : No information available.

Molecular weight : No information available.

10. STABILITY AND REACTIVITY

Reactivity : No information available.

Chemical stability : Stable at normal temperatures and storage conditions.

Possibility of hazardous : No information available.

reactions

Conditions to avoid : None reasonably foreseeable.

Materials to avoid : No information available.

Hazardous : No information available.

decomposition products

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Oral
Tricyclazole : LD50/Rat: 314 mg/kg
Picoxystrobin : LD50/Rat: 5,000 mg/kg
Single Dose/Rat
Effects occurred at levels of exposure that significantly exceed those
expected under labeled usage conditions.
Neurobehavioral parameter effects

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Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

Motor Activity effects

Effects reversed the day following treatment
Inhalation
Tricyclazole : LC50/Rat: 0.146 mg/l
Picoxystrobin : LC50/4 h/Rat male(dust/mist): 2.12 mg/l
Material particle size of 5.9 - 6.8 µm MMAD
LC50/4 h/Rat female(dust/mist): 3.19 mg/l
Material particle size of 5.9 - 6.8 µm MMAD
Dermal
Tricyclazole : LD50/Rabbit: > 2,000 mg/kg
Picoxystrobin : LD50/Rat: > 5,000 mg/kg

Skin corrosion/irritation
Picoxystrobin : Species: Rabbit
Result: No skin irritation
Classification: No skin irritation

Serious eye damage/eye irritation

Tricyclazole : Result: Severe eye irritation
Picoxystrobin : Species: Rabbit
Result: Irritation to eyes, reversing within 7 days
Classification: Mild eye irritation

Respiratory or skin sensitisation

Tricyclazole : Classification: Not a skin sensitizer.
Picoxystrobin : Maximisation Test
Species: Guinea pig
Result: Does not cause skin sensitisation.
Classification: Does not cause skin sensitisation.

Germ cell mutagenicity

Picoxystrobin : Weight of evidence does not support classification as a germ cell
mutagen.

Carcinogenicity
Picoxystrobin : Not classifiable as a human carcinogen.
Overall weight of evidence indicates that the substance is not
carcinogenic.

Reproductive toxicity
Tricyclazole : Reproductive toxicity: No adverse effects expected.Teratogenicity: No
adverse effects expected.
Picoxystrobin : Reproductive toxicity: No toxicity to reproduction
Teratogenicity: Animal testing showed no developmental toxicity.

Specific Target Organ Toxicity

Specific target organ toxicity - single exposure
Picoxystrobin : The substance or mixture is not classified as specific target organ
toxicant, single exposure.
Specific target organ toxicity - repeated exposure

Picoxystrobin : The substance or mixture is not classified as specific target organ

toxicant, repeated exposure.

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Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

Aspiration hazard
Picoxystrobin : No aspiration toxicity classification

Other
Picoxystrobin : Repeated dose toxicity:
The following effects occurred at levels of exposure that significantly
exceed those expected under labeled usage conditions.
Oral - feed/Mouse 28 d
No toxicologically significant effects were found.
Dermal/Rat 28 d
No toxicologically significant effects were found.
Oral/Mouse 90 d
Reduced body weight gain, Increased liver weight
Oral - feed/Rat 90 d
Reduced body weight gain, Increased liver weight, No effect to
neurotoxicity.
Oral/Dog 1 yr
Reduced body weight gain
Oral/Mouse 18 Months
Reduced body weight gain, Increased liver weight, Gastrointestinal effects

12. ECOLOGICAL INFORMATION

Ecotoxicity effects
Acute and prolonged toxicity to fish
Tricyclazole : LC50/96 h/Lepomis macrochirus (Bluegill sunfish): 16.0 mg/l
LC50/96 h/Oncorhynchus mykiss (rainbow trout): 7.3 mg/l
Picoxystrobin : LC50/96 h/Fathead minnow: 0.066 mg/l

Toxicity to aquatic plants

Picoxystrobin : ErC50/96 h/Skeletonema costatum (Diatom): 0.0063 mg/l

Acute toxicity to aquatic invertebrates

Picoxystrobin : EC50/48 h/Daphnia magna (Water flea): 0.024 mg/l

Chronic toxicity to aquatic Invertebrates

Picoxystrobin : NOEC/21 d/Daphnia magna (Water flea): 0.008 mg/l

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Mobility in soil
No information available.

Other adverse effects

No information available.

13. DISPOSAL CONSIDERATIONS

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Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

Waste disposal methods : In accordance with local and national regulations. The product should not be
allowed to enter drains, water courses or the soil.

Contaminated packaging : Do not re-use empty containers.

14. TRANSPORT INFORMATION

IMDG
UN number : 3082
UN proper shipping : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
name
(Picoxystrobin)
Transport hazard class : 9
Packing group : III
Hazchem Code : .3Z
Marine pollutant : yes (Picoxystrobin)

IATA
UN number : 3082
UN proper shipping : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
name
(Picoxystrobin)
Transport hazard class : 9
Packing group : III

Special precaution which a : Not applicable

user to be aware of or
needs to comply with in
connection with transport
or conveyance either within
or outside their premises

15. REGULATORY INFORMATION

Product subject to regulatory requirements under the Insecticides Act, 1968 and Insecticides Rules, 1971

16. OTHER INFORMATION

Sources of key data used to compile the Safety Data Sheet

1. The Factories Act, 1948, The Second Schedule: Permissible levels of certain chemical substances in work
environment, as amended through April, 2001
2. Manufacture, Storage and Import of Hazardous Chemical Rules 1989, as amended through January 2000

References
SDS Number: 130000099870

Revision Date/Version
Date of first preparation : 29.09.2010
Revision Date : 06.05.2016
Version : 2.1

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SAFETY DATA SHEET

Picoxystrobin + Tricyclazole
Version 2.1
Revision Date 06.05.2016 Document no. 130000099870

Take notice of the directions of use on the label.

®
Registered trademark of E.I. du Pont de Nemours and Company

Significant change from previous version is denoted with a double bar.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guide for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
above information relates only to the specific material(s) designated herein and may not be valid for such
material(s) used in combination with any other materials or in any process or if the material is altered or processed,
unless specified in the text.

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